CN102391621B - 一种无卤阻燃tpee热塑性弹性体及其制备方法 - Google Patents
一种无卤阻燃tpee热塑性弹性体及其制备方法 Download PDFInfo
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- CN102391621B CN102391621B CN201110256453A CN201110256453A CN102391621B CN 102391621 B CN102391621 B CN 102391621B CN 201110256453 A CN201110256453 A CN 201110256453A CN 201110256453 A CN201110256453 A CN 201110256453A CN 102391621 B CN102391621 B CN 102391621B
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- tpee
- districts
- halogen
- retardant
- thermoplastic elastomer
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Links
- 229920006346 thermoplastic polyester elastomer Polymers 0.000 title claims abstract description 113
- 239000003063 flame retardant Substances 0.000 title claims abstract description 49
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 22
- 239000012802 nanoclay Substances 0.000 claims abstract description 41
- 238000000034 method Methods 0.000 claims abstract description 26
- 239000002608 ionic liquid Substances 0.000 claims abstract description 22
- 239000002994 raw material Substances 0.000 claims abstract description 14
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 14
- -1 polypropylene Polymers 0.000 claims abstract description 10
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 8
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims abstract description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 39
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 38
- 239000001913 cellulose Substances 0.000 claims description 34
- 229920002678 cellulose Polymers 0.000 claims description 34
- 238000002156 mixing Methods 0.000 claims description 33
- 230000004048 modification Effects 0.000 claims description 32
- 238000012986 modification Methods 0.000 claims description 32
- 239000007788 liquid Substances 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 27
- 238000003756 stirring Methods 0.000 claims description 26
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Natural products C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 25
- 239000012752 auxiliary agent Substances 0.000 claims description 15
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 13
- 230000021736 acetylation Effects 0.000 claims description 13
- 238000006640 acetylation reaction Methods 0.000 claims description 13
- 238000002203 pretreatment Methods 0.000 claims description 11
- 238000001291 vacuum drying Methods 0.000 claims description 11
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 10
- 239000000460 chlorine Substances 0.000 claims description 10
- 229910052801 chlorine Inorganic materials 0.000 claims description 10
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims description 10
- 239000003112 inhibitor Substances 0.000 claims description 10
- ILWRPSCZWQJDMK-UHFFFAOYSA-N triethylazanium;chloride Chemical compound Cl.CCN(CC)CC ILWRPSCZWQJDMK-UHFFFAOYSA-N 0.000 claims description 10
- 239000000314 lubricant Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- FGYHQFZISBDLDR-UHFFFAOYSA-N OCCC[PH2]=O Chemical compound OCCC[PH2]=O FGYHQFZISBDLDR-UHFFFAOYSA-N 0.000 claims description 5
- FIQMHBFVRAXMOP-UHFFFAOYSA-N triphenylphosphane oxide Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(=O)C1=CC=CC=C1 FIQMHBFVRAXMOP-UHFFFAOYSA-N 0.000 claims description 5
- 150000002500 ions Chemical class 0.000 claims description 4
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 claims description 2
- 238000005469 granulation Methods 0.000 claims description 2
- 230000003179 granulation Effects 0.000 claims description 2
- 238000000967 suction filtration Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 35
- 150000002148 esters Chemical class 0.000 abstract description 11
- 239000004743 Polypropylene Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 229920001155 polypropylene Polymers 0.000 abstract 2
- 229920000877 Melamine resin Polymers 0.000 abstract 1
- 229920002301 cellulose acetate Polymers 0.000 abstract 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 28
- 230000014759 maintenance of location Effects 0.000 description 18
- 238000005453 pelletization Methods 0.000 description 18
- 238000012360 testing method Methods 0.000 description 18
- 239000004721 Polyphenylene oxide Substances 0.000 description 14
- 239000002131 composite material Substances 0.000 description 12
- 238000005516 engineering process Methods 0.000 description 11
- 238000011161 development Methods 0.000 description 10
- 239000000779 smoke Substances 0.000 description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
- 239000004927 clay Substances 0.000 description 9
- 238000001816 cooling Methods 0.000 description 9
- 239000001301 oxygen Substances 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 9
- 230000000630 rising effect Effects 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 150000003008 phosphonic acid esters Chemical class 0.000 description 3
- 229920001707 polybutylene terephthalate Polymers 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- BJZYYSAMLOBSDY-QMMMGPOBSA-N (2s)-2-butoxybutan-1-ol Chemical compound CCCCO[C@@H](CC)CO BJZYYSAMLOBSDY-QMMMGPOBSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001449 anionic compounds Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000012620 biological material Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000001457 metallic cations Chemical class 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110256453A CN102391621B (zh) | 2011-08-31 | 2011-08-31 | 一种无卤阻燃tpee热塑性弹性体及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110256453A CN102391621B (zh) | 2011-08-31 | 2011-08-31 | 一种无卤阻燃tpee热塑性弹性体及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN102391621A CN102391621A (zh) | 2012-03-28 |
CN102391621B true CN102391621B (zh) | 2012-10-24 |
Family
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Family Applications (1)
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CN201110256453A Active CN102391621B (zh) | 2011-08-31 | 2011-08-31 | 一种无卤阻燃tpee热塑性弹性体及其制备方法 |
Country Status (1)
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CN (1) | CN102391621B (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103613913B (zh) * | 2013-11-13 | 2016-01-20 | 华东理工大学 | 一种无卤阻燃热塑性聚酯弹性体材料及其制备方法 |
CN103642178B (zh) * | 2013-12-02 | 2017-03-15 | 合肥安聚达新材料科技有限公司 | 一种无卤阻燃热塑性聚酯弹性体纳米复合材料及其制备方法 |
CN104045982A (zh) * | 2014-06-26 | 2014-09-17 | 五行材料科技(江苏)有限公司 | 一种耐热母料及高耐热的无卤阻燃弹性体及其制备方法 |
CN113337083A (zh) * | 2021-05-25 | 2021-09-03 | 苏州润佳高分子材料有限公司 | 汽车仪表板蒙皮用软胶材料 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5502095A (en) * | 1992-11-06 | 1996-03-26 | Japan Synthetic Rubber Co., Ltd. | Thermoplastic elastomer composition |
EP1882717A1 (en) * | 2006-07-28 | 2008-01-30 | DSMIP Assets B.V. | Toughened halogen free flame retardant polyester composition |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101154462B1 (ko) * | 2007-12-20 | 2012-06-13 | 주식회사 엘지화학 | 비할로겐 난연 열가소성 폴리에스테르 엘라스토머 복합수지조성물 |
-
2011
- 2011-08-31 CN CN201110256453A patent/CN102391621B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5502095A (en) * | 1992-11-06 | 1996-03-26 | Japan Synthetic Rubber Co., Ltd. | Thermoplastic elastomer composition |
EP1882717A1 (en) * | 2006-07-28 | 2008-01-30 | DSMIP Assets B.V. | Toughened halogen free flame retardant polyester composition |
Also Published As
Publication number | Publication date |
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CN102391621A (zh) | 2012-03-28 |
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SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee | ||
CP01 | Change in the name or title of a patent holder |
Address after: 225500, Ma 986 Road, Jiangyan Economic Development Zone, Jiangsu, Taizhou, China Patentee after: 5ELEM HI-TECH Corp. Address before: 225500, Ma 986 Road, Jiangyan Economic Development Zone, Jiangsu, Taizhou, China Patentee before: 5ELEM MATERIAL SCIENTIFIC (JIANGSU) Co.,Ltd. |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Halogen free flame retardant TPEE thermoplastic elastomer and its preparation method Effective date of registration: 20210401 Granted publication date: 20121024 Pledgee: Jiangyan Jiangsu rural commercial bank Limited by Share Ltd. Pledgor: 5ELEM HI-TECH Corp. Registration number: Y2021980002332 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20121024 Pledgee: Jiangyan Jiangsu rural commercial bank Limited by Share Ltd. Pledgor: 5ELEM HI-TECH Corp. Registration number: Y2021980002332 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A halogen-free flame retardant TPEE thermoplastic elastomer and its preparation method Granted publication date: 20121024 Pledgee: Jiangyan Jiangsu rural commercial bank Limited by Share Ltd. Pledgor: 5ELEM HI-TECH Corp. Registration number: Y2024320000056 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |