CN102382350A - High density polyethylane bamboo plastic composite tubing and preparation method thereof - Google Patents
High density polyethylane bamboo plastic composite tubing and preparation method thereof Download PDFInfo
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- CN102382350A CN102382350A CN2011103025350A CN201110302535A CN102382350A CN 102382350 A CN102382350 A CN 102382350A CN 2011103025350 A CN2011103025350 A CN 2011103025350A CN 201110302535 A CN201110302535 A CN 201110302535A CN 102382350 A CN102382350 A CN 102382350A
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- bamboo
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- hdpe
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- density polyethylene
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
Abstract
The invention relates to a high density polyethylane bamboo plastic composite tubing, comprising 100 parts of high density polyethylene, 30-50 parts of bamboo powder, 3-8 parts of solubilizer, 5-15 parts of filler, 1-5 parts of fire retardant and 1-5 parts of lubricant. The method comprises the following steps: pretreating bamboo powder; putting each component according to mass ratio into a high speed mixer and carrying out a first mixing for 3-5 min; mixing and stirring uniformly; extruding and granulating the material after the first mixing in a double screw extruder with a temperature controlled at 200-210 DEG C; finally putting dried mixture into a tubing extruder and extruding the high density polyethylane bamboo plastic composite tubing. The invention has simple technology and convenient operation; and prepared material has excellent performances of high modulus, high strength and high dimension stability, etc.
Description
Technical field
The present invention relates to a kind of composite pipe, being specifically related to is a kind of high density polyethylene(HDPE) plastic-bamboo composite tube and preparation method.
Background technology
A kind of type material that different processing modes such as bamboo-plastic composite material is to be raw material with bamboo wood and plastics, adds modified additives such as coupling agent, and is compound through hot pressing, as to melt extrude are processed.This material can be given full play to the advantage of each component, overcomes use limitation low because of bamboo wood intensity, that variability is big etc. causes, can overcome organic materials low elastic modulus etc. again and use defective.And can improve the physical and mechanical property and the processing characteristics of material, and reduce cost, and enlarge its range of application, improve the added value of material.Door and window, template, floor, furred ceiling and the roof boarding of building field have been widely used at present, the carrying backing plate and the pallet of packaging field, the railroad sleeper of field of traffic and the noise baffle of motorway etc.
Bamboo fibers is inexpensive, be easy to get and have certain intensity, can be used as toughener and improves polyolefinic mechanical property and reduce production costs.In addition, bamboo fibers has biological degradability as the natural reproducible material, is a kind of novel material of " white pollution " at present that alleviates.Disclosing " working method of bamboo wood material and the bamboo molding product that uses this method to make " in the prior art, is that bamboo processing is become wood powder, puts in the mixing roll; Add acvator, and UPVC or PVC and various auxiliary agent, mixing once more; Granulation, surface treatment is carried out in moulding at last.But prior art is because easily suction, and the characteristic that polarity is also very strong makes that its consistency with plastics is very poor, and processing technology is had relatively high expectations, and the machine-shaping device of bamboo moulding material is required height.
Summary of the invention
The technical problem that the present invention mainly solves provides a kind of high density polyethylene(HDPE) plastic-bamboo composite tube and preparation method; This preparing method's technology is simple; Easy to operate, and this high density polyethylene(HDPE) plastic-bamboo composite tube has premium propertiess such as high-modulus, HS, high-dimensional stability.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: a kind of high density polyethylene(HDPE) plastic-bamboo composite tube, and this plastic-bamboo composite tube raw material is formed proportioning and is comprised:
100 parts of high density polyethylene(HDPE)s,
Bamboo powder 30-50 part,
Solubilizing agent 3-8 part,
Weighting agent 5-15 part,
Fire retardant 1-5 part,
Lubricant 1-5 part.
In preferred embodiment of the present invention, this bamboo-plastic composite material raw material is formed proportioning and is comprised:
100 parts of high density polyethylene(HDPE)s,
Bamboo powder 35-45 part,
Solubilizing agent 3-5 part,
Weighting agent 10-15 part,
Fire retardant 2-3 part,
Lubricant 2-3 part.
In preferred embodiment of the present invention, this bamboo-plastic composite material raw material is formed proportioning and is comprised:
100 parts of high density polyethylene(HDPE)s,
40 parts in bamboo powder,
4 parts of solubilizing agent,
12 parts of weighting agents,
2.5 parts of fire retardants,
2.5 parts of lubricants.
In preferred embodiment of the present invention, described solubilizing agent is a kind of in toxilic acid modified poly ethylene, ethylene-acrylic acid copolymer or the Injecatable EVA Copolymer.
In preferred embodiment of the present invention, described weighting agent is acicular wollastonite.
In preferred embodiment of the present invention, described fire retardant is that zinc borate and clorafin are according to 1; The powder that 1 mass ratio mixes.
In preferred embodiment of the present invention, described lubricant is one or more of paraffin, glycerine or hard ester acid.
The invention also discloses a kind of preparation method of high density polyethylene(HDPE) plastic-bamboo composite tube, this method comprises the steps:
(1) pre-treatment of bamboo powder: bamboo powder is broken into granularity less than 1.2mm bamboo particle; Then the bamboo particle is flooded 4-6min in anti-mould and moth-proof agent; Again with above-mentioned bamboo particle after handling through anti-mould and anti-moth dry to water ratio be 2-4%, exsiccant bamboo particle, spray water-resisting agent on the finally dried bamboo particle; Bamboo particle after must handling, the consumption of water-resisting agent are the 0.2-0.5% of exsiccant bamboo particle weight;
(2) press ratio of quality and the number of copies each component is dropped into just mixed 3-5min in the high-speed mixer, mixing and stirring will be passed through the material extruding pelletization that just mixes in twin screw extruder, and temperature is controlled at 200-210 ℃;
(3) compound that will dry is put in the pipe extruder, extrude the high density polyethylene(HDPE) plastic-bamboo composite tube.
In preferred embodiment of the present invention, said each section of pipe extruder of step (3) temperature is that one section temperature is 95-100 ℃, and two sections temperature are 175-180 ℃, and three sections temperature are 180-185 ℃, and four sections temperature are 195-200 ℃, and engine speed is 50r/min.
The invention has the beneficial effects as follows:
1, the present invention carries out blend with auxiliary agents such as bamboo powder and coupling agent, expanding material and high density polyethylene(HDPE) and acicular wollastonite; Then through double-screw extruding pelletizing; Utilize the granulation material to extrude and increase firm plastic-bamboo composite tube; The purer HDPE tubing of this composite pipe intensity and rigidity significantly improves, tubing linear shrinkage, over-all propertieies such as tensile strength are significantly increased.
2, the present invention has enlarged the Application Areas of plastic-bamboo composite tube, can apply to be expected to be used for municipal administration and bury fields such as ground draining, blowdown.
3, improve the comprehensive utilization ratio of discarded bamboo powder resource, reduction is dealt with the harm that environment is caused improperly because of discarded bamboo powder resource and has been opened up new way.
Embodiment
A kind of high density polyethylene(HDPE) plastic-bamboo composite tube, this plastic-bamboo composite tube raw material is formed proportioning and is comprised:
100 parts of high density polyethylene(HDPE)s,
30 parts-50 parts in bamboo powder,
Solubilizing agent 3-8 part,
Weighting agent 5-15 part,
Fire retardant 1-5 part,
Lubricant 1-5 part.
Wherein, described solubilizing agent is a kind of in toxilic acid modified poly ethylene, ethylene-acrylic acid copolymer or the Injecatable EVA Copolymer; Described weighting agent is acicular wollastonite; Described fire retardant is that zinc borate and clorafin are according to 1; The powder that 1 mass ratio mixes; Described lubricant is one or more of paraffin, glycerine or hard ester acid.
A kind of preparation method of high density polyethylene(HDPE) plastic-bamboo composite tube, this method comprises the steps:
(1) pre-treatment of bamboo powder: bamboo powder is broken into granularity less than 1.2mm bamboo particle; Then the bamboo particle is flooded 4-6min in anti-mould and moth-proof agent; Again with above-mentioned bamboo particle after handling through anti-mould and anti-moth dry to water ratio be 2-4%, exsiccant bamboo particle, spray water-resisting agent on the finally dried bamboo particle; Bamboo particle after must handling, the consumption of water-resisting agent are the 0.2-0.5% of exsiccant bamboo particle weight;
(2) press ratio of quality and the number of copies each component is dropped into just mixed 3-5min in the high-speed mixer, mixing and stirring will be passed through the material extruding pelletization that just mixes in twin screw extruder, and temperature is controlled at 200-210 ℃;
(3) compound that will dry is put in the pipe extruder, extrude high density polyethylene(HDPE) wood plastic composite material products.
Said each section of pipe extruder of step (3) temperature is that one section temperature is 95-100 ℃, and two sections temperature are 175-180 ℃, and three sections temperature are 180-185 ℃, and four sections temperature are 195-200 ℃, and engine speed is 50r/min.
The knot preferred embodiment is done further detailed explanation to the present invention now.
Embodiment 1
100 parts of high density polyethylene(HDPE)s, 30 parts in bamboo powder, 3 parts of maleic anhydride modified Vilaterm, 15 parts of acicular wollastonites, 2.5 parts of zinc borates, 2.5 parts of clorafins, 5 parts in paraffin.
Making method is: bamboo powder is broken into granularity less than 1.2mm bamboo particle; Then the bamboo particle is flooded 4-6min in anti-mould and moth-proof agent; Again with above-mentioned bamboo particle after handling through anti-mould and anti-moth dry to water ratio be 2-4%, exsiccant bamboo particle, spray water-resisting agent on the finally dried bamboo particle; Bamboo particle after must handling, the consumption of water-resisting agent are the 0.2-0.5% of exsiccant bamboo particle weight; Press ratio of quality and the number of copies each component is dropped into just mixed 3min in the high-speed mixer, mixing and stirring will be passed through the material extruding pelletization that just mixes in twin screw extruder, and temperature is controlled at 200 ℃; The compound of having dried is put in the pipe extruder, and each section of pipe extruder temperature is that one section temperature is 95 ℃, and two sections temperature are 175 ℃, and three sections temperature are 180 ℃, and four sections temperature are 195 ℃, and engine speed is 50r/min.Extrude high density polyethylene(HDPE) plastic-bamboo composite tube goods 1.
Embodiment 2
100 parts of high density polyethylene(HDPE)s, 35 parts in bamboo powder, 4 parts of ethylene-acrylic acid copolymers, 8 parts of acicular wollastonites, 1 part of zinc borate, 1 part of clorafin, 2 parts of glycerine.
Making method is: bamboo powder is broken into granularity less than 1.2mm bamboo particle; Then the bamboo particle is flooded 4-6min in anti-mould and moth-proof agent; Again with above-mentioned bamboo particle after handling through anti-mould and anti-moth dry to water ratio be 2-4%, exsiccant bamboo particle, spray water-resisting agent on the finally dried bamboo particle; Bamboo particle after must handling, the consumption of water-resisting agent are the 0.2-0.5% of exsiccant bamboo particle weight; Press ratio of quality and the number of copies each component is dropped into just mixed 3-5min in the high-speed mixer, mixing and stirring will be passed through the material extruding pelletization that just mixes in twin screw extruder, and temperature is controlled at 200 ℃; The compound of having dried is put in the pipe extruder, and each section of pipe extruder temperature is that one section temperature is 95 ℃, and two sections temperature are 175 ℃, and three sections temperature are 180 ℃, and four sections temperature are 195 ℃, and engine speed is 50r/min.Extrude high density polyethylene(HDPE) plastic-bamboo composite tube goods 2.
Embodiment 3
100 parts of high density polyethylene(HDPE)s, 40 parts in bamboo powder, 4 parts of ethylene-acrylic acid copolymers, 12 parts of acicular wollastonites, 1.25 parts of zinc borates, 1.25 parts of clorafins, 2.5 parts of glycerine.
Making method is: bamboo powder is broken into granularity less than 1.2mm bamboo particle; Then the bamboo particle is flooded 4-6min in anti-mould and moth-proof agent; Again with above-mentioned bamboo particle after handling through anti-mould and anti-moth dry to water ratio be 2-4%, exsiccant bamboo particle, spray water-resisting agent on the finally dried bamboo particle; Bamboo particle after must handling, the consumption of water-resisting agent are the 0.2-0.5% of exsiccant bamboo particle weight; Press ratio of quality and the number of copies each component is dropped into just mixed 3-5min in the high-speed mixer, mixing and stirring will be passed through the material extruding pelletization that just mixes in twin screw extruder, and temperature is controlled at 210 ℃; The compound of having dried is put in the pipe extruder, and each section of pipe extruder temperature is that one section temperature is 100 ℃, and two sections temperature are 180 ℃, and three sections temperature are 185 ℃, and four sections temperature are 200 ℃, and engine speed is 50r/min.Extrude high density polyethylene(HDPE) plastic-bamboo composite tube goods 3.
Embodiment 4
100 parts of high density polyethylene(HDPE)s, 50 parts in bamboo powder, 8 parts of ethylene-acrylic acid copolymers, 5 parts of acicular wollastonites, 0.5 part of zinc borate, 0.5 part of clorafin, 1 part of hard ester acid.
Making method is: bamboo powder is broken into granularity less than 1.2mm bamboo particle; Then the bamboo particle is flooded 4-6min in anti-mould and moth-proof agent; Again with above-mentioned bamboo particle after handling through anti-mould and anti-moth dry to water ratio be 2-4%, exsiccant bamboo particle, spray water-resisting agent on the finally dried bamboo particle; Bamboo particle after must handling, the consumption of water-resisting agent are the 0.2-0.5% of exsiccant bamboo particle weight; Press ratio of quality and the number of copies each component is dropped into just mixed 3-5min in the high-speed mixer, mixing and stirring will be passed through the material extruding pelletization that just mixes in twin screw extruder, and temperature is controlled at 210 ℃; The compound of having dried is put in the pipe extruder, and each section of pipe extruder temperature is that one section temperature is 100 ℃, and two sections temperature are 180 ℃, and three sections temperature are 185 ℃, and four sections temperature are 200 ℃, and engine speed is 50r/min.Extrude high density polyethylene(HDPE) plastic-bamboo composite tube goods 4.
Table 1 is the comprehensive physicals of embodiment 1-4 middle-high density Vilaterm wood plastic composite material products:
| The finished product classification | Tensile strength (MPa) | Linear shrinkage (%) | Shock strength (KJ/m2) | Modulus in flexure (MPa) | Linear expansivity (10/ ℃) |
| Embodiment 1 | 28.5 | 1.82 | 19.5 | 1386 | 1.39 |
| Embodiment 2 | 29.6 | 1.89 | 18.4 | 1379 | 1.40 |
| Embodiment 3 | 29.4 | 1.71 | 18.6 | 1384 | 1.32 |
| Embodiment 4 | 28.7 | 1.78 | 20.5 | 1421 | 1.45 |
This shows; The present invention carries out blend with auxiliary agents such as bamboo powder and coupling agent, expanding material and high density polyethylene(HDPE) and acicular wollastonite; Through double-screw extruding pelletizing, utilize the granulation material to extrude and increase firm plastic-bamboo composite tube then, the purer HDPE tubing of this composite pipe intensity and rigidity significantly improves; Tubing linear shrinkage, over-all propertieies such as tensile strength are significantly increased.
The present invention has enlarged the Application Areas of plastic-bamboo composite tube, can apply to be expected to be used for municipal administration and bury fields such as ground draining, blowdown.
The present invention improves the comprehensive utilization ratio of discarded bamboo powder resource, and reduction is dealt with the harm that environment is caused improperly because of discarded bamboo powder resource and opened up new way.
With above-mentioned foundation desirable embodiment of the present invention is enlightenment, and through above-mentioned description, the related work personnel can carry out various change and modification fully in the scope that does not depart from this invention technological thought.The technical scope of this invention is not limited to the content on the specification sheets, must confirm its technical scope according to the claim scope.
Claims (9)
1. a high density polyethylene(HDPE) plastic-bamboo composite tube is characterized in that, this plastic-bamboo composite tube raw material is formed proportioning and comprised:
100 parts of high density polyethylene(HDPE)s,
Bamboo powder 30-50 part,
Solubilizing agent 3-8 part,
Weighting agent 5-15 part,
Fire retardant 1-5 part,
Lubricant 1-5 part.
2. high density polyethylene(HDPE) plastic-bamboo composite tube according to claim 1 is characterized in that, this bamboo-plastic composite material raw material is formed proportioning and comprised:
100 parts of high density polyethylene(HDPE)s,
Bamboo powder 35-45 part,
Solubilizing agent 3-5 part,
Weighting agent 10-15 part,
Fire retardant 2-3 part,
Lubricant 2-3 part.
3. high density polyethylene(HDPE) plastic-bamboo composite tube according to claim 2 is characterized in that, this bamboo-plastic composite material raw material is formed proportioning and comprised:
100 parts of high density polyethylene(HDPE)s,
40 parts in bamboo powder,
4 parts of solubilizing agent,
12 parts of weighting agents,
2.5 parts of fire retardants,
2.5 parts of lubricants.
4. high density polyethylene(HDPE) plastic-bamboo composite tube according to claim 1 is characterized in that, described solubilizing agent is a kind of in toxilic acid modified poly ethylene, ethylene-acrylic acid copolymer or the Injecatable EVA Copolymer.
5. high density polyethylene(HDPE) plastic-bamboo composite tube according to claim 1 is characterized in that, described weighting agent is acicular wollastonite.
6. high density polyethylene(HDPE) plastic-bamboo composite tube according to claim 1 is characterized in that, described fire retardant is that zinc borate and clorafin are according to 1; The powder that 1 mass ratio mixes.
7. high density polyethylene(HDPE) plastic-bamboo composite tube according to claim 1 is characterized in that, described lubricant is one or more of paraffin, glycerine or hard ester acid.
8. the preparation method of a high density polyethylene(HDPE) plastic-bamboo composite tube is characterized in that, this method comprises the steps:
(1) pre-treatment of bamboo powder: bamboo powder is broken into granularity less than 1.2mm bamboo particle; Then the bamboo particle is flooded 4-6min in anti-mould and moth-proof agent; Again with above-mentioned bamboo particle after handling through anti-mould and anti-moth dry to water ratio be 2-4%, exsiccant bamboo particle, spray water-resisting agent on the finally dried bamboo particle; Bamboo particle after must handling, the consumption of water-resisting agent are the 0.2-0.5% of exsiccant bamboo particle weight;
(2) press ratio of quality and the number of copies each component is dropped into just mixed 3-5min in the high-speed mixer, mixing and stirring will be passed through the material extruding pelletization that just mixes in twin screw extruder, and temperature is controlled at 200-210 ℃;
(3) compound that will dry is put in the pipe extruder, extrude the high density polyethylene(HDPE) plastic-bamboo composite tube.
9. high density polyethylene(HDPE) plastic-bamboo composite tube according to claim 8; It is characterized in that; Said each section of pipe extruder of step (3) temperature is that one section temperature is 95-100 ℃, and two sections temperature are 175-180 ℃, and three sections temperature are 180-185 ℃; Four sections temperature are 195-200 ℃, and engine speed is 50r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103025350A CN102382350A (en) | 2011-10-09 | 2011-10-09 | High density polyethylane bamboo plastic composite tubing and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103025350A CN102382350A (en) | 2011-10-09 | 2011-10-09 | High density polyethylane bamboo plastic composite tubing and preparation method thereof |
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| CN102382350A true CN102382350A (en) | 2012-03-21 |
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| CN2011103025350A Pending CN102382350A (en) | 2011-10-09 | 2011-10-09 | High density polyethylane bamboo plastic composite tubing and preparation method thereof |
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| CN102786809A (en) * | 2012-09-03 | 2012-11-21 | 谢小良 | Bamboo-plastic composite material and preparation process thereof |
| CN104948848A (en) * | 2015-05-11 | 2015-09-30 | 杭州金培科技有限公司 | Energy-saving and environment-friendly composite tube and manufacturing method thereof |
| CN105295499A (en) * | 2015-10-31 | 2016-02-03 | 仇颖超 | Preparation method of modified bamboo dust thermochromic composite coating additive |
| CN108059728A (en) * | 2018-01-17 | 2018-05-22 | 闽南师范大学 | A kind of LBL self-assembly flame retardant type bamboo-plastic composite material and preparation method thereof |
| CN108250545A (en) * | 2018-01-22 | 2018-07-06 | 吴嘉馨 | A kind of anti-bean curd stick moulding material of aeroge |
| CN110317466A (en) * | 2019-08-07 | 2019-10-11 | 福建六正新材料科技有限公司 | Fire-retardant mould proof bamboo-plastic plate of one kind and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102786809A (en) * | 2012-09-03 | 2012-11-21 | 谢小良 | Bamboo-plastic composite material and preparation process thereof |
| CN104948848A (en) * | 2015-05-11 | 2015-09-30 | 杭州金培科技有限公司 | Energy-saving and environment-friendly composite tube and manufacturing method thereof |
| CN104948848B (en) * | 2015-05-11 | 2017-05-10 | 安徽蓝通科技股份有限公司 | Energy-saving and environment-friendly composite tube and manufacturing method thereof |
| CN105295499A (en) * | 2015-10-31 | 2016-02-03 | 仇颖超 | Preparation method of modified bamboo dust thermochromic composite coating additive |
| CN105295499B (en) * | 2015-10-31 | 2017-07-25 | 盐城永悦新材料有限公司 | A kind of preparation method of modified bamboo scraps thermo-color composite coating additive |
| CN108059728A (en) * | 2018-01-17 | 2018-05-22 | 闽南师范大学 | A kind of LBL self-assembly flame retardant type bamboo-plastic composite material and preparation method thereof |
| CN108250545A (en) * | 2018-01-22 | 2018-07-06 | 吴嘉馨 | A kind of anti-bean curd stick moulding material of aeroge |
| CN110317466A (en) * | 2019-08-07 | 2019-10-11 | 福建六正新材料科技有限公司 | Fire-retardant mould proof bamboo-plastic plate of one kind and preparation method thereof |
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Application publication date: 20120321 |