CN102428949A - Pesticide composition containing cycloxaprid and anabasines - Google Patents
Pesticide composition containing cycloxaprid and anabasines Download PDFInfo
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- CN102428949A CN102428949A CN2011104546745A CN201110454674A CN102428949A CN 102428949 A CN102428949 A CN 102428949A CN 2011104546745 A CN2011104546745 A CN 2011104546745A CN 201110454674 A CN201110454674 A CN 201110454674A CN 102428949 A CN102428949 A CN 102428949A
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Abstract
The invention discloses a pesticide composition containing cycloxaprid and anabasines. The composition is mainly characterized by containing an active ingredient A, an active ingredient B and the balance of auxiliaries, wherein the active ingredient A is cycloxaprid; the active ingredient B is any one of imidacloprid, acetamiprid, nitenpyram, thiamethoxam, thiacloprid, clothianidin and dinotefuran; and the weight ratio of the active ingredient A to the active ingredient B is (60:1)-(1:60). The composition can be prepared into wettable powder, water dispersible granules, emulsifiable solution, suspensions, suspoemulsion, emulsion in water, microemulsion, microcapsule suspensions and microcapsule-microcapsule suspensions. The composition can be used for controlling various diseases, has obvious synergistic effect, expands the pesticidal spectrum, has higher activity against the pests on rice, wheat, cruciferous vegetables, tea trees, cotton and fruit trees, has slow release effect, reduces the pesticide application quantity, is harmless to people and livestock, has no phytotoxicity and has good environmental compatibility. The preparations have the advantages of enhanced adhesive forces, rain wash resistance, long duration of efficacy and the like.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of Pesticidal combination that contains pyridine of epoxy worm and anabasine.
Background technology
Epoxy worm pyridine (cycloxaprid) is a kind of novel anabasine insecticide.Chemical name: 9-(6-chloropyridine-3-yl) methyl)-4-nitro-8-oxa--10, the 11-glyoxalidine also (2,3-a) dicyclo (3,2,1) suffering-3-alkene, chemical molecular formula: C
14H
15Cl N
4O
3Insect there are interior suction, stomach toxicity and action of contace poison, can be used for preventing and treating Homoptera, coleopteran pest on the crops, with no cross resistances such as Imidacloprid, Acetamiprid, the pyridines of epoxy worm, also effective to lepidoptera pest.These article using dosage is low, and is environmentally safe, and beneficial organism is not had harm or endangers minimum.The pyridine of epoxy worm is the antagonist of first nAChR in the world; Very likely become the new class insecticide that has material impact power in the world, its activity significantly is superior to Imidacloprid, and project has been accomplished 2 kinds of formulations, the 14 ground tests of pesticide effectiveness at present; The result shows: all efficient to paddy rice brown planthopper, white-backed planthopper, small brown rice planthopper; Cabbage aphid and cucumber aphid also there are good preventive effect, rice leaf roller is had the anti-effect of holding concurrently preferably, cotton field Bemisia tabaci activity is significantly higher than Imidacloprid.
The mechanism of action of anabasine insecticide is different from other insecticide, mainly is through Selective Control insect nervous system nicotinic acetylcholine esterase acceptor, the normal conduction of blocking-up insect central nervous system, thus cause insect paralysis and then dead to occur.
Yet in the real process of agricultural production, the problem that pest control is easy to generate most is the generation of pest resistance to insecticide.The different cultivars composition carries out composite, is the very common method of control resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals all is an additive effect, and the seldom composite of synergistic effect really arranged, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Test discovery in a large number through the inventor, after pyridine of epoxy worm and Imidacloprid, Acetamiprid, Nitenpyram, thiophene worm piperazine, thiophene worm quinoline, thiophene worm amine, MTI-446 were composite, synergistic effect was remarkable, and Environmental compatibility is fabulous, has greatly reduced the agricultural chemicals dosage.
Summary of the invention
The Pesticidal combination that the present invention proposes contains in the pyridine of epoxy worm and Imidacloprid, Acetamiprid, Nitenpyram, thiophene worm piperazine, thiophene worm quinoline, thiophene worm amine, the MTI-446 any one two kinds of active components, and an amount of surfactant and carrier.
A kind of Pesticidal combination that contains pyridine of epoxy worm and anabasine comprises active components A, active component B, the auxiliary agent surplus.It is characterized in that: active components A is the pyridine of epoxy worm, and active component B is a kind of arbitrarily in Imidacloprid, Acetamiprid, Nitenpyram, thiophene worm piperazine, thiophene worm quinoline, thiophene worm amine, the MTI-446, and the weight ratio of active components A and active component B is 60: 1～1: 60.
The described Pesticidal combination that contains pyridine of epoxy worm and anabasine is characterized in that: the weight ratio of active components A and active component B is 40: 1～1: 40.
The described Pesticidal combination that contains pyridine of epoxy worm and anabasine is characterized in that: the weight ratio of active components A and active component B is 20: 1～1: 20.
The described Pesticidal combination that contains pyridine of epoxy worm and anabasine is characterized in that: composition is processed wetting powder, water dispersible granules, missible oil, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, micro-capsule-microcapsule suspending agent.
The described Pesticidal combination that contains pyridine of epoxy worm and anabasine is used to prevent and treat the application of insect on paddy rice, wheat, brassicaceous vegetable, tea tree, cotton, the fruit tree.
Described application, pest control comprises: rice fulgorid, aphid, leafhopper, trialeurodes vaporariorum, small brown rice planthopper, diamond-back moth, dive fly, Grapholita spp, cotten aphid, tea lesser leafhopper, scale insect.
At least contain a kind of surfactant in the Pesticidal combination of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 5%～30% of a total formulation weight amount, and surplus is solid or liquid diluent.The surfactant that Pesticidal combination of the present invention is selected for use is known in those skilled in the art: can be selected from dispersant, wetting agent, emulsifier or the antifoaming agent one or more.
The said Pesticidal combination that contains pyridine of epoxy worm and anabasine is characterized in that: comprise following constituent content when processing wetting powder: active components A 0.1%～60%, active component B0.1%～60%, dispersant 5%～10%, wetting agent 2%～10%, filler 8%～92.8%.
Active components A, active component B, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, promptly can be made into epoxy worm pyridine imidacloprid wettable powder product.
The said Pesticidal combination that contains pyridine of epoxy worm and anabasine is characterized in that: comprise following constituent content when composition is processed water dispersible granules: active components A 0.1%～60%, active component B 0.1%～60%, dispersant 3%～12%, wetting agent 1%～8%, disintegrant 1%～10%, filler 10%～94.8%.
Active components A, active component B, dispersant, wetting agent, disintegrant, filler etc. are obtained the particle diameter that needs through comminution by gas stream together, obtain the materials of granulating.It is interior through after granulation and the drying to expect that article are quantitatively sent the fluidized bed granulation dryer to, makes epoxy worm pyridine imidacloprid water dispersible granule product.
The said Pesticidal combination that contains pyridine of epoxy worm and anabasine; It is characterized in that: comprise following constituent content when composition is processed suspending agent: active components A 0.1%～50%, active component B 0.1%～50%, dispersant 2～10%, wetting agent 2～10%, antifoaming agent 0.1～1%, thickener 0.1～2%, antifreeze 0.1～8%, emulsifier 0.5%～5%, water adds to 100%.
Dispersant, wetting agent, antifoaming agent, thickener, antifreeze, emulsifier in the above-mentioned formulation material are mixed through high speed shear; Add the pyridine of epoxy worm, Imidacloprid ball milling 2～3 hours in ball mill; Make diameter of particle all below 5 μ m, make suspending agent product of the present invention.
The said Pesticidal combination that contains pyridine of epoxy worm and anabasine; It is characterized in that: comprise following constituent content when composition is processed suspension emulsion: active components A 0.1%～50%, active component B 0.1%～50%, emulsifier 2%～12%, dispersant 2%～10%, antifoaming agent 0.1%～2%, thickener 0.1%～2%, antifreeze 0.1%～8%, stabilizing agent 0.05%～3%, deionized water add to 100%.
Dispersant, antifoaming agent, thickener, antifreeze, stabilizing agent in the above-mentioned formulation material are mixed through high speed shear; Add the former medicine of epoxy worm pyridine; Ball milling is 2～3 hours in ball mill, makes diameter of particle all below 5 μ m, makes epoxy worm pyridine suspending agent; Then with the former medicine of active component B, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make suspension emulsion product of the present invention.
Comprise following constituent content when composition is processed aqueous emulsion: active components A 0.1%～50%, active component B 0.1%～50%, solvent 0%～30%, emulsifier 1%～15%, co-emulsifier 0%～8%, antifreeze 0%～10%, thickener 0.1%～2%, antifoaming agent 0.01%～2%, deionized water are supplied surplus.
Above-mentioned prescription is mixed, active ingredient, solvent, emulsifier, co-emulsifier are added together, make and be dissolved into even oil phase; Water, antifreeze, thickener, antifoaming agent are mixed, become the homogeneous water.Under high-speed stirred, water is added oil phase, make aqueous emulsion product of the present invention.
Comprise following constituent content when composition is processed microemulsion: active components A 0.1%～50%, active component B 0.1%～50%, solvent 0%～30%, emulsifier 3%～20%, co-emulsifier 0%～12%, antifreeze 0%～10%, thickener 0.1%～2%, antifoaming agent 0.01%～2%, stabilizing agent 0%～4%, deionized water is supplied surplus.
Pyridine of epoxy worm and the former medicine of active component B are dissolved in the homogenizer that solvent and cosolvent are housed; Give intense mixing and homogenize after joining emulsifier, stabilizing agent and antifreeze, water in the homogenizer that above-mentioned solution is housed, obtain the as clear as crystal microemulsion product of the present invention of outward appearance at last.
The formulation technology that composition is processed missible oil, microcapsule suspending agent, micro-capsule-microcapsule suspending agent is technical matters conventionally known to one of skill in the art.
Described dispersant is selected from alkylnaphthalene sulfonate; Two (alkyl) naphthalenesulfonate formaldehyde condensation compound; Naphthalene sulfonic acid-formaldehyde condensation product; Aryl phenol polyoxyethylene succinate sulfonate; Octylphenol polyethylene oxyethylene group ether sulfate; Polycarboxylate; Lignosulfonates; The phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy; Alkyl benzene sulfonate calcium salt; The naphthalene sulfonic acid-formaldehyde condensation product sodium salt; Alkylphenol-polyethenoxy is phonetic; Aliphatic amine polyoxyethylene is phonetic; Polyoxyethylene carboxylate; During the ester polyoxyethylene is phonetic one or more.
Described wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, washing powder, farming breast 2000
#Series, sldium lauryl sulfate, wetting and penetrating agent F, wetting agent T, spaonin powder, tea are withered, in the silkworm excrement, soapberry powder one or more.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, the glucose.
Described emulsifier is selected from: farming breast 500
#(alkyl benzene calcium sulfonate), OP series phosphate (NPE phosphate), 600
#Phosphate (phenyl phenol polyoxy ethyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, farming breast 400
#(benzyl dimethyl phenol polyoxy ethyl ether), farming breast 600
#(phenyl phenol polyoxy ethyl ether), Nongru-700
#(alkylphenol-formaldehyde resin polyoxy ethyl ether), farming breast 36
#(phenethyl fluosite polyoxy ethyl ether), farming breast 1600
#(phenethyl phenol polyoxy ethyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (NPE), By series (castor oil polyoxyethylene ether), farming breast 33
#(alkylaryl polyoxyethylene polyoxypropylene ether), farming breast 34
#In (alkylaryl polyoxyethylene poly-oxygen propylene aether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), the EO series (the pure APEO of fat) one or more.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, the polyethylene glycol.
Described antifoaming agent is selected from: silicone, C
8～10Aliphatic alcohols, C
10～20In saturated fat acids (like capric acid) and acid amides, silicone oil, the silicone compound one or more.
Described thickener is selected from: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, the polyvinyl alcohol.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate, the vegetable oil.
Described macromolecule cyst material: PIC, polyfunctional group acyl halide polyamines, polyfunctional group acyl halide dihydroxylic alcohols.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Missible oil the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension of the present invention-suspending agent the key technical indexes:
The invention has the advantages that:
(1) pyridine of epoxy worm and Imidacloprid, Acetamiprid, Nitenpyram, thiophene worm piperazine, thiophene worm quinoline, thiophene worm amine, MTI-446 composite after, have notable synergistic and lasting effect;
(2) enlarged insecticidal spectrum, the rice fulgorid of paddy rice, wheat, brassicaceous vegetable, tea tree, cotton, fruit tree, aphid, leafhopper, trialeurodes vaporariorum, small brown rice planthopper, diamond-back moth, dive fly, Grapholita spp, cotten aphid, tea lesser leafhopper, scale insect etc. have all been had greater activity;
(3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution;
(4) to the person poultry safety, Environmental compatibility is good, and insect is difficult for developing immunity to drugs.
Embodiment
The present invention is explained further that the percentage among the embodiment is weight ratio below in conjunction with embodiment, but the present invention is not limited thereto.
Application implementation example one
Embodiment 1 40% epoxy worm pyridine imidacloprid wettable powder
Epoxy worm pyridine 35%, Imidacloprid 5%, polyoxyethylene carboxylate 6.2%, wetting and penetrating agent F5.8%, bentonite add to 100%, and mixture carries out comminution by gas stream, make 40% epoxy worm pyridine imidacloprid wettable powder.
Embodiment 2 60.1% epoxy worm pyridine imidacloprid wettable powders
Epoxy worm pyridine 60%, Imidacloprid 0.1%, aliphatic amine polyoxyethylene are phonetic 7.2%, expoxy propane condensation product 4.8%, white carbon 6%, and kaolin adds to 100%, and mixture carries out comminution by gas stream, makes 60.1% epoxy worm pyridine imidacloprid wettable powder.
Embodiment 3 36% epoxy worm pyridine Acetamiprid wetting powders
The phonetic formaldehyde condensation products sulphate of epoxy worm pyridine 3%, Acetamiprid 33%, alkylphenol-polyethenoxy 6.7%, soapberry powder 4.3%, bentonite add to 100%, and mixture carries out comminution by gas stream, makes 36% epoxy worm pyridine Acetamiprid wetting powder.
Embodiment 4 56% epoxy worm pyridine Acetamiprid wetting powders
Epoxy worm pyridine 2%, Acetamiprid 54%, aryl phenol polyoxyethylene succinate sulfonate 6.5%, neopelex 4.5%, spaonin powder 2%, kaolin add to 100%; Mixture carries out comminution by gas stream, makes 56% epoxy worm pyridine Acetamiprid wetting powder.
Embodiment 5 50% epoxy worm pyridine Nitenpyram wetting powders
Epoxy worm pyridine 10%, Nitenpyram 40%, aliphatic amine polyoxyethylene are phonetic 6.5%, soapberry powder 5.5%, white carbon 7%, and kaolin adds to 100%, and mixture carries out comminution by gas stream, makes 50% epoxy worm pyridine Nitenpyram wetting powder.
Embodiment 6 60.1% epoxy worm pyridine Nitenpyram wetting powders
Epoxy worm pyridine 0.1%, Nitenpyram 60%, ester polyoxyethylene are phonetic 7.2%, silkworm excrement 4.8%, bentonite add to 100%, and mixture carries out comminution by gas stream, makes 60.1% epoxy worm pyridine Nitenpyram wetting powder.
Embodiment 7 40% epoxy worm pyridine thiophene worm piperazine wetting powders
Epoxy worm pyridine 30%, thiophene worm piperazine 10%, polyoxyethylene carboxylate 6.2%, wetting and penetrating agent F 5.8%, bentonite add to 100%, and mixture carries out comminution by gas stream, make 40% epoxy worm pyridine thiophene worm piperazine wetting powder.
Embodiment 8 61% epoxy worm pyridine thiophene worm piperazine wetting powders
Epoxy worm pyridine 1%, thiophene worm piperazine 60%, aliphatic amine polyoxyethylene are phonetic 5.5%, expoxy propane condensation product 4.5%, white carbon 8%, and kaolin adds to 100%, and mixture carries out comminution by gas stream, makes 61% epoxy worm pyridine thiophene worm piperazine wetting powder.
Embodiment 9 45% epoxy worm pyridine thiophene worm quinoline wetting powders
Epoxy worm pyridine 5%, thiophene worm quinoline 40%, aryl phenol polyoxyethylene succinate sulfonate 5.5%, neopelex 3.5%, spaonin powder 2%, kaolin add to 100%; Mixture carries out comminution by gas stream, makes 45% epoxy worm pyridine thiophene worm quinoline wetting powder.
Embodiment 10 60% epoxy worm pyridine thiophene worm quinoline wetting powders
The phonetic formaldehyde condensation products sulphate of epoxy worm pyridine 5%, thiophene worm quinoline 55%, alkylphenol-polyethenoxy 6.5%, soapberry powder 5.5%, bentonite add to 100%, and mixture carries out comminution by gas stream, makes 60% epoxy worm pyridine thiophene worm quinoline wetting powder.
Embodiment 11 48% epoxy worm pyridine thiophene worm amine wetting powders
Epoxy worm pyridine 2%, thiophene worm amine 46%, aliphatic amine polyoxyethylene are phonetic 5.5%, soapberry powder 7%, white carbon 6.5%, and kaolin adds to 100%, and mixture carries out comminution by gas stream, makes 48% epoxy worm pyridine thiophene worm amine wetting powder.
Embodiment 12 58% epoxy worm pyridine thiophene worm amine wetting powders
Epoxy worm pyridine 12%, thiophene worm amine 46%, ester polyoxyethylene are phonetic 7.5%, silkworm excrement 4.5%, bentonite add to 100%, and mixture carries out comminution by gas stream, makes 58% epoxy worm pyridine thiophene worm amine wetting powder.
Embodiment 13 36% epoxy worm pyridine MTI-446 wetting powders
Epoxy worm pyridine 6%, MTI-446 30%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 6.5%, tea are withered 5.5%, bentonite adds to 100%, and mixture carries out comminution by gas stream, makes 36% epoxy worm pyridine MTI-446 wetting powder.
Embodiment 14 56% epoxy worm pyridine MTI-446 wetting powders
Epoxy worm pyridine 7%, MTI-446 49%, octylphenol polyethylene oxyethylene group ether sulfate 6.5%, Nekal BX 4.5%, spaonin powder 2%, kaolin add to 100%, and mixture carries out comminution by gas stream, make 56% epoxy worm pyridine MTI-446 wetting powder.
Embodiment 15 40% epoxy worm pyridine imidacloprid water dispersible granules
Epoxy worm pyridine 32%, Imidacloprid 8%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 6.5%, expoxy propane condensation product 4.5%, kaolin add to 100%, the mixed 40% epoxy worm pyridine imidacloprid water dispersible granule that gets.
Embodiment 16 65% epoxy worm pyridine imidacloprid water dispersible granules
Epoxy worm pyridine 60%, Imidacloprid 5%, wetting agent T6.5%, naphthalene sulfonic acid-formaldehyde condensation product 6.5%, polyvinylpyrrolidone 3.5%, white carbon 5.5%, bentonite add to 100%, the mixed 65% epoxy worm pyridine imidacloprid water dispersible granule that gets.
Embodiment 17 36% epoxy worm pyridine acetamiprid water dispersible granules
Epoxy worm pyridine 34%, Acetamiprid 2%, polyoxyethylene carboxylate 7.5%, soapberry powder 5.5%, aluminium chloride 3.5%, kaolin add to 100%, the mixed 36% epoxy worm pyridine acetamiprid water dispersible granules that gets.
Embodiment 18 60% epoxy worm pyridine acetamiprid water dispersible granules
Epoxy worm pyridine 40%, Acetamiprid 20%, polycarboxylate 6.5%, wetting and penetrating agent F 3.5%, sodium bicarbonate 2.5%, gum Arabic 2.5%, bentonite add to 100%, the mixed 60% epoxy worm pyridine acetamiprid water dispersible granules that gets.
Embodiment 19 42% epoxy worm pyridine Nitenpyram water dispersible granules
Epoxy worm pyridine 36%, Nitenpyram 6%, wetting agent T6.5%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 5.5%, polyvinylpyrrolidone 3.5%, white carbon 5.5%, bentonite add to 100%, the mixed 42% epoxy worm pyridine Nitenpyram water dispersible granules that gets.
Embodiment 20 61% epoxy worm pyridine Nitenpyram water dispersible granules
Epoxy worm pyridine 60%, Nitenpyram 1%, octylphenol polyethylene oxyethylene group ether sulfate 5.5%, Nekal BX 4.5%, sodium bicarbonate 4.5%, white dextrin 2.5%, bentonite add to 100%, the mixed 61% epoxy worm pyridine Nitenpyram water dispersible granules that gets.
Embodiment 21 49% epoxy worm pyridine thiophene worm piperazine water dispersible granules
Epoxy worm pyridine 14%, thiophene worm piperazine 35%, wetting agent T6%, naphthalene sulfonic acid-formaldehyde condensation product 6.5%, polyvinylpyrrolidone 4.5%, white carbon 5.5%, bentonite add to 100%, the mixed 49% epoxy worm pyridine thiophene worm piperazine water dispersible granules that gets.
Embodiment 22 55% epoxy worm pyridine thiophene worm piperazine water dispersible granules
Epoxy worm pyridine 5%, thiophene worm piperazine 50%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 6.5%, expoxy propane condensation product 4.5%, kaolin add to 100%, the mixed 55% epoxy worm pyridine thiophene worm piperazine water dispersible granules that gets.
Embodiment 23 45% epoxy worm pyridine thiophene worm quinoline water dispersible granules
Epoxy worm pyridine 35%, thiophene worm quinoline 10%, polycarboxylate 6.5%, wetting and penetrating agent F 4.5%, sodium bicarbonate 4.5%, gum Arabic 2%, bentonite add to 100%, the mixed 45% epoxy worm pyridine thiophene worm quinoline water dispersible granules that gets.
Embodiment 24 62% epoxy worm pyridine thiophene worm quinoline water dispersible granules
Epoxy worm pyridine 54%, thiophene worm quinoline 8%, polyoxyethylene carboxylate 6.5%, soapberry powder 5.5%, aluminium chloride 2.5%, kaolin add to 100%, the mixed 62% epoxy worm pyridine thiophene worm quinoline water dispersible granules that gets.
Embodiment 25 45% epoxy worm pyridine thiophene worm amine water dispersible granules
Epoxy worm pyridine 15%, thiophene worm amine 30%, octylphenol polyethylene oxyethylene group ether sulfate 5.5%, Nekal BX 3.5%, sodium bicarbonate 3.5%, white dextrin 2%, bentonite add to 100%, the mixed 45% epoxy worm pyridine thiophene worm amine water dispersible granules that gets.
Embodiment 26 65% epoxy worm pyridine thiophene worm amine water dispersible granules
Epoxy worm pyridine 10%, thiophene worm amine 55%, wetting agent T7.5%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 4.5%, polyvinylpyrrolidone 3.5%, white carbon 5%, bentonite add to 100%, the mixed 65% epoxy worm pyridine thiophene worm amine water dispersible granules that gets.
Embodiment 27 40% epoxy worm pyridine MTI-446 water dispersible granules
Epoxy worm pyridine 32%, MTI-446 8%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 6.5%, expoxy propane condensation product 4.5%, bentonite add to 100%, the mixed 40% epoxy worm pyridine MTI-446 water dispersible granules that gets.
Embodiment 28 56% epoxy worm pyridine MTI-446 water dispersible granules
Epoxy worm pyridine 50%, MTI-446 6%, wetting agent T6.5%, alkylphenol-polyethenoxy are phonetic 6.5%, sodium alginate 3.5%, white carbon 5.5%, bentonite add to 100%, mixed 56% epoxy worm pyridine MTI-446 water dispersible granules.
Embodiment 29 24% epoxy worm pyridine imidacloprid suspending agents
Epoxy worm pyridine 16%, Imidacloprid 8%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6.5%, amide-type antifoaming agent 4.5%, aluminium-magnesium silicate 3.5%, OP series 6.5%, deionized water add to 100%, the mixed 24% epoxy worm pyridine imidacloprid suspending agent that gets.
Embodiment 30 42% epoxy worm pyridine imidacloprid suspending agents
Epoxy worm pyridine 35%, Imidacloprid 7%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6.5%, wetting agent T 5.5%, C
8～10Aliphatic alcohols 3.5%, polyvinyl alcohol 3.5%, deionized water add to 100%, the mixed 42% epoxy worm pyridine imidacloprid suspending agent that gets.
Embodiment 31 32% epoxy worm pyridine acetamiprid suspending agents
Epoxy worm pyridine 30%, Acetamiprid 2%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 8.5%, spaonin powder 2.5%, PAA 5.5%, silicone oil 1.5%, deionized water add to 100%, the mixed 32% epoxy worm pyridine acetamiprid suspending agent that gets.
Embodiment 32 40% epoxy worm pyridine acetamiprid suspending agents
The phonetic formaldehyde condensation products sulphate of epoxy worm pyridine 36%, Acetamiprid 4%, polycarboxylate 5.5%, alkylphenol-polyethenoxy 4.5%, silicone antifoaming agent 2.5%, aluminium-magnesium silicate 1.5%, phenyl phenol polyoxy ethyl ether phosphate 5.5%, deionized water add to 100%, mixed 40% epoxy worm pyridine acetamiprid suspending agent.
Embodiment 33 24% epoxy worm pyridine Nitenpyram suspending agents
Epoxy worm pyridine 12%, Nitenpyram 12%, polyoxyethylene carboxylate 8.5%, silicone antifoaming agent 2.5%, aluminium-magnesium silicate 3.5%, OP series 6.5%, deionized water add to 100%, the mixed 24% epoxy worm pyridine Nitenpyram suspending agent that gets.
Embodiment 34 39% epoxy worm pyridine Nitenpyram suspending agents
Epoxy worm pyridine 3%, Nitenpyram 36%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8.5%, soapberry powder 2.5%, PAA 5.5%, silicone oil 1.5%, deionized water add to 100%, the mixed 39% epoxy worm pyridine Nitenpyram suspending agent that gets.
Embodiment 35 24% epoxy worm pyridine thiophene worm piperazine suspending agents
Epoxy worm pyridine 16%, thiophene worm piperazine 8%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6.5%, amide-type antifoaming agent 4.5%, aluminium-magnesium silicate 3.5%, OP series 6%, deionized water add to 100%, the mixed 24% epoxy worm pyridine thiophene worm piperazine suspending agent that gets.
Embodiment 36 42% epoxy worm pyridine thiophene worm piperazine suspending agents
Epoxy worm pyridine 7%, thiophene worm piperazine 35%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6.5%, wetting agent T 5.5%, C
8～10Aliphatic alcohols 3.5%, polyvinyl alcohol 3.5%, deionized water add to 100%, the mixed 42% epoxy worm pyridine thiophene worm piperazine suspending agent that gets.
Embodiment 37 40% epoxy worm pyridine thiophene worm quinoline suspending agents
The phonetic formaldehyde condensation products sulphate of epoxy worm pyridine 4%, thiophene worm quinoline 36%, polycarboxylate 5.5%, alkylphenol-polyethenoxy 4.5%, silicone antifoaming agent 1.5%, aluminium-magnesium silicate 1.5%, phenyl phenol polyoxy ethyl ether phosphate 5%, deionized water add to 100%, mixed 40% epoxy worm pyridine thiophene worm quinoline suspending agent.
Embodiment 38 48% epoxy worm pyridine thiophene worm quinoline suspending agents
Epoxy worm pyridine 12%, thiophene worm quinoline 36%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 8.5%, spaonin powder 2.5%, PAA 5.5%, silicone oil 1.5%, deionized water add to 100%, the mixed 48% epoxy worm pyridine thiophene worm quinoline suspending agent that gets.
Embodiment 39 24% epoxy worm pyridine thiophene worm amine suspending agents
Epoxy worm pyridine 12%, thiophene worm amine 12%, polyoxyethylene carboxylate 6.5%, silicone antifoaming agent 4.5%, aluminium-magnesium silicate 3.5%, OP series 6.5%, deionized water add to 100%, the mixed 24% epoxy worm pyridine thiophene worm amine suspending agent that gets.
Embodiment 40 36% epoxy worm pyridine thiophene worm amine suspending agents
Epoxy worm pyridine 9%, thiophene worm amine 27%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7.5%, soapberry powder 3.5%, PAA 5.5%, silicone oil 1.5%, deionized water add to 100%, the mixed 36% epoxy worm pyridine thiophene worm amine suspending agent that gets.
Embodiment 41 24% epoxy worm pyridine MTI-446 suspending agents
Epoxy worm pyridine 8%, MTI-446 16%, polyoxyethylene carboxylate 6.5%, C
8～10Aliphatic alcohols 4.5%, aluminium-magnesium silicate 3.5%, agricultural newborn 1600#6.5%, deionized water add to 100%, the mixed 24% epoxy worm pyridine MTI-446 suspending agent that gets.
Embodiment 42 32% epoxy worm pyridine MTI-446 suspending agents
Epoxy worm pyridine 8%, MTI-446 24%, ester polyoxyethylene are phonetic 6.5%, lauryl sodium sulfate 5.5%, silicone 2.5%, methylcellulose 2.5%, deionized water add to 100%, mixed 32% epoxy worm pyridine MTI-446 suspending agent.
Embodiment 43 20% epoxy worm pyridine Imidacloprid suspension emulsions
Epoxy worm pyridine 19.5%, Imidacloprid 0.5%, lignosulfonates 5.5%, Nekal BX 5.5%, 600# phosphate 5.5%, PVPP 3.5%, glycerine 2.5%, deionized water add to 100%, the mixed 20% epoxy worm pyridine Imidacloprid suspension emulsion that gets.
Embodiment 44 27% epoxy worm pyridine Imidacloprid suspension emulsions
Epoxy worm pyridine 24%, Imidacloprid 3%, ester polyoxyethylene are phonetic 6.5%, spaonin powder 4.5%, sodium alginate 2.5%, Nongru-700 #5%, triethylene glycol 3.5%, silicone oil 1.5%, deionized water add to 100%, through mixed 27% epoxy worm pyridine Imidacloprid suspension emulsion.
Embodiment 45 22% epoxy worm pyridine Acetamiprid suspension emulsions
Epoxy worm pyridine 20%, Acetamiprid 2%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 7.5%, tea are withered 6.5%, polyvinylpyrrolidone 1.5%, agricultural newborn 36#6.5%, glycerine 2.5%, silicone 1.5%, deionized water add to 100%, through mixed 22% epoxy worm pyridine Acetamiprid suspension emulsion.
Embodiment 46 35% epoxy worm pyridine Acetamiprid suspension emulsions
Epoxy worm pyridine 30%, Acetamiprid 5%, triethanolamine salt 5.5%, agricultural newborn 33#6.5%, silicone compound 3.5%, polyethylene glycol 2.5%, propane diols 2.5%, deionized water add to 100%, the mixed 35% epoxy worm pyridine Acetamiprid suspension emulsion that gets.
Embodiment 47 25% epoxy worm pyridine Nitenpyram suspension emulsions
Epoxy worm pyridine 5%, Nitenpyram 20%, lignosulfonates 5.5%, Nekal BX 4.5%, agricultural newborn 1600#5.5%, carboxymethyl cellulose 3.5%, glycerine 2.5%, deionized water add to 100%, the mixed 25% epoxy worm pyridine Nitenpyram suspension emulsion that gets.
Embodiment 48 45% epoxy worm pyridine Nitenpyram suspension emulsions
Epoxy worm pyridine 30%, Nitenpyram 15%, ester polyoxyethylene are phonetic 6.5%, spaonin powder 4.5%, polyvinylpyrrolidone 2.5%, agricultural newborn 1600#5.5%, glycerine 3.5%, C
8～10Aliphatic alcohols 1.5%, deionized water add to 100%, through the mixed 45% epoxy worm pyridine Nitenpyram suspension emulsion that gets.
Embodiment 49 20% epoxy worm pyridine thiophene worm piperazine suspension emulsions
Epoxy worm pyridine 14%, thiophene worm piperazine 6%, lignosulfonates 5.5%, Nekal BX 4.5%, 600# phosphate 5.5%, PVPP 3.5%, glycerine 2.5%, deionized water add to 100%, the mixed 20% epoxy worm pyridine thiophene worm piperazine suspension emulsion that gets.
Embodiment 50 40% epoxy worm pyridine thiophene worm piperazine suspension emulsions
Epoxy worm pyridine 10%, thiophene worm piperazine 30%, ester polyoxyethylene are phonetic 6.5%, spaonin powder 4.5%, sodium alginate 2.5%, Nongru-700 #5%, triethylene glycol 3%, silicone oil 1.5%, deionized water add to 100%, through mixed 40% epoxy worm pyridine thiophene worm piperazine suspension emulsion.
Embodiment 51 35% epoxy worm pyridine thiacloprid suspending agents
Epoxy worm pyridine 5%, thiophene worm quinoline 30%, triethanolamine salt 5.5%, agricultural newborn 33#7.5%, silicone compound 3.5%, polyethylene glycol 2.5%, propane diols 2.5%, deionized water add to 100%, the mixed 35% epoxy worm pyridine thiacloprid suspending agent that gets.
Embodiment 52 40% epoxy worm pyridine thiacloprid suspending agents
Epoxy worm pyridine 20%, thiophene worm quinoline 20%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 5.5%, tea are withered 6.5%, polyvinylpyrrolidone 1.5%, agricultural newborn 36#7.5%, glycerine 2.5%, silicone 1.5%, deionized water add to 100%, through mixed 40% epoxy worm pyridine thiacloprid suspending agent.
Embodiment 53 25% epoxy worm pyridine thiophene worm amine suspension emulsions
Epoxy worm pyridine 20%, thiophene worm amine 5%, lignosulfonates 5%, Nekal BX 4.5%, agricultural newborn 1600#5.5%, carboxymethyl cellulose 3.5%, glycerine 2.5%, deionized water add to 100%, the mixed 25% epoxy worm pyridine thiophene worm amine suspension emulsion that gets.
Embodiment 54 45% epoxy worm pyridine thiophene worm amine suspension emulsions
Epoxy worm pyridine 15%, thiophene worm amine 30%, ester polyoxyethylene are phonetic 6.5%, spaonin powder 4.5%, polyvinylpyrrolidone 2.5%, agricultural newborn 1600#5.5%, glycerine 3.5%, C
8～10Aliphatic alcohols 1.2%, deionized water add to 100%, through the mixed 45% epoxy worm pyridine thiophene worm amine suspension emulsion that gets.
Embodiment 55 20% epoxy worm pyridine MTI-446 suspension emulsions
The phonetic formaldehyde condensation products sulphate of epoxy worm pyridine 8%, MTI-446 12%, alkylphenol-polyethenoxy 5.5%, expoxy propane condensation product 5.5%, alkyl biphenyl ether disulfonic acid magnesium salts 5.5%, PAA 3.5%, glycerine 2.5%, deionized water add to 100%, mixed 20% epoxy worm pyridine MTI-446 suspension emulsion.
Embodiment 56 36% epoxy worm pyridine MTI-446 suspension emulsions
Epoxy worm pyridine 12%, MTI-446 24%, polyoxyethylene carboxylate 6.5%, silkworm excrement 4.5%, sodium alginate 2.5%, agricultural newborn 1600#5.2%, triethylene glycol 3.5%, silicone oil 1.2%, deionized water add to 100%, through the mixed 36% epoxy worm pyridine MTI-446 suspension emulsion that gets.
Embodiment 57 63% epoxy worm pyridine Imidacloprid missible oil
Epoxy worm pyridine 36%, Imidacloprid 27%, ethanol 4.5%, OP series 6.5%, polyethylene glycol 5.5%, toluene add to 100%, through the mixed 63% epoxy worm pyridine Imidacloprid missible oil that gets.
Embodiment 58 60% epoxy worm pyridine acetamiprid ECs
Epoxy worm pyridine 35%, Acetamiprid 25%, triethanolamine salt 6.5%, agricultural newborn 33#6.5%, polyethylene glycol 6.5%, propane diols 5.5%, xylol add to 100%, the mixed 60% epoxy worm pyridine acetamiprid EC that gets.
Embodiment 59 75% epoxy worm pyridine Nitenpyram missible oil
Epoxy worm pyridine 60%, Nitenpyram 15%, styrene polyoxyethylene ether ammonium sulfate salt 5.5%, agricultural newborn 600#5.5%, diethylene glycol (DEG) 6.5%, propane diols 5.5%, acetone add to 100%, the mixed 75% epoxy worm pyridine Nitenpyram missible oil that gets.
Embodiment 60 60% epoxy worm pyridine thiophene worm piperazine missible oil
Epoxy worm pyridine 40%, thiophene worm piperazine 20%, triethanolamine salt 6.5%, agricultural newborn 33#6.5%, polyethylene glycol 6.5%, propane diols 5.5%, xylol add to 100%, the mixed 60% epoxy worm pyridine thiophene worm piperazine missible oil that gets.
Embodiment 61 54% epoxy worm pyridine thiophene worm quinoline missible oil
Epoxy worm pyridine 36%, thiophene worm quinoline 18%, triethanolamine salt 6.5%, agricultural newborn 33#6.5%, polyethylene glycol 6.5%, propane diols 5.5%, xylol add to 100%, the mixed 54% epoxy worm pyridine thiophene worm quinoline missible oil that gets.
Embodiment 62 60% epoxy worm pyridine thiophene worm amine missible oil
Epoxy worm pyridine 30%, thiophene worm amine 30%, ethanol 4.5%, OP series 6.5%, polyethylene glycol 5.5%, toluene add to 100%, through the mixed 60% epoxy worm pyridine thiophene worm amine missible oil that gets.
Embodiment 63 52% epoxy worm pyridine MTI-446 missible oil
Epoxy worm pyridine 17%, MTI-446 35%, ethanol 4.5%, tween series 6.5%, white dextrin 5.5%, cyclohexanone add to 100%, through the mixed 52% epoxy worm pyridine MTI-446 missible oil that gets.
Embodiment 64 15% epoxy worm pyridine imidacloprid emulsions
The phonetic formaldehyde condensation products sulphate of epoxy worm pyridine 10%, Imidacloprid 5%, ethylene oxide-propylene oxide block copolymer 5.5%, alkylphenol-polyethenoxy 5.5%, propane diols 3.5%, butyl ether 2.5%; Deionized water supplies 100%, the mixed 15% epoxy worm pyridine imidacloprid emulsion that gets.
Embodiment 65 40% epoxy worm pyridine imidacloprid emulsions
Epoxy worm pyridine 32%, Imidacloprid 8%, sapn series 5.6%, methyl alcohol 5.5%, aliphatic alcohol polyoxyvinethene phosphate 5.5%, propane diols 2.5%, gelatin 1.5%, deionized water supplies 100%, the mixed 40% epoxy worm pyridine imidacloprid emulsion that gets.
Embodiment 66 30% epoxy worm pyridine acetamiprid micro emulsion agent
Epoxy worm pyridine 28%, Acetamiprid 2%, By series 6.5%, ethyl acetate 5.5%, polyethylene glycol 6.5%, C
10～20Saturated fat acids 2.5%, deionized water adds to 100%, through mixed 30% epoxy worm pyridine acetamiprid micro emulsion agent.
Embodiment 67 40% epoxy worm pyridine acetamiprid micro emulsion agent
Epoxy worm pyridine 30%, Acetamiprid 10%, AEO series 6.5%, methyl alcohol 4.5%, aliphatic alcohol polyoxyvinethene phosphate 5.5%, propane diols 2.5%, gelatin 1.5%, deionized water supplies 100%, mixed 40% epoxy worm pyridine acetamiprid micro emulsion agent.
Embodiment 68 20% epoxy worm pyridine Nitenpyram microemulsions
The phonetic formaldehyde condensation products sulphate of epoxy worm pyridine 10%, Nitenpyram 10%, By series 6.5%, alkylphenol-polyethenoxy 5.5%, propane diols 3.5%, butyl ether 2.5%, deionized water supplies 100%, mixed 20% epoxy worm pyridine Nitenpyram microemulsion.
Embodiment 69 38% epoxy worm pyridine Nitenpyram microemulsions
Epoxy worm pyridine 4%, Nitenpyram 34%, ethylene oxide-propylene oxide block copolymer 6.5%, methyl alcohol 4.5%, aliphatic alcohol polyoxyvinethene phosphate 6.5%, propane diols 2.5%, gelatin 1.5%; Deionized water supplies 100%, the mixed 38% epoxy worm pyridine Nitenpyram microemulsion that gets.
Embodiment 70 15% epoxy worm pyridine thiophene worm piperazine microemulsions
The phonetic formaldehyde condensation products sulphate of epoxy worm pyridine 10%, thiophene worm piperazine 5%, ethylene oxide-propylene oxide block copolymer 6.5%, alkylphenol-polyethenoxy 5.5%, propane diols 3.5%, butyl ether 2.5%; Deionized water supplies 100%, the mixed 15% epoxy worm pyridine thiophene worm piperazine microemulsion that gets.
Embodiment 71 35% epoxy worm pyridine thiophene worm piperazine microemulsions
Epoxy worm pyridine 5%, thiophene worm piperazine 30%, sapn series 6.5%, methyl alcohol 5.5%, aliphatic alcohol polyoxyvinethene phosphate 5.5%, propane diols 2.5%, gelatin 1.5%, deionized water supplies 100%, the mixed 35% epoxy worm pyridine thiophene worm piperazine microemulsion that gets.
Embodiment 72 32% epoxy worm pyridine thiophene worm quinoline microemulsions
Epoxy worm pyridine 4%, thiophene worm quinoline 28%, By series 6.5%, ethyl acetate 5.5%, polyethylene glycol 6.5%, C
10～20Saturated fat acids 2.5%, deionized water adds to 100%, through the mixed 32% epoxy worm pyridine thiophene worm quinoline microemulsion that gets.
Embodiment 73 40% epoxy worm pyridine thiophene worm quinoline microemulsions
Epoxy worm pyridine 1%, thiophene worm quinoline 39%, AEO series 5.6%, methyl alcohol 4.5%, aliphatic alcohol polyoxyvinethene phosphate 5.5%, propane diols 2.5%, gelatin 1.5%, deionized water supplies 100%, the mixed 40% epoxy worm pyridine thiophene worm quinoline microemulsion that gets.
Embodiment 74 20% epoxy worm pyridine thiophene worm amine microemulsions
The phonetic formaldehyde condensation products sulphate of epoxy worm pyridine 19%, thiophene worm amine 1%, By series 6.5%, alkylphenol-polyethenoxy 5.5%, propane diols 3.5%, butyl ether 2.5%, deionized water supplies 100%, mixed 20% epoxy worm pyridine thiophene worm amine microemulsion.
Embodiment 75 38% epoxy worm pyridine thiophene worm amine microemulsions
Epoxy worm pyridine 10%, thiophene worm amine 28%, ethylene oxide-propylene oxide block copolymer 5.5%, methyl alcohol 4.5%, aliphatic alcohol polyoxyvinethene phosphate 5.5%, propane diols 2.5%, gelatin 1.5%; Deionized water supplies 100%, the mixed 38% epoxy worm pyridine thiophene worm amine microemulsion that gets.
Embodiment 76 15% epoxy worm pyridine MTI-446 microemulsions
Epoxy worm pyridine 10%, MTI-446 5%, ethylene oxide-propylene oxide block copolymer 5.5%, polyoxyethylene carboxylate 5.5%, propane diols 3.5%, butyl ether 2.5%, deionized water supplies 100%, the mixed 15% epoxy worm pyridine MTI-446 microemulsion that gets.
Embodiment 77 40% epoxy worm pyridine MTI-446 microemulsions
Epoxy worm pyridine 8%, MTI-446 32%, AEO series 5.5%, ethanol 5.5%, aliphatic alcohol polyoxyvinethene phosphate 5.5%, propane diols 2.5%, gelatin 1.5%, deionized water supplies 100%, the mixed 40% epoxy worm pyridine MTI-446 microemulsion that gets.
Embodiment 78 20% epoxy worm pyridine Imidacloprid aqueous emulsions
Epoxy worm pyridine 5%, Imidacloprid 15%, OP series phosphate 6.5%, butanols 5.5%, ethylene glycol 3.5%, silicone compound 2.5%, deionized water adds to 100%, makes 20% epoxy worm pyridine Imidacloprid aqueous emulsion.
Embodiment 79 40% epoxy worm pyridine Imidacloprid aqueous emulsions
Epoxy worm pyridine 36%, Imidacloprid 4%, aryl phenol polyoxyethylene succinate sulfonate 6.5%, agricultural newborn 1600#6.5%, glycerine 2.5%, gum Arabic 2.5%, silicone oil 1.5%; Deionized water supplies 100%, makes 40% epoxy worm pyridine Imidacloprid aqueous emulsion.
Embodiment 80 24% epoxy worm pyridine Acetamiprid aqueous emulsions
The phonetic formaldehyde condensation products sulphate of epoxy worm pyridine 20%, Acetamiprid 4%, alkylphenol-polyethenoxy 6.5%, agricultural newborn 33#5.5%, gelatin 3.5%, glycerine 3.5%, sodium chloride 2.5%, C
10～20Saturated fat acids 1.5%, deionized water supplies 100%, makes 24% epoxy worm pyridine Acetamiprid aqueous emulsion.
Embodiment 81 32% epoxy worm pyridine Acetamiprid aqueous emulsions
Epoxy worm pyridine 31%, Acetamiprid 1%, phenethyl phenol polyethenoxy ether 6.5%, alkylbenzenesulfonate 2.5%, agricultural newborn 36#5.5%, glycerine 3.5%, gum Arabic 2.5%, silicone oil 1.5%; Deionized water supplies 100%, makes 32% epoxy worm pyridine Acetamiprid aqueous emulsion.
Embodiment 82 36% epoxy worm pyridine Nitenpyram aqueous emulsions
Epoxy worm pyridine 6%, Nitenpyram 30%, aryl phenol polyoxyethylene succinate sulfonate 6.5%, OP series 6.5%, glycerine 1.5%, gum Arabic 2.5%, silicone oil 1.5%; Deionized water supplies 100%, makes 36% epoxy worm pyridine Nitenpyram aqueous emulsion.
Embodiment 83 45% epoxy worm pyridine Nitenpyram aqueous emulsions
The phonetic formaldehyde condensation products sulphate of epoxy worm pyridine 40%, Nitenpyram 5%, alkylphenol-polyethenoxy 6.5%, OP series 5.5%, gelatin 3.5%, glycerine 3.5%, sodium chloride 2.5%, C
10～20Saturated fat acids 1.5%, deionized water supplies 100%, makes 45% epoxy worm pyridine Nitenpyram aqueous emulsion.
Embodiment 84 21% epoxy worm pyridine thiophene worm piperazine aqueous emulsions
Epoxy worm pyridine 3%, thiophene worm piperazine 18%, OP series phosphate 6.5%, butanols 5.5%, ethylene glycol 3.5%, silicone compound 2.5%, deionized water adds to 100%, makes 21% epoxy worm pyridine thiophene worm piperazine aqueous emulsion.
Embodiment 85 40% epoxy worm pyridine thiophene worm piperazine aqueous emulsions
Epoxy worm pyridine 4%, thiophene worm piperazine 36%, aryl phenol polyoxyethylene succinate sulfonate 6.5%, agricultural newborn 1600#6.5%, glycerine 1.5%, gum Arabic 2%, silicone oil 1.5%, deionized water supplies 100%, makes 40% epoxy worm pyridine thiophene worm piperazine aqueous emulsion.
Embodiment 86 32% epoxy worm pyridine thiophene worm quinoline aqueous emulsions
Epoxy worm pyridine 31%, thiophene worm quinoline 1%, phenethyl phenol polyethenoxy ether 4.5%, alkylbenzenesulfonate 5.5%, agricultural newborn 36#5.5%, gum Arabic 1.8%, silicone oil 1.2%, deionized water supplies 100%, makes 32% epoxy worm pyridine thiophene worm quinoline aqueous emulsion.
Embodiment 87 45% epoxy worm pyridine thiophene worm quinoline aqueous emulsions
The phonetic formaldehyde condensation products sulphate of epoxy worm pyridine 5%, thiophene worm quinoline 40%, alkylphenol-polyethenoxy 7.5%, agricultural newborn 33#5.5%, gelatin 3.5%, glycerine 2.5%, sodium chloride 1%, C
10～20Saturated fat acids 1%, deionized water supplies 100%, makes 45% epoxy worm pyridine thiophene worm quinoline aqueous emulsion.
Embodiment 88 24% epoxy worm pyridine thiophene worm amine aqueous emulsions
Epoxy worm pyridine 3%, thiophene worm amine 21%, aryl phenol polyoxyethylene succinate sulfonate 6.5%, OP series 7.5%, glycerine 1.8%, gum Arabic 2.5%, silicone oil 1.2%, deionized water supplies 100%, makes 24% epoxy worm pyridine thiophene worm amine aqueous emulsion.
Embodiment 89 45% epoxy worm pyridine thiophene worm amine aqueous emulsions
The phonetic formaldehyde condensation products sulphate of epoxy worm pyridine 1%, thiophene worm amine 44%, alkylphenol-polyethenoxy 6.8%, OP series 6.8%, gelatin 2.5%, glycerine 1.5%, sodium chloride 1.2%, C
10～20Saturated fat acids 1%, deionized water supplies 100%, makes 45% epoxy worm pyridine thiophene worm amine aqueous emulsion.
Embodiment 90 21% epoxy worm pyridine MTI-446 aqueous emulsions
Epoxy worm pyridine 7%, MTI-446 14%, OP series phosphate 6.5%, butanols 5.5%, ethylene glycol 3.5%, silicone compound 2.5%, deionized water adds to 100%, makes 21% epoxy worm pyridine MTI-446 aqueous emulsion.
Embodiment 91 40% epoxy worm pyridine MTI-446 aqueous emulsions
Epoxy worm pyridine 4%, MTI-446 36%, aryl phenol polyoxyethylene succinate sulfonate 6.5%, agricultural newborn 1600#7.5%, glycerine 2.5%, sodium phosphate trimer 2.5%, silicone oil 1.5%; Deionized water supplies 100%, makes 40% epoxy worm pyridine MTI-446 aqueous emulsion.
Embodiment 92 50.1% epoxy worm pyridine active component B microcapsule suspending agents
Epoxy worm pyridine 0.1%, active component B 50%, gamma cyhalothrin 9%, PIC 4%, octylphenol polyethylene oxyethylene group ether sulfate 3.5%, cyclohexanone 2%, ethylene oxide-propylene oxide block copolymer 3%; Deionized water adds to 100% weight portion, makes 50.1% epoxy worm pyridine active component B microcapsule suspending agent.
Embodiment 93 50.1% epoxy worm pyridine active component B micro-capsule-microcapsule suspending agents
The phonetic formaldehyde condensation products sulphate of epoxy worm pyridine 50%, active component B 0.1%, polyfunctional group acyl halide dihydroxylic alcohols 3%, alkylphenol-polyethenoxy 5%, cyclohexanone 3.2%; By series 6%; Deionized water adds to 100% weight portion, makes 50.1% epoxy worm pyridine active component B micro-capsule-microcapsule suspending agent.
The foregoing description 92, embodiment 93 described active component B are a kind of arbitrarily in Imidacloprid, Acetamiprid, Nitenpyram, thiophene worm piperazine, thiophene worm quinoline, thiophene worm amine, the MTI-446, and the weight ratio of pyridine of epoxy worm and active component B is 0.1～50: any ratio between 50～0.1.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Pass through Toxicity Determination earlier, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80≤CTC≤120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field trial again.
Test method: respectively the mother liquor of each mixed agent is diluted to five series concentration during test, places beaker subsequent use respectively.Adopt and to soak the method that connects worm behind the leaf earlier, the blade of the same size that does not contact any medicament is soaked taking-up behind the 5s, dries naturally in the soup that configures, put into insect box; Connect then and supply the examination larva, under 25 ℃ of conditions, raise, every processing repeats for 3 times; Every to repeat used examination borer population be 50, establishes blank simultaneously, checks dead borer population in 72h; Calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50Value.If the contrast lethality then is regarded as invalid test greater than 10%.Computing formula is following:
The insect corrected mortality is converted into probit value (y), and concentration of treatment (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates the value of every kind of medicament thus.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula is (with the pyridine of epoxy worm is the standard medicament, and its toxicity index is 100) as follows:
TI * the P of the theoretical toxicity index (TTI) of M=epoxy worm pyridine
The pyridine of epoxy wormTI * P of+active component B
Active component B
In the formula: M is the mixture of different proportionings;
P
Active component BBe active component B shared ratio in composition;
P
The pyridine of epoxy wormBe epoxy worm pyridine shared ratio in composition.
Annotate: active component B is a kind of arbitrarily in Imidacloprid, Acetamiprid, Nitenpyram, thiophene worm piperazine, thiophene worm quinoline, thiophene worm amine, the MTI-446.
Application implementation example two:
Supply the examination insect: rice fulgorid.
Experimental scheme: effective lethal concentration scope of confirming the pyridine of epoxy worm, the former medicine of Imidacloprid and the two different proportioning mixture through preliminary experiment.
Toxicity test result one
The different proportionings with Imidacloprid of table 1 epoxy worm pyridine are to the toxicity test of rice fulgorid
Can be known that by table 1 proportioning of the composite control of pyridine of epoxy worm and Imidacloprid rice fulgorid was at 60: 1 to 1: 60 o'clock, co-toxicity coefficient is all greater than 120; Explaining that both were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect; Especially when the pyridine of epoxy worm and Imidacloprid got proportioning at 16: 1 to 1: 2, synergistic effect was more obviously outstanding, wherein co-toxicity coefficient maximum when the pyridine of epoxy worm and Imidacloprid weight ratio are 2: 1; Synergistic effect is the most obvious; Find that through the test people pyridine of epoxy worm and Imidacloprid are composite also to have synergistic effect preferably to insects such as control brown planthopper, small brown rice planthopper, Bemisia tabaci, trialeurodes vaporariorums, co-toxicity coefficient is all greater than 150.
Application implementation example three:
Supply the examination insect: diamond-back moth.
Experimental scheme: effective lethal concentration scope of confirming the pyridine of epoxy worm, the former medicine of Acetamiprid and the two different proportioning mixture through preliminary experiment.
Toxicity test result two
The different proportionings with Acetamiprid of table 2 epoxy worm pyridine are to the toxicity test of diamond-back moth
Can be known that by table 2 proportioning of the composite control of pyridine of epoxy worm and Acetamiprid diamond-back moth was at 60: 1 to 1: 60 o'clock, co-toxicity coefficient is all greater than 120; Explaining that both were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect; Especially when the pyridine of epoxy worm and Acetamiprid got proportioning at 16: 1 to 1: 2, synergistic effect was more obviously outstanding, wherein co-toxicity coefficient maximum when the pyridine of epoxy worm and Acetamiprid weight ratio are 2: 1; Synergistic effect is the most obvious; Find that through the test people pyridine of epoxy worm and Acetamiprid are composite also to have synergistic effect preferably to insects such as control cabbage caterpillar, apple leaf miners, co-toxicity coefficient is all greater than 150.
Application implementation example four:
Supply the examination insect: aphid.
Experimental scheme: effective lethal concentration scope of confirming the pyridine of epoxy worm, the former medicine of Nitenpyram and the two different proportioning mixture through preliminary experiment.
Toxicity test result three
The different proportionings with Nitenpyram of table 3 epoxy worm pyridine are to the toxicity test of aphid
Can be known that by table 3 the composite anti-proportioning that eliminates aphis of pyridine of epoxy worm and Nitenpyram was at 60: 1 to 1: 60 o'clock, co-toxicity coefficient is all greater than 120; Explaining that both were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect; Especially when the pyridine of epoxy worm and Nitenpyram got proportioning at 16: 1 to 1: 2, synergistic effect was more obviously outstanding, wherein co-toxicity coefficient maximum when the pyridine of epoxy worm and Nitenpyram weight ratio are 2: 1; Synergistic effect is the most obvious; Find that through the test people pyridine of epoxy worm and Nitenpyram are composite also to have synergistic effect preferably to insects such as control diamond-back moth, beet armyworm, leaf miners, co-toxicity coefficient is all greater than 150.
Application implementation example five:
Supply the examination insect: leafhopper.
Experimental scheme: effective lethal concentration scope of confirming the pyridine of epoxy worm, the former medicine of thiophene worm piperazine and the two different proportioning mixture through preliminary experiment.
Toxicity test result four
Pyridine of table 4 epoxy worm and the toxicity test of the different proportionings of thiophene worm piperazine to leafhopper
Can be known that by table 4 proportioning of pyridine of epoxy worm and Thiamethoxam compound control leafhopper was at 60: 1 to 1: 60 o'clock, co-toxicity coefficient is all greater than 120; Explaining that both were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect; Especially when the pyridine of epoxy worm and thiophene worm piperazine got proportioning at 16: 1 to 1: 2, synergistic effect was more obviously outstanding, wherein co-toxicity coefficient maximum when the pyridine of epoxy worm and thiophene worm piperazine weight ratio are 2: 1; Synergistic effect is the most obvious; Find through the test people, the pyridine of epoxy worm and Thiamethoxam compound to prevent eliminating aphis, insects such as diamond-back moth, leaf miner also have synergistic effect preferably, co-toxicity coefficient is all greater than 150.
Application implementation example six:
Supply the examination insect: scale insect.
Experimental scheme: effective lethal concentration scope of confirming the pyridine of epoxy worm, the former medicine of thiophene worm quinoline and the two different proportioning mixture through preliminary experiment.
Toxicity test result five
Pyridine of table 5 epoxy worm and the toxicity test of the different proportionings of thiophene worm quinoline to scale insect
Can know by table 5; The proportioning of pyridine of epoxy worm and the composite control scale insect of thiophene worm quinoline is at 60: 1 to 1: 60 o'clock, and co-toxicity coefficient is all greater than 120, explains that both were mixed in the scope at 60: 1 to 1: 60 all to show synergistic effect; Especially when the pyridine of epoxy worm and thiophene worm quinoline get proportioning at 10: 1 to 1: 10; Synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when the pyridine of epoxy worm and thiophene worm quinoline weight ratio are 1: 1 wherein, and synergistic effect is the most obvious.
Application implementation example seven:
Supply the examination insect: trialeurodes vaporariorum.
Experimental scheme: effective lethal concentration scope of confirming the pyridine of epoxy worm, the former medicine of thiophene worm amine and the two different proportioning mixture through preliminary experiment.
Toxicity test result six
Pyridine of table 6 epoxy worm and the toxicity test of the different proportionings of thiophene worm amine to trialeurodes vaporariorum
Can be known that by table 6 proportioning of pyridine of epoxy worm and the composite control trialeurodes vaporariorum of thiophene worm amine was at 60: 1 to 1: 60 o'clock, co-toxicity coefficient is all greater than 120; Explaining that both were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect; Especially when the pyridine of epoxy worm and thiophene worm amine got proportioning at 10: 1 to 1: 10, synergistic effect was more obviously outstanding, wherein co-toxicity coefficient maximum when the pyridine of epoxy worm and thiophene worm amine weight ratio are 1: 1; Synergistic effect is the most obvious; Find that through the test people pyridine of epoxy worm and thiophene worm amine are composite also to have synergistic effect preferably to insects such as control small brown rice planthopper, brown planthoppers, co-toxicity coefficient is all greater than 150.
Application implementation example eight:
Supply the examination insect: Americal rice leaf miner.
Experimental scheme: effective lethal concentration scope of confirming the pyridine of epoxy worm, the former medicine of MTI-446 and the two different proportioning mixture through preliminary experiment.
Toxicity test result seven
The different proportionings with MTI-446 of table 7 epoxy worm pyridine are to the toxicity test of Americal rice leaf miner
Can know by table 7; The proportioning of the composite control Americal rice leaf miner of pyridine of epoxy worm and MTI-446 is at 60: 1 to 1: 60 o'clock, and co-toxicity coefficient is all greater than 120, explains that both were mixed in the scope at 60: 1 to 1: 60 all to show synergistic effect; Especially when the pyridine of epoxy worm and MTI-446 get proportioning at 2: 1 to 1: 16; Synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when the pyridine of epoxy worm and MTI-446 weight ratio are 1: 2 wherein, and synergistic effect is the most obvious.
Application implementation example nine epoxy worm pyridines and the Imidacloprid and the composite control rice leaf roller test of pesticide effectiveness thereof
This test medicine is provided by the individual, contrast medicament 25% epoxy worm pyridine wetting powder (commercial), 48% imidacloprid suspending agent (commercial).
Conventional spray-on process is adopted in test, and investigation rice leaf roller insect pest index before the medicine in the their early stage dispenser, was investigated the insect pest indexes in 3 days, 7 days, 14 days after the dispenser and calculated preventive effect.Experimental result is as follows:
The pyridine of table 8 epoxy worm, Imidacloprid and the composite control rice leaf roller test of pesticide effectiveness thereof
Can find out by table 8; Can effectively prevent and treat rice leaf roller after pyridine of epoxy worm and Imidacloprid are composite; Find that through the test people pyridine of epoxy worm and Imidacloprid are composite all to have favorable effect to control paddy rice brown planthopper, white-backed planthopper, small brown rice planthopper etc., 14 days preventive effects are up to more than 95% behind the medicine; Control efficiency all is superior to the preventive effect of single agent, and the preventive effect time is long.In the test scope of medication, the target crop is had no adverse effects.
Application implementation example bull's eye oxygen worm pyridine and the Acetamiprid and the composite control cotten aphid test of pesticide effectiveness thereof
This test medicine is provided by the individual, contrast medicament 25% epoxy worm pyridine wetting powder (commercial), 5% Acetamiprid wetting powder (commercial).
Conventional spray-on process is adopted in test, and investigation cotten aphid insect pest index before the medicine in the their early stage dispenser, was investigated the insect pest indexes in 3 days, 7 days, 14 days after the dispenser and calculated preventive effect.Experimental result is as follows:
The pyridine of table 9 epoxy worm, Acetamiprid and the composite control cotten aphid test of pesticide effectiveness thereof
Can find out by table 9, can effectively prevent and treat cotten aphid after pyridine of epoxy worm and Acetamiprid are composite, find through the applicant; The composite back of pyridine of epoxy worm and Acetamiprid is also better to preventive effects such as aphid, tetranychids; 14 days preventive effects reach more than 95% behind the medicine, and control efficiency all is superior to the preventive effect of single agent, and the preventive effect time is long.In the test scope of medication, the target crop is had no adverse effects.
Application implementation example 11 epoxy worm pyridines and the Nitenpyram and the composite control Americal rice leaf miner test of pesticide effectiveness thereof
This test medicine is provided by the individual, contrast medicament 25% epoxy worm pyridine wetting powder (commercial), 10% Nitenpyram suspending agent (commercial).
Conventional spray-on process is adopted in test, and investigation Americal rice leaf miner insect pest index before the medicine in the their early stage dispenser, was investigated the insect pest indexes in 3 days, 7 days, 14 days after the dispenser and calculated preventive effect.Experimental result is as follows:
The pyridine of table 10 epoxy worm, Nitenpyram and the composite control Americal rice leaf miner test of pesticide effectiveness thereof
Can find out by table 10; Can effectively prevent and treat Americal rice leaf miner after pyridine of epoxy worm and Nitenpyram are composite; Find that through the applicant the composite back of pyridine of epoxy worm and Nitenpyram is also better to preventive effects such as Liriomyza, tetranychid, Bemisia tabaci, diamond-back moth, beet armyworms, 14 days preventive effects reach more than 95% behind the medicine; Control efficiency all is superior to the preventive effect of single agent, and the preventive effect time is long.In the test scope of medication, the target crop is had no adverse effects.
Application implementation example ten diepoxy worm pyridines and the thiophene worm piperazine and the composite control beet armyworm test of pesticide effectiveness thereof
This test medicine is provided by the individual, contrast medicament 25% epoxy worm pyridine wetting powder (commercial), 25% thiophene worm piperazine wetting powder (commercial).
Conventional spray-on process is adopted in test, and investigation beet armyworm insect pest index before the medicine in the their early stage dispenser, was investigated the insect pest indexes in 3 days, 7 days, 14 days after the dispenser and calculated preventive effect.Experimental result is as follows:
The pyridine of table 11 epoxy worm, thiophene worm piperazine and the composite control beet armyworm test of pesticide effectiveness thereof
Can find out by table 11; Can effectively prevent and treat beet armyworm behind pyridine of epoxy worm and the Thiamethoxam compound; Find that through the applicant also better to preventive effects such as Liriomyza, tetranychid, Bemisia tabaci, diamond-back moths behind pyridine of epoxy worm and the Thiamethoxam compound, 14 days preventive effects reach more than 95% behind the medicine; Control efficiency all is superior to the preventive effect of single agent, and the preventive effect time is long.In the test scope of medication, the target crop is had no adverse effects.
Application implementation example 13 epoxy worm pyridines and the thiophene worm quinoline and the composite control tea lesser leafhopper test of pesticide effectiveness thereof
This test medicine is provided by the individual, contrast medicament 25% epoxy worm pyridine wetting powder (commercial), 50% thiophene worm quinoline wetting powder (commercial).
Conventional spray-on process is adopted in test, and investigation tea lesser leafhopper insect pest index before the medicine in the their early stage dispenser, was investigated the insect pest indexes in 3 days, 7 days, 14 days after the dispenser and calculated preventive effect.Experimental result is as follows:
The pyridine of table 12 epoxy worm, thiophene worm quinoline and the composite control tea lesser leafhopper test of pesticide effectiveness thereof
Can find out by table 12; Can effectively prevent and treat tea lesser leafhopper after pyridine of epoxy worm and thiophene worm quinoline are composite; Find that through the applicant the composite back of pyridine of epoxy worm and thiophene worm quinoline is also better to preventive effects such as diamond-back moth, beet armyworms, 14 days preventive effects reach more than 95% behind the medicine; Control efficiency all is superior to the preventive effect of single agent, and the preventive effect time is long.In the test scope of medication, the target crop is had no adverse effects.
Application implementation example ten Fourth Ring oxygen worm pyridines and the thiophene worm amine and the composite control peach fruit borer test of pesticide effectiveness thereof
This test medicine is provided by the individual, contrast medicament 25% epoxy worm pyridine wetting powder (commercial), 50% thiophene worm amine wetting powder (commercial).
Conventional spray-on process is adopted in test, and investigation peach fruit borer insect pest index before the medicine in the their early stage dispenser, was investigated the insect pest indexes in 3 days, 7 days, 14 days after the dispenser and calculated preventive effect.Experimental result is as follows:
The pyridine of table 13 epoxy worm, thiophene worm amine and the composite control peach fruit borer test of pesticide effectiveness thereof
Can be found out that by table 13 can effectively prevent and treat peach fruit borer after pyridine of epoxy worm and thiophene worm amine are composite, 14 days preventive effects reach more than 95% behind the medicine, control efficiency all is superior to the preventive effect of single agent, and the preventive effect time is long.In the test scope of medication, the target crop is had no adverse effects.
Application implementation example ten five rings oxygen worm pyridines and the MTI-446 and the composite control trialeurodes vaporariorum test of pesticide effectiveness thereof
This test medicine is provided by the individual, contrast medicament 25% epoxy worm pyridine wetting powder (commercial), 20% MTI-446 wetting powder (commercial).
Conventional spray-on process is adopted in test, and investigation trialeurodes vaporariorum insect pest index before the medicine in the their early stage dispenser, was investigated the insect pest indexes in 3 days, 7 days, 14 days after the dispenser and calculated preventive effect.Experimental result is as follows:
The pyridine of table 14 epoxy worm, MTI-446 and the composite control trialeurodes vaporariorum test of pesticide effectiveness thereof
Can find out by table 14; Can effectively prevent and treat trialeurodes vaporariorum after pyridine of epoxy worm and MTI-446 are composite; Find that through the applicant the composite back of pyridine of epoxy worm and MTI-446 is also better to preventive effects such as Bemisia tabaci, scale insects, 14 days preventive effects reach more than 95% behind the medicine; Control efficiency all is superior to the preventive effect of single agent, and the preventive effect time is long.In the test scope of medication, the target crop is had no adverse effects.
Claims (6)
1. a Pesticidal combination that contains pyridine of epoxy worm and anabasine comprises active components A, active component B, the auxiliary agent surplus.It is characterized in that: active components A is the pyridine of epoxy worm, and active component B is a kind of arbitrarily in Imidacloprid, Acetamiprid, Nitenpyram, thiophene worm piperazine, thiophene worm quinoline, thiophene worm amine, the MTI-446, and the weight ratio of active components A and active component B is 60: 1～1: 60.
2. the Pesticidal combination that contains pyridine of epoxy worm and anabasine according to claim 1 is characterized in that: the weight ratio of active components A and active component B is 40: 1～1: 40.
3. the Pesticidal combination that contains pyridine of epoxy worm and anabasine according to claim 2 is characterized in that: the weight ratio of active components A and active component B is 20: 1～1: 20.
4. according to any described Pesticidal combination that contains pyridine of epoxy worm and anabasine in the claim 1～3, it is characterized in that: composition is processed wetting powder, water dispersible granules, missible oil, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, micro-capsule-microcapsule suspending agent.
5. the Pesticidal combination that contains pyridine of epoxy worm and anabasine according to claim 4 is used to prevent and treat the application of insect on paddy rice, wheat, brassicaceous vegetable, tea tree, cotton, the fruit tree.
6. application according to claim 5, pest control comprises: rice fulgorid, aphid, leafhopper, trialeurodes vaporariorum, small brown rice planthopper, diamond-back moth, dive fly, Grapholita spp, cotten aphid, tea lesser leafhopper, scale insect.
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| CN103250714A (en) * | 2013-05-22 | 2013-08-21 | 吴江市德佐日用化学品有限公司 | Insecticidal composition |
| CN103651510A (en) * | 2013-12-13 | 2014-03-26 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing cycloxaprid and chloronicotinyl insecticide |
| CN104322532A (en) * | 2014-09-29 | 2015-02-04 | 江苏省绿盾植保农药实验有限公司 | Composite pesticide containing dinotefuran and cycloxaprid and application thereof |
| CN113447590A (en) * | 2021-06-30 | 2021-09-28 | 广西大学 | Preparation method and application of loaded silkworm excrement-based porous carbon material pesticide sustained-release agent |
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| CN103250714A (en) * | 2013-05-22 | 2013-08-21 | 吴江市德佐日用化学品有限公司 | Insecticidal composition |
| CN103651510A (en) * | 2013-12-13 | 2014-03-26 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing cycloxaprid and chloronicotinyl insecticide |
| CN104322532A (en) * | 2014-09-29 | 2015-02-04 | 江苏省绿盾植保农药实验有限公司 | Composite pesticide containing dinotefuran and cycloxaprid and application thereof |
| CN113447590A (en) * | 2021-06-30 | 2021-09-28 | 广西大学 | Preparation method and application of loaded silkworm excrement-based porous carbon material pesticide sustained-release agent |
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Application publication date: 20120502 |