CN102329527A - Simple substance carbon purifying machine - Google Patents
Simple substance carbon purifying machine Download PDFInfo
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- CN102329527A CN102329527A CN201110173287A CN201110173287A CN102329527A CN 102329527 A CN102329527 A CN 102329527A CN 201110173287 A CN201110173287 A CN 201110173287A CN 201110173287 A CN201110173287 A CN 201110173287A CN 102329527 A CN102329527 A CN 102329527A
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Abstract
The invention provides a simple substance carbon purifying machine, which is characterized by consisting of a chemical combination unit, a cracking unit and a circulating unit, wherein coal is used as purification raw materials, the alive replacement performance of hydrogen gas is utilized in the chemical combination unit for reducing alkyl combined with carbon bases for forming hydrocarbon, then, the hydrocarbon is cracked through high temperature and strong heat in the cracking unit to be formed into simple substance carbon and simple substance hydrogen, the simple substance hydrogen is polymerized into hydrogen gas, and the hydrogen gas returns to the chemical combination unit through the circulating unit for being circulated again, so the simple substance carbon is obtained. The simple substance carbon purifying machine has the beneficial effects that the material taking range is wide, more carbon simple substances in carbon based compounds can be extracted, the whole machine operates in a fully sealed way, the harm of easily absorbed simple substance carbon to human bodies is avoided, the circulating unit is adopted, the simple substance hydrogen is cyclically utilized, raw materials are saved to a certain degree, and the simple substance carbon purifying machine is widely applied to simple substance carbon application industries.
Description
Technical field
The present invention relates to a kind of equipment that can make simple substance carbon, especially a kind of through refining the equipment of coal manufacturing simple substance carbon.
Background technology
Carbon black (carbon black has another name called carbon black) is a kind of decolorizing carbon.Gently, pine and superfine black powder, specific surface area is very big, scope is from 10-3000m2/g, be organism (Sweet natural gas, heavy oil, fuel wet goods) under the condition of lack of air through incomplete combustion or decomposes and product.The title that proportion 1.8-2.1 is processed by Sweet natural gas " channel black "; The title of processing by oils " dim "; Title " acetylene black " by acetylene is processed also has " channel black ", " furnace black " in addition, and distinguishing by the carbon black performance has " hard(carbon)black ", " graphitized carbon black ", " abrasion resistant carbon black " etc.Can make black dyes, be used to make ink stick, printing ink, paint etc., also be used to cook the strengthening agent of rubber.
The main application of carbon black in industry is that the adding carbon black is made tire in the rubber, can strengthen wear resistance, prolongs its work-ing life.The big purposes of it another is manufacture of ink, paint and blackwash etc.The staple of carbon dust is not a carbon, and great majority are made up of resin and carbon black, electric charge agent, magnetic etc.In the paper fiber, resin is oxidized to the gas that has pungent odour to ink powder through high temperature melt, Here it is everybody said ozone, and this gas has only a kind of benefit, preserves our planet exactly, reduces the harm of solar radiation.Human body itself is not had benefit, can cause stimulation to the human body mucous membrane, it is irritated to improve asthma incidence or nose easily, even phenomenons such as dizziness, vomiting.If it is can avirulent (as: original-pack manufacturer or Mitsubishi's carbon dust, Ba Chuan carbon dust, Central China carbon dust etc.) under the user mode that the various starting material stdn of carbon dust are manufactured on sealing.
Producing pigment sooty raw material is petroleum products and pitch coke oil prodn.Form through hydro carbons incomplete combustion or pyrolysis at high temperature.The sooty production technique mainly contains the production technique of dim production technique, channel black, the production technique and the furnace black production technique of channel black at present.
According to the AMES-test, various in the market bottled loose powder are because conditionalities such as production technology all are difficult to reach the nontoxicity requirement.
Summary of the invention
For overcome existing carbon black plant link isolated, can't eliminate toxic shortcoming of simple substance carbon and drawback fully, the object of the present invention is to provide a kind of ME in order, get the material scope and eliminate the toxic carbon black of carbon extensively, to greatest extent and make machine.
The simple substance carbon purifying machine; It is characterized in that being made up of chemical combination unit and cracking unit and cycling element, adopt coal as the purification starting material, the alkyl that in the chemical combination unit, utilizes the active in-place property of hydrogen to restore to combine carbon back forms hydrocarbon polymer; In the cracking unit, pass through high temperature fine melt hydrocarbon polymer then; Form simple substance carbon and simple substance hydrogen, simple substance hydrogen polymerization becoming hydrogen is got back to the chemical combination unit through cycling element and is circulated once more, obtains the equipment of simple substance carbon thus.
The invention has the beneficial effects as follows; It is wide to get the material scope, can extract the central carbon simple substance of more carbon group compound, and whole machine using is sealed close operation entirely; Stop to be prone to of the injury of the simple substance carbon of absorption to human body; The present invention that more holds concurrently adopts cycling element recycle simple substance hydrogen, on certain limit, has practiced thrift raw material again, is widely used in the industry that simple substance carbon is used.
Embodiment
Below in conjunction with case study on implementation the present invention is further specified
Coal cracking simple substance carbon purifying machine adopts coal as the purification starting material; The alkyl that utilizes the active in-place property of hydrogen to displace the combination carbon back forms hydrocarbon polymer; Through high temperature fine melt hydrocarbon polymer, form simple substance carbon and simple substance hydrogen again, the polymerization of simple substance hydrogen becomes hydrogen recycle to permute unit; The pollution-free purifying machine of coal cracking simple substance carbon is made up of permute unit, cracking unit, cycling element; Take coal or higher carbon compounds as raw material, utilize the active in-place property combined carbon element of hydrogen, strengthen the thermally decomposed carbon hydrogen compound in the cracking unit at permute unit; Carbon simple substance is collected as the finished product carbon black, and the polymerization of hydrogen simple substance becomes hydrogen recycle to permute unit.
Permute unit at this machine utilizes the active in-place property of hydrogen to displace the alkyl formation hydrocarbon polymer of combination carbon back; Permute unit is connected with cycling element; The hydrogen base can be replaced most of common chemical based groups, and reduction combines other base groups of carbon back under the environment of heat-flash.
The cracking unit utilizes scission reaction that carbon, hydrogen are separated adding under the environment of heat-flash, produce carbon simple substance and hydrogen simple substance, and the polymerization of hydrogen simple substance produces hydrogen recycle to permute unit, and carbon simple substance polymerization generation carbon black reclaims as finished product.
Wherein, The hydrogen collection of permute unit adopts the method for brine electrolysis to produce the required a part of hydrogen of initial operating stage; In the high pressure tank, feed direct current and be H+ and O-ionic condition so that the water of polyelectrolyte is electrolyzed to produce; The sodium potassium that O+ is prone to oxidation absorbs, thereby isolates simple substance hydrogen, and simple substance hydrogen polymerization becoming hydrogen is used in the reduction higher carbon compounds.
The cracking unit adopts the high frequency microwave concussion to make and produces high temperature in the local space; Under the environment of heat-flash; Hydrocarbon polymer is separated into carbon ion and hydrogen ion, utilizes generating positive and negative voltage to separate carbon ion and hydrogen ion again, and high pressure makes its polymerization; The carbon ion polymerization becomes the simple substance carbon black and is utilized as finished product, and the hydrogen ion polymerization becomes hydrogen recycle to permute unit.
The purpose of cycling element is that the hydrogen that complete machine is existed is utilized at permute unit and the circulation of cracking unit, imposes negative voltage and absorbs the unitary H+ of cracking of the present invention to permute unit in the cracking unit.
Claims (4)
1. simple substance carbon purifying machine; It is characterized in that being made up of chemical combination unit and cracking unit and cycling element, adopt coal as the purification starting material, the alkyl that in the chemical combination unit, utilizes the active in-place property of hydrogen to restore to combine carbon back forms hydrocarbon polymer; In the cracking unit, pass through high temperature fine melt hydrocarbon polymer then; Form simple substance carbon and simple substance hydrogen, simple substance hydrogen polymerization becoming hydrogen is got back to the chemical combination unit through cycling element and is circulated once more, obtains the equipment of simple substance carbon thus.
2. require described simple substance carbon purifying machine according to right 1; It is characterized in that: the hydrogen collection of permute unit adopts the method for brine electrolysis to produce the required a part of hydrogen of initial operating stage; In the high pressure tank, feed direct current and be H+ and O-ionic condition so that the water of polyelectrolyte is electrolyzed to produce; The sodium potassium that O+ is prone to oxidation absorbs, thereby isolates simple substance hydrogen, and simple substance hydrogen polymerization becoming hydrogen is used in the reduction higher carbon compounds.
3. require described simple substance carbon purifying machine according to right 1; It is characterized in that: the cracking unit adopts the high frequency microwave concussion to make and produces high temperature in the local space, and under the environment of heat-flash, hydrocarbon polymer is separated into carbon ion and hydrogen ion; Utilize generating positive and negative voltage to separate carbon ion and hydrogen ion again; High pressure makes its polymerization, and the carbon ion polymerization becomes the simple substance carbon black and is utilized as finished product, and the hydrogen ion polymerization becomes hydrogen recycle to permute unit.
4. require described simple substance carbon purifying machine according to right 1; It is characterized in that: the purpose of cycling element is that the hydrogen that complete machine is existed is utilized at permute unit and the circulation of cracking unit, imposes negative voltage and absorbs the unitary H+ of cracking of the present invention to permute unit in the cracking unit.
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CN201110173287A CN102329527A (en) | 2011-06-25 | 2011-06-25 | Simple substance carbon purifying machine |
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CN201110173287A CN102329527A (en) | 2011-06-25 | 2011-06-25 | Simple substance carbon purifying machine |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102732067A (en) * | 2012-07-12 | 2012-10-17 | 韩钊武 | Method for preparing carbon black with coal serving as raw material |
TWI644723B (en) * | 2016-05-20 | 2018-12-21 | 鴻海精密工業股份有限公司 | Method for making carbon fiber film |
US10386316B2 (en) | 2016-05-20 | 2019-08-20 | Tsinghua University | Device for in-situ measuring electrical properties of carbon nanotube array |
US10408871B2 (en) | 2016-05-20 | 2019-09-10 | Tsinghua University | Method for calculating surface electric field distribution of nanostructures |
US10429425B2 (en) | 2016-05-20 | 2019-10-01 | Tsinghua University | Method for detecting surface electric field distribution of nanostructures |
US10661289B2 (en) | 2016-05-20 | 2020-05-26 | Tsinghua University | Device for making charged nanoparticles |
US10844480B2 (en) | 2016-05-20 | 2020-11-24 | Tsinghua University | Method for making carbon nanotube film |
CN113493193A (en) * | 2020-03-20 | 2021-10-12 | 国家能源投资集团有限责任公司 | Amorphous carbon material and preparation method thereof, sodium ion battery cathode and sodium ion battery |
US11214860B2 (en) | 2016-05-20 | 2022-01-04 | Tsinghua University | Carbon fiber film and method for making the same |
-
2011
- 2011-06-25 CN CN201110173287A patent/CN102329527A/en active Pending
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102732067A (en) * | 2012-07-12 | 2012-10-17 | 韩钊武 | Method for preparing carbon black with coal serving as raw material |
TWI644723B (en) * | 2016-05-20 | 2018-12-21 | 鴻海精密工業股份有限公司 | Method for making carbon fiber film |
US10386316B2 (en) | 2016-05-20 | 2019-08-20 | Tsinghua University | Device for in-situ measuring electrical properties of carbon nanotube array |
US10408871B2 (en) | 2016-05-20 | 2019-09-10 | Tsinghua University | Method for calculating surface electric field distribution of nanostructures |
US10429425B2 (en) | 2016-05-20 | 2019-10-01 | Tsinghua University | Method for detecting surface electric field distribution of nanostructures |
US10563325B2 (en) | 2016-05-20 | 2020-02-18 | Tsinghua University | Method for making carbon fiber film |
US10661289B2 (en) | 2016-05-20 | 2020-05-26 | Tsinghua University | Device for making charged nanoparticles |
US10844480B2 (en) | 2016-05-20 | 2020-11-24 | Tsinghua University | Method for making carbon nanotube film |
US11214860B2 (en) | 2016-05-20 | 2022-01-04 | Tsinghua University | Carbon fiber film and method for making the same |
CN113493193A (en) * | 2020-03-20 | 2021-10-12 | 国家能源投资集团有限责任公司 | Amorphous carbon material and preparation method thereof, sodium ion battery cathode and sodium ion battery |
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Application publication date: 20120125 |