CN102370587A - Mascara Remover - Google Patents
Mascara Remover Download PDFInfo
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- CN102370587A CN102370587A CN 201110234222 CN201110234222A CN102370587A CN 102370587 A CN102370587 A CN 102370587A CN 201110234222 CN201110234222 CN 201110234222 CN 201110234222 A CN201110234222 A CN 201110234222A CN 102370587 A CN102370587 A CN 102370587A
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Abstract
The invention provides a mascara remover. The mascara remover at least includes (A) a jydrophilic surface active agent and (B) clay mineral. The jydrophilic surface active agent is polyoxyethylene sorbitan fatty acid ester. The clay mineral is clay mineral of bentonite organically modified. The viscosity is 550 Pa.s-1800m Pa.s measured by a single cylindrical rotational viscometer under a following condition: temperature 20 DEG C, rotor serial number SB3, and rotor speed 30 <-1>minutes.
Description
Technical field
The present invention relates to the mascara remover.
Background technology
As the employed cleaning agent of makeup removing, have states such as creaminess, emulsion form, aqueous, gel.In addition, in these, there are aqueous type, oiliness type, latex type etc. again, use respectively corresponding to separately the usability and the kind of cosmetics.
In recent years; In cosmetics, there is multiple mascara to sell; For example preparation has a lipophile base material, is difficult for can forming the resistance to water thin film because of antiperspirant or the water proof type mascara (for example opening the 2002-327019 communique with reference to the spy) being got wet and cause the woman's persona that falls by water after the drying; Also be difficult to permeated even got wet, can make eyelashes seem longer or make the film type mascara (for example with reference to special table 2008-525443 communique) etc. of crimping eyelash by water.
Be the thin tender and lovely position of skin around the eyes, need provide and can only be coated on the eyelashes, can be with the mascara remover of mascara selective removal.In addition because the danger that exists cleaning agent to get into eyes, so require little to eye irritation, the mascara remover that has proper viscosity and when smearing eyelashes, can not drip from eyelashes.
Therefore, there is the problem (for example, opening the 2004-115467 communique with reference to the spy) that is not suitable for selective removal mascara aspect in the employed cleaning agent in the past of face usually.
In addition, according to the mascara type of in the past above-mentioned water proof type or above-mentioned film type etc., existence needs corresponding its type separately to use the problem of above-mentioned cleaning agent aspect.
This has been proposed to contain at least the oil preparation of 1 weight %, the eyelash cosmetics remover of viscosity below the above 150000mPas of 10000mPas in the time of 25 ℃ (with reference to No. the 3332917th, patent).Through above-mentioned eyelash cosmetics remover, just can remove mascara and mascara bed material etc. efficiently and spread upon the cosmetics on the eyelashes.
, above-mentioned eyelash cosmetics remover is except stability is not high, and also existence need be wiped, make water clean after around eyes also can stay the problem of Hei Quan aspect.
In addition, when cleaning, much need to use eyelash cosmetics that hot water cleans (for example though exist; Open the 2010-077042 communique with reference to the spy), promote the tender and lovely exsiccant problem of eyelid skin (for example, with reference to mountain bank reason favour but use hot water to clean and have; Fragrance Journal; 2010,38 (3), 22～27).
Therefore, present situation is that requirement provides a kind of Shi Buhui of smearing from the eyelashes drippage, can spread upon on the eyelashes by homogeneous; There is not zest; Eye can adapt to and usability good, no matter the mascara kind can both be removed it, have when repeating to smear two or more mascara such as water proof type and film type also can be at short notice with the excellence removal effect of its removal; Can be cleaned the mascara remover of excellent storage stability by water.
Summary of the invention
For solving above-mentioned variety of issue in the past, the present invention is a problem to reach following purpose.That is, the purpose of this invention is to provide a kind of Shi Buhui of smearing, can spread upon equably on the eyelashes from the eyelashes drippage; There is not zest; Eye can adapt to and usability good, no matter the mascara kind can both be removed it, though have when repeating to smear the mascara of two or more types also can be at short notice with the excellence removal effect of its removal; Can clean the mascara remover of excellent storage stability with water.
In order to solve above-mentioned problem, processes such as the inventor study intensively, and the result obtains following discovery.Promptly; (A) hydrophilic surfactant active and (B) the mascara remover of clay mineral have been found to contain at least; Above-mentioned (A) hydrophilic surfactant active is the polyoxyethylene sorbitan fatty acid ester; Above-mentioned (B) clay mineral is the clay mineral of organically-modified swelling penus, and using single cylinder type rotating cylinder viscometer is that 20 ℃, rotor are numbered SB3 number in temperature, and rotor revolution number is 30min
-1, the viscosity that records under the condition in 30 seconds is 550mPas～1800mPas, said mascara remover is smeared Shi Buhui and is dripped from eyelashes; Can spread upon on the eyelashes by homogeneous, nonirritant, eye can adapt to and usability good, no matter the mascara kind can both be removed it; Even have when repeating to smear the mascara of two or more types also can be at short notice with the excellence removal effect of its removal; Can clean with water, excellent storage stability, thus accomplish the present invention.
The present invention is that inventor etc. obtains based on above-mentioned discovery, and is following as the means that solve above-mentioned problem.That is,
<1>The mascara remover; It is characterized in that contain (A) hydrophilic surfactant active and (B) clay mineral at least, above-mentioned (A) hydrophilic surfactant active is the polyoxyethylene sorbitan fatty acid ester; Above-mentioned (B) clay mineral is the clay mineral of organically-modified swelling penus; Using single cylinder type rotating cylinder viscometer is 20 ℃ in temperature, and rotor is numbered SB3 number, and rotor speed is 30min
-1, the viscosity that records under the condition in 30 seconds is 550mPas～1800mPas.
< 2>the mascara remover of record in above-mentioned < 1 >, whole with respect to the mascara remover, (A) hydrophilic surfactant active's content is 10% quality～20% quality.
< 3>the mascara remover of any record in above-mentioned < 1>to < 2 >, whole with respect to the mascara remover, (B) clay mineral content is 3% quality～4% quality.
< 4>the mascara remover of any record in above-mentioned < 1>to < 3>also contains (C) lipophilic surfactant.
< 5>the mascara remover of any record in above-mentioned < 1>to < 4 >, the HLB value is 10～11.
< 6>the mascara remover of any record in above-mentioned < 1>to < 4 >, (A) hydrophilic surfactant active is polyoxyethylene 20 sorbitan trioleate (the addition molal quantity of ethylene oxide is 20).
According to the present invention, the mascara remover is provided, it can solve the above-mentioned variety of issue that in the past existed; Achieve the above object, it smears Shi Buhui from the eyelashes drippage, can spread upon on the eyelashes by homogeneous; Nonirritant, eye can adapt to and usability good, no matter the mascara kind can both be removed it; Even have when repeating to smear two or more mascara and also can clean excellent storage stability with water at short notice with the excellence removal effect of its removal.
Description of drawings
Fig. 1 is an example of skiagraph that holds the container of mascara remover of the present invention.
Concrete said mode
(mascara remover)
Mascara remover of the present invention contains hydrophilic surfactant active's ((A) composition) and clay mineral ((B) composition) at least, as required, can also contain lipophilic surfactant ((C) composition) and wait other composition.
(A) hydrophilic surfactant active
As the hydrophilic surfactant active of above-mentioned (A) composition, if the polyoxyethylene sorbitan fatty acid ester, not special restriction can suitably be selected according to purpose, but preferably more than 30 ℃ be aqueous polyoxyethylene sorbitan fatty acid ester.For example, polyoxyethylene 20 sorbitan monolaurate (polysorbate 20), polyoxyethylene 20 sorbitan monopalmitate (polysorbate 40), polyoxyethylene 20 sorbitan monostearate (polysorbate 60), polyoxyethylene 20 sorbitan monooleate (polyoxyethylene sorbitan monoleate), polyoxyethylene 20 sorbitan trioleate (polysorbate 85), polyoxyethylene sorbitan cocos nucifera oil acid esters etc.These both can use a kind separately, also can two or morely also use together.
Above-mentioned (A) if composition polyoxyethylene sorbitan fatty acid ester beyond the hydrophilic surfactant active, then the removal effect is insufficient, and stronger to eye irritation, thereby not preferred.
Ethylene oxide (oxirane in above-mentioned (A) composition; E.O.) the not special restriction of addition molal quantity can suitably be selected according to purpose, but preferred 1～50, and more preferably 6～20, preferred especially 10～20.
As the HLB value of above-mentioned (A) composition, not special restriction can suitably not selected according to purpose, but preferred 9～17, and more preferably 9～12, preferred especially 10～11.If above-mentioned HLB value is less than 9, then the removal effect is insufficient, if greater than 17, the removal effect is insufficient, and bad stability.
Here so-called HLB value; Be that expression constitutes the hydrophilic group of surfactant and the value of the strength balance between the hydrophobic group; In general 1～8 is hydrophobicity; Greater than 8 less than 10 be hydrophilic and hydrophobic in the middle of character, then show as hydrophilic more than 10, but also have condition of different according to the structure of surfactant.
Among the present invention, 854～855 pages are put down in writing the assay method of the HLB value of above-mentioned (A) composition in the revised edition of distribution in clear and on February 1st, 52 [Ha Application De Block ッ Network-cosmetic formulations raw material-change version] passes through emulsion process actual measurement HLB value based on Nikko Chemicals Co., Ltd.
The concrete grammar of the HLB value of above-mentioned as obtaining (A) composition; Above-mentioned (A) composition and as sorbitan monostearate (the NIKKOL SS-10 of emulsifying agent standard substance; HLB4.7) combined, it is constant that the total amount of these two kinds of emulsifying agents is decided to be certain value, only changes the two ratio; The emulsifying conduct is by the liquid paraffin of emulsion (HLB10.1); Place behind the diel from emulsifying amount, nebulousurine degree, the separated form water of lower floor etc. is obtained the emulsifier proportion of suitable stability, can calculate the HLB value x of above-mentioned (A) composition through following formula (1).
Y=(x * use amount (quality %)+z * use amount (quality %))/100... formula (1)
Here, in formula (1), the HLB value of [x] expression above-mentioned (A) composition, the HLB value of [y] express liquid paraffin, the HLB value of [z] expression sorbitan monostearate (NIKKOL SS-10).
In addition, the HLB value of aforesaid liquid paraffin can through the combination sorbitan monostearate (NIKKOL SS-10, HLB4.7) and polyoxyethylene 20 sorbitan monostearate (NIKKOL TS-10, HLB14.9), making uses the same method obtains.
Wherein, As mentioned component (A); Preferred polyoxyethylene 20 sorbitan trioleate (20E.O), polyoxyethylene 20 sorbitan monooleate (6E.O) (PEG-6 sorbitan monooleate); Polyoxyethylene 20 sorbitan trioleate (20E.O) the removal effect and stable aspect excellent, thereby preferred especially.
The method of above-mentioned as obtaining (A) composition, not special restriction can suitably not selected according to purpose, for example can enumerate synthetic method or the method directly bought etc.
As the object lesson of the commodity of above-mentioned (A) composition, adducible trade name is レ オ De one Le TW-O320V (HLB11), レ オ De one Le TW-O106V (HLB10) (above is that Kao Corp produces), NIKKOL TS-10V (HLB14.9), NIKKOLTO-106V (HLB10), NIKKOL TO-10V (HLB15) (above be Nikko Chemicals Co., Ltd's production) etc.
Content as above-mentioned (A) composition is not done special restriction, can suitably select according to purpose, but preferred 8 quality %～25 quality %, more preferably 10% quality～20% quality, preferred especially 13 quality %～17 quality %.The content of mentioned component (A) is if less than 8 quality %, and the removal effect reduces, if greater than 25 quality %, then usability variation and removal effect reduce.
(B) clay mineral
As the clay mineral that is above-mentioned (B) composition, if the clay mineral of swelling penus is not done special restriction, can suitably select according to purpose, for example, can enumerate, oronain hectorite etc. draws in distearyl dimethylammonium Strese Hofmann's hectorite., department.These are as commercially available article; Can directly buy; For example; Can enumerate, oronain hectorite (trade name: BENTONE 27V, Elementis Specialities company produce) etc. draws in distearyl dimethylammonium Strese Hofmann's hectorite. (trade name: BENTONEGEL ISD V, Elementis Specialities company produce), department.
In addition, above-mentioned (B) composition obtains after also can swelling type clay minerals such as hectorite, Montmorillonitum, beidellite, nontronite, saponite being used modifier modification.
As above-mentioned modifier; Do not do special restriction; Can suitably select according to purpose; For example, can enumerate quaternary ammonium salts such as DTAC, tetradecyl trimethyl ammonium chloride, hexadecyltrimethylammonium chloride, OTAC, mountain Yu base trimethyl ammonium chloride, myristyl dimethyl ethyl ammonium chloride, hexadecyldimethyl benzyl ammonium ethyl ammonium chloride, alkyl trimethyl ammonium chloride, octadecyl dimethyl ethyl ammonium chloride, alkyl dimethyl ethyl ammonium chloride, mountain Yu base dimethyl ethyl ammonium chloride, myristyl methyl diethyl ammonium chloride, cetyl methyl diethyl ammonium chloride, octadecyl methyl diethyl ammonium chloride, alkyl methyl diethyl ammonium chloride, mountain Yu ylmethyl diethyl ammonium chloride, myristyl dimethyl benzyl ammonium chloride, cetalkonium chloride, stearyl dimethyl benzyl ammonium chloride, mountain Yu base dimethyl benzyl ammonium chloride, cetyl Methylethyl benzyl ammonium chloride, octadecyl methyl ethylbenzylammonium chloride, two octadecyl dimethyl ethyl ammonium chloride, two mountain Yu base dihydroxy ethyl ammonium chloride and equal proglumide, double hexadecyl propyl group ethyl ammonium Methylsulfate etc.These quaternary ammonium salts etc. can use a kind separately, also can two or morely also use together.
As above-mentioned method of modifying; Not special restriction; Can from disclosed method, suitably select according to purpose; For example, can enumerate with above-mentioned clay mineral with in low boiling point solvents such as water, acetone, lower alcohol, disperse stir process as the quaternary ammonium salt cationic surfactant of modifier, remove the method for low boiling point solvent etc.
Above-mentioned (B) composition can use a kind separately, also can two or morely also use together.Wherein, as above-mentioned (B) composition, preferred distearyl dimethylammonium Strese Hofmann's hectorite. and Si La oronain hectorite, distearyl dimethylammonium Strese Hofmann's hectorite. the removal effect and stable aspect excellence, preferred especially.
If above-mentioned (B) composition is not the clay mineral of organically-modified swelling penus, can be difficult to smear from the eyelashes drippage, eyes are had strong stimulation, insufficient, the bad stability of removal effect, thereby not preferred.
Content as above-mentioned (B) composition; Not special restriction; Can suitably select according to purpose, preferred 2.5 quality %～4.5 quality %, more preferably 3 quality %～4.5 quality %, be more preferably 3 quality %～4 quality %, preferred especially 3.1 quality %～4 quality %.The content of mentioned component (B) is if less than 2.5 quality %, and then bad stability, eye stimulation enhancing, removal effect descend, if surpass 4.5 quality %, then is difficult to smear and eye stimulation enhancing.
(C) lipophilic surfactant
Above-mentioned mascara remover the removal effect and stable aspect preferably also contain lipophilic surfactant ((C) composition).
As above-mentioned (C) composition; So long as lipophilic surfactant is not done special restriction, can suitably select according to purpose; But preferably be aqueous lipophilic surfactant more than 30 ℃; For example, can enumerate sorbitan fatty acid ester classes such as sorbitan monooleate, sorbitan sesquioleate, sorbitan trioleate, anhydrous sorbitol list isostearate, anhydrous sorbitol sesquialter isostearate; Polyglyceryl fatty acid ester classes such as diglycerol monoleate, diglycerol dioleic acid ester, diglycerol isostearate, four polyglycereol monoleates, ten polyglycereol, five oleates, ten polyglycereol, five isostearates, six polyglycereol laurates, ten polyglycereol trioleates, ten Risorex PGIS 22s; Polyoxyethylene hydrogenated Oleum Ricini (5E.O), polyoxyethylene hydrogenated Oleum Ricini polyoxyethylene hydrogenated Oleum Ricini classes such as (10E.O); Sucrose-fatty esters such as sucrose five eruciates.These can use a kind separately, also can two or morely also use together.
As the HLB value of above-mentioned (C) composition, do not do special restriction, can suitably select according to purpose, preferred 2～9, more preferably 3～4.If above-mentioned HLB value is less than 2, and then the removal effect reduces, if greater than 9, then is difficult to smear and eye stimulation enhancing.
The HLB value of above-mentioned (C) composition can use the method identical with (A) composition to measure; But as standard substance; Need to use polyoxyethylene 20 sorbitan monostearate (NIKKOL TS-10, HLB14.9) replace sorbitan monostearate (NIKKOL SS-10, HLB4.7).Therefore, in following formula (1), the HLB value of [z] expression polyoxyethylene 20 sorbitan monostearate (NIKKOL TS-10).
Wherein, the preferred sorbitan fatty acid ester class of above-mentioned (C) composition, preferred especially sorbitan sesquioleate.
As the content of above-mentioned (C) composition, do not do special restriction, can suitably select according to purpose, but preferred 0.5 quality %～7.5 quality %, more preferably 1 quality %～3 quality %.If above-mentioned (C) composition is less than 0.5 quality %, then removal effect decline and bad stability, if greater than 7.5 quality %, then the removal effect descends.
As the total content of the surfactant of above-mentioned mascara remover, not special restriction can suitably not selected according to purpose, but preferred 9 quality %～24 quality %, more preferably 15 quality %～17 quality %.If the total content of above-mentioned surfactant is less than 9 quality %, and then the removal effect descends, if greater than 24 quality %, then usability variation and removal effect descend.
< other compositions >
As above-mentioned other compositions; As long as to not infringement of effect of the present invention, not special restriction can suitably be selected according to purpose; For example; Can enumerate general additive or the adjuvant that adds in the cosmetics, the surfactant beyond the general oiliness composition (ester oil, vegetable oil, mineral oil, ether oil etc.), above-mentioned (A) composition and above-mentioned (C) composition, vitamins, alcohols, water etc.
As the content of above-mentioned other compositions, do not do special restriction, can suitably select according to purpose.
< viscosity >
The viscosity of above-mentioned mascara remover can be measured according to JIS K7117-1:1999, uses single cylinder type rotating cylinder viscometer to be numbered SB3 number, rotor speed at 20 ℃ of temperature, rotors and is 30min
-1, the viscosity measured under the condition in 30 seconds is 550mPas～1800mPas, but preferred 600mPas～1500mPas, more preferably 800mPas～1000mPas.If above-mentioned viscosity is less than 550mPas, then eye stimulate strengthen, be difficult to smear from the eyelashes drippage, usability and bad stability etc., if greater than 1800mPas, then removal effect decline, usability and bad stability etc.
As above-mentioned single cylinder type rotating cylinder viscometer, for example can enumerate TV-10 type viscometer (Toki Sangyo Co., Ltd.'s production) etc.
As the viscosity method of adjustment of above-mentioned mascara remover, not special restriction can suitably not selected according to purpose, for example, can enumerate the method for adjusting with the method for the amount of preparation adjustment of above-mentioned (B) composition, with manufacturing approach etc.
< HLB value >
As the HLB value of above-mentioned mascara remover, not special restriction can suitably be selected according to purpose, but preferred 9～11.5, preferred especially 10～11.If above-mentioned HLB value is less than 9, degradation under the removal effect then, if greater than 11.5, and then removal effect decline and bad stability etc.
Above-mentioned HLB value can draw through the additivity average computation of HLB value.
< manufacturing approach >
As the production method of making above-mentioned mascara remover; Not special restriction can suitably be selected according to purpose, for example can enumerate; After above-mentioned (B) composition, as required above-mentioned (C) composition and other compositions mixed, add above-mentioned (A) composition restir method of mixing etc.
As above-mentioned stirring means, do not do special restriction, but both hand mix, also available mechanical mixture, but high preferred with the method for mechanical mixture because of production efficiency.
As the machinery that in above-mentioned stirring, uses, do not do special restriction, can from known machinery, suitably select according to purpose, for example can enumerate dispersing and mixing machine, magnetic force mixer, intimate mixing machine etc.
< method for using >
Method for using as above-mentioned mascara remover is not done special restriction, can suitably select according to purpose, for example, can enumerate and be applied in eyelashes in right amount, gradually method such as infiltration.Because above-mentioned mascara remover can appear mascara in eyelashes in one's mind effectively; So after infiltration, can directly wipe also available water flush away, but the method for washing, because got into not eyes; Stimulation to tender and lovely eyes peripheries such as eye face is little, so be preferred.Even above-mentioned mascara remover because without warm water, also can clean with cold water well, so can to clean this respect under the xerodermatic situation of eyes peripheries be favourable not making.
In addition, so-called here water for example can be enumerated tap water etc., and water temperature is all variant according to season, at about about 10 ℃～30 ℃, even but above-mentioned mascara remover of the present invention also is being fit to removal than this lower temperature.Because the available water flushing, so need not to wipe, the easy this respect of the removal of mascara is favourable.
The amount of smearing of above-mentioned mascara remover, time of penetration, washing time, do not do special restriction, can suitably select according to purpose.
< container >
As the container of above-mentioned mascara remover, do not do special restriction, can suitably select according to purpose, for example can enumerate, bottle, jar, pump, pipe, bag, scalable container, have the container of dauber etc.
Wherein, the container that has dauber as shown in Figure 1 is smeared on eyelashes easily, and it is preferred can taking out this respect quantitatively.
In Fig. 1, have the container 1 of dauber, form by the cover 4 that mascara remover 9 is accommodated in inner container body 3, rod 5 and is provided with dauber 7 with part of smearing 6.In container body 3, in order to keep inner sealing, preferably can packages sealed 8 in the upper limb setting of peristome 2.The internal diameter of packing 8 is close with the external diameter shape of rod 5.Pack 8 thus and also can be used as the extraction aperture removal attached to the unnecessary mascara remover of smearing on the part 6.
The material of container body 3 is not done special restriction, can suitably select according to purpose.For example, can enumerate glass, plastics etc.
From the state of Fig. 1, cover 4 can spirally combine with container body 3, through twisting cover 4, can open-close lid part 4 and opening portion 2 between screw togather.After opening cover 4 and container body 3, can hand cover 4 dauber 7 is pulled out from container body, be applied in eyelashes with being attached to the mascara remover of smearing part 6 in right amount.In addition, when screwing togather between closing lid part 4 and the opening portion 2, packing 8 is connected with cover 4 deep inside.
The part 6 of smearing shown in Fig. 1 is pectination, but is not limited thereto.For example, also can be brush shape or lamellar.Through utilizing this part 6 of smearing, mascara remover 9 is applied in eyelashes, can simple and easy and uniformly the mascara remover be applied in eyelashes.
In addition, above-mentioned mascara remover not only can be accommodated in said vesse, also can be contained in the sheet material and use.
As above-mentioned sheet material, do not do special restriction.Can, skin suitably select from feeling good known sheet material according to purpose.For example, can enumerate non-woven fabrics such as cellulosic nonwoven fabric, artificial silk non-woven fabrics, polyester acetate non-woven fabrics or natural cotton sheet etc.If during above-mentioned sheet material non-woven fabrics, from the skin feel aspect, the non-woven fabrics of preferably handing over the network method to produce by current.
These also can be to overlap or adherent sheet material with the sheet material of two or more cellulosic material combinations or with two or more sheets.
The average level ground of above-mentioned sheet material is measured (weight of per unit area), the average fineness through the fiber determination of electron microscopy, shape, size and thickness and is not done special restriction, can suitably select according to purpose.
In addition, as the also restriction especially of amount of the above-mentioned mascara remover of impregnation in above-mentioned sheet material, can suitably select according to purpose.
Above-mentioned sheet material also can be accommodated in the container.
Above-mentioned mascara remover not from the eyelashes drippage, can spread upon on the eyelashes when smearing equably; Nonirritant, the usability during the infiltration eye is good, and the mascara kind all can be removed it; Even have when repeating to smear two or more mascara also can be at short notice with the excellence removal effect of its removal; Can wash by water, excellent storage stability, thereby can be suitable for removing fibrous mascara, water proof type mascara, the various mascara of film type eyelashes wet goods.
The specific embodiment
Below enumerate embodiments of the invention and specify the present invention, but the present invention is not limited to these embodiment.In addition, in following embodiment and comparative example, [%] all do not represent [quality %] if do not do special instruction.Each becomes component all to be expressed as the value that is converted into pure composition.In addition; In table 1 below～3; Propylene carbonate is represented (the distearyl dimethylammonium Strese Hofmann's hectorite. from trade name BENTONE GEL ISD V; The production of Elementis Specialities company) amount of preparation that the cubage in goes out, the content among Fancol ID (isododecane) the expression trade name BENTONE GEL ISD V and total amount of preparation of suitable addition.
(embodiment 1～4,6～9,11 and 12)
Embodiment 1～4, and 6～9,11 and 12 mascara remover is modulated through following method according to the composition and the amount of preparation of following table 1～2.
(B) composition, (C) composition, isononyl isononanoate (isononyl isononanoate) and Fancol ID as required stirred 3 minutes with 3000rpm through using dispersing and mixing machine (production of T.K robotmix primix company).Then, add octyl palmitate (Ethylhexyl Palmitate), use magnetic force mixer (MG600H, yamato company produces) to stir 5 minutes.Add (A) composition then, use magnetic force mixer (MG600H, yamato company produces) to stir 5 minutes.Add 1,3 butylene glycol (1,3-Butylene Glycol) and Purified Water then, use magnetic force mixer (MG600H, yamato company produces) to stir the mascara remover of preparation embodiment 1～4,6～9,11 and 12 5 minutes.
(embodiment 5)
At embodiment 1～4; 6～9; In 11 and 12, stir 60 minutes except the stirring condition of (B) composition, (C) composition and isononyl isononanoate is stirred to become in 3 minutes with 1000rpm by 3000rpm, with embodiment 1～4; 6～9,11 and 12 identical methods are prepared the mascara remover of embodiment 5.
(embodiment 10)
According to the composition and the amount of preparation of following table 2, use dispersing and mixing machine (productions of T.K robotmix primix company) with the Purified Water of (B) composition, (C) composition, isononyl isononanoate and 1% with 3000rpm stirring 3 minutes.Then, add octyl palmitate, use magnetic force mixer (MG600H, yamato company produces) to stir 5 minutes.Then, add (A) composition, use magnetic force mixer (MG600H, yamato company produces) to stir 5 minutes.Add 1,3 butylene glycol and 1% Purified Water then, use magnetic force mixer (MG600H, yamato company produces) to stir the mascara remover of preparation embodiment 10 5 minutes.
(comparative example 1～5)
According to the composition and the amount of preparation of following table 3, at embodiment 1～4, in 6～9,11 and 12 except that using (A ') composition to replace (A) the composition, with embodiment 1～4, the mascara remover of 6～9,11 and 12 same methods preparation comparative examples 1～5.
In addition, comparative example 3 suitably manually stirs but the limit is heated to 80 ℃ of limits because cause machinery to be difficult to stir in the increase of preparation medium viscosity.
(comparative example 6)
Composition and amount of preparation according to following table 3 are heated to 80 ℃ with (C) composition, Fancol ID and isononyl isononanoate.In addition, heating (B ') composition and octyl palmitate to 80 ℃.Use mixed liquor that magnetic force mixer (MG600H, yamato company produces) will contain these (C) compositions and contain the mixed liquor of (B ') composition to stir 5 minutes down at 80 ℃.Then, leave standstill and be cooled to 30 ℃, add (A) composition and stirred 5 minutes with magnetic force mixer (MG600H, yamato company produces).Add 1,3 butylene glycol and Purified Water then and use magnetic force mixer (MG600H, yamato company produces) to stir the mascara remover of preparation comparative example 65 minutes.
(comparative example 7,8)
According to the composition and the amount of preparation of following table 3, use dispersing and mixing machine (production of T.K robotmix primix company) (B) composition, (C) composition, Fancol ID, isononyl isononanoate and 0.5% Purified Water to be stirred 3 minutes with 3000rpm.Then, add octyl palmitate, use magnetic force mixer (MG600H, yamato company produces) to stir 5 minutes.Adding (A) composition then uses magnetic force mixer (MG600H, yamato company produces) to stir 5 minutes.Add 1,3 butylene glycol and 1.5% Purified Water then and use magnetic force mixer (MG600H, yamato company produces) to stir 5 minutes, the mascara remover of comparative example 7 and 8 is made in preparation.
The mascara remover of embodiment 1～12 and comparative example 1～8 carries out the calculating of HLB value, the mensuration of viscosity and the evaluation of stability through following method.
In addition, the easness that has also carried out smearing, usability, eye stimulation, removal time, flushing back are to the functional evaluation of adhering to and wash the black circle of back circumference of eyes of eyelashes.
< calculating of HLB value >
-(A) calculating of the HLB value of composition-
With (A) composition with as the sorbitan monostearate of emulsifying agent standard substance (NIKKOL SS-10, HLB4.7) combined, be quantitative with the total amount of these 2 kinds of emulsifying agents; Change ratio, emulsifying be as by the liquefied petrolatum of emulsion (HLB10.1), place diel after; From the emulsifying amount; The nebulousurine degree, the separated form water of lower floor etc. is obtained the emulsifier proportion of optimum stabilization, calculates the HLB value x of above-mentioned (A) composition through following formula (1).
Y=(x * use amount (quality %)+z * use amount (quality %))/100 ... Formula (1)
In the formula here (1), the HLB value of [x] expression above-mentioned (A) composition, the HLB value of [y] express liquid paraffin, the HLB value of [z] expression sorbitan monostearate (NIKKOL SS-10).
The HLB value of aforesaid liquid paraffin through the combination sorbitan monostearate (NIKKOL SS-10, HLB4.7) and polyoxyethylene 20 sorbitan monostearate (NIKKOL TS-10, HLB14.9), making uses the same method calculates.
-(C) calculating of the HLB value of composition-
Except in the calculating of the HLB value of above-mentioned (A) composition, using (C) composition to replace (A) composition and using polyoxyethylene 20 sorbitan monostearate (NIKKOL TS-10; HLB14.9) replacement is as sorbitan monostearate (the NIKKOL SS-10 of emulsifying agent standard substance; HLB4.7) in addition, use the HLB value of calculating (C) composition with the same method of the HLB value of calculating above-mentioned (A) composition.
The calculating of the HLB value of-mascara remover-
HLB value (the HLB of (A) composition that draws from aforementioned calculation
A) and (C) HLB value (HLB of composition
C) through additivity, calculate the HLB value (HLBAC) of mascara remover by following formula (2).
HLB
AC=(HLB
A* x+HLB
C* y)/(x+y) ... Formula (2)
Here, in formula (2), the use amount (quality %) of [x] expression above-mentioned (A) composition, the use amount (quality %) of [y] expression above-mentioned (C) composition.
< mensuration of viscosity >
According to JIS K7117-1:1999, use single cylinder type rotating cylinder viscometer TV-10 viscometer (Toki Sangyo Co., Ltd.'s production), at 20 ℃, M3 rotor (rotor is numbered SB3), rotating speed 30rpm (30min
-1), measure viscosity under the condition in 30 seconds.The result is shown in table 1～3.
< stability >
Behind the mascara remover of preparation embodiment 1～12 and comparative example 1～8, about 20ml is filled in the transparent vessel at once, after preserving for 2 weeks under 50 ℃, according to the stability of following metewand evaluation range estimation.
[metewand]
◎: outward appearance is even, does not separate
Zero: some is inhomogeneous a little for outward appearance, does not separate
△: do not separate though outward appearance is inhomogeneous
*: the inhomogeneous and separation of outward appearance
< functional evaluation >
Functional evaluation is undertaken by 5 beautifying technique persons' (expert) women valuation officer.Be coated with the mascara (trade name: Volum express hypercurl WP 01black of water proof type on the eyelashes respectively at the valuation officer; New York Maybelline company produces); Treat the overlapping again film type mascara (trade name: Dejavu Fiberwig Extralong PureBlack, imyu Co., Ltd. produces) of smearing after its drying.The mascara remover of after smearing 12 hours, from embodiment 1～12 and comparative example 1～8, choosing arbitrary 0.06g is applied in the eyelash of a side, uses finger to make the mascara remover fused mutually with mascara.Next use tap water (about 22 ± 5 ℃) to clean the mascara remover.
-smear easness-
Viscosity viewpoint when using the mascara remover is carried out functional evaluation according to the easness of following standards of grading when smearing, and calculates 5 valuation officers' meansigma methods, estimates according to this average mark according to following benchmark.Ecbatic in table 1～3.
[scoring]
5 minutes: good
4 minutes: better
3 minutes: medium
2 minutes: not so good
1 minute: bad
[metewand]
◎: meansigma methods is more than 4.2 minutes
Zero: meansigma methods is assigned between 4.2 minutes 3.5
△: meansigma methods is assigned between 3.5 minutes 2.7
*: meansigma methods is lower than 2.7 fens
-usability-
To carrying out functional evaluation, calculate five valuation officers' meansigma methods, according to following scoring according to estimating with above-mentioned [smearing easness] identical metewand with the mix thoughts and feelings of fashionable circumference of eyes of mascara.Ecbatic in table 1～3.
[scoring]
5 minutes: good
4 minutes: better
3 minutes: medium
2 minutes: not so good
1 minute: bad
The stimulation of-eye-
To carrying out functional evaluation, calculate 5 valuation officers' meansigma methods, according to following scoring according to estimating with above-mentioned [smearing easness] identical metewand with the mascara fashionable eye that whether infiltrates that mixes.Ecbatic in table 1～3.
[scoring]
5 minutes: do not infiltrate
4 minutes: infiltrate hardly
3 minutes: intermediate degree
2 minutes: infiltrate slightly
1 minute: infiltrate
-removal time-
According to following scoring to carrying out functional evaluation to the fused time that finishes of mascara remover and mascara (mascara is fully from time that eyelashes come off) from the mascara remover being applied in eyelashes; Carry out functional evaluation according to following standards of grading; Calculate 5 valuation officers' meansigma methods; From this average mark, according to estimating with above-mentioned [smearing easness] identical metewand.Ecbatic in table 1～3.
5 minutes: fast
4 minutes: very fast
3 minutes: medium
2 minutes: slower
1 minute: slow
-flushing back to the adhering to of eyelashes-
The eyelashes of mascara remover were washed in observation; Whether eyelashes are adhered to mascara carry out functional evaluation according to following standards of grading; Calculate 5 valuation officers' meansigma methods, estimate from the metewand branch that this average mark basis is identical with above-mentioned [smearing easness].Ecbatic in table 1～3.
[scoring]
5 minutes: can remove fully
4 minutes: almost can remove fully
3 minutes: intermediate degree
2 minutes: can not remove a little
1 minute: can not remove
The circumocular black circle in-flushing back-
Observe the eye after water washes the mascara remover; Whether circumference of eyes (eyelid skin up and down) is existed black circle; Carry out functional evaluation according to following scoring; Calculate 5 valuation officers' meansigma methods, from this average mark, according to estimating with above-mentioned [smearing easness] identical metewand.Ecbatic in table 1～3.
[scoring]
5 minutes: not black circle
4 minutes: almost not black circle
3 minutes: intermediate degree
2 minutes: some deceived circle a little
1 minute: black circle is arranged
Table 1
Table 2
Table 3
(Test Example 1)
Use usual method that embodiment 1 synthetic mascara remover 9 is fills up in the container body 3 of the container 1 that has a dauber shown in Figure 1.
Except in the functional evaluation method that embodiment 1～12 and comparative example 1～8 are carried out; When smearing mascara remover 9; The comb (smearing part 6) of front end of dauber 7 that use is arranged at the cover 4 of the above-mentioned container 1 that has a dauber will be filled in mascara remover 9 in the above-mentioned container 1 that has a dauber and be applied in and repeat to be coated with outside the eyelashes of two kinds of mascara, use with the same method of above-mentioned functions evaluation methodology and remove mascara.
Its results verification, can be an amount of obtain mascara remover 9, mascara remover 9 is not dripped from eyelashes, can be applied in eyelashes more equably, the usability when smearing mascara remover 9 is good.
The raw material that embodiment 1～12, comparative example 1～8 and Test Example 1 are used is shown in following table 4.
Table 4
Mascara remover of the present invention is because drip from eyelashes smearing Shi Buhui; Can evenly spread upon on the eyelashes; Do not have zest, usability is good during the infiltration eye, and no matter the mascara kind can both be removed it; Have when repeating to smear two or more mascara also can be at short notice with the excellence removal effect of its removal; Can clean by water, excellent storage stability is so go for removing fibrous mascara, water proof type mascara, the multiple mascara of film type eyelashes wet goods.
Claims (6)
1. mascara remover is characterized in that:
At least contain (A) hydrophilic surfactant active and (B) clay mineral, said (A) hydrophilic surfactant active is the polyoxyethylene sorbitan fatty acid ester, and said (B) clay mineral is the clay mineral of organically-modified swelling penus,
Use single cylinder type rotating cylinder viscometer at 20 ℃, rotor numbering SB3 number, rotor speed 30min
-1, the viscosity that records under the condition in 30 seconds is 550mPas～1800mPas.
2. mascara remover according to claim 1, whole with respect to the mascara remover, (A) hydrophilic surfactant active's content is 10 quality %～20 quality %.
3. mascara remover according to claim 1, whole with respect to the mascara remover, (B) clay mineral content is 3 quality %～4 quality %.
4. mascara remover according to claim 1 also contains (C) lipophilic surfactant.
5. mascara remover according to claim 1, HLB value are 10～11.
6. mascara remover according to claim 1, (A) hydrophilic surfactant active is polyoxyethylene 20 sorbitan trioleate (the addition molal quantity of ethylene oxide is 20).
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010181372A JP4916568B2 (en) | 2010-08-13 | 2010-08-13 | Mascara remover |
| JP2010-181372 | 2010-08-13 |
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| Publication Number | Publication Date |
|---|---|
| CN102370587A true CN102370587A (en) | 2012-03-14 |
| CN102370587B CN102370587B (en) | 2013-09-04 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110234222 Active CN102370587B (en) | 2010-08-13 | 2011-08-12 | Mascara Remover |
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| Country | Link |
|---|---|
| JP (1) | JP4916568B2 (en) |
| CN (1) | CN102370587B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111936113A (en) * | 2018-03-30 | 2020-11-13 | 株式会社爱茉莉太平洋 | Cosmetic composition for removing makeup containing water-soluble surfactant and oil-soluble surfactant |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11478666B2 (en) | 2018-12-14 | 2022-10-25 | L'oreal | Eye makeup removal systems and cosmetic kits |
| US11234504B2 (en) | 2018-12-14 | 2022-02-01 | L'oreal | Systems and cosmetic kits for removing makeup from a region of an eye |
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| CN1307865A (en) * | 2000-01-21 | 2001-08-15 | 莱雅公司 | Nanometer emulsion containing amphiphilic lipoid and polyglycol ester |
| CN1335125A (en) * | 2000-06-27 | 2002-02-13 | 强生消费者公司 | Cleaning composition |
| US20040156812A1 (en) * | 2002-12-12 | 2004-08-12 | L'oreal | Dispersions of polymers in organic medium, and compositions comprising them |
| CN101132834A (en) * | 2005-03-04 | 2008-02-27 | 宝洁公司 | Rinse-off or wipe-off skin cleansing compositions |
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| JP2004115467A (en) * | 2002-09-27 | 2004-04-15 | Kao Corp | Cleansing method |
| JP3798744B2 (en) * | 2002-11-11 | 2006-07-19 | カネボウ株式会社 | Skin cleanser |
| JP4145238B2 (en) * | 2003-12-04 | 2008-09-03 | 太陽化学株式会社 | Polyglycerin medium chain fatty acid ester-containing composition |
| JP4805595B2 (en) * | 2005-03-30 | 2011-11-02 | 株式会社コーセー | Oily salmon cosmetic |
| JP4953287B2 (en) * | 2006-08-11 | 2012-06-13 | 株式会社 資生堂 | Gel composition |
| JP4602999B2 (en) * | 2007-01-29 | 2010-12-22 | 花王株式会社 | Cleansing composition |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1307865A (en) * | 2000-01-21 | 2001-08-15 | 莱雅公司 | Nanometer emulsion containing amphiphilic lipoid and polyglycol ester |
| CN1335125A (en) * | 2000-06-27 | 2002-02-13 | 强生消费者公司 | Cleaning composition |
| US20040156812A1 (en) * | 2002-12-12 | 2004-08-12 | L'oreal | Dispersions of polymers in organic medium, and compositions comprising them |
| CN101132834A (en) * | 2005-03-04 | 2008-02-27 | 宝洁公司 | Rinse-off or wipe-off skin cleansing compositions |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111936113A (en) * | 2018-03-30 | 2020-11-13 | 株式会社爱茉莉太平洋 | Cosmetic composition for removing makeup containing water-soluble surfactant and oil-soluble surfactant |
| US11904039B2 (en) | 2018-03-30 | 2024-02-20 | Amorepacific Corporation | Cosmetic composition for makeup removal comprising water-soluble surfactant and oil-soluble surfactant |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4916568B2 (en) | 2012-04-11 |
| CN102370587B (en) | 2013-09-04 |
| JP2012041278A (en) | 2012-03-01 |
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