CN102389693A - Waste gas treatment device applied to ultrapure ammonia extraction process - Google Patents
Waste gas treatment device applied to ultrapure ammonia extraction process Download PDFInfo
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- CN102389693A CN102389693A CN201110309437XA CN201110309437A CN102389693A CN 102389693 A CN102389693 A CN 102389693A CN 201110309437X A CN201110309437X A CN 201110309437XA CN 201110309437 A CN201110309437 A CN 201110309437A CN 102389693 A CN102389693 A CN 102389693A
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- ammonia
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- extraction process
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- hydrogen purifier
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Treating Waste Gases (AREA)
Abstract
The invention discloses a waste gas treatment device applied to an ultrapure ammonia extraction process, which comprises an ammonia decomposition furnace, a hydrogen purifier and a tail gas elution tower, wherein the output of a condenser at the top of a rectifying tower is connected to the ammonia decomposition furnace, the output of the ammonia decomposition furnace is connected to the hydrogen purifier, and the output of the hydrogen purifier is connected to the tail gas elution tower. The waste gas treatment device disclosed by the invention is simple in structure and convenient to use; and by using the waste gas treatment device, by-products generated in waste gas treatment are changed, the resource consumption generated in waste gas treatment is reduced, the influence on environments is reduced, and the economic benefit arising from the ultrapure ammonia extraction process is improved.
Description
Technical field
The present invention relates to environmental protection industry (epi), is the corollary equipment in the ultra-pure ammonia extraction process, the emission-control equipment in particularly a kind of ultra-pure ammonia extraction process.
Background technology
Prepare in the process in existing ultra-pure ammonia, can produce the useless ammonia of more gas in the rectifying column, and the emission-control equipment great majority all are waste gas eluting column or aeration tower.The weak solution that these emission-control equipments all need use acidic materials such as sulfuric acid is as the spray agent, with in waste gas in ammonia, thereby reach standard to airborne release.In this course, need the acid and the water of labor, the accessory substance ammonium sulfate of generation also needs further to handle, and therefore, these emission-control equipments have not in the past caught up with strict day by day environmental protection and energy-conservation requirement.
Summary of the invention
Problem to be solved by this invention just provides the emission-control equipment in a kind of ultra-pure ammonia extraction process; Simple in structure; Easy to use, change the accessory substance that exhaust-gas treatment produces, reduce the resource consumption in the exhaust-gas treatment; Minimizing improves the economic benefit that the ultra-pure ammonia extraction process is brought to the influence of environment.
In order to solve the problems of the technologies described above; The present invention adopts following technical scheme: the emission-control equipment in a kind of ultra-pure ammonia extraction process; It is characterized in that: comprise ammonia destruction furnace, hydrogen purifier and tail gas eluting column; The output of rectifying column overhead condenser is connected to ammonia destruction furnace, and ammonia destruction furnace output is connected to hydrogen purifier, and hydrogen purifier output is connected in the tail gas eluting column.
Further, the output of the top, rear end of said rectifying column overhead condenser is connected on the ammonia destruction furnace.
Further, the output of the furnace roof of said ammonia destruction furnace is connected to the hydrogen purifier front end.
Further, the output of the front top of said hydrogen purifier is connected in the tail gas eluting column.
Further, said hydrogen purifier is a palladium film purifier.
Further, the rear end of said hydrogen purifier also is connected to hydrogen-holder.The accessory substance ultra-pure hydrogen is stored utilization.
After adopting technique scheme, the present invention has following advantage: do not use acid solution can obtain helping the ultra-pure hydrogen product of the environment and the energy, all there is considerable influence environmental protection aspect and economic benefit aspect; Simultaneously all the other tail gas are environment to be pollution-free type light-component gas, can to pass through high altitude discharge, not only environmental protection but also simple.
Description of drawings
Below in conjunction with accompanying drawing the present invention is described further:
Fig. 1 is the structural representation of an embodiment of the present invention.
The specific embodiment
The structural representation of an embodiment of the present invention as shown in Figure 1; Emission-control equipment in a kind of ultra-pure ammonia extraction process; Comprise ammonia destruction furnace 1, hydrogen purifier 2 and tail gas eluting column 3; 41 outputs of rectifying column 4 overhead condensers are connected to ammonia destruction furnace, and ammonia destruction furnace output is connected to hydrogen purifier, and hydrogen purifier output is connected in the tail gas eluting column.In the present embodiment, the top, rear end of rectifying column overhead condenser output is connected on the ammonia destruction furnace, and uncooled gas in the condenser is transported in the ammonia destruction furnace, and the ammonia of remnants is decomposed into nitrogen and hydrogen; The furnace roof output of ammonia destruction furnace is connected to the hydrogen purifier front end, behind the hydrogen purifier purifying, obtains high-purity hydrogen; The front top output of hydrogen purifier is connected in the tail gas eluting column; Fail the gas through hydrogen purifier at the inlet end of hydrogen purifier; Be transported to and carry out drip washing in the tail gas eluting column; Thoroughly remove the ammonia of trace, make it not get into atmosphere, thereby realize zero emission intensity in the ultra-pure ammonia extraction process.
In the foregoing description, said hydrogen purifier is a palladium film purifier; The rear end of hydrogen purifier also is connected to hydrogen-holder 5, stores the accessory substance ultra-pure hydrogen and utilizes.
The present invention adopts ammonia destruction furnace that the light component impurity of rectifying column discharging is carried out the waste gas decomposition, and wherein most ammonia is decomposed into nitrogen and hydrogen, and catabolite is further purified through palladium film purifier, obtains the ultra-pure hydrogen product as byproduct; It is pollution-free type light-component gas that all the other tail gas are environment, can pass through high altitude discharge emptying.Ultra-pure hydrogen is a kind of energy resources of high-quality, is used widely in current society.Therefore, than the accessory substance ammonium sulfate of traditional eluting column device, no matter accessory substance ultra-pure hydrogen of the present invention is from the environment aspect, or the economic benefit aspect, all considerably beyond traditional emission-control equipment.
Except that above-mentioned preferred embodiment, the present invention also has other embodiment, and those skilled in the art can make various changes and distortion according to the present invention, only otherwise break away from spirit of the present invention, all should belong to the defined scope of accompanying claims of the present invention.
Claims (6)
1. the emission-control equipment in the ultra-pure ammonia extraction process; It is characterized in that: comprise ammonia destruction furnace (1), hydrogen purifier (2) and tail gas eluting column (3); Rectifying column (4) overhead condenser (41) output is connected to ammonia destruction furnace; Ammonia destruction furnace output is connected to hydrogen purifier, and hydrogen purifier output is connected in the tail gas eluting column.
2. the emission-control equipment in a kind of ultra-pure ammonia extraction process according to claim 1 is characterized in that: top, the rear end output of said rectifying column overhead condenser is connected on the ammonia destruction furnace.
3. the emission-control equipment in a kind of ultra-pure ammonia extraction process according to claim 1 is characterized in that: the furnace roof output of said ammonia destruction furnace is connected to the hydrogen purifier front end.
4. the emission-control equipment in a kind of ultra-pure ammonia extraction process according to claim 1 is characterized in that: the front top output of said hydrogen purifier is connected in the tail gas eluting column.
5. according to the emission-control equipment in claim 1 or the 4 described a kind of ultra-pure ammonia extraction processes, it is characterized in that: said hydrogen purifier is a palladium film purifier.
6. according to the emission-control equipment in claim 1 or the 4 described a kind of ultra-pure ammonia extraction processes, it is characterized in that: the rear end of said hydrogen purifier also is connected to hydrogen-holder (5).
Priority Applications (1)
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CN201110309437XA CN102389693A (en) | 2011-10-13 | 2011-10-13 | Waste gas treatment device applied to ultrapure ammonia extraction process |
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CN201110309437XA CN102389693A (en) | 2011-10-13 | 2011-10-13 | Waste gas treatment device applied to ultrapure ammonia extraction process |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106268238A (en) * | 2016-10-20 | 2017-01-04 | 湖南野森环保科技有限责任公司 | A kind of multipurpose industrial waste gas purifying processing means |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1256961A (en) * | 1998-12-14 | 2000-06-21 | 日本派欧尼股份株式会社 | Process and apparatus for purefying waste gas |
WO2004018353A1 (en) * | 2002-08-23 | 2004-03-04 | The Boc Group Plc | Utilisation of waste gas streams |
CN1704336A (en) * | 2004-05-28 | 2005-12-07 | 大连保税区科利德化工科技开发有限公司 | Method and apparatus for purification treatment of ammonia |
CN202336285U (en) * | 2011-10-13 | 2012-07-18 | 周平 | Waste gas treatment device for ultra pure ammonia extraction process |
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2011
- 2011-10-13 CN CN201110309437XA patent/CN102389693A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1256961A (en) * | 1998-12-14 | 2000-06-21 | 日本派欧尼股份株式会社 | Process and apparatus for purefying waste gas |
US6331281B1 (en) * | 1998-12-14 | 2001-12-18 | Japan Pionics Co., Ltd. | Process and apparatus for cleaning exhaust gas |
WO2004018353A1 (en) * | 2002-08-23 | 2004-03-04 | The Boc Group Plc | Utilisation of waste gas streams |
CN1704336A (en) * | 2004-05-28 | 2005-12-07 | 大连保税区科利德化工科技开发有限公司 | Method and apparatus for purification treatment of ammonia |
CN202336285U (en) * | 2011-10-13 | 2012-07-18 | 周平 | Waste gas treatment device for ultra pure ammonia extraction process |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106268238A (en) * | 2016-10-20 | 2017-01-04 | 湖南野森环保科技有限责任公司 | A kind of multipurpose industrial waste gas purifying processing means |
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Application publication date: 20120328 |