CN102392083A - Method for manufacturing high temperature-resistant wool sheepskin for shoes and boots - Google Patents
Method for manufacturing high temperature-resistant wool sheepskin for shoes and boots Download PDFInfo
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- CN102392083A CN102392083A CN2011103060496A CN201110306049A CN102392083A CN 102392083 A CN102392083 A CN 102392083A CN 2011103060496 A CN2011103060496 A CN 2011103060496A CN 201110306049 A CN201110306049 A CN 201110306049A CN 102392083 A CN102392083 A CN 102392083A
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Abstract
The invention relates to a manufacturing method for improving the heat-resistant performance of leatherboard in the wool sheepskin industry, in particular to a method for manufacturing high temperature-resistant wool sheepskin for shoes and boots. In the high temperature-resistant wool sheepskin, the leatherboard can resist high temperature of 150 DEG C. The method comprises the steps of: preparing blank skin before weighing and processing the blank skin after degreasing; and the method is characterized in that: a process between the weighing process and the degreasing process comprises the steps of retanning, standing, pickling and rinsing, wherein in the retanning step, a fatliquor GLH which is diluted by adding hot water, diluted formic acid, chromium powder, Bayer zirconium ZB33 and sodium bicarbonate are added to extract alkali. In the key technology, a method for combining a chrome tanning agent and a zirconium tanning agent is adopted in the retanning process; and the leatherboard of products produced under the condition that the using amount of the chrome tanning agent and the zirconium tanning agent is adjusted to a reasonable ratio meets the requirement of resisting temperature of 150 DEG C completely, fibers of the leatherboard are compact, and the dyed leatherboard is bright and strong in colors. The products are suitable for fields of manufacturing the shoes and boots, the high temperature-resistant wool sheepskin and the like.
Description
Technical fieldThe present invention relates to the making that shearling industry dermatotome resistance toheat improves, especially relate to the high temperature resistant footwear boots shearling making method that the dermatotome heatproof will reach 150 ℃.
Background technologyCompany obtains client's information at the beginning of 2010, and a kind of product that a domestic foreign trade corporation makes is badly in need of wanting a kind of heatproof to reach 150 ℃ high temperature resistant footwear boots shearling.All about 95 ℃, the shearling that can reach anti-150 ℃ of high-temperatures still belongs to blank at home, outward shearling product heatproof degree generally speaking.
Retanning occupies critical role in fur industry; It is that the good skin base of tanning is carried out another tanning, can replenish the deficiency of just tanning, and improves the stability of skin base chemically-resistant effect; Help follow-up housekeeping operation; Improve use properties, increase value-added content of product to greatest extent, be suitable for the needs of various uses.
At present, chrome tanning agent retanning, aldehyde tanning agent retanning, aluminum tanning agent retanning or synthetic tanning agent, vegetable tanning agent, resene tanning agent retanning several different methods are generally taked in the fur retanning, and effect that different retanning methods reaches and excellent, shortcoming thereof have nothing in common with each other.The advantage of chrome tanning agent retanning is to improve the shrinkage temperature of dermatotome, and the stability of the fullness of increase dermatotome, elasticity, flexibility, chemical-resistant reagent and anionic dyestuff are to the colourability of dermatotome; Along with the fur industrial expansion, requirement higher, that upgrade has been proposed for fur and goods thereof both at home and abroad, impel fur manufacturing technology constantly to be able to improve.How to improve anti-shrinkage temperature, reach customer requirement, become the problem that fur retanning operation presses for solution.
Product development for the shearling of accomplishing anti-150 ℃ of high-temperatures; My engineering technical personnel of company mainly from screening material, change test such as processing condition and start with, combine retanning with chromium with different retanning materials, through contrasting to the simultaneous test of several kinds of retanning materials with to the test of many times of retanning method; The retanning technology that development makes new advances; After the appearance piece is manufactured experimently out, under 150 ° of C conditions, test, do not shrink in 2 minutes; The color of footwear boots skin through draw a design, setting-out reaches customer requirement, makes product dermatotome heatproof and the hair color produced reach customer requirement.
Summary of the inventionThe object of the present invention is to provide a kind of high temperature resistant footwear boots shearling making method, the shearling that this method is made, heatproof can reach 150 ℃.
The present invention realizes that the technical scheme that above-mentioned purpose takes is following: a kind of high temperature resistant footwear boots shearling making method; Comprise base skin before weighing prepare with degreasing after the base skin handle, it is characterized in that weighing and degreasing between process flow be: retanning, leave standstill, pickling, rinsing; Concrete technical matters step is following:
Steps A, base skin are prepared
Undertaken by existing following common process step: footwear boots base skin, cropping, swabbing, boiling hot hair, cropping, secondary swabbing are scalded hair, carding, cropping, brush formic acid liquid, scald hair, cropping, are checked, weigh, and said weighing is accurately to weigh 132 kg/ grooves as following operation materials foundation;
Step B, retanning
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 45～48 ℃,
Material: GLH fatting agent 1.0g/l 60 minutes
It is 2.9～3.2 that formic acid 1g/l surveyed PH in 30 minutes
Chromium powder 20g/l
Bayer zirconium ZB33 5g/l stops after 60 minutes to draw, and per 2 hours intermittences, paddling was 20 minutes, early carried alkali next day
Sodium bicarbonate (1) 1.0g/l 120 minutes
Sodium bicarbonate (2) 1.0g/l 120 minutes
Sodium bicarbonate (3) 1.0g/l 120 minutes
Sodium bicarbonate (4) 1.0g/l 120 minutes
Sodium bicarbonate (5) 1.0g/l 120 minutes, surveying pH value is 3.9～4.2
Subsequent use sodium bicarbonate (6) 0.5～1.0g/l 30 minutes, surveying pH value is 3.9～4.2; Spend the night, early go out skin next day;
Working method: the temperature adjustment to 45 that discharges water～48 ℃ hypodermis; Added the continuous paddling of fatting agent GLH that dilutes with 1 times of 60～65 ℃ of hot water 60 minutes; Add again and diluted good formic acid and continued paddling 30 minutes, after surveying PH and reaching 2.9～3.2 requirement, added chromium powder and the continuous paddling of Bayer zirconium ZB33 60 minutes, stop stroke; Paddling was 20 minutes in per 2 hours later on, stopped night to draw, and early carried alkali next day; Order adds (5) five parts in sodium bicarbonate (1) to sodium bicarbonate, and the continuous paddling of a sodium bicarbonate of every adding stopped to draw 90 minutes in 30 minutes, and after the continuous paddling of adding sodium bicarbonate (5) stopped to draw 90 minutes in 30 minutes, surveying pH value was 3.9～4.2; Added subsequent use sodium bicarbonate (6) and paddling again 30 minutes as pH value is improper, being adjusted to pH value suitable is that pH value is 3.9～4.2, can stop to draw, and spends the night; Next day, early continuous paddling went out skin in 30 minutes;
Specification of quality and precaution: a, material must be sequentially added into; PH value must be controlled at every turn and can continue in the claimed range down to carry out; B, sodium bicarbonate are opened with 5～10 times of 30 ℃ of aquations, and formic acid is even with 10 times of normal-temperature water dilutions, after c, various material add; Want continuous paddling, guarantee that the leather suction is even;
Step C, leave standstill
The base skin that retanning goes out behind the skin left standstill 1～2 day;
Step D, pickling
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 34～36 ℃;
Material: formic acid 1.0～1.2g/l, paddling 30 minutes is surveyed PH:3.6～3.8
Working method: the temperature adjustment to 34 that discharges water～36 ℃ hypodermis, add and diluted the continuous paddling of uniform formic acid 30 minutes with 10 times of normal-temperature water, after reaching 3.6～3.8, the survey pH value goes out skin;
Step e, rinsing
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 20～25 ℃, the time: 15 minutes
Working method: the temperature adjustment to 20 that discharges water～25 ℃ hypodermis, paddling went out skin after 15 minutes continuously;
Step F, base skin are handled
By existing following common process step with rinsing after the base skin handle: degreasing, flushing, dyeing, flushing, water dumping, brush stuffing, drying, moisture regain, stretching, extension, toggling, placement, swabbing, scald hair, brush formic acid liquid two times, scald hair two times, cropping, do and scald hair, cropping, inspection after construction, gage friendship storehouse.
Most critical technology of the present invention is the method for taking chromium, zirconium tanning agent to combine in the retanning operation; Adjust at the consumption of chrome tanning agent, zirconium tanning agent under the situation of reasonable proportioning; Its dermatotome of the product of producing not only heatproof can reach 150 ℃ requirement fully; And the dermatotome fiber is tightr, and dyeing back dermatotome is bright in colour, dense, bright.The footwear boots shearling of manufacturing according to the present invention obtains foreign trader's favorable comment, for a new route has been broken in company's trade.Through research and experiment; High temperature resistant footwear boots shearling making method is fit to make homemade three generations above improvement fine furs and Australian shearling; Its product is applicable to fields such as making footwear boots and high temperature resistant shearling; This technical renovation is that good basis has been established in company developing foreign trade market, and is of far-reaching significance and will bring good economic benefits.
Embodiment
Embodiment 1
1, the base skin is prepared
Undertaken by the existing conventional process step: footwear boots base skin, cropping, swabbing, boiling hot hair, cropping, secondary swabbing are scalded hair, carding, cropping, brush formic acid liquid, are scalded hair, cropping, check; The 132 kg/ groove base skins of then accurately weighing, and as following operation materials foundation.
2, retanning:
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 47 ℃
Material: GLH fatting agent 1.0g/l * 3800=3800 g
Formic acid 1g/l * 3800=3800 g
Chromium powder 20g/l * 3800=76000 g
Bayer zirconium ZB33 5g/l * 3800=19000 g
Sodium bicarbonate (1) 1.0g/l * 3800=3800 g
Sodium bicarbonate (2) 1.0g/l * 3800=3800 g
Sodium bicarbonate (3) 1.0g/l * 3800=3800 g
Sodium bicarbonate (4) 1.0g/l * 3800=3800 g
Sodium bicarbonate (5) 1.0g/l * 3800=3800 g
Subsequent use sodium bicarbonate (6) 0.6g/l * 3800=2280 g
65 ℃ of hot water with 7600g are evenly subsequent use with the dilution of GLH fatting agent; With the 38kg normal-temperature water that the formic acid dilution is evenly subsequent use; Open subsequent use with 30 ℃ of aquations of 6 times of its weight sodium bicarbonate (1) to sodium bicarbonate (6) respectively.
Working method: temperature adjustment to the 47 ℃ hypodermis that discharges water, add and diluted the continuous paddling of uniform fatting agent GLH 60 minutes, add again and diluted good formic acid continuation paddling 30 minutes; Surveying PH is 3.0; Added chromium powder and the continuous paddling of Bayer zirconium ZB33 60 minutes, and stopped drawing, paddling was 20 minutes in later per 2 hours; Stop night to draw, early carry alkali next day; The sodium bicarbonate that addingization is good (1), paddling stopped to draw 90 minutes in 30 minutes continuously; The sodium bicarbonate (2) that addingization is good again, paddling stopped to draw 90 minutes in 30 minutes continuously ..., until the good sodium bicarbonate of addingization (5), paddling stopped to draw 90 minutes in 30 minutes continuously; Survey PH3.7, because of pH value is improper, the subsequent use sodium bicarbonate (6) that adding is good again, paddling is 30 minutes continuously, surveys pH value 4.2, and suitable the stopping of pH value drawn, and spends the night; Next day, early continuous paddling went out skin in 30 minutes.
3, left standstill 2 days after leaving standstill out skin.
4, pickling
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 35 ℃
Material: formic acid: 1.1g/l * 3800=4180 g surveys PH:3.6
Working method: temperature adjustment to the 35 ℃ hypodermis that discharges water, add and diluted the continuous paddling of uniform formic acid 30 minutes with 10 times of normal-temperature water, the survey pH value reaches will obtain skin.
5, rinsing
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 24 ℃, the time: 15 minutes
Working method: temperature adjustment to the regulation that discharges water hypodermis, paddling went out skin after 15 minutes continuously.
6, the base skin is handled
By existing following common process step with rinsing after the base skin handle: degreasing, flushing, dyeing, flushing, water dumping, brush stuffing, drying, moisture regain, stretching, extension, toggling, placement, swabbing, scald hair, brush formic acid liquid two times, scald hair two times, cropping, do and scald hair, cropping, inspection after construction, gage friendship storehouse.
Embodiment 2
1, the base skin is prepared identical with embodiment 1.
2, retanning
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 45 ℃
Material: do not need subsequent use sodium bicarbonate (6), it is subsequent use to use 30 ℃ of aquations of 10 times of its weight to open respectively in sodium bicarbonate (1) to sodium bicarbonate (5), and all the other are identical with embodiment 1;
Survey PH:3.0 after adding formic acid, add continuously paddling 30 minutes of sodium bicarbonate (5), stop drawing that to survey PH after 90 minutes be 3.9: all the other are identical with embodiment 1.
3, left standstill 1 day after leaving standstill out skin.
4, pickling temperature: 36 ℃, survey PH:3.7; All the other are identical with embodiment 1.
5, rinsing temperature: 23 ℃; All the other are identical with embodiment 1.
Embodiment 3
1, the base skin is prepared identical with embodiment 1.
2, retanning
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 48 ℃;
Material: subsequent use sodium bicarbonate (6) 1g/l * 3800=3800 g, it is subsequent use to use 30 ℃ of aquations of 8 times of its weight to open respectively in sodium bicarbonate (1) to sodium bicarbonate (6), and all the other are identical with embodiment 1;
Survey PH:3.1 after adding formic acid, add continuously paddling 30 minutes of sodium bicarbonate (5), stop drawing that to survey PH after 90 minutes be 3.6, add subsequent use sodium bicarbonate (6) back and survey PH:4.1; All the other are identical with embodiment 1.
3, left standstill 2 days after leaving standstill out skin.
4, pickling temperature: 34 ℃, survey PH:3.8; All the other are identical with embodiment 1.
5, rinsing temperature: 25 ℃; All the other are identical with embodiment 1.
Claims (3)
1. high temperature resistant footwear boots shearling making method, comprise base skin before weighing prepare with degreasing after the base skin handle, it is characterized in that: weigh and degreasing between process flow be: retanning, leave standstill, pickling, rinsing; Concrete technical matters step is following:
Steps A, base skin are prepared
Step B, retanning
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 45～48 ℃,
Material: GLH fatting agent 1.0g/l 60 minutes
It is 2.9～3.2 that formic acid 1g/l surveyed PH in 30 minutes
Chromium powder 20g/l
Bayer zirconium ZB33 5g/l stops after 60 minutes to draw, and per 2 hours intermittences, paddling was 20 minutes, early carried alkali next day
Sodium bicarbonate (1) 1.0g/l 120 minutes
Sodium bicarbonate (2) 1.0g/l 120 minutes
Sodium bicarbonate (3) 1.0g/l 120 minutes
Sodium bicarbonate (4) 1.0g/l 120 minutes
Sodium bicarbonate (5) 1.0g/l 120 minutes, surveying pH value is 3.9～4.2
Subsequent use sodium bicarbonate (6) 0.5～1.0g/l 30 minutes, surveying pH value is 3.9～4.2; Spend the night, early go out skin next day;
Working method: the temperature adjustment to 45 that discharges water～48 ℃ hypodermis; Added the continuous paddling of fatting agent GLH that dilutes with 1 times of 60～65 ℃ of hot water 60 minutes; Add again and diluted good formic acid and continued paddling 30 minutes, after surveying PH and reaching 2.9～3.2 requirement, added chromium powder and the continuous paddling of Bayer zirconium ZB33 60 minutes, stop stroke; Paddling was 20 minutes in per 2 hours later on, stopped night to draw, and early carried alkali next day; Order adds (5) five parts in sodium bicarbonate (1) to sodium bicarbonate, and the continuous paddling of a sodium bicarbonate of every adding stopped to draw 90 minutes in 30 minutes, and after the continuous paddling of adding sodium bicarbonate (5) stopped to draw 90 minutes in 30 minutes, surveying pH value was 3.9～4.2; Added subsequent use sodium bicarbonate (6) and paddling again 30 minutes as pH value is improper, being adjusted to pH value suitable is that pH value is 3.9～4.2, can stop to draw, and spends the night; Next day, early continuous paddling went out skin in 30 minutes;
Step C, leave standstill
The base skin that retanning goes out behind the skin left standstill 1～2 day;
Step D, pickling
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 34～36 ℃;
Material: formic acid 1.0～1.2g/l, paddling 30 minutes is surveyed PH:3.6～3.8
Working method: the temperature adjustment to 34 that discharges water～36 ℃ hypodermis, add and diluted the continuous paddling of uniform formic acid 30 minutes with 10 times of normal-temperature water, after reaching 3.6～3.8, the survey pH value goes out skin;
Step e, rinsing
Equipment: 3.8 tons of paddle-tumbles, liquor ratio: 1:29, temperature: 20～25 ℃, the time: 15 minutes
Working method: the temperature adjustment to 20 that discharges water～25 ℃ hypodermis, paddling went out skin after 15 minutes continuously;
Step F, base skin are handled.
2. a kind of high temperature resistant footwear boots shearling making method as claimed in claim 1 is characterized in that: the said working method of step B retanning, and material must be sequentially added into, and pH value must be controlled at every turn and can continue in the claimed range down to carry out; Sodium bicarbonate is opened with 5～10 times of 30 ℃ of aquations, and formic acid with 10 times of normal-temperature water dilutions evenly after various materials add, continuous paddling, guarantees that the leather suction is even.
3. a kind of high temperature resistant footwear boots shearling making method as claimed in claim 1; It is characterized in that: it is to be undertaken by existing following common process step that said steps A base skin is prepared: footwear boots base skin, cropping, swabbing, boiling hot hair, cropping, secondary swabbing are scalded hair, carding, cropping, brush formic acid liquid, scald hair, cropping, are checked, weigh, and said weighing is accurately to weigh 132 kg/ grooves as subsequent handling materials foundation; It is that the base skin after the step e rinsing is undertaken by existing following common process step that said step F base skin is handled: by existing following common process step with rinsing after the base skin handle: degreasing, flushing, dyeing, flushing, water dumping, brush stuffing, drying, moisture regain, stretching, extension, toggling, placement, swabbing, scald hair, brush formic acid liquid two times, scald hair two times, cropping, do and scald hair, cropping, inspection after construction, gage friendship storehouse.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103060496A CN102392083B (en) | 2011-10-11 | 2011-10-11 | Method for manufacturing high temperature-resistant wool sheepskin for shoes and boots |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103060496A CN102392083B (en) | 2011-10-11 | 2011-10-11 | Method for manufacturing high temperature-resistant wool sheepskin for shoes and boots |
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| CN102392083A true CN102392083A (en) | 2012-03-28 |
| CN102392083B CN102392083B (en) | 2013-04-24 |
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| CN2011103060496A Expired - Fee Related CN102392083B (en) | 2011-10-11 | 2011-10-11 | Method for manufacturing high temperature-resistant wool sheepskin for shoes and boots |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105349710A (en) * | 2015-12-17 | 2016-02-24 | 湖南科技职业学院 | Chromium-free combination tannage method for cattle hides |
| CN105624340A (en) * | 2015-12-08 | 2016-06-01 | 浙江中辉皮草有限公司 | Production process for suede fur or leather with dark fur cover and white leather disk |
| CN108424983A (en) * | 2018-03-19 | 2018-08-21 | 江西隆华皮革有限公司 | Sheepskin thickening method |
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| CN105624340A (en) * | 2015-12-08 | 2016-06-01 | 浙江中辉皮草有限公司 | Production process for suede fur or leather with dark fur cover and white leather disk |
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| CN105349710B (en) * | 2015-12-17 | 2018-07-10 | 湖南科技职业学院 | A kind of method of ox-hide Chrome-free combination tanning |
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| CN108424983B (en) * | 2018-03-19 | 2020-07-24 | 江西隆华材料科技股份有限公司 | Sheep skin thickening method |
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| CN102392083B (en) | 2013-04-24 |
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