CN102328477B - Method for compounding double-layer plating films on plastic surface by fully dry method - Google Patents
Method for compounding double-layer plating films on plastic surface by fully dry method Download PDFInfo
- Publication number
- CN102328477B CN102328477B CN201110143826.XA CN201110143826A CN102328477B CN 102328477 B CN102328477 B CN 102328477B CN 201110143826 A CN201110143826 A CN 201110143826A CN 102328477 B CN102328477 B CN 102328477B
- Authority
- CN
- China
- Prior art keywords
- plastic
- metal
- plating
- plastic cement
- double
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Landscapes
- Physical Vapour Deposition (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
The invention provides a method for compounding double-layer plating films on the plastic surface by a fully dry method, which relates to a method for obtaining a metal compound layer on the plastic surface. Pigment is added into plastic cement master batch for carrying out dyeing treatment, then, the materials are formed into plastic cement blanks through injection molding, the plastic cement blanks are cleaned and activated by a dry method, the activated plastic cement blanks are sprayed and coated with organic coating layers, the plastic blanks are placed into a physical gas-phase furnace to plate metal ceramic composite films, and final products are obtained. Through tests, the metallized plastic products prepared by the method have the advantages of anti-corrosion, wear resistance, weather resistance, temperature resistance, colorful performance and the like, in addition, the surface is hard and smooth, the quality of the prepared metallized plastic products is comparable to the quality of traditional water electroplating metal products, the coarsening and activating and water washing processes in the traditional water electroplating process are omitted, no harmful electroplating liquid medicine is adopted, and the toxic hexavalent chromium is not adopted. In the process, the metal consumption is low, the waste gas is little, and the complete waste-water-free discharge is also realized. The function and the quality of the plastic surface treatment product can be improved, the production cost can be reduced, the efficiency can be improved, the water is saved, and the environment is protected.
Description
Technical field
The present invention relates to obtain at frosting the method for metal composite layer, particularly relate to a kind of method of full-dry method at the frosting double-layer plating that adopt.
Background technology
Carry out traditional water (wet method) at frosting and electroplate and can obtain high anticorrosion, high abrasion, DE Specular Lighting and to decorate extremely strong product, this kind of plastic-metal (plating Cu/Ni/Cr metal film) is widely used, and for a long time prevailing.But there is following shortcoming in the water power depositing process: the power consumption of (1) water consumption is large, and a large amount of waste water of output.(2) use harmful chemical plating fluid and additive.(3) discharge poisonous fume.(4) the consumption amount of metal is large.(5) use harmful Cr VI.Obviously, this traditional handicraft environmental pollution and harm are quite large, need improvement badly.For many years, numerous scientific research persons are devoted to traditional water power depositing process and improve, and obtain certain initial achievements: the dry method coating process is developed, and its application can replace the partly plastic electroplated product.As Chinese patent CN101338409 discloses a kind of coating method of automobile hub cover, comprise successively the steps such as pretreatment, photocuring primary coat, Ions Bombardment chromium plating, the painting of photocuring face.This dry method plating method, not containing noxious material, does not have three wastes problem, without the three wastes, processes, and technical process is simple, environmentally safe.Workman's working condition is good, little on the healthy impact of workman.Do not need to use the precious metals such as copper, nickel, chromium, only use a small amount of aluminium, cost reduces greatly.Technique is simple, and operation is few, and production cost is low.Power consumption is about 1/5～1/7 of plating, and water consumption is about 1/10～1/20 of plating.The integral production cost is about 1/2 of plating, has higher economic benefit.And be coated with in raw material and add Nano Ceramic Particles at the photocuring face, improved dispersion and hybrid technique, significantly improved surface abrasion resistance.
Chinese patent CN1468976 discloses a kind of suitable metal and nonmetallic surface treatment method, mainly because existing surface treatment method environmental pollution is serious, and after processing, its anticorrosion ability and surface gloss are poor, be that a kind of tool electric conductivity of research and development can be for the fixed mount of article location, article are positioned on fixed support, prior to a counterdie on article surface, form electrodeposition of metals with vacuum plating again, afterwards, fixed mount is directly carried out to electricity together with article and coating, make the electrodeposited coating surface form corrosion resistance high, wear-resisting, the acrylic layer of tool glossiness, can effectively improve by this problem that the general surface processing method exists.Above-mentioned dry method plated film also has the electrophoretic painting of employing to do finish paint.Yet this dry method coating technique still exists following problem and shortcoming:
1) cleaning used and deoiling step are still mostly used chemical agent, and discharge waste water.
2) outside surperficial organic coating directly is exposed to, weather-proof and resistance to water is comparatively poor.
3) outermost layer is organic matter, and non-metallic film, therefore hardness is poor, lacks metal-like.
4) need spraying priming paint and finish paint, yields is not high, and the VOC discharge capacity is high, not environmental protection.
The applicant provides a kind of composite interlayer coating technology in Chinese patent 201010585736.1, but this kind of dry method plated film still needs three road plated films, and cost and energy consumption are still higher.
Summary of the invention
The object of the invention is to for the existing shortcoming of existing dry method plated film, a kind of function and quality that promotes the frosting treatment product is provided, can reduce production costs, can raise the efficiency, the employing full-dry method of water-saving and environmental protection is in the method for frosting double-layer plating.
The present invention includes following steps:
1) add pigment in plastic mother granules, the processing of dyeing, then injection mo(u)lding plastic cement blank;
In step 1) in, described plastic mother granules is optional from thermoplasticity plastic cement or thermosetting plastic etc., and described thermoplastic plastic can be selected from a kind of in the thermoplastic plastics such as ABS, PC/ABS, HIPS, PC, PPO, PP, PBT, PPS, PERT, HDPE, PA6, PA66, ABS/TPU, PMMA, PLA; Described thermosetting plastic can be selected from BMC etc.; Described pigment can be selected from red metal, red copper, brass, bronze, nickel look, a kind of in stainless steel colored etc.
3) the plastic cement blank is carried out to dry clean and activation;
In step 2) in, the concrete grammar of described dry clean is as follows: first use dry cloth wiping plastic cement blank surface, remove grease and dust, then utilize the grease of high-temperature flame treatment metal surface, reach the purpose of oil removing grease removal, by electrostatic precipitation, remove the dust that is adsorbed on plastic cement blank surface and the particle that burns and produce again;
The concrete grammar of described activation is as follows: the extension contacting metal surface by high-temperature flame treatment, and make its moment reach the high temperature of 1000 ℃, make outer metallic surface there are a large amount of polar bonds, be easy to paint film and form good combination power.
Described high-temperature flame treatment, can adopt gas as burning gases, processing time 1～60s.
3) the plastic cement blank after activating, be coated with organic coating;
In step 3) in, the thickness of described organic coating can be 5～60 μ m; Described organic coating can be colourless or color, described color are arranged can be all kinds of colors such as gold, silver color, coppery, nickel look, black, redness, yellow; Described organic coating can be that ultraviolet light polymerization is crosslinked or heat cure is crosslinked; The crosslinked time of described ultraviolet light polymerization can be 10～120s; The crosslinked temperature of described heat cure can be 70～180 ℃, and the crosslinked time of described heat cure can be 10～60min.
4) by step 3) the plastics blank that obtains puts into physical vapour deposition (PVD) (PVD) stove plating ceramic composite membrane, obtains final products.
In step 4) in, the thickness of described metal ceramic composite membrane can be 0.05～5 μ m; Described metal can adopt single metal or the various metals alloys such as copper, nickel, chromium, aluminium, stainless steel, zirconium or titanium, or the compound of the metals such as copper, nickel, chromium, aluminium, stainless steel, zirconium or titanium; The method of described plating ceramic composite membrane can be:
The plastics blank is turned linked to physical vapour deposition (PVD) (PVD) stove, connect ion gun, logical protective gas, the rete that sprays paint after solidifying carries out the activation of ion aura; Close ion gun, open electric arc target, sputtering target or evaporation power supply, carry out the plating ceramic composite membrane;
Described protective gas can adopt nitrogen, argon gas or oxygen etc.; The time of described ion aura activation can be 1～10min; The time of described vacuum metal film plating can be 1～30min.
Because film layer structure of the present invention adopts one deck organic coating, the layer of metal ceramic layer, be referred to as double-layer plating; Play the effects such as levelling, covering blank blemish, raising glossiness by organic coating, again by the high hard wear-proof metal ceramic composite membrane of PVD (physical vapour deposition (PVD)) plating, play the effect of wear-resisting Hardening, reach the product of electroplating the identical appearance effect with existing traditional water (wet method).
After tested, the advantages such as that the metal plastic goods that made by the present invention not only have is anticorrosion, wear-resisting, weather-proof, heatproof and colorful property, and surface is hard level and smooth, can compare favourably with traditional water (wet method) plated metal product quality, dispel alligatoring, activation water-washing process in traditional water (wet method) plating, do not use any harmful electroplating liquid medicine, especially do not adopt poisonous Cr VI.Simultaneously, in process, the metal consumption is little, and waste gas is few, and complete non-wastewater discharge again, therefore be the Novel film-coated technology of a kind of economy and environmental protection.The present invention has opened up wide spectrum metallization of plastic surface field, plates out product function excellence and good appearance, is highly suitable for bathroom, electronics, household electrical appliances and automobile and other industries.
The accompanying drawing explanation
The Electronic Speculum figure that Fig. 1 is the embodiment of the present invention (100 times).In Fig. 1, respectively be labeled as: 1 is metal ceramic composite membrane, and 2 is organic coating, and 3 is plastic basis material.
The specific embodiment
The present invention is further illustrated in connection with accompanying drawing for following examples.
1 one kinds of ABS material Cr VI light chromium taps of embodiment
1) the ABS master batch that silvery white processes of having illicit sexual relations, the injection mo(u)lding blank, carry out flame and clean and activation after dry cloth wiping, then electrostatic precipitation, and wherein the flame treatment time is 4s.
2) workpiece after the cleaning, the thick ultraviolet-curing paint of spray one deck 20 μ m.Heat levelling (60 ℃ * 8min) with infrared lamp, then solidify (1000J/m through ultraviolet lamp
2* 40s).
The blank that 3) will spray ultraviolet-curing paint turn linked in PVD (physical vapour deposition (PVD)) stove, implement the plasma gas activation (condition: ion gun electric current 0.3A, bias voltage 100V, vacuum pressure 0.2Pa in stove, working air current is Ar
2and O
2mixed airflow, blending ratio 50SCCM: 50SCCM, soak time 5min); Then on lacquer painting, plating a layer thickness is that (the arc coating deposition condition: chromium target current 80A, bias voltage 70V, pass into 30SCCM Ar to 0.1 μ m metal film Cr
2, vacuum pressure 0.2Pa, plated film time 1min), then plating a layer thickness is that (the arc coating deposition condition: chromium target current 80A, bias voltage 70V, pass into 100SCCM Ar to 0.3um chromium nitride ceramic membrane
2100SCCM N
2, vacuum pressure 0.4Pa, plated film time 10min), (the arc coating deposition condition: chromium target current 80A, bias voltage 70V, pass into 30SCCM Ar then to plate layer of metal film Cr again
2, vacuum pressure 0.2Pa, plated film time 2min).
Technique resulting product thus, surperficial high light is as mirror, and can be by following functional test:
(A) CASS anticorrosion: 8h;
(B) 8 circulations of thermal shock circulation;
(C) knockout impacts: the 18L knockout;
(D) adhesion (hundred cut): 5A;
(E) water logging is 38 ℃: 24h;
(F) pencil hardness (Mitsubishi): 3H;
(G) the wear-resisting test of RCA: 500 times.
Fig. 1 provides the Electronic Speculum figure (100 times) of the embodiment of the present invention.In Fig. 1, respectively be labeled as: 1 is metal ceramic composite membrane, and 2 is organic coating, and 3 is plastic basis material.
2 one kinds of imitative golden handles of nylon material plating of embodiment
1) the golden PA master batch of processing of having illicit sexual relations, the injection mo(u)lding blank, carry out flame and clean and activation after dry cloth wiping, then electrostatic precipitation, and wherein the flame treatment time is 12s.
2) the thick heat curing coating of spray one deck 30 μ m, by levelling temperature (60 ℃ * 15min), then through solidifying (80 ℃ * 25min).
3) blank of sprayed coating is turned linked to into implement in PVD (physical vapour deposition (PVD)) stove the plasma gas activation (condition: ion gun electric current 0.3A, bias voltage 100V, vacuum pressure 0.2Pa in stove, working air current is Ar
2and O
2mixed airflow, blending ratio 70SCCM: 30SCCM, soak time 5min); Then on lacquer painting, plating a layer thickness is that (the arc coating deposition condition: zirconium target current 120A, bias voltage 70V, pass into 50SCCM Ar to 0.1 μ m metal film Zr
2, vacuum pressure 0.2Pa, plated film time 2min), (the arc coating deposition condition: zirconium target current 120A, bias voltage 70V, pass into 200SCCM N then to plate one deck 0.3um zirconium nitride film again
2, vacuum pressure 0.4Pa, plated film time 3min).
Technique resulting product thus, surperficial high light is as mirror, and can be by following functional test:
(A) CASS anticorrosion: 16h;
(B) 8 circulations of thermal shock circulation;
(C) knockout impacts: the 18L knockout;
(D) adhesion (hundred cut): 5A;
(E) water logging is 38 ℃: 24h;
(F) pencil hardness (Mitsubishi): 2H;
(G) the wear-resisting test of RCA: 500 times.
3 one kinds of stainless steel colored refrigerator handles of BMC material of embodiment
1) will the have illicit sexual relations BMC bulk particle of stainless steel colored processing, the injection mo(u)lding blank, carry out flame and clean and activation after dry cloth wiping, then electrostatic precipitation, and wherein the flame treatment time is 15s.
2) workpiece is preheating to 120 degree, the thick heat curing coating of spray one deck 50 μ m, and heat curing coating preheat temperature (130 ℃ * 5min), then through levelling (150 ℃ * 5min), then through solidifying (170 ℃ * 20min).
3) blank of sprayed coating is turned linked to into implement in PVD (physical vapour deposition (PVD)) stove the plasma gas activation (condition: ion gun electric current 0.3A, bias voltage 120V, vacuum pressure 0.2Pa in stove, working air current is Ar
2and O
2mixed airflow, blending ratio 50SCCM: 100SCCM, soak time 5min); Then on lacquer painting, plating a layer thickness is that (the arc coating deposition condition: zirconium target current 120A, bias voltage 70V, pass into 50SCCM Ar to 0.1 μ m metal film Zr
2, vacuum pressure 0.2Pa, plated film time 1min), (the arc coating deposition condition: zirconium target current 120A, bias voltage 70V, pass into Ar 100SCCM80SCCM N then to plate one deck 0.6um zirconium nitride film again
2, vacuum pressure 0.3Pa, plated film time 6min).
Technique resulting product thus, surperficial high light is as mirror, and can be by following functional test:
(A) CASS anticorrosion: 16h;
(B) 8 circulations of thermal shock circulation;
(C) knockout impacts: the 18L knockout;
(D) adhesion (hundred cut): 5A;
(E) water logging is 38 ℃: 24h;
(F) pencil hardness (Mitsubishi): 3H;
(G) the wear-resisting test of RCA: 500 times.
4 one kinds of pp material silvery whites of embodiment are decorated photo frame
1) will dye the photo frame that silvery white pp material is arranged and carry out carrying out flame cleaning and activation after dry cloth wiping, then electrostatic precipitation, wherein the flame treatment time is 4s.
2) the thick ultraviolet-curing paint of spraying one deck 20 μ m.Heat levelling (50 ℃ * 10min) with infrared lamp, then solidify (1200J/m through ultraviolet lamp
2* 40s).
3) blank sprayed is turned linked to into implement in PVD (physical vapour deposition (PVD)) stove the plasma gas activation (condition: ion gun electric current 0.4A, bias voltage 150V, vacuum pressure 0.4Pa in stove, working air current is Ar
2and O
2mixed airflow, blending ratio 100SCCM: 100SCCM, soak time 5min); Then on lacquer painting, plating a layer thickness is that (the arc coating deposition condition: chromium target current 100A, bias voltage 70V, pass into 50SCCM Ar to 0.1 μ m metal film Cr
2, vacuum pressure 0.2Pa, plated film time 1min), (the arc coating deposition condition: chromium target current 80A, bias voltage 120V, pass into Ar 100SCCM20SCCM N then to plate one deck 0.2um chromium nitride again
2, vacuum pressure 0.3Pa, plated film time 5min).
Technique resulting product thus, surperficial high light is as mirror, and can be by following functional test:
(A) CASS anticorrosion: 48h;
(B) 8 circulations of thermal shock circulation;
(C) knockout impacts: the 18L knockout;
(D) adhesion (hundred cut): 5A;
(E) water logging is 38 ℃: 24h;
(F) pencil hardness (Mitsubishi): 3H;
(G) the wear-resisting test of RCA: 300 times.
Above functional test comprises:
1, anticorrosive functional test:
CASS tests (ASTM B368-09);
2, abrasion resisting functional test:
Sand trail (ASTM D968-05).
3, adhesion test:
1) hundred cut test (ASTM D3359-02);
2) thermal cycling test (ASME A112.18.1-2005/CSA B125.1-05).
4, water-fast test
Water logging test (ASTM D870-02).
5, scratch resistance test
1) pencil hardness test (ASTM D3363-05);
2) scratch resistance test (ASTM D5178-9).
Claims (6)
1. one kind adopts the method for full-dry method at the frosting double-layer plating, it is characterized in that comprising the following steps:
1) add pigment in plastic mother granules, the processing of dyeing, then injection mo(u)lding plastic cement blank; Described plastic mother granules is selected from thermoplastic plastic or thermosetting plastic; Described thermoplastic plastic is selected from a kind of in ABS, PC/ABS, HIPS, PC, PPO, PP, PBT, PPS, PERT, HDPE, PA6, PA66, ABS/TPU, PMMA, PLA thermoplastic plastic; Described thermosetting plastic is selected from BMC;
2) the plastic cement blank is carried out to dry clean and activation; The concrete grammar of described dry clean is as follows: first use dry cloth wiping plastic cement blank surface, remove grease and dust, then utilize the grease of high-temperature flame treatment metal surface, reach the purpose of oil removing grease removal, by electrostatic precipitation, remove the dust that is adsorbed on plastic cement blank surface and the particle that burns and produce again; The concrete grammar of described activation is as follows: the extension contacting metal surface by high-temperature flame treatment makes its moment reach the high temperature of 1000 ℃;
3) the plastic cement blank after activating, be coated with organic coating; Described organic coating is that ultraviolet light polymerization is crosslinked or heat cure is crosslinked; The crosslinked time of described ultraviolet light polymerization is 10～120s; The crosslinked temperature of described heat cure is 70～180 ℃, and the crosslinked time of described heat cure is 10～60min;
4) plastics blank step 3) obtained is put into physical vapour deposition (PVD) stove plating ceramic composite membrane, obtains final products; The thickness of described metal ceramic composite membrane is 0.05～5 μ m; Described metal adopts copper, nickel, chromium, aluminium, stainless steel, zirconium or the single metal of titanium or various metals alloy, or the compound of copper, nickel, chromium, aluminium, stainless steel, zirconium or titanium.
2. a kind of method of full-dry method at the frosting double-layer plating that adopt as claimed in claim 1, is characterized in that in step 1), and described pigment is selected from red metal, red copper, brass, bronze, nickel look, a kind of in stainless steel colored.
3. a kind of method of full-dry method at the frosting double-layer plating that adopt as claimed in claim 1, is characterized in that in step 2) in, described high-temperature flame treatment, be to adopt gas as burning gases, processing time 1～60s.
4. a kind of method of full-dry method at the frosting double-layer plating that adopt as claimed in claim 1, is characterized in that in step 3), and the thickness of described organic coating is 5～60 μ m; Described organic coating is colourless or color, described color are arranged is gold, silver color, coppery, nickel look, black, redness, yellow.
5. a kind of method of full-dry method at the frosting double-layer plating that adopt as claimed in claim 1, is characterized in that in step 4), and the method for described plating ceramic composite membrane is:
The plastics blank is turned linked to the physical vapour deposition (PVD) stove, connect ion gun, logical protective gas, the rete that sprays paint after solidifying carries out the activation of ion aura; Close ion gun, open electric arc target, sputtering target or evaporation power supply, carry out the plating ceramic composite membrane.
6. a kind of method of full-dry method at the frosting double-layer plating that adopt as claimed in claim 1, is characterized in that in step 4), and described protective gas adopts nitrogen, argon gas or oxygen; The time of described ion aura activation is 1～10min; The time of described vacuum metal film plating is 1～30min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110143826.XA CN102328477B (en) | 2011-05-31 | 2011-05-31 | Method for compounding double-layer plating films on plastic surface by fully dry method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110143826.XA CN102328477B (en) | 2011-05-31 | 2011-05-31 | Method for compounding double-layer plating films on plastic surface by fully dry method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102328477A CN102328477A (en) | 2012-01-25 |
| CN102328477B true CN102328477B (en) | 2014-01-08 |
Family
ID=45480564
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110143826.XA Active CN102328477B (en) | 2011-05-31 | 2011-05-31 | Method for compounding double-layer plating films on plastic surface by fully dry method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102328477B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103568428B (en) * | 2013-11-14 | 2016-01-13 | 厦门建霖工业有限公司 | A kind of Hard film structure be applied on engineering plastics and preparation method thereof |
| CN104858092A (en) * | 2015-06-02 | 2015-08-26 | 周健华 | Vacuum plating paint spraying process and system |
| CN105276283A (en) * | 2015-09-29 | 2016-01-27 | 李文霞 | Manufacturing method of plastic valve with metal feeling |
| CN109666910B (en) * | 2018-12-29 | 2021-06-11 | 金华万得福日用品股份有限公司 | Production process of coated plastic tableware |
| CN111534798A (en) * | 2020-03-31 | 2020-08-14 | 成霖企业股份有限公司 | Base material dry-type surface treatment method and bathroom accessory applying same |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1388186A (en) * | 2001-05-25 | 2003-01-01 | 日本油漆株式会社 | Method for coating plastic moulded prodcts with evaporated metal ultraviolet photocureable priming paint and plastic moulded goods |
| CN1651266A (en) * | 2004-02-02 | 2005-08-10 | 精工爱普生株式会社 | Plastics ornament,its mfg. method and timepiece |
| CN1754006A (en) * | 2002-11-08 | 2006-03-29 | 应用薄膜两合公司 | Coating for a plastic substrate |
| CN1986869A (en) | 2005-12-22 | 2007-06-27 | 佛山市顺德区汉达精密电子科技有限公司 | Plastic surface vacuum plating process |
| CN101220454A (en) * | 2008-01-16 | 2008-07-16 | 哈尔滨工业大学 | Method for manufacturing surface antimicrobial, abrasion-proof metal/ceramic nano-multilayer film |
| CN101985738A (en) * | 2009-07-29 | 2011-03-16 | 中国科学院福建物质结构研究所 | Method for depositing metal or hard ornament film on plastic substrate |
-
2011
- 2011-05-31 CN CN201110143826.XA patent/CN102328477B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1388186A (en) * | 2001-05-25 | 2003-01-01 | 日本油漆株式会社 | Method for coating plastic moulded prodcts with evaporated metal ultraviolet photocureable priming paint and plastic moulded goods |
| CN1754006A (en) * | 2002-11-08 | 2006-03-29 | 应用薄膜两合公司 | Coating for a plastic substrate |
| CN1651266A (en) * | 2004-02-02 | 2005-08-10 | 精工爱普生株式会社 | Plastics ornament,its mfg. method and timepiece |
| CN1986869A (en) | 2005-12-22 | 2007-06-27 | 佛山市顺德区汉达精密电子科技有限公司 | Plastic surface vacuum plating process |
| CN101220454A (en) * | 2008-01-16 | 2008-07-16 | 哈尔滨工业大学 | Method for manufacturing surface antimicrobial, abrasion-proof metal/ceramic nano-multilayer film |
| CN101985738A (en) * | 2009-07-29 | 2011-03-16 | 中国科学院福建物质结构研究所 | Method for depositing metal or hard ornament film on plastic substrate |
Non-Patent Citations (2)
| Title |
|---|
| 塑料涂饰前的表面处理技术;孙永泰;《塑料助剂》;20070228(第1期);第55-56页 * |
| 孙永泰.塑料涂饰前的表面处理技术.《塑料助剂》.2007,(第1期),第55-56页. |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102328477A (en) | 2012-01-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102152541B (en) | Method for preparing composite interlayer coating film on surface of engineering plastics | |
| CN102218393B (en) | Method for coating double-layer composite film on surface of metal by adopting fully drying method | |
| CN102218961B (en) | Environment-friendly coating method for implementing blackening bronze wire drawing element on metal piece | |
| CN102166565B (en) | Method for applying metal wire-imitated coating film on surface of engineering plastics | |
| CN100507080C (en) | Technological process for aluminizing or coppering on aluminum or aluminum-magnesium alloy substrate | |
| CN102328477B (en) | Method for compounding double-layer plating films on plastic surface by fully dry method | |
| CN102758176A (en) | Method for carrying out full dry method composite film plating on metal surface | |
| CN102728529B (en) | Metal alloy imitation hexavalent chromium color high-corrosion-resistant dry surface processing method | |
| CN102978571B (en) | Fully dry wire drawing method for plastic base material | |
| CN102501463B (en) | Method for preparing simulated metal drawn wire on surface of plastic | |
| CN102758170B (en) | Method for high-power vacuum plating and antique color wire drawing of plastic substrate | |
| CN101469427A (en) | Nano spray plating technique for silver mirror | |
| CN102371722B (en) | Film coating method for implementing blackened bronze and antique nickel wire-drawing component on plastic | |
| CN102851639B (en) | Environment-friendly electroless plating drawn wire-imitating surface treatment method for engineering plastic | |
| CN104384088A (en) | Electroplating-free antique metal surface treatment method | |
| CN106319446A (en) | Preparation method for decorative film bottoming vacuum coating | |
| CN107253343A (en) | The preparation method of car light ornamental strip | |
| CN106086790B (en) | A kind of kirsite antique copper vacuum coating method | |
| CN106011762A (en) | Car trim and preparation method of surface coating of car trim | |
| CN101700703B (en) | Chromium-plated plastic product | |
| CN103397328B (en) | A kind of absolutely dry method of carrying out high decoration functions composite film coating in metallic surface | |
| CN102328471B (en) | Hexavalent-chromium appearance imitated anti-corrosion membrane plating method | |
| CN102758178B (en) | Method for high-power vacuum plating and wire drawing of plastic substrate | |
| CN104647854B (en) | It is a kind of to replace material surface decoration overcoat of plating and preparation method thereof | |
| CN104099616B (en) | The chromic surface treatment method of the imitative plating of a kind of zinc alloy high-hardness wear-resistant |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: Tianfeng road in Jimei District of Xiamen City, Fujian Province, No. 69 361000 Patentee after: Xiamen Jian Lin health home Limited by Share Ltd Address before: 361000, room 12, building 1208, lotus tower, 859 Lotus Road, Fujian, Xiamen Patentee before: Xiamen Runner Industrial Corporation |