CN102391721A - UV (ultraviolet) cured inkjet ink composition - Google Patents
UV (ultraviolet) cured inkjet ink composition Download PDFInfo
- Publication number
- CN102391721A CN102391721A CN2011102964084A CN201110296408A CN102391721A CN 102391721 A CN102391721 A CN 102391721A CN 2011102964084 A CN2011102964084 A CN 2011102964084A CN 201110296408 A CN201110296408 A CN 201110296408A CN 102391721 A CN102391721 A CN 102391721A
- Authority
- CN
- China
- Prior art keywords
- ink
- photo
- pigment
- curing
- jet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a UV (ultraviolet) cured inkjet ink composition. The composition comprises the following components by mass: 1.0-6.0% of nano pigments (D90<200nm), 2-3% of UV blocking agents (D90<200nm), 1.0-6.0% of a dispersing agent, 5-15% of prepolymer, 3-6% of initiators, 0.5-1.0% of a wetting agent and the balance of active monomers. The ink composition can be widely applied to LED (light emitting diode) light sources and high-precision printers and has excellent weather resistance and chemical erosion resistance while ensuring high quality printing effect. The ink film can not be aged or embrittled even if the ink film is cured.
Description
Technical field
The present invention relates to a kind of UV photo-curing ink-jet composition for ink, more precisely, relate to a kind of composition for ink that possesses excellent weather resistance and chemerosiveness resistent, adaptable across led light source and high precision stamping machine.
Background technology
UV spray ink Printing owing to have prints on demand, at a high speed, high quality, advantage cheaply, employed UV printing ink has solvent-free volatilization, save energy consumption, reduce the advantage of environmental pollution, more and more receives people's favor.The drying of UV printing ink is a photoprocess; The UV luminous energy is absorbed by light trigger in the UV ink adhesive; Cause liquid unit molecule or oligomerization resin polymerization and reticulate solid-state macromolecular process; But the two keys on the light trigger in the ink system and each component molecular structure can not be participated in reaction fully, cause the printing ink after the curing to contain the two keys that have neither part nor lot in reaction.These unreacted trace molecules can continue when daily use and during sun exposure to decompose, and then some chemical bond in the ink molecules chain after solidifying produced decompose, and cause ink film after the curing aging phenomenon such as become fragile to occur.
CN 1632006A one Chinese patent application discloses a kind of ultraviolet cured printing ink for digital flat ink jet printer; By weight percentage, comprising: the light trigger of the prepolymer of 5-25%, the reactive monomer of 60-80%, 1-5% pigment, 3-8%, the tensio-active agent of 0.1-1%, the dispersion agent of 0.5-3%.Wherein, reactive monomer is the mixture of simple function group monomer, bifunctional monomer and trifunctional monomer or polyfunctional monomer.Though this kind UV solidified ink has viscosity preferably, be used for common UV type printer and can obtain good printing effect, because of not using suitable compsn, weathering resistance and chemerosiveness resistent are not good.
Summary of the invention
The present invention is directed to deficiency of the prior art, a kind of UV photo-curing ink-jet composition for ink is provided, when obtaining good printing effect, also possess excellent weathering resistance and chemerosiveness resistent.
Technical scheme of the present invention is: a kind of UV photo-curing ink-jet composition for ink, composed of the following components by weight percentage:
Nano-level pigment 1.0-6.0%;
Ultraviolet isolating agent 2-3%;
Dispersion agent 1.0-6.0%;
Prepolymer 5-15%;
Initiator 3-6%;
Wetting agent 0.5-1.0%;
The reactive monomer surplus;
Wherein, the D90＜200nm of nano-level pigment and ultraviolet isolating agent.
Preferably: said nano-level pigment is selected from C.I. Pigment black 7, C.I. pigment Blue 15: 3, at least a in C.I. pigment Green 7, C.I. pigment Orange 13, C.I. pigment red 122, C.I. pigment violet 19, C.I. Pigment Yellow 73 155, the C.I. Pigment white 6.
Preferably: said ultraviolet isolating agent is selected from least a in silicon-dioxide, the zinc oxide.
Preferably: said dispersion agent is the macromolecule polyacrylic acid dispersion agent.
Preferably: described prepolymer is mono acrylic ester performed polymer and/or polyester acrylate performed polymer.
Preferably: described initiator is one or more in bisacylphosphine oxide, st-yrax diethyl ether, the α-amido ketone.
Preferably: said wetting agent is reactive silicone acrylates.
Preferably: said reactive monomer is ethoxy ethoxy ethyl propylene acid esters, propylene glycol diacrylate.
Preferably: described ink jet ink composition is used for led light source solidified ink-jet printer.
Composition for ink of the present invention can be adaptable across led light source and high precision stamping machine, when having guaranteed the high quality printing effect, possess excellent weathering resistance and chemerosiveness resistent, even after solidifying, aging phenomenon such as become fragile can not appear in ink film yet.
Embodiment
Below in conjunction with specific embodiment technical scheme of the present invention is further described, but protection scope of the present invention is not limited thereto.
EFKA 4800 in the embodiment of the invention (vapour Bagong department) staple is the polyacrylic ester of modification, is as macromolecule dispersing agent; CN 152 (Sartomer) staple is the mono acrylic ester oligopolymer, and CN 2295 (Sartomer) staple is the polyester acrylic ester oligomer, is prepolymer;
819 (vapour Bagong department) staple is a bisacylphosphine oxide;
651 (vapour Bagong department) staple is the two ether of st-yrax;
907 (vapour Bagong department) staple is α-amido ketone, is initiator;
RAD 2100 (Di Gao chemical company) staple is an organic silicon acrylic ester, is reactive silicone acrylates class wetting agent.
Embodiment 1
UV photo-curing ink-jet ink, it comprises following component by weight percentage: 76% C.I. Pigment black, 1.5% silicon-dioxide, zinc oxide 0.5%, EFKA 4050 (vapour Bagong department) 6%, CN 2295 (Sartomer) 6%,
819 (vapour Bagong department) 3%, Irgacure651 (vapour Bagong department) 3%, TEGO
2100 (Di Gao chemical company) 1%, ethoxy ethoxy ethyl propylene acid esters 20%, propylene glycol diacrylate surplus.Said components is mixed in proportion after 0.22 micron membrane filtration can make UV photo-curing ink-jet ink.
Embodiment 2
UV photo-curing ink-jet ink, it comprises following component by weight percentage: the C.I. pigment Blue 15: 35%, silicon-dioxide 2%, EFKA 4800 (vapour Bagong department) 4%, CN 2295 (Sartomer) 6%,
819 (vapour Bagong department) 3%,
651 (vapour Bagong department) 3%,
RAD2100 (Di Gao chemical company) 1%, ethoxy ethoxy ethyl propylene acid esters 20%, propylene glycol diacrylate surplus.Said components is mixed in proportion after 0.22 micron membrane filtration can make UV photo-curing ink-jet ink.
Embodiment 3
UV photo-curing ink-jet ink, it comprises following component by weight percentage: C.I. pigment red 122 5%, silicon-dioxide 3%, EFKA 4800 (vapour Bagong department) 4%, CN 2295 (Sartomer) 6%,
819 (vapour Bagong department) 4%,
651 (vapour Bagong department) 2%, TEGO
2100 (Di Gao chemical company) 0.9%, ethoxy ethoxy ethyl propylene acid esters 20%, propylene glycol diacrylate surplus.Said components is mixed in proportion after 0.22 micron membrane filtration can make UV photo-curing ink-jet ink.
Embodiment 4
UV photo-curing ink-jet ink, it comprises following component by weight percentage: C.I. Pigment Yellow 73 1556%, silica 1 %, zinc oxide 2%, EFKA 4800 (vapour Bagong department) 4%, CN 2295 (Sartomer) 6%,
819 (vapour Bagong department) 3%,
651 (vapour Bagong department) 3%, TEGO
2100 (Di Gao chemical company) 0.8%, ethoxy ethoxy ethyl propylene acid esters 20%, propylene glycol diacrylate surplus.Said components is mixed in proportion after 0.22 micron membrane filtration can make UV photo-curing ink-jet ink.
Embodiment 5
UV photo-curing ink-jet ink, it comprises following component by weight percentage: the C.I. pigment Blue 15: 31%, silicon-dioxide 2%, EFKA 4050 (vapour Bagong department) 2%, CN 152 (Sartomer) 15%,
907 (vapour Bagong department) 2%,
184 (vapour Bagong department) 1%, TEGO
2100 (Di Gao chemical company) 0.5%, ethoxy ethoxy ethyl propylene acid esters 30%, propylene glycol diacrylate surplus.Said components is mixed in proportion after 0.22 micron membrane filtration can make UV photo-curing ink-jet ink.
Embodiment 6
UV photo-curing ink-jet ink, it comprises following component by weight percentage: C.I. pigment red 122 1.2%, zinc oxide 2%, EFKA 4800 (vapour Bagong department) 1%, CN 152 (Sartomer) 15%,
907 (vapour Bagong department) 2%,
184 (vapour Bagong department) 1%, TEGO
2100 (Di Gao chemical company) 0.5%, ethoxy ethoxy ethyl propylene acid esters 30%, propylene glycol diacrylate surplus.Said components is mixed in proportion after 0.22 micron membrane filtration can make UV photo-curing ink-jet ink.
Embodiment 7 (comparative example)
UV photo-curing ink-jet ink, it comprises following component by weight percentage: C.I. Pigment Yellow 73 1556%, EFKA 4800 (vapour Bagong department) 4%, CN 2295 (Sartomer) 6%,
819 (vapour Bagong department) 3%,
651 (vapour Bagong department) 3%, TEGO
2100 (Di Gao chemical company) 0.8%, ethoxy ethoxy ethyl propylene acid esters 20%, propylene glycol diacrylate surplus.Said components is mixed in proportion after 0.22 micron membrane filtration can make UV photo-curing ink-jet ink.
Embodiment 8 (comparative example)
UV photo-curing ink-jet ink, it comprises following component by weight percentage: the C.I. pigment Blue 15: 35%, silicon-dioxide 2%, EFKA 4800 (vapour Bagong department) 4%, CN 152 (Sartomer) 20%,
819 (vapour Bagong department) 3%,
651 (vapour Bagong department) 3%, TEGO
2100 (Di Gao chemical company) 1%, ethoxy ethoxy ethyl propylene acid esters 30%, propylene glycol diacrylate surplus.Said components is mixed in proportion after 0.22 micron membrane filtration can make UV photo-curing ink-jet ink.
The test of printing fluency:
The UV photo-curing ink-jet ink of case study on implementation 1-6 and embodiment 7-8 is respectively printed 5 square metres of monochromatic color lumps on rowland LED-330UV stamping machine, the printing test page or leaf is seen initial broken string situation; Room temperature condition is shut down after 7 days down, and the printing test page or leaf is seen the intermittent printing performance again.Print result such as following table:
Annotate: " ◎ " expression test sheets broken string is below 5, and fluency/intermittent printing performance is qualified.
" ● " expression test sheets breaks more than 5 fluency/intermittent printing performance inconsistency lattice.
The fastness test:
The UV photo-curing ink-jet ink of case study on implementation 1-6 and embodiment 7-8 is respectively printed monochromatic color lump on rowland LED-330UV stamping machine, after the LED irradiation is solidified, test color lumps cured film fastness.Test result such as following table:
Claims (9)
1. UV photo-curing ink-jet composition for ink is characterized in that: composed of the following components by weight percentage:
Nano-level pigment 1.0-6.0%;
Ultraviolet isolating agent 2-3%;
Dispersion agent 1.0-6.0%;
Prepolymer 5-15%;
Initiator 3-6%;
Wetting agent 0.5-1.0%;
The reactive monomer surplus;
Wherein, the D90＜200nm of nano-level pigment and ultraviolet isolating agent.
2. UV photo-curing ink-jet composition for ink according to claim 1 is characterized in that: said nano-level pigment is selected from C.I. Pigment black 7, C.I. pigment Blue 15: 3, at least a in C.I. pigment Green 7, C.I. pigment Orange 13, C.I. pigment red 122, C.I. pigment violet 19, C.I. Pigment Yellow 73 155, the C.I. Pigment white 6.
3. UV photo-curing ink-jet composition for ink according to claim 1 is characterized in that: said ultraviolet isolating agent is selected from least a in silicon-dioxide, the zinc oxide.
4. UV photo-curing ink-jet composition for ink according to claim 1 is characterized in that: said dispersion agent is the macromolecule polyacrylic acid dispersion agent.
5. UV photo-curing ink-jet composition for ink according to claim 1 is characterized in that: described prepolymer is mono acrylic ester performed polymer and/or polyester acrylate performed polymer.
6. UV photo-curing ink-jet composition for ink according to claim 1 is characterized in that: described initiator is one or more in bisacylphosphine oxide, st-yrax diethyl ether, the α-amido ketone.
7. UV photo-curing ink-jet composition for ink according to claim 1 is characterized in that: said wetting agent is reactive silicone acrylates.
8. UV photo-curing ink-jet composition for ink according to claim 1 is characterized in that: said reactive monomer is ethoxy ethoxy ethyl propylene acid esters, propylene glycol diacrylate.
9. UV photo-curing ink-jet composition for ink according to claim 1 is characterized in that: described ink jet ink composition is used for led light source solidified ink-jet printer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102964084A CN102391721A (en) | 2011-09-30 | 2011-09-30 | UV (ultraviolet) cured inkjet ink composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102964084A CN102391721A (en) | 2011-09-30 | 2011-09-30 | UV (ultraviolet) cured inkjet ink composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102391721A true CN102391721A (en) | 2012-03-28 |
Family
ID=45859110
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011102964084A Pending CN102391721A (en) | 2011-09-30 | 2011-09-30 | UV (ultraviolet) cured inkjet ink composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102391721A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104238198A (en) * | 2014-08-21 | 2014-12-24 | 京东方科技集团股份有限公司 | Display panel and fabrication method thereof |
| CN104479460A (en) * | 2014-12-25 | 2015-04-01 | 郑州鸿盛数码科技股份有限公司 | LED-UV-cured ink-jet ink for flexible substrate printing |
| CN105153810A (en) * | 2015-09-21 | 2015-12-16 | 珠海诚威电子有限公司 | Flexible LED-UV jet ink |
| CN107513309A (en) * | 2017-08-01 | 2017-12-26 | 珠海赛纳打印科技股份有限公司 | Three-dimensionally shaped photocuring transparent ink composition and its preparation method and application |
| CN110551420A (en) * | 2019-09-28 | 2019-12-10 | 河北经贸大学 | Water-based UV ink-jet ink and preparation method thereof |
| CN111114162A (en) * | 2020-01-19 | 2020-05-08 | 昆山美普森包装有限公司 | High-precision plate-free hot stamping process |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1296041A (en) * | 2000-11-30 | 2001-05-23 | 上海博纳科技发展有限公司 | Process for preparing nanometer zinc oxide |
| US20030021983A1 (en) * | 2000-10-02 | 2003-01-30 | Nohr Ronald S. | Recording medium with nanoparticles and methods of making the same |
| CN1613925A (en) * | 2004-09-22 | 2005-05-11 | 东华大学 | Ultraviolet light curing printing ink for digital printing and dyeing preparation thereof |
| CN101240129A (en) * | 2007-02-09 | 2008-08-13 | 上海中大科技发展有限公司 | Ink-jet ink composition used for photosensitive plate fabrication and fabricating method thereof |
-
2011
- 2011-09-30 CN CN2011102964084A patent/CN102391721A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030021983A1 (en) * | 2000-10-02 | 2003-01-30 | Nohr Ronald S. | Recording medium with nanoparticles and methods of making the same |
| CN1296041A (en) * | 2000-11-30 | 2001-05-23 | 上海博纳科技发展有限公司 | Process for preparing nanometer zinc oxide |
| CN1613925A (en) * | 2004-09-22 | 2005-05-11 | 东华大学 | Ultraviolet light curing printing ink for digital printing and dyeing preparation thereof |
| CN101240129A (en) * | 2007-02-09 | 2008-08-13 | 上海中大科技发展有限公司 | Ink-jet ink composition used for photosensitive plate fabrication and fabricating method thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104238198A (en) * | 2014-08-21 | 2014-12-24 | 京东方科技集团股份有限公司 | Display panel and fabrication method thereof |
| CN104479460A (en) * | 2014-12-25 | 2015-04-01 | 郑州鸿盛数码科技股份有限公司 | LED-UV-cured ink-jet ink for flexible substrate printing |
| CN105153810A (en) * | 2015-09-21 | 2015-12-16 | 珠海诚威电子有限公司 | Flexible LED-UV jet ink |
| CN107513309A (en) * | 2017-08-01 | 2017-12-26 | 珠海赛纳打印科技股份有限公司 | Three-dimensionally shaped photocuring transparent ink composition and its preparation method and application |
| CN107513309B (en) * | 2017-08-01 | 2018-10-30 | 珠海赛纳打印科技股份有限公司 | Three-dimensionally shaped photocuring transparent ink composition and its preparation method and application |
| EP3626789A4 (en) * | 2017-08-01 | 2021-02-24 | Zhuhai Sailner 3D Technology Co., Ltd. | Photocurable transparent ink composition for three-dimensional molding and preparation method and application thereof |
| CN110551420A (en) * | 2019-09-28 | 2019-12-10 | 河北经贸大学 | Water-based UV ink-jet ink and preparation method thereof |
| CN111114162A (en) * | 2020-01-19 | 2020-05-08 | 昆山美普森包装有限公司 | High-precision plate-free hot stamping process |
| CN111114162B (en) * | 2020-01-19 | 2021-07-09 | 昆山美普森包装有限公司 | High-precision plate-free hot stamping process |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US10767068B2 (en) | Photocurable inkjet printing ink composition | |
| CN109206980A (en) | A kind of UV ink-jet white ink | |
| CN102391721A (en) | UV (ultraviolet) cured inkjet ink composition | |
| CN107459871B (en) | 3D inkjet printings photocuring transparent ink and preparation method thereof | |
| CN102344716B (en) | Ink composition, ink set, ink jet recording method, printed matter, forming printed matter and manufacturing method of forming printed matter | |
| JP6560504B2 (en) | Photocurable ink composition for ink jet printing | |
| CN101921511B (en) | Ink composition for ink-jet printing | |
| CN102459479A (en) | Photocurable ink composition for inkjet printing, and printed material | |
| CN103642318B (en) | Boiling-resistant UV (Ultraviolet) curing jet-ink for non-absorbent substrate and preparation method of jet-ink | |
| US20160340529A1 (en) | Radiation curable inks and coatings containing diacetone acrylamide | |
| JP5084485B2 (en) | Inkjet yellow ink, inkjet coloring method and colored product | |
| CN104497707A (en) | LED-UV curing white inkjet ink applicable to piezoelectric inkjet printer | |
| CN104937049A (en) | Inkjet ink composition, inkjet recording method, printed matter and method of producing formed printed matter | |
| JP2009052030A (en) | Ink set for ink jet, ink jet coloring process and colored product for outdoor | |
| CN104479460A (en) | LED-UV-cured ink-jet ink for flexible substrate printing | |
| EP3626789B1 (en) | Photocurable transparent ink composition for three-dimensional molding and preparation method and application thereof | |
| CN102381023A (en) | Ink-jet recording method, printed matter, molded printed matter manufacturing method and molded printed matter | |
| JP2019031618A (en) | Ink composition for active energy ray-curable inkjet printing | |
| EP2703460B1 (en) | Inkjet ink composition and method for producing the same, inkjet recording method, pigment dispersion for inkjet ink and method for producing the same | |
| CN103391979A (en) | Ink composition, image forming method and printed material | |
| JP2018024757A (en) | Photocurable clear ink composition for inkjet printing | |
| CN103602142B (en) | Ultra-violet curing transfer ink | |
| CN109517433A (en) | High covering UV ink that can be recoated and its preparation method and application | |
| JP2010018739A (en) | Pigment dispersion, and ink composition using the same | |
| CN101709181B (en) | UV curable ink for large inkjet printer and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20120328 |