CN102392128A - Acid adding device with accurate and automatic pH value control function - Google Patents
Acid adding device with accurate and automatic pH value control function Download PDFInfo
- Publication number
- CN102392128A CN102392128A CN2011104089237A CN201110408923A CN102392128A CN 102392128 A CN102392128 A CN 102392128A CN 2011104089237 A CN2011104089237 A CN 2011104089237A CN 201110408923 A CN201110408923 A CN 201110408923A CN 102392128 A CN102392128 A CN 102392128A
- Authority
- CN
- China
- Prior art keywords
- acid solution
- storage tank
- divider
- acid
- value
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
Abstract
Belonging to the technical field of hydrometallurgical equipment, the invention relates to an acid adding device with an accurate and automatic pH value control function. The device comprises an acid solution storage tank (2), an acid solution distributor (10) and an acid solution control system. The acid solution distributor (10) is installed inside a reaction container (5). The acid solution storage tank (2) is arranged at a position higher than the acid solution distributor (10), and is in connection with the acid solution distributor (10) through a hand stop valve (4), an electric butterfly valve (6), an infusion tube (7) and a movable sleeve (8) in order. By employing an advanced on-line real time control technology, the device provided in the invention generates no acid fog while adding a high concentration acid solution, and has the advantages of high pH value control precision, low labor intensity, simple structure and reliable operation.
Description
Technical field
The high concentrated acid that the present invention relates in the hydrometallurgical plant technical field adds sour device automatically, especially relates to a kind of sour device that adds of precisely controlling the pH value automatically.
Background technology
In the hydrometallurgy production process, the leaching of metals ion is everlasting and is carried out under the acid system, and the pH value is then as a very important reaction conditions index.At present, to the acid solution of high density add the acid operation mainly through manually, mode such as pipeline spray realizes.And means gained such as generally employing experience of monitoring reaction liquid acidity sensation, pH test paper, acidometer.Because the precision of control depends on test paper or experience is judged, has certain MC hysteresis quality, so often can not get excellent control effect.In addition, because the corrodibility of high density acid solution is strong, it is very high to operations staff's requirement to add the acid operation, when the acid solution of carrying out high density adds the acid operation, careless slightlyly then will cause personal injury, and danger is bigger; And when adopting the pipeline spray, the acid solution amount of adding is inhomogeneous, causes the pH value of acid system to fluctuate bigger.Acid in the spray also will produce a large amount of acid mists, and acid mist is bigger to corrosion on Equipment, also pollute the production operation environment simultaneously.
In order to address the above problem; Prior art also has the trial of this respect, such as: on May 4th, 2011, Chinese utility model patent Granted publication CN 201817331 U; A kind of fuel-burning power plant cooling towers that the people proposed such as, the Zhou Yi flat by Institutes Of Technology Of Changsha Zhu Zhi that discloses add sour device automatically; This device comprises sulfuric acid storage tank, batch meter, sour volume pump and motor thereof, and batch meter is connected with sour volume pump through valve, and sour volume pump outlet directly is connected with pond of cooling tower.This device is provided with the pH value of pH value on-line monitoring instrument monitoring backwater; And decide to the pH value controller measurement feedback to add the acid amount; Then wave is passed to variable-frequence governor, control sour volume pump rotating speed of motor, thereby realize adding the automatic control of acid by variable-frequence governor.This device institute Monitoring and Controlling be the pH value of backwater, be not whole pond of cooling tower the pH value, therefore still solve the hysteresis quality of control.
Summary of the invention
The purpose of this invention is to provide a kind of sour device that adds of precisely controlling the pH value automatically; Adopt advanced online in real time control techniques, add in the high density acid solution do not produce acid mist, pH value control accuracy height in the sour process, labour intensity is low and simple in structure, reliable.
The technical scheme that the present invention adopts in order to achieve the above object is:
A kind of sour device that adds of precisely controlling the pH value automatically comprises acid solution storage tank, acid solution divider and acid solution system; The acid solution divider is installed in the reaction vessel; The position of acid solution storage tank setting will exceed the acid solution divider, and the acid solution storage tank is connected the acid solution divider through hand stop valve, electric butterfly valve, tubing successively with moving casing; There is the supply pipeline described acid solution storage tank top, and there is liquidometer the side of acid solution storage tank; Described acid solution divider is circular arc distribution piping and a threeway and five the straight-through circular lines that are linked to be that curve 60 ° of radians by six; Use pipe connection between threeway and the moving casing; Have the sour aperture of a plurality of sprays on the tube wall of each circular arc distribution piping, wherein circular arc distribution piping workplace up the direction tube wall open the spray sour aperture hole count far more than workplace towards the lower direction tube wall; Described acid solution system is made up of pH meter probe, PLC microprocessor and signal output part; The pH meter probe is installed in the reaction liquid level in the reaction vessel, and the pH meter probe is connected the feedback end of PLC microprocessor, and signal output part connects the signal input part of electric butterfly valve.
Adopt the sour device that adds of precisely controlling the pH value automatically of technique scheme; When reaction vessel leached work, acid solution was got in the acid solution storage tank by the supply pipeline earlier, then through hand stop valve, electric butterfly valve, tubing and moving casing; Spray in the reaction vessel by the acid solution divider; The pH meter probe that is arranged in the reaction liquid level in the reaction vessel feeds back to the PLC microprocessor with the reacting liquid pH value that monitors, be presented on the panel of PLC with the form of state value, the PLC microprocessor with this pH value with control set(ting)value and compare calculating; After adjusting, process intelligence decides the acid amount that adds; And wave passed to electric butterfly valve, by electric butterfly valve control aperture, thereby realize adding the automatic control of acid.
Liquidometer of the present invention is used for monitoring the storage of acid solution storage tank acid solution, and is irregular through supply pipeline supply acid solution in the acid solution storage tank; Can make things convenient for the consumption that promptly calculates acid solution through the liquidometer graduation apparatus.The acid solution storage tank avoids causing bigger conversion error in the regular unanimity of shape of liquidometer scale section.
Hand stop valve of the present invention is used for emergency situation, such as have a power failure, emergency situation such as during maintenance.
Moving casing of the present invention is used to control tubing length, makes the acid solution divider be in suitable liquid level position in the reaction vessel.
Acid solution divider of the present invention leads directly to and is convenient to installation and removal through a threeway and five straight-through being formed by connecting, and the whole back that connects forms a circular pipeline.The circular arc distribution piping workplace of acid solution divider up the direction tube wall open the spray sour aperture hole count far more than workplace towards the lower direction tube wall; Make whole pipeline by the rounded symmetry infiltration of acid solution, thereby reach consistent acidity distribution gradient.
The acidity of reaction vessel internal reaction liquid of the present invention feeds back to the PLC microprocessor through the pH meter probe measurement, is presented on the panel of PLC microprocessor signal passing ratio integration (PID) arithmetic expression with the form of state value:
u(t)=K
p÷e(t)+K
iΣe(t)+u
o
U (t) wherein: output, K
p: ratio scale-up factor, K
i: integration scale-up factor, u
o: the manipulated variable benchmark value.
Whole PID execution cycle is 0.1 second, and operation result feeds back to electric butterfly valve through signal output part, thereby reaches effective control butterfly valve valve opening.Its scope is 0～100%.When state value and set(ting)value difference were big, the operation result signal can guarantee butterfly valve opening in the position near standard-sized sheet, and when set(ting)value leveled off to set(ting)value, the operation result signal was closed by the butterfly valve convergence.Flow through electric butterfly valve control total system acid solution reaches the requirement of acidity in the accurate control retort.Hand stop valve of the present invention is used for the emergency situation of total system to be handled, thus the smooth smooth running of assurance system.
The present invention compared with prior art has following obvious advantage:
Use the present invention can effectively solve local excessive concentration problem when adding acid, control pH value in reaction accurately, reduce simultaneously, even avoid the generation of acid mist, improved the production operation environment.Specifically:
1. acid solution adds from liquid internal, and no acid mist produces, and helps equipment protection and environment protection;
2. acid solution can be penetrated in the solution through acid solution divider spray orifice uniformly, has avoided the too high problem of local acidity;
3. the acid solution flow is by the difference decision of state value and set(ting)value, and along with closing on of state value and set(ting)value, the aperture of electric butterfly valve is also more and more littler, until closing at last.The flow velocity of acid solution is effectively controlled in the whole process, and message feedback is timely, avoids manual work to lag behind and the problems such as excessive acid that cause;
4. the control accuracy of liquid pH value can arrive set(ting)value ± 0.05.
In sum; The present invention has adopted advanced online in real time control techniques; It is a kind of sour device that adds of precisely controlling the pH value automatically that sour precision is high, labour intensity is low and simple in structure, reliable that adds; Can eliminate the artificial ununiformity of acid and hysteresis quality and the inaccuracy that grab sampling is analyzed of regularly adding, system is operated steadily.
Description of drawings
Fig. 1 is apparatus of the present invention synoptic diagram;
Fig. 2 is an acid solution divider synoptic diagram.
Among the figure: 1 supply pipeline; 2 acid solution storage tanks; 3 liquidometers; 4 hand stop valves; 5 reaction vessels; 6 electric butterfly valves; 7 tubings; 8 moving casings; 9 threeways; 10 acid solution dividers; 11 is straight-through; 12pH counts probe; 13 signal output parts; The 14PLC microprocessor; The sour aperture of 15 sprays.
Embodiment
Describe the present invention below in conjunction with accompanying drawing in detail with embodiment:
A kind of sour device that adds of precisely controlling the pH value automatically comprises acid solution storage tank 2, acid solution divider 10 and acid solution system; It is characterized in that: acid solution divider 10 is installed in the reaction vessel 5; The position of acid solution storage tank setting will exceed acid solution divider 10, and acid solution storage tank 2 is connected acid solution divider 10 through hand stop valve 4, electric butterfly valve 6, tubing 7 with moving casing 8 successively; There is supply pipeline 1 described acid solution storage tank top, and there is liquidometer 3 side of acid solution storage tank; Described acid solution divider 10 is circular arc distribution piping and a threeway 9 and five straight-through 11 circular lines that are linked to be that curve 60 ° of radians by six; Use pipe connection between threeway 9 and the moving casing 8; Have the sour aperture 15 of a plurality of sprays on the tube wall of each circular arc distribution piping, wherein circular arc distribution piping workplace up the direction tube wall open the spray sour aperture 15 hole count far more than workplace towards the lower direction tube wall; Described acid solution system is made up of pH meter probe 12, PLC microprocessor 14 and signal output part 13; In the reaction liquid level that pH meter probe 12 is installed in the reaction vessel 5, pH meter probe 12 is connected the feedback end of PLC microprocessor 14, and signal output part 13 connects the signal input part of electric butterfly valve 6.
The concrete use as follows:
The production practice of leaching the cupric oxide slag with diluted acid are example.In order to accelerate the leaching of copper, prevent a large amount of dissolvings of other foreign metal simultaneously, whole leaching reaction requires control pH value of solution value >=2.35, and near this numerical value of such as reaction acidity ability stable existence.
Start PLC microprocessor 14, set(ting)value is adjusted to 2.35, show on PLC microprocessor 14 panels that the pH value of ore pulp this moment is 12.67.Electric butterfly valve 6 inserts signal end, turns on hand stop valve 4, writes down acid solution storage tank 2 liquid level numerical value simultaneously, total system entry into service this moment.Along with leaching constantly carrying out of reaction, state value levels off to set(ting)value gradually on PLC microprocessor 14 panels, and electric butterfly valve 6 also levels off to and cuts out.When state value reaches consistent with set(ting)value numerical value; Get the top layer ore pulp through pH meter probe 12 and measure its acidity, the result shows that pH is slightly larger than 0.20, continues to keep this state; And regular 30 minutes sampling analysis; When ore pulp also reaches set(ting)value up to the top layer, close total system, close hand stop valve 4 at last.
Claims (1)
1. the sour device that adds of precisely controlling the pH value automatically comprises acid solution storage tank (2), acid solution divider (10) and acid solution system; It is characterized in that: acid solution divider (10) is installed in the reaction vessel (5); The position of acid solution storage tank setting will exceed acid solution divider (10), and acid solution storage tank (2) is connected acid solution divider (10) through hand stop valve (4), electric butterfly valve (6), tubing (7) with moving casing (8) successively; There is supply pipeline (1) described acid solution storage tank top, and there is liquidometer (3) side of acid solution storage tank; Described acid solution divider (10) is circular arc distribution piping and a threeway (9) and five circular lines that straight-through (11) are linked to be that curve 60 ° of radians by six; Use pipe connection between threeway (9) and the moving casing (8); Have the sour aperture of a plurality of sprays (15) on the tube wall of each circular arc distribution piping, wherein circular arc distribution piping workplace up the direction tube wall open the spray sour aperture (15) hole count far more than workplace towards the lower direction tube wall; Described acid solution system is made up of pH meter probe (12), PLC microprocessor (14) and signal output part (13); PH meter probe (12) is installed in the reaction liquid level in the reaction vessel (5), and pH meter probe (12) is connected the feedback end of PLC microprocessor (14), and signal output part (13) connects the signal input part of electric butterfly valve (6).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104089237A CN102392128B (en) | 2011-12-11 | 2011-12-11 | Acid adding device with accurate and automatic pH value control function |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104089237A CN102392128B (en) | 2011-12-11 | 2011-12-11 | Acid adding device with accurate and automatic pH value control function |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102392128A true CN102392128A (en) | 2012-03-28 |
| CN102392128B CN102392128B (en) | 2013-03-20 |
Family
ID=45859508
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011104089237A Active CN102392128B (en) | 2011-12-11 | 2011-12-11 | Acid adding device with accurate and automatic pH value control function |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102392128B (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103682471A (en) * | 2013-12-28 | 2014-03-26 | 淄博鑫旭电源科技有限公司 | Novel distribution block |
| CN104372717A (en) * | 2013-08-12 | 2015-02-25 | 苏州维艾普新材料股份有限公司 | System and method for on-line monitoring and modulating slurry pH |
| CN104898724A (en) * | 2015-06-10 | 2015-09-09 | 中国石油天然气集团公司 | Automatic pH value control device for sulfide stress cracking resistance test, and control method thereof |
| CN104944380A (en) * | 2015-07-09 | 2015-09-30 | 安徽淮化股份有限公司 | Acid dosing device of hydrogen peroxide production system |
| CN105388921A (en) * | 2015-12-17 | 2016-03-09 | 吉首大学 | Chemical combination barrel acid adding system and method |
| CN105603467A (en) * | 2016-02-19 | 2016-05-25 | 金川集团股份有限公司 | Hysteretic pH value control device and control method |
| CN105845990A (en) * | 2016-04-28 | 2016-08-10 | 安徽超威电源有限公司 | Paste mixing temperature and automatic acid-adding controlling device |
| CN106186253A (en) * | 2016-08-04 | 2016-12-07 | 沈阳华控科技发展有限公司 | In a kind of waste water based on soft-measuring technique and autocontrol method |
| CN113088688A (en) * | 2021-04-15 | 2021-07-09 | 攀钢集团攀枝花钢铁研究院有限公司 | Acid adding device suitable for vanadium slag leaching process |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201942525U (en) * | 2011-01-04 | 2011-08-24 | 福建正盛无机材料股份有限公司 | White carbon black reaction acidulation device adopting precipitation method |
| CN202390507U (en) * | 2011-12-11 | 2012-08-22 | 郴州市金贵银业股份有限公司 | Acid adding device capable of controlling PH value accurately and automatically |
-
2011
- 2011-12-11 CN CN2011104089237A patent/CN102392128B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201942525U (en) * | 2011-01-04 | 2011-08-24 | 福建正盛无机材料股份有限公司 | White carbon black reaction acidulation device adopting precipitation method |
| CN202390507U (en) * | 2011-12-11 | 2012-08-22 | 郴州市金贵银业股份有限公司 | Acid adding device capable of controlling PH value accurately and automatically |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104372717A (en) * | 2013-08-12 | 2015-02-25 | 苏州维艾普新材料股份有限公司 | System and method for on-line monitoring and modulating slurry pH |
| CN104372717B (en) * | 2013-08-12 | 2016-09-21 | 苏州维艾普新材料股份有限公司 | A kind of on-line monitoring and the system and method for regulation and control slurry pH |
| CN103682471A (en) * | 2013-12-28 | 2014-03-26 | 淄博鑫旭电源科技有限公司 | Novel distribution block |
| CN103682471B (en) * | 2013-12-28 | 2016-01-06 | 淄博鑫旭电源科技有限公司 | Novel distribution block |
| CN104898724A (en) * | 2015-06-10 | 2015-09-09 | 中国石油天然气集团公司 | Automatic pH value control device for sulfide stress cracking resistance test, and control method thereof |
| CN104898724B (en) * | 2015-06-10 | 2017-02-22 | 中国石油天然气集团公司 | Automatic pH value control device for sulfide stress cracking resistance test, and control method thereof |
| CN104944380A (en) * | 2015-07-09 | 2015-09-30 | 安徽淮化股份有限公司 | Acid dosing device of hydrogen peroxide production system |
| CN105388921A (en) * | 2015-12-17 | 2016-03-09 | 吉首大学 | Chemical combination barrel acid adding system and method |
| CN105603467A (en) * | 2016-02-19 | 2016-05-25 | 金川集团股份有限公司 | Hysteretic pH value control device and control method |
| CN105845990A (en) * | 2016-04-28 | 2016-08-10 | 安徽超威电源有限公司 | Paste mixing temperature and automatic acid-adding controlling device |
| CN106186253A (en) * | 2016-08-04 | 2016-12-07 | 沈阳华控科技发展有限公司 | In a kind of waste water based on soft-measuring technique and autocontrol method |
| CN113088688A (en) * | 2021-04-15 | 2021-07-09 | 攀钢集团攀枝花钢铁研究院有限公司 | Acid adding device suitable for vanadium slag leaching process |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102392128B (en) | 2013-03-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102392128B (en) | Acid adding device with accurate and automatic pH value control function | |
| CN100546706C (en) | Automatic control method for hydrochloric acid solution dilution technique | |
| CN204356408U (en) | A kind of heating in water bath pickling experimental installation | |
| CN202390507U (en) | Acid adding device capable of controlling PH value accurately and automatically | |
| CN103641236A (en) | Intelligent aeration system with dissolved oxygen meter | |
| CN204825109U (en) | A electrolytic pickling solution pH value automatic regulating apparatus for belted steel pickling production | |
| CN201912923U (en) | Equipment for automatically metering charging material of titanium tetrachloride | |
| CN201334388Y (en) | Automatic acid/alkali adding device | |
| CN207628335U (en) | A kind of cutting fluid automatic solution proportioning apparatus | |
| CN2855501Y (en) | Oil-water interface controller of sedimentation separating tank | |
| CN203816485U (en) | Chemical adding device | |
| CN112062266A (en) | Device and method for on-line monitoring and evaluation of sludge activity of municipal sewage treatment plant | |
| CN103768989A (en) | Dilute sulfuric acid automatic preparation device and method | |
| CN205080039U (en) | Oil gas well casing line, gas gathering station corrode monitoring devices | |
| CN212151744U (en) | Automatic regulator for generator inner cooling water | |
| CN102880199A (en) | Full-automatic PH (potential of hydrogen) value detecting and monitoring and automatic chemical replenishing system for metal spraying | |
| CN203904276U (en) | Demulsifying agent injection device | |
| CN110082254A (en) | A kind of concentration basin ladder concentration polling type self-operated measuring unit | |
| CN205502142U (en) | Building water supply process control simulation experiment device | |
| CN204330519U (en) | The device of uninterrupted measurement slurry density of desulfurizing absorption column and pH value | |
| CN217561955U (en) | Recirculated cooling water acidification controlling means | |
| CN112504506A (en) | Device and method for in-situ online monitoring of performance of biological tank of sewage treatment plant | |
| CN207405215U (en) | A kind of gold mud displacement apparatus | |
| CN202865302U (en) | Laboratory is with biological column test device that soaks | |
| CN207660595U (en) | Oil field shaft mouth chemicals dosing plant |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20191126 Granted publication date: 20130320 |
|
| PP01 | Preservation of patent right | ||
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20201130 Granted publication date: 20130320 |
|
| PD01 | Discharge of preservation of patent |