CN102311634A - PPO (poly phenylene oxide) composite material as well as preparation method and application thereof - Google Patents
PPO (poly phenylene oxide) composite material as well as preparation method and application thereof Download PDFInfo
- Publication number
- CN102311634A CN102311634A CN201110110706A CN201110110706A CN102311634A CN 102311634 A CN102311634 A CN 102311634A CN 201110110706 A CN201110110706 A CN 201110110706A CN 201110110706 A CN201110110706 A CN 201110110706A CN 102311634 A CN102311634 A CN 102311634A
- Authority
- CN
- China
- Prior art keywords
- percentage composition
- quality percentage
- ppo
- composite material
- matrix material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 28
- 239000002131 composite material Substances 0.000 title claims abstract description 26
- 239000004721 Polyphenylene oxide Substances 0.000 title abstract description 64
- 229920006380 polyphenylene oxide Polymers 0.000 title abstract description 64
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 claims abstract description 25
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000011787 zinc oxide Substances 0.000 claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 18
- 239000000314 lubricant Substances 0.000 claims abstract description 18
- 239000006229 carbon black Substances 0.000 claims abstract description 17
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims description 158
- 239000011159 matrix material Substances 0.000 claims description 44
- -1 nonyl phenyl ester Chemical class 0.000 claims description 19
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 19
- 238000002156 mixing Methods 0.000 claims description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 8
- 238000012545 processing Methods 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 4
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 claims description 3
- 235000010290 biphenyl Nutrition 0.000 claims description 3
- 239000004305 biphenyl Substances 0.000 claims description 3
- 125000006267 biphenyl group Chemical group 0.000 claims description 3
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 abstract description 7
- 230000003712 anti-aging effect Effects 0.000 abstract description 7
- 230000007062 hydrolysis Effects 0.000 abstract description 4
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 4
- 229920006351 engineering plastic Polymers 0.000 abstract description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- BJRMDQLATQGMCQ-UHFFFAOYSA-N C=C.C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 Chemical compound C=C.C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 BJRMDQLATQGMCQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003508 Dilauryl thiodipropionate Substances 0.000 abstract 1
- BQPNUOYXSVUVMY-UHFFFAOYSA-N [4-[2-(4-diphenoxyphosphoryloxyphenyl)propan-2-yl]phenyl] diphenyl phosphate Chemical compound C=1C=C(OP(=O)(OC=2C=CC=CC=2)OC=2C=CC=CC=2)C=CC=1C(C)(C)C(C=C1)=CC=C1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 BQPNUOYXSVUVMY-UHFFFAOYSA-N 0.000 abstract 1
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 abstract 1
- 229920013636 polyphenyl ether polymer Polymers 0.000 abstract 1
- 229920002223 polystyrene Polymers 0.000 abstract 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 26
- 230000000052 comparative effect Effects 0.000 description 16
- 229960003742 phenol Drugs 0.000 description 13
- 238000010438 heat treatment Methods 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- 238000005453 pelletization Methods 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- 230000032683 aging Effects 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- DRITYCRTIHBMEO-UHFFFAOYSA-N C1(=CC=CC=C1)CCC1=C(C=CC=C1)O.CC1(C(=O)O)CC(C(=O)O)=CC=C1 Chemical compound C1(=CC=CC=C1)CCC1=C(C=CC=C1)O.CC1(C(=O)O)CC(C(=O)O)=CC=C1 DRITYCRTIHBMEO-UHFFFAOYSA-N 0.000 description 2
- TXQVDVNAKHFQPP-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CO)(CO)CO TXQVDVNAKHFQPP-UHFFFAOYSA-N 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 2
- 239000012964 benzotriazole Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 230000004224 protection Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- IPBIPEHNUKRTBD-UHFFFAOYSA-N 2-butan-2-yl-6-butylphenol Chemical group CCCCC1=CC=CC(C(C)CC)=C1O IPBIPEHNUKRTBD-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229940045860 white wax Drugs 0.000 description 1
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 1
Images
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention is applicable to the technical field of engineering plastics and provides a PPO (poly phenylene oxide) composite material as well as a preparation method and application thereof. The PPO composite material comprises the following components by percent: polyphenyl ether, polystyrene, bisphenol A bis(diphenyl phosphate), SEBS (styrene ethylene butadiene styrene), triethylene glycol bis-3-(3-tertiary butyl-4-hydroxy-5-methylbenzene phenyl) acrylate, dilauryl thiodipropionate, tri(nonylphenyl) phosphite, zinc oxide, an uvioresistant agent, carbon black and a lubricating agent. In the invention, the PPO composite material prepared from the above components has excellent mechanical properties and excellent anti-aging, uvioresistant and hydrolysis-resistant properties; and the preparation method of the PPO composite material provided by the invention is simple to operate and low in cost, and is applicable to industrialized application.
Description
Technical field
The invention belongs to the engineering plastics technical field, relate in particular to a kind of PPO matrix material, its preparation method and application.
Background technology
That gets does not advance, and nexhaustible sun power is because of its safety, green grass or young crops clean, that environmental protection more and more receives people narrow.The photovoltaic industry becomes the sunrise industry that competitively chase in the whole world, and in China, more and more enterprises is come in the middle of joining this " industry day by day ", and China has become global the third-largest photovoltaic manufacture base, is only second to Japan, Germany.Simultaneously, also promoted the development of sun power related components industry, like photovoltaic terminal box, photovoltaic connector, unit, invertor, store battery or the like.The photovoltaic terminal box is as a vitals of solar module; Be between the solar cell array of solar module formation and the junctor between the rechargeable solar battery gear; Be the cross-cutting comprehensive design that the design of a current collection gas, Machine Design and Materials science combine, the scheme that is connected of solar panel is provided for the user.
As a kind of junctor of solar module, photovoltaic terminal box significant feature is exactly that the electric energy that solar module produces is derived through cable.Because the singularity of solar cell use occasion and the costliness of itself are worth, the photovoltaic terminal box must have following main characteristic: (one) shell has anti-aging, the ultraviolet-resistant capacity of intensive; (2) accord with request for utilization under the outdoor severe environmental conditions; (3) outstanding radiating mode effectively reduces internal temperature with rational cavity volume, to satisfy the electrical safety requirement; (4) excellent waterproof, proofing dust and protecting provide safe connectivity scenario for the user.
At present, the time limit of service of photovoltaic terminal box is shorter, and the used plastics of photovoltaic terminal box use out of doors, can not resist the erosion of solar ultraviolet, airborne moisture etc. for a long time.
Summary of the invention
In view of this, it is a kind of anti-aging that the embodiment of the invention provides, uvioresistant, PPO matrix material, its preparation method and application that the photovoltaic terminal box of hydrolysis is used.
The present invention is achieved in that
A kind of PPO matrix material comprises the component of following quality percentage composition:
And,
A kind of PPO composite material and preparation method thereof comprises the steps:
The quality percentage composition is respectively the SEBS of 3-8%, the BDP mixing of 5-12%; Add the quality percentage composition be respectively the triglycol of PS, 0.1-0.3% of ppe, the 10-35% of 50-75% two-3-(3-tertiary butyl-4-hydroxy-5-toluene phenyl) propenoate, the Tyox B of 0.1-0.3%, the tricresyl phosphite (nonyl phenyl ester) of 0.1-0.3%, the zinc oxide of 0.1-0.3%, the anti UV agent of 0.2-0.8, the carbon black of 0.5-2.5% and the lubricant of 0.5-1.0%, mix obtaining mixture;
This mixture is extruded processing, obtain the PPO matrix material.
Embodiment of the invention PPO matrix material through selecting said components and content for use, makes the mechanical property that having of PPO matrix material is excellent, and excellent is anti-aging, uvioresistant, the hydrolysis characteristic can, be very suitable for being used in the photovoltaic terminal box; Embodiment of the invention PPO composite material and preparation method thereof, simple to operate, with low cost, be suitable for industrial applications.
Description of drawings
Fig. 1 is an embodiment of the invention PPO composite material and preparation method thereof schema.
Embodiment
In order to make the object of the invention, technical scheme and advantage clearer,, the present invention is further elaborated below in conjunction with accompanying drawing and embodiment.Should be appreciated that specific embodiment described herein only in order to explanation the present invention, and be not used in qualification the present invention.
The embodiment of the invention provides a kind of PPO matrix material, comprises the component of following quality percentage composition:
The quality percentage composition of this ppe is 50-70% in the embodiment of the invention PPO matrix material particularly, is preferably 60-65%.
Particularly, this PS is General Purpose Polystyrenre GPPS, and in the embodiment of the invention PPO matrix material, the quality percentage composition of PS is 10-35%, is preferably 18-22%.
Particularly, this dihydroxyphenyl propane two (diphenyl phosphoesters) also is halogen-free flame retardants BDP, belongs to a kind of in the phosphorus flame retardant, and wherein phosphorus content is 8.9%.In the embodiment of the invention PPO matrix material, the quality percentage composition of dihydroxyphenyl propane two (diphenyl phosphoester) is 5-12%, is preferably 8-11%.
Particularly, this SEBS also is thermoplastic elastomer SEBS, the molecular chain of this SEBS star-shaped (is the center with some carbon, to around disperse), and the hardness of this SEBS is Shao Shi 45-75A.In the embodiment of the invention PPO matrix material, the quality percentage composition of SEBS is 3-8%, is preferably 5-7%.
Particularly; This triglycol is two-and 3-(3-tertiary butyl-4-hydroxy-5-toluene phenyl) propenoate belongs to a kind of in the hindered phenol antioxygen; In the embodiment of the invention PPO matrix material, this triglycol is two-and the quality percentage composition of 3-(3-tertiary butyl-4-hydroxy-5-toluene phenyl) propenoate is 0.1-0.3%;
Particularly, this Tyox B relative molecular mass 514.84, fusing point are 38-40 ℃; In the embodiment of the invention PPO matrix material, the quality percentage composition of Tyox B is 0.1-0.3%;
Particularly, this tricresyl phosphite (nonyl phenyl ester) relative molecular weight is 689, and in the embodiment of the invention PPO matrix material, the quality percentage composition of this tricresyl phosphite (nonyl phenyl ester) is 0.1-0.3%;
Particularly, the relative molecular weight of this zinc oxide is 81.4, and in the embodiment of the invention PPO matrix material, the quality percentage composition of this zinc oxide is 0.1-0.3%;
Through the Tyox B that in the PPO matrix material, mixes, tricresyl phosphite (nonyl phenyl ester) and zinc oxide, this three mutually promotes aspect anti-oxidant, and is collaborative each other, and antioxygenation is played significant castering action; Add simultaneously triglycol two-3-(3-tertiary butyl-4-hydroxy-5-toluene phenyl) propenoate makes the antioxidant property of PPO matrix material improve greatly as oxidation inhibitor.
Particularly, this anti UV agent is restriction not, benzotriazole category for example, 2-(2H-benzotriazole-2-yl)-4 ,-6-two (1-methyl isophthalic acid-phenylethyl) phenol, (2-(2H-benzotriazole-2-the yl)-4-tertiary butyl-6-sec-butyl phenol) etc.; In the embodiment of the invention PPO matrix material, the quality percentage composition of this anti UV agent is 0.2-0.8%.
Particularly, this carbon black is restriction not, is preferably furnace treated black, and particle diameter is the 15-25 nanometer; In the embodiment of the invention PPO matrix material, sooty quality percentage composition is 0.5-2.5%.Through adding carbon black, because the effect of sooty light shield makes the PPO matrix material to sunshine good resistant function arranged, particularly ultraviolet infringement.
Particularly, this lubricant is restriction not, for example; Zinic stearas; BS, amine hydroxybenzene, ethylenebisstearamide; Glyceryl monostearate and pentaerythritol stearate (white wax shape) etc., the quality percentage composition of lubricant is 0.5-1.0% in the embodiment of the invention PPO matrix material.
Embodiment of the invention PPO matrix material through selecting said components and content for use, makes the PPO matrix material have excellent mechanical property, and excellent is anti-aging, uvioresistant, and hydrolysis characteristic ability is very suitable for being used in the photovoltaic terminal box; Simultaneously, because the employed starting material of PPO matrix material all are the environmentally-friendly sanitary levels, the material of preparation contacts with human body can not cause any harmful material.
See also Fig. 1, Fig. 1 shows embodiment of the invention PPO composite material and preparation method thereof schema, comprises the steps:
Step S01 mixes
The quality percentage composition is respectively the SEBS of 3-8%, the BDP mixing of 5-12%; Add the quality percentage composition be respectively the triglycol of PS, 0.1-0.3% of ppe, the 10-35% of 50-75% two-3-(3-tertiary butyl-4-hydroxy-5-toluene phenyl) propenoate, the Tyox B of 0.1-0.3%, the tricresyl phosphite (nonyl phenyl ester) of 0.1-0.3%, the zinc oxide of 0.1-0.3%, the anti UV agent of 0.2-0.8, the carbon black of 0.5-2.5% and the mix lubricant of 0.5-1.0%, obtain mixture;
Step S02 extrudes processing
This mixture is extruded processing, obtain the PPO matrix material.
Particularly, among the step S01, the limiting viscosity of this ppe (polyphenylene oxide resin) is 38-47dl/g, by 2, and 6-dimethyl--1, the 4-phenylate is polymerized; This Tyox B is that flakey is with regard to crystalline solid; The amber thick liquid of this tricresyl phosphite (nonyl phenyl ester); This zinc oxide is for being white hex crystal.
Particularly; Among the step S01; This SEBS, BDP, ppe, PS, triglycol be two-and 3-(3-tertiary butyl-4-hydroxy-5-toluene phenyl) propenoate, Tyox B, tricresyl phosphite (nonyl phenyl ester), zinc oxide, anti UV agent, carbon black and lubricant be with aforesaid identical, do not repeat to set forth at this.
Particularly, among the step S01, after SEBS and BDP mixed, add other raw material again, mix.In the mixing step, the equipment of use is restriction not, for example mixing roll, stirrer etc.
Among the step S02, the condition of extruding processing is:
Screw extrusion press one district temperature 230-240 ℃, two district temperature 240-250 ℃, three district temperature 250-260 ℃, four district temperature 240-250 ℃, head 250-260 ℃, the residence time 2～3min, pressure are 12-18MPa.The extrusion equipment that uses in this step is restriction not, for example single screw extrusion machine, twin screw extruder.
Embodiment of the invention PPO composite material and preparation method thereof, simple to operate, with low cost, be suitable for industrial applications.
Below in conjunction with specific embodiment above-mentioned PPO composite material and preparation method thereof is set forth in detail.
Among the embodiment of embodiment of the invention PPO composite material and preparation method thereof, polyphenylene oxide resin is selected limiting viscosity 43.72dl/g for use, like the blue star Chemical Manufacture, trade names LXR045; PS is selected general purpose grade GPPS for use, produces trade names PG-33 like Qi Mei company; BDP selects phosphorus content 8.9% for use, produces trade names 693 like Zhejiang Heng Qiao; SEBS selects star-like high-molecular weight for use, like Yueyang petrochemical iy produced, trade names YH-602; Hindered phenol antioxygen select for use triglycol two-3-(3-tertiary butyl-4-hydroxy-5-toluene phenyl) propenoate, like the production of vapour Bagong department, trade names 245; Tyox B is selected the flake-like crystal solid for use, produces trade names PS800 like vapour Bagong department; Tricresyl phosphite (nonyl phenyl ester) selects amber thick liquid for use, as in grand Chemical Manufacture, trade names TP-30; Zinc oxide is selected white hex crystal shape for use, like the holy Chemical Manufacture in east, trade names Z100; Anti ultraviolet agent is selected benzotriazole category for use, 2-(2H-benzotriazole-2-yl)-4, and-6-two (1-methyl isophthalic acid-phenylethyl) phenol is produced trade names UV-234 like vapour Bagong department; Carbon black is selected furnace treated black for use, and particle diameter 15-25nm produces trade names 900L like goldschmidt chemical corporation; Lubricant is selected pentaerythritol stearate for use, produces trade names PETS-4 like Dao Er chemical industry ltd.
Embodiment one
Embodiment of the invention PPO composite material and preparation method thereof comprises the steps:
With the quality percentage composition is that 7% BDP, quality percentage composition are that 5% SEBS (YH-602) mixes; Add the quality percentage composition again and be 50% PPO, quality percentage composition and be 35% GPPS, quality percentage composition and be 0.2% hindered phenol antioxygen 245, quality percentage composition and be 0.2% Tyox B, quality percentage composition and be 0.2% tricresyl phosphite (nonyl phenyl ester), quality percentage composition and be 0.3% zinc oxide, quality percentage composition and be 0.3% anti ultraviolet agent; The quality percentage composition is 1.2% carbon black; The quality percentage composition is 0.6% lubricant; Stir, obtain mixture;
This mixture is joined in the hopper of twin screw extruder, through melt blending, extruding pelletization becomes matrix material.Wherein, each heating region temperature setting of screw rod is respectively: 240 ℃ of district's temperature; 250 ℃ of two district's temperature; 260 ℃ of three district's temperature; 250 ℃ of four district's temperature; Head: 260 ℃; The residence time 2～3min, pressure are 16MPa.
Embodiment two
Embodiment of the invention PPO composite material and preparation method thereof comprises the steps:
With the quality percentage composition is that 7% BDP, quality percentage composition are that 5% SEBS (YH-602) mixes; Add the quality percentage composition again and be 62% PPO, quality percentage composition and be 23% GPPS, quality percentage composition and be 0.2% hindered phenol antioxygen 245, quality percentage composition and be 0.2% Tyox B, quality percentage composition and be 0.2% tricresyl phosphite (nonyl phenyl ester), quality percentage composition and be 0.3% zinc oxide, quality percentage composition and be 0.3% anti ultraviolet agent; The quality percentage composition is 1.2% carbon black; The quality percentage composition is 0.6% lubricant; Stir, obtain mixture;
This mixture is joined in the hopper of twin screw extruder, through melt blending, extruding pelletization becomes matrix material.Wherein, each heating region temperature setting of screw rod is respectively: 240 ℃ of district's temperature; 250 ℃ of two district's temperature; 260 ℃ of three district's temperature; 250 ℃ of four district's temperature; Head: 260 ℃; The residence time 2～3min, pressure are 16MPa.
Embodiment three
Embodiment of the invention PPO composite material and preparation method thereof comprises the steps:
With the quality percentage composition is that 7% BDP, quality percentage composition are that 5% SEBS (YH-602) mixes; Add the quality percentage composition again and be 75% PPO, quality percentage composition and be 10% GPPS, quality percentage composition and be 0.2% hindered phenol antioxygen 245, quality percentage composition and be 0.2% Tyox B, quality percentage composition and be 0.2% tricresyl phosphite (nonyl phenyl ester), quality percentage composition and be 0.3% zinc oxide, quality percentage composition and be 0.3% anti ultraviolet agent; The quality percentage composition is 1.2% carbon black; The quality percentage composition is 0.6% lubricant; Stir, obtain mixture;
This mixture is joined in the hopper of twin screw extruder, through melt blending, extruding pelletization becomes matrix material.Wherein, each heating region temperature setting of screw rod is respectively: 240 ℃ of district's temperature; 250 ℃ of two district's temperature; 260 ℃ of three district's temperature; 250 ℃ of four district's temperature; Head: 260 ℃; The residence time 2～3min, pressure are 16MPa.
Embodiment four
Embodiment of the invention PPO composite material and preparation method thereof comprises the steps:
With the quality percentage composition is that 5% BDP, quality percentage composition are that 3% SEBS (YH-602) mixes; Add the quality percentage composition again and be 74.1% PPO, quality percentage composition and be 15% GPPS, quality percentage composition and be 0.1% hindered phenol antioxygen 245, quality percentage composition and be 0.3% Tyox B, quality percentage composition and be 0.1% tricresyl phosphite (nonyl phenyl ester), quality percentage composition and be 1.2% zinc oxide, quality percentage composition and be 0.2% anti ultraviolet agent; The quality percentage composition is 0.5% carbon black; The quality percentage composition is 0.5% lubricant; Stir, obtain mixture;
This mixture is joined in the hopper of twin screw extruder, through melt blending, extruding pelletization becomes matrix material.Wherein, each heating region temperature setting of screw rod is respectively: 240 ℃ of district's temperature; 250 ℃ of two district's temperature; 260 ℃ of three district's temperature; 250 ℃ of four district's temperature; Head: 260 ℃; The residence time 2～3min, pressure are 16MPa.
Embodiment five
Embodiment of the invention PPO composite material and preparation method thereof comprises the steps:
With the quality percentage composition is that 15% BDP, quality percentage composition are that 8% SEBS (YH-602) mixes; Add the quality percentage composition again and be 60% PPO, quality percentage composition and be 12.5% GPPS, quality percentage composition and be 0.3% hindered phenol antioxygen 245, quality percentage composition and be 0.1% Tyox B, quality percentage composition and be 0.3% tricresyl phosphite (nonyl phenyl ester), quality percentage composition and be 1.0% zinc oxide, quality percentage composition and be 0.3% anti ultraviolet agent; The quality percentage composition is 2.5% carbon black; The quality percentage composition is 1.0% lubricant; Stir, obtain mixture;
This mixture is joined in the hopper of twin screw extruder, through melt blending, extruding pelletization becomes matrix material.Wherein, each heating region temperature setting of screw rod is respectively: 240 ℃ of district's temperature; 250 ℃ of two district's temperature; 260 ℃ of three district's temperature; 250 ℃ of four district's temperature; Head: 260 ℃; The residence time 2～3min, pressure are 16MPa.
Comparative Examples one
This contrast PPO composite material and preparation method thereof comprises the steps:
With the quality percentage composition is that 7% BDP, quality percentage composition are that 5% SBS (YH-503) mixes; Add the quality percentage composition again and be 62% PPO, quality percentage composition and be 23% GPPS, quality percentage composition and be 0.2% hindered phenol antioxygen 245, quality percentage composition and be 0.2% Tyox B, quality percentage composition and be 0.2% tricresyl phosphite (nonyl phenyl ester), quality percentage composition and be 0.3% zinc oxide, quality percentage composition and be 0.3% anti ultraviolet agent; The quality percentage composition is 1.2% carbon black; The quality percentage composition is 0.6% lubricant; Stir, obtain mixture;
This mixture is joined in the hopper of twin screw extruder, through melt blending, extruding pelletization becomes matrix material.Wherein, each heating region temperature setting of screw rod is respectively: 240 ℃ of district's temperature; 250 ℃ of two district's temperature; 260 ℃ of three district's temperature; 250 ℃ of four district's temperature; Head: 260 ℃; The residence time 2～3min, pressure are 16MPa.
Comparative Examples two
This contrast PPO composite material and preparation method thereof comprises the steps:
With the quality percentage composition is that 7% BDP, quality percentage composition are that 5% SBS mixes; Add the quality percentage composition again and be 62% PPO, quality percentage composition and be 23% GPPS, quality percentage composition and be 0.2% hindered phenol antioxygen 245, quality percentage composition and be 0.2% Tyox B, quality percentage composition and be 0.2% tricresyl phosphite (nonyl phenyl ester), quality percentage composition and be 0.3% zinc oxide, quality percentage composition and be 0.3% anti ultraviolet agent; The quality percentage composition is 1.2% carbon black; The quality percentage composition is 0.6% lubricant; Stir, obtain mixture;
This mixture is joined in the hopper of twin screw extruder, through melt blending, extruding pelletization becomes matrix material.Wherein, each heating region temperature setting of screw rod is respectively: 240 ℃ of district's temperature; 250 ℃ of two district's temperature; 260 ℃ of three district's temperature; 250 ℃ of four district's temperature; Head: 260 ℃; The residence time 2～3min, pressure are 16MPa.
Comparative Examples three
This contrast PPO composite material and preparation method thereof comprises the steps:
With the quality percentage composition is that 7% BDP, quality percentage composition are that 62.4% PPO, quality percentage composition are that 23% GPPS, quality percentage composition are that 0.2% hindered phenol antioxygen 245, quality percentage composition are that 0.3% zinc oxide, quality percentage composition are 0.3% anti ultraviolet agent; The quality percentage composition is 1.2% carbon black; The quality percentage composition is 0.6% lubricant; Stir, obtain mixture;
This mixture is joined in the hopper of twin screw extruder, through melt blending, extruding pelletization becomes matrix material.Wherein, each heating region temperature setting of screw rod is respectively: 240 ℃ of district's temperature; 250 ℃ of two district's temperature; 260 ℃ of three district's temperature; 250 ℃ of four district's temperature; Head: 260 ℃; The residence time 2～3min, pressure are 16MPa.
Comparative Examples four
This contrast PPO composite material and preparation method thereof comprises the steps:
With the quality percentage composition is that 7% BDP, quality percentage composition are that 5% SEBS (YH-602) mixes; Add the quality percentage composition again and be 62.3% PPO, quality percentage composition and be 23% GPPS, quality percentage composition and be 0.2% hindered phenol antioxygen 245, quality percentage composition and be 0.2% Tyox B, quality percentage composition and be 0.2% tricresyl phosphite (nonyl phenyl ester), quality percentage composition and be 0.3% anti ultraviolet agent; The quality percentage composition is 1.2% carbon black; The quality percentage composition is 0.6% lubricant; Stir, obtain mixture;
This mixture is joined in the hopper of twin screw extruder, through melt blending, extruding pelletization becomes matrix material.Wherein, each heating region temperature setting of screw rod is respectively: 240 ℃ of district's temperature; 250 ℃ of two district's temperature; 260 ℃ of three district's temperature; 250 ℃ of four district's temperature; Head: 260 ℃; The residence time 2～3min, pressure are 16MPa.
Comparative Examples five
This contrast PPO composite material and preparation method thereof comprises the steps:
With the quality percentage composition is that 7% BDP, quality percentage composition are that 5% SEBS (YH-602) mixes; Add the quality percentage composition again and be 63.2% PPO, quality percentage composition and be 23% GPPS, quality percentage composition and be 0.2% hindered phenol antioxygen 245, quality percentage composition and be 0.2% Tyox B, quality percentage composition and be 0.2% tricresyl phosphite (nonyl phenyl ester), quality percentage composition and be 0.3% anti ultraviolet agent, quality percentage composition and be 0.6% lubricant; Stir, obtain mixture;
This mixture is joined in the hopper of twin screw extruder, through melt blending, extruding pelletization becomes matrix material.Wherein, each heating region temperature setting of screw rod is respectively: 240 ℃ of district's temperature; 250 ℃ of two district's temperature; 260 ℃ of three district's temperature; 250 ℃ of four district's temperature; Head: 260 ℃; The residence time 2～3min, pressure are 16MPa.
Performance test
Get stretching, bending is impacted batten and is done quick ultraviolet ageing test, and test back batten carries out surface observation and performance test, and concrete standard is following.
Ultraviolet ageing is tested by ASTM G154-06 standard fast, 65 ℃ of black standard temperatures, and relative humidity circulation in 65%, 2 hour, the 18min water spray, 102min is dry, ultraviolet wavestrip 300-400nm, test duration 500h, every 100h sampling is tested.
Tensile strength is tested by GB/T 1040 standards, and specimen types is an II type sample, batten size (mm): 115 (length) * (6 ± 0.04) (middle parallel portion width) * 2 (thickness), and draw speed is 50mm/min;
Flexural strength and modulus in flexure are tested by GB 9341/T standard.Specimen types is specimen size (mm): (80 ± 0.4) * (10 ± 0.1) * (4 ± 0.02), rate of bending are 20mm/min;
Notched Izod impact strength is tested by ASTM D-256 standard.Specimen types is the I type, specimen size (mm): (80 ± 2) * (10 ± 0.2) * (4 ± 0.2); The breach type is a category-A, and the breach residual thickness is 3.2mm.
The component contrast of embodiment one to three, Comparative Examples one to five is shown in table one:
Intensity
Table 1
By embodiment one, two, three can find out; Along with the raising of PPO content, the mechanical property of material constantly rises, under the condition that does not change other component; All PPO matrix material of 3 embodiment has extremely strong anti-aging, and the uvioresistant ability is after 500 hours quick ultraviolet ageing test; The shock strength of material still remains on more than 75%, slight curing, and tensile strength and flexural strength raise slightly;
Comparing embodiment two can find out that with Comparative Examples one, two SEBS and SBS are very approaching on the toughening effect; But anti-aging, on the ultra-violet resistance ability, SEBS obviously is superior to SBS; Be of SEBS among the embodiment one and Comparative Examples one of toughner, material is behind the quick ultraviolet ageing of 500h, and material mechanical performance keeps better; And Comparative Examples two is aging serious; Degradation is obvious, and wherein embodiment one is better than the ultraviolet-resistent property of Comparative Examples one, explains that star-like SEBSYH-602 is better as the resistance to deterioration of toughner than SEBS YH-503;
Comparative example two can find out Comparative Examples three with Comparative Examples three, four; Four resistance of aging is relatively poor; Tyox B, the interpolation of tricresyl phosphite (nonyl phenyl ester) and zinc oxide is significantly improved to the resistance of aging of material, has synergy between 3;
Can find out that with Comparative Examples five Comparative Examples five resistance to deteriorations are very poor by comparative example two, material property descends obviously, and surface crack is serious, explains that the uvioresistant ability that sooty adds material has significant lifting, has good light shielding effect.
Preferred embodiment of the present invention not in order to restriction the present invention, all any modifications of within spirit of the present invention and principle, being done, is equal to and replaces and improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. PPO matrix material comprises the component of following quality percentage composition:
2. PPO matrix material as claimed in claim 1 is characterized in that, the quality percentage composition of said ppe is 60-65%.
3. PPO matrix material as claimed in claim 1 is characterized in that, the quality percentage composition of said PS is 18-22%.
4. PPO matrix material as claimed in claim 1 is characterized in that, the quality percentage composition of said dihydroxyphenyl propane two (diphenyl phosphoester) is 8-11%.
5. PPO matrix material as claimed in claim 1 is characterized in that, the quality percentage composition of said SEBS is 5-7%.
6. PPO matrix material as claimed in claim 1 is characterized in that, said sooty particle diameter is the 15-25 nanometer.
7. a PPO composite material and preparation method thereof comprises the steps:
The quality percentage composition is respectively the SEBS of 3-8%, the BDP mixing of 5-12%; Add the quality percentage composition be respectively the triglycol of PS, 0.1-0.3% of ppe, the 10-35% of 50-75% two-3-(3-tertiary butyl-4-hydroxy-5-toluene phenyl) propenoate, the Tyox B of 0.1-0.3%, the tricresyl phosphite (nonyl phenyl ester) of 0.1-0.3%, the zinc oxide of 0.1-0.3%, the anti UV agent of 0.2-0.8, the carbon black of 0.5-2.5% and the lubricant of 0.5-1.0%, mix obtaining mixture;
Said mixture is extruded processing, obtain the PPO matrix material.
8. PPO composite material and preparation method thereof as claimed in claim 7 is characterized in that, the limiting viscosity of said ppe is 38-47dl/g.
9. PPO composite material and preparation method thereof as claimed in claim 7 is characterized in that, said Tyox B relative molecular mass 514.84, fusing point are 38-40 ℃.
10. PPO composite material and preparation method thereof as claimed in claim 7 is characterized in that, said sooty particle diameter is the 15-25 nanometer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110110706.XA CN102311634B (en) | 2011-04-29 | 2011-04-29 | PPO (poly phenylene oxide) composite material as well as preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110110706.XA CN102311634B (en) | 2011-04-29 | 2011-04-29 | PPO (poly phenylene oxide) composite material as well as preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102311634A true CN102311634A (en) | 2012-01-11 |
| CN102311634B CN102311634B (en) | 2014-05-28 |
Family
ID=45425220
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110110706.XA Expired - Fee Related CN102311634B (en) | 2011-04-29 | 2011-04-29 | PPO (poly phenylene oxide) composite material as well as preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102311634B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105164205B (en) * | 2013-05-30 | 2017-07-28 | 沙特基础全球技术有限公司 | Poly- (phenylene ether) composition and product |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101280096A (en) * | 2008-05-20 | 2008-10-08 | 上海大学 | High-glaze strengthened toughened polyethylene glycol terephthalate nanometer composite material and preparation thereof |
| CN101747616A (en) * | 2009-12-11 | 2010-06-23 | 重庆启蓝塑料有限公司 | Modified polyphenyl ether material and preparation method thereof |
-
2011
- 2011-04-29 CN CN201110110706.XA patent/CN102311634B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101280096A (en) * | 2008-05-20 | 2008-10-08 | 上海大学 | High-glaze strengthened toughened polyethylene glycol terephthalate nanometer composite material and preparation thereof |
| CN101747616A (en) * | 2009-12-11 | 2010-06-23 | 重庆启蓝塑料有限公司 | Modified polyphenyl ether material and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105164205B (en) * | 2013-05-30 | 2017-07-28 | 沙特基础全球技术有限公司 | Poly- (phenylene ether) composition and product |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102311634B (en) | 2014-05-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103108917B (en) | Polyphenylene ether resin composition and molded article of same | |
| CN104356620B (en) | A kind of degradable Electric insulation material | |
| CN101508834B (en) | PC/PBT alloy and method for producing the same | |
| CN103087518B (en) | Glass-fiber-reinforced halogen-free flame-retardant nylon 46 composite material and preparation method thereof | |
| CN101805506B (en) | Polycarbonate resin composition for lighting tube material and preparation method thereof | |
| CN102337029B (en) | Halogen-free flame-retardant nylon 66 composite material and preparation method thereof | |
| CN103554863A (en) | LED lampshade material polycarbonate resin composition and preparation method thereof | |
| CN104497533A (en) | Halogen-free flame-retardant high-gloss reflective heat-conducting polycarbonate material and preparation method thereof | |
| CN102964829B (en) | Environment-friendly and flame-retardant glass fiber reinforced PA (polyamide) 66/PPO (polyphenylene oxide) alloy material with high CTI (comparative tracking index) value and high GWIT (glow-wire ignition temperature) value and preparation method thereof | |
| CN104893226A (en) | Halogen-free flame-retardant thermoplastic elastomer cable material and halogen-free flame-retardant cable | |
| CN102898805B (en) | Polycarbonate composite material, its preparation method and application | |
| CN104672831A (en) | High-toughness strengthened flame-retardant anti-aging PC composition | |
| CN103421290A (en) | Low-temperature resisting, high-impact and flame-retardant glass-fiber reinforced polycarbonate composite material as well as preparation method and application thereof | |
| CN112321955A (en) | Environment-friendly flame-retardant insulating rubber composite material and preparation method thereof | |
| CN106987120A (en) | A kind of oil resistant high CTI value halogen free flame-retardant polyphenylene oxide composite material and preparation method thereof | |
| CN102311634B (en) | PPO (poly phenylene oxide) composite material as well as preparation method and application thereof | |
| CN102382439B (en) | Modified polycarbonate and preparation method thereof | |
| CN105111576A (en) | Tight-buffered low-smoke halogen-free flame-retardant sheathing compound for 4G network cable and preparation method thereof | |
| CN101875775B (en) | Low-smoke zero-halogen flame-retardant polyphenyl ether composition and preparation method thereof | |
| CN102051037A (en) | Halogen-free flame-proof polyenyl ether composition | |
| CN107001797B (en) | High flow polyetherimide compositions, methods of manufacture, and articles made therefrom | |
| CN114539757A (en) | Low-temperature-resistant and salt-fog-resistant polycarbonate composite material and preparation method thereof | |
| CN109467922A (en) | Height flowing halogen-free flameproof reinforced plastic PA66 composition | |
| CN103214839A (en) | Preparation method of fiberglass reinforced black halogen-free flame-retardant polyamide alloy material | |
| CN113372707A (en) | Composition for shell of power lithium battery pack |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: PPO (poly phenylene oxide) composite material as well as preparation method and application thereof Effective date of registration: 20150817 Granted publication date: 20140528 Pledgee: China Everbright Bank Shenzhen branch Pledgor: Shenzhen Keju New Material Co., Ltd. Registration number: 2015990000679 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20161202 Granted publication date: 20140528 Pledgee: China Everbright Bank Shenzhen branch Pledgor: Shenzhen Keju New Material Co., Ltd. Registration number: 2015990000679 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: PPO (poly phenylene oxide) composite material as well as preparation method and application thereof Effective date of registration: 20170106 Granted publication date: 20140528 Pledgee: Bank of Shizuishan Limited by Share Ltd Yinchuan branch Pledgor: Anhui science and Technology Co., Ltd.|Shenzhen branch poly new materials Co., Ltd.|Xu Dong Registration number: 2016990001133 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20180904 Granted publication date: 20140528 Pledgee: Bank of Shizuishan Limited by Share Ltd Yinchuan branch Pledgor: Polymer Science (Anhui) New Material Co., Ltd.|Shenzhen Keju New Material Co., Ltd.|Xu Dong Registration number: 2016990001133 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: PPO (poly phenylene oxide) composite material as well as preparation method and application thereof Effective date of registration: 20181119 Granted publication date: 20140528 Pledgee: Bank of Shizuishan Limited by Share Ltd Yinchuan branch Pledgor: Shenzhen Keju New Material Co., Ltd.|Polymer Science (Anhui) New Material Co., Ltd. Registration number: 2018440020071 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140528 Termination date: 20190429 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |