CN102329549A - Water-borne inflation type refractory coating and preparation method thereof - Google Patents
Water-borne inflation type refractory coating and preparation method thereof Download PDFInfo
- Publication number
- CN102329549A CN102329549A CN201110172456A CN201110172456A CN102329549A CN 102329549 A CN102329549 A CN 102329549A CN 201110172456 A CN201110172456 A CN 201110172456A CN 201110172456 A CN201110172456 A CN 201110172456A CN 102329549 A CN102329549 A CN 102329549A
- Authority
- CN
- China
- Prior art keywords
- emulsion
- water
- nano
- content
- proof coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention discloses a water-borne inflation type refractory coating and a preparation method thereof. The refractory coating is prepared from the following components: 30-40% of emulsion compound, 40-58% of modified antiflaming system of a nanometer material, 0.3-0.6% of emulsifying agent, 0.2-0.4% of plasticizer, 0.4-0.8% of reinforcing agent, 0.1-0.15% of pigment filler, 0.2-0.6% of dispersing agent and the balance of water. Compared with the prior art, the water-borne inflation type refractory coating has the advantages of excellent environmental performance, simple technology, sufficient raw material resources, proper price and the like and can be widely applied.
Description
Technical field
The invention belongs to the frie retardant coating technical field, relate to a kind of water expansion fire-proof coating and preparation method thereof.
Background technology
Along with high stratification, clustered, the development of industrial large-sizedization and the expansion utilization of organic synthesis material of building, coating is with its good protectiveness and ornamentally give comfortable enjoyment, but the combustibility of most of coating and inflammableness have also been brought disaster hidden-trouble.Therefore developing frie retardant coating becomes more and more important to adapt to security against fire.
Frie retardant coating is divided into expanded polystyrene veneer and non-expansion type frie retardant coating by its fire prevention form and moity.Expanding fire-proof paint is domestic most popular coating, can be divided into two types of water-based and solvent borne expanding fire-proof paints, and wherein, water expansion fire-proof coating accounts for more than 75% of coating of expanded polystyrene veneer fire.Aqueous fire-proof coating cost on the home market is low, toxicity is low, pollution is little, but humidity resistance is relatively poor, only is applicable under the exsiccant environment to use.Though aqueous fire-proof coating possesses above performance simultaneously on the world market, price is surprisingly high, is not suitable for the development need of China market.In addition; Existing frie retardant coating adopts ammonium polyphosphate-tetramethylolmethane-trimeric cyanamide (APP-PER-MEL) type flame-retardant system mostly, though the frie retardant coating fire resistance of this flame-retardant system is better, weather resistance and water tolerance are relatively poor; When in environment that directly contacts with water or wet environment, using; Phenomenons such as the easy generation of its fire retardant is water-soluble, saltout cause frie retardant coating to lose efficacy, thereby make coating lose fire prevention usefulness.
Summary of the invention
Technical problem to be solved by this invention is to propose a kind of water expansion fire-proof coating and preparation method thereof, and this water expansion fire-proof coating has advantages such as cost is low, toxicity is little, the fire-proof and water-proof performance is good.
Technical solution of the present invention is following:
A kind of preparation method of water expansion fire-proof coating, at first by following each material of mass percent weighing:
Emulsion mixture 30%～40%;
Nano-material modified flame-retardant system 40%～58%;
Emulsifying agent 0.3%～0.6%;
Softening agent 0.2%～0.4%;
Toughener 0.4%～0.8%;
Color stuffing 0.1～0.15%;
Dispersion agent 0.2%～0.6%;
Water surplus;
Described emulsion mixture is to utilize the silane coupling agent vinyl triethoxyl silane (A-151) that contains unsaturated double-bond; Under initiator ammonium persulfate (APS) effect; Ammonium persulphate content is to account for 2.5%～4.5% of emulsion mixture quality, carries out the silicone-modified polyacrylate emulsion that the organosilicon crylic acid latex polyreaction obtains with polyacrylic ester; The content of polyacrylic ester is 40%～45% of emulsion mixture quality, and the content of vinyltriethoxysilane is 10%～12% of emulsion mixture quality;
Described nano-material modified flame-retardant system is by nano-TiO
2, trimeric cyanamide, tetramethylolmethane and ammonium polyphosphate form; The mass content of nano TiO 2 is 0.9%～1.2%, and the mass content of trimeric cyanamide is 9.1%～16.8%, and the mass content of tetramethylolmethane is 5%～10%, and the mass content of ammonium polyphosphate is 25%～30%;
Take by weighing each component by proportioning raw materials, then, the 50-70% and the dispersion agent of said water are put into reaction vessel, stir, add nano-TiO then successively
2, trimeric cyanamide, tetramethylolmethane and ammonium polyphosphate process solution;
Get remainder water in addition, add emulsifying agent, stir into homogeneous latex emulsion;
Above solution and emulsion are merged, progressively add softening agent, toughener, color stuffing then, add the emulsion mixture at last, after the stirring, less than 60um, can obtain the finished product of water expansion fire-proof coating with ball mill grinding to fineness.
Prepare in the process of said solution, the speed of stirring is 600～700r/min, prepares in the process of said homogeneous latex emulsion, and stirring velocity is 1200～1300r/min, and in the process of preparation finished product, stirring velocity is 1300～1400r/min, and churning time is 1～2h.
A kind of water expansion fire-proof coating, the mass percentage content of each feed composition is following:
Emulsion mixture 30%～40%;
Nano-material modified flame-retardant system 40%～58%;
Emulsifying agent 0.3%～0.6%;
Softening agent 0.2%～0.4%;
Toughener 0.4%～0.8%;
Color stuffing 0.1～0.15%;
Dispersion agent 0.2%～0.6%;
Water surplus.
Described emulsion mixture is to utilize the silane coupling agent vinyl triethoxyl silane (A-151) that contains unsaturated double-bond; Under initiator ammonium persulfate (APS) effect; Ammonium persulphate content is to account for 2.5%～4.5% of emulsion mixture quality, carries out the silicone-modified polyacrylate emulsion that the organosilicon crylic acid latex polyreaction obtains with polyacrylic ester; The content of polyacrylic ester is 40%～45% of emulsion mixture quality, and the content of vinyltriethoxysilane is 10%～12% of emulsion mixture quality
Described nano-material modified flame-retardant system is by nano-TiO
2, trimeric cyanamide, tetramethylolmethane and ammonium polyphosphate form; The mass content of nano TiO 2 is 0.9%～1.2%, and the mass content of trimeric cyanamide is 9.1%～16.8%, and the mass content of tetramethylolmethane is 5%～10%, and the mass content of ammonium polyphosphate is 25%～30%.
Described emulsifying agent is OP-9, and described softening agent is the mixture of Tritolyl Phosphate and β-trieline SULPHOSUCCINIC ACID ESTER, and mass ratio is 1: 1.1～1.3.
Described toughener is the mixture of three kinds of zinc oxide, Antimony Trioxide: 99.5Min and talcum powder, and mass ratio is 1.1～1.3: 1.1～1.3: 1.1～1.3; Described color stuffing is a white titanium pigment, and described dispersion agent is a Sodium hexametaphosphate 99.
Described water expansion fire-proof coating adopts the preparation method of aforesaid water expansion fire-proof coating to be prepared from.
Beneficial effect:
Water expansion fire-proof coating of the present invention and preparation method thereof; Adopt the silicone-modified polyacrylate emulsion as base-material; To the flame-retardant system modification,, improved film-forming properties, snappiness, the mechanical property of frie retardant coating greatly with nano material through effective cooperation of above component and auxiliary agent; Make frie retardant coating have the hydrophobicity of excellent weathering resistance, contamination resistance, air permeability and good and height again simultaneously; The product environmental-protecting performance is good, and technology is simple, sufficient raw, and price suits, is widely used.
The present invention and domestic comparing with prior art have following advantage:
1, polyacrylic ester can form good luster and water-proof film, and is bonding firm, incrust; The Si-O key (bond energy is up to 425kJ/mol) that contains high bond energy in the organosilicon molecular backbone chain, performance such as have that heat resistanceheat resistant is decomposed and anti-oxidant, and the organosilicon molecular volume is big, and cohesive energy density(CED) is low; The present invention adopts the silicone-modified polyacrylate emulsion as base-material; Make full use of above the two advantage; The mechanical property that had both had good film-forming properties, snappiness, brilliance has the hydrophobicity of excellent weathering resistance, contamination resistance, air permeability and good and height again.
2, nano-material modified flame-retardant system is in frie retardant coating, to add nano-TiO
2, the nano-TiO of interpolation
2, can stop action of ultraviolet ray, again because nano-TiO
2Good dispersivity, can form the nanoscale interpenetrating(polymer)networks, improve the ability of resistant moisture through " labyrinth " effect.Therefore, adopt above-mentioned nano-material modified coating, have good foaming effect and flameproof effect.
3, nano-material modified flame-retardant system is to be made up of halogen-free low-smoke flame retardant material, when burning, can not produce a large amount of smog and halogenous toxic and harmful, belongs to the clean and environment-friendly flame-retardant system.
4, technology particularly of the present invention is to be solvent with water when the preparation frie retardant coating, does not contain organic solvent, and organic volatile part (VOC) is very low, so environmental-protecting performance is good.
5, sufficient raw such as simple, the polyacrylic ester of preparation technology of the present invention, price suits, is widely used.
Embodiment
Below in conjunction with specific embodiment, a kind of water expansion fire-proof coating of the present invention and preparation method thereof is made more detailed description.
Embodiment 1: a kind of water expansion fire-proof coating, be prepared from following component, and each component concentration (gross weight is by 100%) is:
Above-mentioned raw materials is the commercial goods.
The preparation method of this embodiment: a certain amount of water and Sodium hexametaphosphate 99 are put into reaction kettle, and stirring at low speed adds nano-TiO then successively
2, trimeric cyanamide, tetramethylolmethane and ammonium polyphosphate process solution.Get a part of water in addition, add polyoxyethylene nonylphenol ether-9, high-speed stirring mixes homogeneous latex emulsion.The above aqueous solution and emulsion are merged; Progressively add Tritolyl Phosphate, β-trieline SULPHOSUCCINIC ACID ESTER then, zinc oxide, Antimony Trioxide: 99.5Min and talcum powder, white titanium pigment; Add the silicone-modified polyacrylate emulsion at last; Behind high-speed stirring 1～2h, less than 60um, can obtain the finished product of frie retardant coating with ball mill grinding to fineness.
The main performance index of product:
State in the container: there are not caking, viscous fluid,
Surface drying time: 1 hour,
Water tolerance: surpass 120 hours,
Cohesive strength/MPa:0.48
Ultimate compression strength/MPa:1.6
Thermal conductivity/w. (m.k)
-1: 0.086
Sticking power: 2 grades-1 grade,
Fire-resistant coating thickness/mm:13
Fire endurance/h: greater than 3 hours
Embodiment 2: a kind of water expansion fire-proof coating, be prepared from following component, and each component concentration (gross weight is by 100%) is:
Above-mentioned raw materials is the commercial goods.
The preparation method of this embodiment: a certain amount of water and Sodium hexametaphosphate 99 are put into reaction kettle, and stirring at low speed adds nano-TiO then successively
2, trimeric cyanamide, tetramethylolmethane and ammonium polyphosphate process solution.Get a part of water in addition, add polyoxyethylene nonylphenol ether-9, high-speed stirring mixes homogeneous latex emulsion.The above aqueous solution and emulsion are merged; Progressively add Tritolyl Phosphate, β-trieline SULPHOSUCCINIC ACID ESTER then, zinc oxide, Antimony Trioxide: 99.5Min and talcum powder, white titanium pigment; Add the silicone-modified polyacrylate emulsion at last; Behind high-speed stirring 1～2h, less than 60um, can obtain the finished product of frie retardant coating with ball mill grinding to fineness.
The main performance index of product:
State in the container: there are not caking, viscous fluid,
Surface drying time: 1 hour,
Water tolerance: surpass 120 hours,
Cohesive strength/MPa:0.46
Ultimate compression strength/MPa:1.7
Thermal conductivity/w. (m.k)
-1: 0.085
Sticking power: 2 grades-1 grade,
Fire-resistant coating thickness/mm:13.3
Fire endurance/h: greater than 3 hours
Embodiment 3: a kind of water expansion fire-proof coating, be prepared from following component, and each component concentration (gross weight is by 100%) is:
Emulsion mixture 38%,
Nano-material modified flame-retardant system 49%,
Emulsifying agent 0.4%,
Softening agent 0.3%,
Toughener 0.5%,
Color stuffing 0.05%,
Dispersion agent 0.4%,
Water 11.35%;
Above-mentioned raw materials is the commercial goods.
The preparation method of this embodiment: a certain amount of water and Sodium hexametaphosphate 99 are put into reaction kettle, and stirring at low speed adds nano-TiO then successively
2, trimeric cyanamide, tetramethylolmethane and ammonium polyphosphate process solution.Get a part of water in addition, add polyoxyethylene nonylphenol ether-9, high-speed stirring mixes homogeneous latex emulsion.The above aqueous solution and emulsion are merged; Progressively add Tritolyl Phosphate, β-trieline SULPHOSUCCINIC ACID ESTER then, zinc oxide, Antimony Trioxide: 99.5Min and talcum powder, white titanium pigment; Add the silicone-modified polyacrylate emulsion at last; Behind high-speed stirring 1～2h, less than 60um, can obtain the finished product of frie retardant coating with ball mill grinding to fineness.
The main performance index of product:
State in the container: there are not caking, viscous fluid,
Surface drying time: 1 hour,
Water tolerance: surpass 120 hours,
Cohesive strength/MPa:0.44,
Ultimate compression strength/MPa:1.9,
Thermal conductivity/w. (m.k)
-1: 0.086,
Sticking power: 2 grades-1 grade,
Fire-resistant coating thickness/mm:12.8,
Fire endurance/h: greater than 3 hours.
Claims (8)
1. the preparation method of a water expansion fire-proof coating is characterized in that, at first by following each material of mass percent weighing:
Emulsion mixture 30%～40%;
Nano-material modified flame-retardant system 40%～58%;
Emulsifying agent 0.3%～0.6%;
Softening agent 0.2%～0.4%;
Toughener 0.4%～0.8%;
Color stuffing 0.1～0.15%;
Dispersion agent 0.2%～0.6%;
Water surplus;
Described emulsion mixture is to utilize the silane coupling agent vinyl triethoxyl silane (A-151) that contains unsaturated double-bond; Under initiator ammonium persulfate (APS) effect; Ammonium persulphate content is to account for 2.5%～4.5% of emulsion mixture quality, carries out the silicone-modified polyacrylate emulsion that the organosilicon crylic acid latex polyreaction obtains with polyacrylic ester; The content of polyacrylic ester is 40%～45% of emulsion mixture quality, and the content of vinyltriethoxysilane is 10%～12% of emulsion mixture quality;
Described nano-material modified flame-retardant system is by nano-TiO
2, trimeric cyanamide, tetramethylolmethane and ammonium polyphosphate form; The mass content of nano TiO 2 is 0.9%～1.2%, and the mass content of trimeric cyanamide is 9.1%～16.8%, and the mass content of tetramethylolmethane is 5%～10%, and the mass content of ammonium polyphosphate is 25%～30%;
Take by weighing each component by proportioning raw materials, then, the 50-70% and the dispersion agent of said water are put into reaction vessel, stir, add nano-TiO then successively
2, trimeric cyanamide, tetramethylolmethane and ammonium polyphosphate process solution;
Get remainder water in addition, add emulsifying agent, stir into homogeneous latex emulsion;
Above solution and emulsion are merged, progressively add softening agent, toughener, color stuffing then, add the emulsion mixture at last, after the stirring, less than 60um, can obtain the finished product of water expansion fire-proof coating with ball mill grinding to fineness.
2. according to claim 1; Prepare in the process of said solution, the speed of stirring is 600～700r/min, prepares in the process of said homogeneous latex emulsion; Stirring velocity is 1200～1300r/min; In the process of preparation finished product, stirring velocity is 1300～1400r/min, and churning time is 1～2h.
3. a water expansion fire-proof coating is characterized in that, the mass percentage content of each feed composition is following:
Emulsion mixture 30%～40%;
Nano-material modified flame-retardant system 40%～58%;
Emulsifying agent 0.3%～0.6%;
Softening agent 0.2%～0.4%;
Toughener 0.4%～0.8%;
Color stuffing 0.1～0.15%;
Dispersion agent 0.2%～0.6%;
Water surplus.
4. water expansion fire-proof coating according to claim 3; It is characterized in that; Described emulsion mixture is to utilize the silane coupling agent vinyl triethoxyl silane (A-151) that contains unsaturated double-bond; Under initiator ammonium persulfate (APS) effect, ammonium persulphate content is to account for 2.5%～4.5% of emulsion mixture quality, carries out the silicone-modified polyacrylate emulsion that the organosilicon crylic acid latex polyreaction obtains with polyacrylic ester; The content of polyacrylic ester is 40%～45% of emulsion mixture quality, and the content of vinyltriethoxysilane is 10%～12% of emulsion mixture quality
5. water expansion fire-proof coating according to claim 3 is characterized in that, described nano-material modified flame-retardant system is by nano-TiO
2, trimeric cyanamide, tetramethylolmethane and ammonium polyphosphate form; The mass content of nano TiO 2 is 0.9%～1.2%, and the mass content of trimeric cyanamide is 9.1%～16.8%, and the mass content of tetramethylolmethane is 5%～10%, and the mass content of ammonium polyphosphate is 25%～30%.
6. water expansion fire-proof coating according to claim 4 is characterized in that described emulsifying agent is OP-9, and described softening agent is the mixture of Tritolyl Phosphate and β-trieline SULPHOSUCCINIC ACID ESTER, and mass ratio is 1: 1.1～1.3.
7. according to each described water expansion fire-proof coating of claim 3-6, it is characterized in that described toughener is the mixture of three kinds of zinc oxide, Antimony Trioxide: 99.5Min and talcum powder, mass ratio is 1.1～1.3: 1.1～1.3: 1.1～1.3; Described color stuffing is a white titanium pigment, and described dispersion agent is a Sodium hexametaphosphate 99.
8. water expansion fire-proof coating according to claim 7 is characterized in that, adopts the preparation method of the described water expansion fire-proof coating of claim 1 to be prepared from.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110172456A CN102329549A (en) | 2011-06-24 | 2011-06-24 | Water-borne inflation type refractory coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110172456A CN102329549A (en) | 2011-06-24 | 2011-06-24 | Water-borne inflation type refractory coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102329549A true CN102329549A (en) | 2012-01-25 |
Family
ID=45481523
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110172456A Pending CN102329549A (en) | 2011-06-24 | 2011-06-24 | Water-borne inflation type refractory coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102329549A (en) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102634256A (en) * | 2012-04-18 | 2012-08-15 | 北京国泰瑞华精藻硅特种材料有限公司 | Water expansion type fire-proof mildew-proof coating for tunnels |
| CN102911570A (en) * | 2012-11-02 | 2013-02-06 | 浙江志强涂料有限公司 | Environmental-friendly decorative fire retardant coating and preparation method thereof |
| CN103694832A (en) * | 2013-12-10 | 2014-04-02 | 张家港市民扬塑胶科技有限公司 | Intumescent fire-retardant coating material and preparation method thereof |
| CN103711210A (en) * | 2012-09-29 | 2014-04-09 | 北京建筑材料科学研究总院有限公司 | Method for manufacturing flame-retardant, waterproof and breathable films for external heat insulation for curtain walls |
| CN106479297A (en) * | 2016-11-21 | 2017-03-08 | 青岛爱尔家佳新材料股份有限公司 | A kind of aeroge Water-borne inflation type refractory coating and preparation method thereof |
| CN107418346A (en) * | 2017-09-17 | 2017-12-01 | 葛彬斌 | A kind of expansion type flame-retarding interior wall coating and preparation method thereof |
| CN108676410A (en) * | 2018-05-29 | 2018-10-19 | 徐红花 | A kind of Intumescent Fire Retardant Coatings for Steel Structure and preparation method thereof |
| CN108841230A (en) * | 2018-07-18 | 2018-11-20 | 合肥欧仕嘉机电设备有限公司 | A kind of New Building Materials fireproof coating and preparation method thereof |
| CN108864864A (en) * | 2018-05-29 | 2018-11-23 | 芜湖市元奎新材料科技有限公司 | Fireproofing paint for steel structure |
| CN108997911A (en) * | 2018-07-11 | 2018-12-14 | 河南爱彼爱和新材料有限公司 | A kind of aeroge fire-proof and thermal-insulation coating and preparation method thereof |
| CN109135478A (en) * | 2018-08-17 | 2019-01-04 | 盛世瑶兰（深圳）科技有限公司 | A kind of environmentally friendly fire prevention composite coating |
| CN109294383A (en) * | 2018-10-27 | 2019-02-01 | 国网河南省电力公司南阳供电公司 | A kind of fireproof coating and preparation method thereof |
| CN111500161A (en) * | 2020-05-29 | 2020-08-07 | 竺浩亮 | Water-based intumescent low-smoke fireproof coating material |
| CN114806314A (en) * | 2022-04-27 | 2022-07-29 | 菲沐盛(山西)材料科技有限公司 | P/N/Si/Ca synergistic flame-retardant water-based intumescent flame-retardant coating and preparation method thereof |
| CN115746609A (en) * | 2018-06-15 | 2023-03-07 | 博里利斯股份公司 | Flame retardant composition |
| CN116023112A (en) * | 2023-03-27 | 2023-04-28 | 广州市泓景首饰铸造材料有限公司 | Gypsum material for jewelry mold and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1030779A (en) * | 1987-07-17 | 1989-02-01 | 北京建筑防火材料喷涂工程公司 | Expansible fireproof decorative coating for steel structure |
| CN1076947A (en) * | 1992-04-01 | 1993-10-06 | 薛志纯 | Frie retardant coating |
| CN1394923A (en) * | 2001-07-10 | 2003-02-05 | 同济大学 | Water thin type expanding steel structure fire-resisting paint and its preparation method |
| CN1544552A (en) * | 2003-11-28 | 2004-11-10 | 厦门大学 | Tunnel fireproof paint based on nano-surface-treatment technology and method for making same |
| CN1680501A (en) * | 2004-04-09 | 2005-10-12 | 中国科学院金属研究所 | Weather-resistant and fire-proof nanometer coating for expanding ultrathin steel structure and production thereof |
| CN101747821A (en) * | 2008-12-09 | 2010-06-23 | 同济大学 | Steel-structure ultrathin intumescent fire retardant coating and preparation method thereof |
| CN101857760A (en) * | 2010-07-01 | 2010-10-13 | 华东理工大学 | Aqueous ultra-thin expansion type steel structure fire-proof anti-corrosive paint and preparation method thereof |
-
2011
- 2011-06-24 CN CN201110172456A patent/CN102329549A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1030779A (en) * | 1987-07-17 | 1989-02-01 | 北京建筑防火材料喷涂工程公司 | Expansible fireproof decorative coating for steel structure |
| CN1076947A (en) * | 1992-04-01 | 1993-10-06 | 薛志纯 | Frie retardant coating |
| CN1394923A (en) * | 2001-07-10 | 2003-02-05 | 同济大学 | Water thin type expanding steel structure fire-resisting paint and its preparation method |
| CN1544552A (en) * | 2003-11-28 | 2004-11-10 | 厦门大学 | Tunnel fireproof paint based on nano-surface-treatment technology and method for making same |
| CN1680501A (en) * | 2004-04-09 | 2005-10-12 | 中国科学院金属研究所 | Weather-resistant and fire-proof nanometer coating for expanding ultrathin steel structure and production thereof |
| CN101747821A (en) * | 2008-12-09 | 2010-06-23 | 同济大学 | Steel-structure ultrathin intumescent fire retardant coating and preparation method thereof |
| CN101857760A (en) * | 2010-07-01 | 2010-10-13 | 华东理工大学 | Aqueous ultra-thin expansion type steel structure fire-proof anti-corrosive paint and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 彭华乔等: "填料对膨胀型钢结构防火涂料性能影响的研究进展", 《现代涂料与涂装》 * |
| 徐晓楠等编著: "《防火涂料》", 31 January 2004 * |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102634256A (en) * | 2012-04-18 | 2012-08-15 | 北京国泰瑞华精藻硅特种材料有限公司 | Water expansion type fire-proof mildew-proof coating for tunnels |
| CN103711210A (en) * | 2012-09-29 | 2014-04-09 | 北京建筑材料科学研究总院有限公司 | Method for manufacturing flame-retardant, waterproof and breathable films for external heat insulation for curtain walls |
| CN103711210B (en) * | 2012-09-29 | 2016-05-04 | 北京建筑材料科学研究总院有限公司 | A kind of preparation method of the flame retardant type waterproof ventilated membrane for the outer insulation of curtain wall |
| CN102911570A (en) * | 2012-11-02 | 2013-02-06 | 浙江志强涂料有限公司 | Environmental-friendly decorative fire retardant coating and preparation method thereof |
| CN103694832A (en) * | 2013-12-10 | 2014-04-02 | 张家港市民扬塑胶科技有限公司 | Intumescent fire-retardant coating material and preparation method thereof |
| CN106479297A (en) * | 2016-11-21 | 2017-03-08 | 青岛爱尔家佳新材料股份有限公司 | A kind of aeroge Water-borne inflation type refractory coating and preparation method thereof |
| CN107418346A (en) * | 2017-09-17 | 2017-12-01 | 葛彬斌 | A kind of expansion type flame-retarding interior wall coating and preparation method thereof |
| CN108676410B (en) * | 2018-05-29 | 2021-01-29 | 河北掌坤科技有限公司 | Steel structure expansion type fireproof coating and preparation method thereof |
| CN108864864A (en) * | 2018-05-29 | 2018-11-23 | 芜湖市元奎新材料科技有限公司 | Fireproofing paint for steel structure |
| CN108676410A (en) * | 2018-05-29 | 2018-10-19 | 徐红花 | A kind of Intumescent Fire Retardant Coatings for Steel Structure and preparation method thereof |
| CN115746609A (en) * | 2018-06-15 | 2023-03-07 | 博里利斯股份公司 | Flame retardant composition |
| CN108997911B (en) * | 2018-07-11 | 2020-11-27 | 河南爱彼爱和新材料有限公司 | Aerogel fireproof heat-insulating coating and preparation method thereof |
| CN108997911A (en) * | 2018-07-11 | 2018-12-14 | 河南爱彼爱和新材料有限公司 | A kind of aeroge fire-proof and thermal-insulation coating and preparation method thereof |
| CN108841230A (en) * | 2018-07-18 | 2018-11-20 | 合肥欧仕嘉机电设备有限公司 | A kind of New Building Materials fireproof coating and preparation method thereof |
| CN109135478A (en) * | 2018-08-17 | 2019-01-04 | 盛世瑶兰（深圳）科技有限公司 | A kind of environmentally friendly fire prevention composite coating |
| CN109135478B (en) * | 2018-08-17 | 2021-04-30 | 河南省阳光防腐涂装有限公司 | Environment-friendly fireproof composite coating |
| CN109294383A (en) * | 2018-10-27 | 2019-02-01 | 国网河南省电力公司南阳供电公司 | A kind of fireproof coating and preparation method thereof |
| CN111500161A (en) * | 2020-05-29 | 2020-08-07 | 竺浩亮 | Water-based intumescent low-smoke fireproof coating material |
| CN114806314A (en) * | 2022-04-27 | 2022-07-29 | 菲沐盛(山西)材料科技有限公司 | P/N/Si/Ca synergistic flame-retardant water-based intumescent flame-retardant coating and preparation method thereof |
| CN114806314B (en) * | 2022-04-27 | 2023-02-03 | 菲沐盛(山西)材料科技有限公司 | P/N/Si/Ca synergistic flame-retardant water-based intumescent flame-retardant coating and preparation method thereof |
| CN116023112A (en) * | 2023-03-27 | 2023-04-28 | 广州市泓景首饰铸造材料有限公司 | Gypsum material for jewelry mold and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102329549A (en) | Water-borne inflation type refractory coating and preparation method thereof | |
| CN102040790B (en) | A kind of fireproof polyvinyl acetate emulsion and preparation method thereof | |
| CN103045037B (en) | Water-based expandable fireproof steel structure coating and preparation method | |
| CN106995643B (en) | A kind of water paint and preparation method thereof of containing graphene/zinc-aluminum gavite nano-complex | |
| CN101649153B (en) | Organic silicon modified acrylic ester aqueous wood lacquer latex and synthesizing method thereof | |
| CN104130671A (en) | Aqueous ultrathin expansion-type fireproof coating for steel structure and preparation method thereof | |
| CN103146275B (en) | A kind of Grey heat-insulation flame-retardant external wall paint | |
| CN103740231A (en) | Water-based expansive type nano fireproof coating for cable and preparation method thereof | |
| CN101323727A (en) | Environment-friendly aqueous expansion type fireproof coating and preparation thereof | |
| CN102408220A (en) | All-in-one water-borne inorganic-organic hybrid architectural coating and preparation method thereof | |
| CN102786644A (en) | Preparation method of acrylic resin finishing agent modified by nano silicon dioxide (SiO2)-coated multi-walled carbon nanotubes | |
| CN111732885B (en) | Waterborne elastic polyurethane flame-retardant coating and preparation method thereof | |
| CN103387757A (en) | Method for preparing supercritical hydrotalcite grafted with flame retardant | |
| CN102433052A (en) | Aqueous polyurethane modified silicon-acrylate multifunctional waterproof heat-insulation elastic paint and preparation method thereof | |
| CN105037804A (en) | Preparation method of synergetic silicon-magnesium composite fire retardant with core-shell structure | |
| CN102876172A (en) | Water-based fireproof paint | |
| CN104610487A (en) | Vac-veova emulsion, preparation method of vac-veova emulsion and redispersible latex powder | |
| CN112759967A (en) | Inorganic paint for water-based mineral interior wall and preparation method thereof | |
| CN109266080B (en) | Water-based smokeless and odorless inorganic nano ceramic fireproof coating and preparation method thereof | |
| CN103045047A (en) | Water-based ultrathin expansion type formed steel construction fire retardant coating based on expansible graphite and crystal whisker system | |
| CN102241931A (en) | Environment-friendly type flame-retarding and smoke-suppressing paint and preparation method thereof | |
| CN113621281B (en) | Waterproof and impervious asphalt coating and preparation method thereof | |
| CN115895309B (en) | Flame-retardant inorganic composite resin, preparation method thereof and application thereof in inorganic coating | |
| CN111500161B (en) | Water-based intumescent low-smoke fireproof coating material | |
| CN105802436B (en) | A kind of nanometer expansion-type transparent fire-retardant coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20120125 |