CN102297827A - Test method, test pool and test device of air permeability of membrane electrode of fuel cell - Google Patents
Test method, test pool and test device of air permeability of membrane electrode of fuel cell Download PDFInfo
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- CN102297827A CN102297827A CN2010102100773A CN201010210077A CN102297827A CN 102297827 A CN102297827 A CN 102297827A CN 2010102100773 A CN2010102100773 A CN 2010102100773A CN 201010210077 A CN201010210077 A CN 201010210077A CN 102297827 A CN102297827 A CN 102297827A
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- 238000012360 testing method Methods 0.000 title claims abstract description 102
- 239000012528 membrane Substances 0.000 title claims abstract description 60
- 239000000446 fuel Substances 0.000 title claims abstract description 24
- 238000010998 test method Methods 0.000 title claims abstract description 13
- 230000035699 permeability Effects 0.000 title abstract 8
- 239000007789 gas Substances 0.000 claims abstract description 103
- 238000000034 method Methods 0.000 claims abstract description 24
- 239000011261 inert gas Substances 0.000 claims description 28
- 239000001257 hydrogen Substances 0.000 claims description 18
- 229910052739 hydrogen Inorganic materials 0.000 claims description 18
- 238000009434 installation Methods 0.000 claims description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- 238000007789 sealing Methods 0.000 claims description 10
- 210000000170 cell membrane Anatomy 0.000 claims description 9
- 230000035515 penetration Effects 0.000 claims description 7
- 238000002347 injection Methods 0.000 claims description 5
- 239000007924 injection Substances 0.000 claims description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 3
- 230000009467 reduction Effects 0.000 claims description 3
- 239000003570 air Substances 0.000 claims description 2
- 229910052786 argon Inorganic materials 0.000 claims description 2
- 239000006260 foam Substances 0.000 claims description 2
- 230000006641 stabilisation Effects 0.000 claims description 2
- 238000011105 stabilization Methods 0.000 claims description 2
- 238000005259 measurement Methods 0.000 claims 1
- 230000008901 benefit Effects 0.000 abstract description 5
- 238000004817 gas chromatography Methods 0.000 abstract description 4
- 239000012159 carrier gas Substances 0.000 abstract 3
- 239000003566 sealing material Substances 0.000 abstract 1
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- 210000004027 cell Anatomy 0.000 description 10
- 230000008569 process Effects 0.000 description 10
- 238000002848 electrochemical method Methods 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 5
- 238000012512 characterization method Methods 0.000 description 5
- 238000011161 development Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 238000009738 saturating Methods 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000007731 hot pressing Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 1
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- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
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- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
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- 238000003912 environmental pollution Methods 0.000 description 1
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- 238000002156 mixing Methods 0.000 description 1
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
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- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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Abstract
The invention discloses a test method and device of the air permeability of a membrane electrode of a fuel cell, which can be used for testing the air permeability of the membrane electrode of the fuel cell under actual running conditions. The method comprises the following steps of: assembling the membrane electrode in a testing pool, wherein a gas inlet and outlet channel is arranged at one side of the test pool and a test channel is formed at the other side of the test pool; and respectively introducing tested gas and carrier gas to two sides of the test pool, introducing a gas outlet at the carrier gas side of the test pool into a gas chromatography, and calculating the air permeability of the membrane electrode through testing the content of the tested gas in the tested carrier gas through the gas chromatography. The test device of the air permeability of the membrane electrode mainly comprises the test pool and an air permeability test system. The test pool consists of two plate clamps and corresponding sealing materials, wherein each plate clamp is provided with a gas inlet and a gas outlet. The invention provides an intrinsic test method for testing the air permeability of the membrane electrode of the fuel cell accurately and effectively; and the test pool and the test device have the advantages of simple structure, easiness in control and low cost and can be used for accurately representing the intrinsic air permeability of the membrane electrode under offline or online state.
Description
Technical field
The present invention relates to a kind of air penetrability method of testing and test pool and isolated plant, specifically a kind of method of testing of fuel cell membrane electrode air penetrability and test pool and proving installation.
Background technology
The energy and environment are two big key factors of human social development, and along with increasing and rapid development of economy of population, fossil energy will be petered out, and a large amount of consumption of fossil energy have caused the serious environmental pollution simultaneously.According to statistics, urban atmospheric pollution is mainly derived from automobile exhaust pollution.Therefore, the cleaning vehicle of research, development and utilization regenerative resource is realized energy variation, guarantees that national energy security and environmental protection are significant.
Fuel cell (Fuel Cell) is a kind of isothermal electrochemical generating unit that directly chemical energy is converted into electric energy, and it is not subjected to the restriction of Carnot cycle without the overheated machine process, energy conversion efficiency height (can reach 40~60%).Simultaneously, it also has eco-friendly advantage, discharges nitrogen and sulfur oxide hardly, and emission amount of carbon dioxide also reduces more than 40% than conventional power generation usage factory.Thereby, it is not only automobile one of the most promising alternative clean energy resource, can also be widely used in space shuttle, submarine, underwater robot, communication system, middle and small scale power station, domestic power supply, be fit to very much to provide mobile, decentralized power s again and supply with, and can solve the problem of peak load regulation network near terminal user's electric power.Also just because of above these outstanding superiority, fuel cell might become behind thermoelectricity, water power, nuclear power the 4th generation generation mode.
It is big that organic bath membrane cell (comprising Proton Exchange Membrane Fuel Cells, high temperature proton exchange film fuel cell and DMFC) has power density, advantages such as startup and response speed are fast are considered to one of optimal candidate power source of following automobile.The development FC-EV not only can reduce China's urban atmospheric pollution significantly, and to solving national energy security, realizes energy variation, develops national cleaning vehicle industry and fuel cell industry and has vital role.
Membrane electrode assembly is a core of forming fuel cell, and it is mainly by gas diffusion layers (being divided into anode gas diffusion layer and cathode gas diffusion layer), and Catalytic Layer (being divided into anode catalyst layer and cathode catalysis layer) and PEM are formed.
Air penetrability is one of important characterization parameter of characterization of membrane electrode life, and it is by the barrier property and the factors decisions such as film and Catalytic Layer combination degree of membrane material itself.Membrane electrode assembly will be by processes such as hot pressing in preparation process, improving contacting of Catalytic Layer and PEM, but PEM generation swelling in the hot pressing, thus the PEM air penetrability is increased; Simultaneously, in the process of compacting membrane electrode, catalyzer will partly cover the surface of film, can reduce the air penetrability of membrane electrode again accordingly.In addition, membrane electrode is in actual moving process, to tolerate the impact of different operating condition (as variation of on-stream pressure, humidification temperature, operating temperature and stoichiometric proportion etc.), cause the air penetrability of membrane electrode and PEM that bigger variation takes place, thereby can influence the performance and the life-span of membrane electrode and battery.When the air penetrability of membrane electrode increases to a certain degree, can cause the interior string of battery easily, thereby cause fuel and oxygenant to mix, the efficient of fuel cell is reduced.When the reaction velocity of fuel and oxygenant mixing is uncontrollable, can discharge a large amount of heats at short notice, cause burning or blast, cause danger.Thereby, in time, the air penetrability of test membrane electrode is most important effectively.
At present, the air penetrability of membrane electrode mainly calculates by the method for electrochemical method test fuel cell leakage hydrogen electric current.This method is only applicable to the saturating hydrogen amount of test membrane electrode.The influence that numerous factors such as electrostatic double layer, catalyst surface adsorbed state in the hydrogen current method test membrane electrode air penetrability process are leaked in the electrochemical method test is bigger, thereby the test data accuracy is reduced; And in test process, the adsorbing species of catalyst surface and the adsorbed state of species, purge time and electrochemical apparatus kind etc. all have considerable influence to the test result of the saturating hydrogen amount of membrane electrode.Thereby, the present invention proposes a kind of air penetrability method of testing and anchor clamps and proving installation of accurate and effective fuel cell membrane electrode; This method not only can avoid the electrochemical method test to leak the influence of numerous factors such as electrostatic double layer, catalyst surface adsorbed state in the hydrogen current method test membrane electrode air penetrability process, make test data more objective, accurate, and test process is simple, easily control, good reproducibility; This method is the air penetrability of off-line test membrane electrode exactly not only, also can online in real time detects the air penetrability of battery, the security that improves membrane electrode; In addition, this method can overcome the shortcoming that electrochemical method can only be tested the hydrogen air penetrability, the amount of saturating hydrogen, oxygen flow gas and air permeable that can the test membrane electrode.
Summary of the invention
The object of the present invention is to provide a kind of method of testing and test pool and proving installation of fuel cell membrane electrode air penetrability.This method of testing is simple and easy to control, accuracy is high, good reproducibility.This proving installation is simple in structure, and price is low, accurately the intrinsic air penetrability under characterization of membrane electrode off-line or the presence.
To achieve these goals, the technical solution used in the present invention is:
The method of testing of a kind of fuel cell membrane electrode (membrane electrode) gas penetration potential may further comprise the steps,
(1) membrane electrode is clipped between two anchor clamps that fasten relatively, be equipped with groove on the buckling surface of two anchor clamps, and groove is symmetrical, amplexiforms mutually with the periphery of membrane electrode around the groove, form disconnected two air chambers mutually in the both sides of membrane electrode, assembling obtains the experimental test pond;
On two anchor clamps, be respectively equipped with the groove that makes anchor clamps and the gas feed and the outlet of exterior;
(2) feed tested gas and inert gas respectively in the both sides of test pool, make the pressure of air chamber both sides keep balance or specific pressure differential;
(3) flow velocity of the both sides gas of test test pool;
(4) after the flow speed stability of gas, with the exit flow feeding gas chromatograph injection port of inert gas, and the record chromatogram, go out the concentration of tested gas according to the calculated by peak area that tested gas reflected on the chromatogram, and then know the air penetrability of membrane electrode.
Described tested gas is hydrogen, oxygen or air; Described inert gas is nitrogen or argon gas; The pressure of described tested gas and inert gas is 0.01-0.3MPa; The pressure differential of described test gas and inert gas is-0.3MPa-0.3MPa.
The humidity of described tested gas and inert gas is that the temperature of 0-100%, test pool is 15-180 ℃; Be more than the 2h after test pool feeds gas the stabilization time of gas flow rate.
The test pool of described membrane electrode gas penetration potential test comprises anchor clamps and lower clamp; Last anchor clamps and lower clamp are the plate-like structure that a side has groove, offer the gas feed and the outlet that run through dull and stereotyped on the inwall of groove, and last anchor clamps and lower clamp are symmetrical structure, and the groove of last anchor clamps is relative with the groove of lower clamp to fasten.
Between last anchor clamps and lower clamp, be provided with seal; Described seal is O-ring seal, potted line or sealing gasket.
Be provided with the sealing wire casing that is used to place O-ring seal around the slot opening end of last anchor clamps and lower clamp; Offer screw on last anchor clamps and the lower clamp, last lower clamp is fixed by screw bolt and nut.
The proving installation of described membrane electrode air penetrability test comprises control pressurer system, moisture control system, flow control system, tested gas source of the gas and inert gas source of the gas, the described test pool of claim 4, gas chromatograph;
Tested gas source of the gas links to each other by the gas feed of anchor clamps and lower clamp on the described test pool of pipeline and claim 4 respectively with the inert gas source of the gas, the inert gas outlet of lower clamp links to each other with the injection port of gas chromatograph, and the tested gas vent of last anchor clamps communicates with atmosphere;
Be respectively equipped with switch valve, reduction valve, precision pressure gauge or pressure transducer, gas meter, humidification jar humidification or dew point humidifier on the connecting line between tested gas source of the gas and inert gas source of the gas and test pool, constitute control pressurer system, moisture control system, flow control system respectively.
Shown gas flow is counted mass flowmeter, soap-foam flowmeter, rotary drum flowmeter or flow sensor etc.
The present invention compares with the technology of existing test membrane electrode air penetrability, has the following advantages: (1) is simple and easy to control, accuracy is high, good reproducibility; (2) can be accurately, the intrinsic air penetrability of characterization of membrane electrode under off-line or presence objectively; (3) gaseous tension can be regulated in very big pressure limit, to adapt to the test request of membrane electrode gas penetration potential under the different condition; (4) this proving installation is simple in structure, and price is low, and is easy to operate.
Description of drawings
Fig. 1 special test apparatus structure of the present invention synoptic diagram
1-test gas 2-inert gas 3-humidification system 4-air penetrability test unit clamp 5-test gas outlet 6-inert gas outlet 7-control pressurer system 8-flow control system 9-gas chromatography 10-gas chromatography
Fig. 2 is the anchor clamps synoptic diagram of special use of the present invention
(a) planimetric map, (b) side view, (c) vertical view,
11-gas vent 12-gas access 13-goes up anchor clamps or lower clamp 14-bolt hole 15-sealing wire casing;
Fig. 3 is the air penetrability collection of illustrative plates of the membrane electrode of the embodiment of the invention 1 test
Fig. 4 is the air penetrability collection of illustrative plates of the membrane electrode of the embodiment of the invention 2 tests.
Embodiment
Specify embodiments of the present invention below in conjunction with embodiment, the present invention is not limited in these specific embodiments certainly.
The test pool of described membrane electrode gas penetration potential test comprises anchor clamps and lower clamp; Last anchor clamps and lower clamp are the plate-like structure that a side has groove, offer the gas feed and the outlet that run through dull and stereotyped on the inwall of groove, and last anchor clamps and lower clamp are symmetrical structure, and the groove of last anchor clamps is relative with the groove of lower clamp to fasten.
Between last anchor clamps and lower clamp, be provided with seal; Described seal is O-ring seal, potted line or sealing gasket.
Be provided with the sealing wire casing that is used to place O-ring seal around the slot opening end of last anchor clamps and lower clamp; Offer screw on last anchor clamps and the lower clamp, last lower clamp is fixed by screw bolt and nut.
The proving installation of described membrane electrode air penetrability test comprises control pressurer system, moisture control system, flow control system, tested gas source of the gas and inert gas source of the gas, the described test pool of claim 4, gas chromatograph;
Tested gas source of the gas links to each other by the gas feed of anchor clamps and lower clamp on the described test pool of pipeline and claim 4 respectively with the inert gas source of the gas, the inert gas outlet of lower clamp links to each other with the injection port of gas chromatograph, and the tested gas vent of last anchor clamps communicates with atmosphere;
Be respectively equipped with switch valve, reduction valve, precision pressure gauge or pressure transducer, gas meter, humidification jar humidification or dew point humidifier on the connecting line between tested gas source of the gas and inert gas source of the gas and test pool, constitute control pressurer system, moisture control system, flow control system respectively.
Embodiment 1
The negative electrode of employing serigraphy preparation and the new membrane electrode of anode and Dupont 212 mould systems are as sample.Fuel cell membrane electrode is placed in the middle of two anchor clamps shown in Figure 2, makes both sides form air chamber, as the experimental test pond as sample.Specimen is placed in the middle of two anchor clamps shown in Figure 2, makes both sides form air chamber, as the experimental test pond.Adopt linear sealing between anchor clamps and the sample, both sides form air chamber.Test unit synoptic diagram shown in the experimental test pond is installed on the test unit shown in Figure 1.In temperature is 25 ℃, feeds in the both sides of air chamber respectively, and the humidification temperature is 25 ℃, and pressure is hydrogen and the nitrogen of 0.1MPa, makes the pressure of air chamber both sides keep balance.The pressure of both sides is mainly controlled by precision pressure gauge.Stablize 2h, adopt gas chromatograph to detect from the inert gas that flow out in the experimental test pond and contain the concentration of permeating the tested gas of coming from the opposite side of membrane electrode, and the record chromatogram, see accompanying drawing 3.By chromatogram H
2The peak calculates the hydrogen amount.
After the test result of use standard hydrogen was demarcated, the leakage hydrogen speed of this membrane electrode was 0.015ml/min cm
2
Embodiment 2
Continuous current is moved fuel cell membrane electrode behind the 400h be placed in the middle of two anchor clamps shown in Figure 2, make both sides form air chamber, as the experimental test pond.Adopt linear sealing between anchor clamps and the sample, both sides form air chamber.The experimental test pond is installed on the test unit according to test unit synoptic diagram 1.In experimental test pond temperature is 75 ℃, feeds in the both sides of air chamber respectively, and the humidification temperature is 70 ℃, and pressure is hydrogen and the 0.05MPa nitrogen of 0.1MPa, makes the pressure differential of the pressure maintenance 0.05MPa of air chamber both sides.The pressure of both sides is mainly controlled by precision pressure gauge.Stablize 6h, adopt gas chromatograph to detect from the inert gas that flow out in the experimental test pond and contain the concentration of permeating the tested gas of coming from the opposite side of membrane electrode, and the record chromatogram, see accompanying drawing 4.By chromatogram H
2The peak calculates the hydrogen amount.After the test result of applied code hydrogen was demarcated, the leakage hydrogen speed of this membrane electrode was 0.10ml/mincm
2
Advantage of the present invention is: the air penetrability intrinsic method of testing and test pool and the proving installation that have proposed a kind of accurate and effective fuel cell membrane electrode; This method not only can avoid the electrochemical method test to leak the influence of numerous factors such as electrostatic double layer, catalyst surface adsorbed state in the hydrogen current method test membrane electrode air penetrability process, make test data more objective, accurate, and test process is simple, easily control, good reproducibility; This method is the air penetrability of off-line test membrane electrode exactly not only, also can online in real time ground detects the air penetrability of battery, the security that improves membrane electrode; In addition, this method can overcome electrochemical method and can only test H
2The shortcoming of air penetrability, the directly saturating H of test membrane electrode
2, oxygen and air amount.The control simple in structure, easy of this test pool and proving installation, price is low, accurately the intrinsic air penetrability under characterization of membrane electrode off-line or the presence.
Claims (10)
1. the method for testing of a fuel cell membrane electrode gas penetration potential is characterized in that: this method comprises the steps,
(1) membrane electrode is clipped between two anchor clamps that fasten relatively, be equipped with groove on the buckling surface of two anchor clamps, and groove is symmetrical, amplexiforms mutually with the periphery of membrane electrode around the groove, form disconnected two air chambers mutually in the both sides of membrane electrode, assembling obtains the experimental test pond;
On two anchor clamps, be respectively equipped with the groove that makes anchor clamps and the gas feed and the outlet of exterior;
(2), in two air chambers of test pool both sides,, make the pressure of air chamber both sides keep balance or specific pressure differential respectively by tested gas and inert gas by gas feed and outlet;
(3) measurement is by the flow velocity of the both sides gas of test pool;
(4) after the flow speed stability of both sides gas, the outlet tail gas of inert gas is fed the gas chromatograph injection port, and the record chromatogram, go out the concentration of tested gas according to the calculated by peak area of tested gas that tested gas reflects on the chromatogram, and then know the air penetrability of membrane electrode.
2. method of testing according to claim 1 is characterized in that: tested gas is hydrogen, oxygen or air; Described inert gas is nitrogen or argon gas; The pressure of tested gas and inert gas is 0.01-0.3MPa; The pressure differential of test gas and inert gas is-0.3MPa-0.3MPa.
3. method of testing according to claim 1 is characterized in that: the humidity of described tested gas and inert gas is that the temperature of 0-100%, test pool is 15 ℃-180 ℃; Be more than the 2h after test pool feeds gas the stabilization time of gas flow rate.
4. the test pool of the described membrane electrode gas penetration potential test of a claim 1, it is characterized in that: it comprises the last anchor clamps (1) and the lower clamp (2) of relative fastening; Last anchor clamps (1) and lower clamp (2) are the plate-like structure that a side has groove, on the inwall of groove, offer the gas feed and the outlet that run through dull and stereotyped, last anchor clamps (1) and lower clamp (2) are symmetrical structure, and the groove of the groove of last anchor clamps (1) and lower clamp (2) is symmetrical.
5. test pool according to claim 4 is characterized in that: be provided with seal between last anchor clamps (1) and lower clamp (2).
6. test pool according to claim 5 is characterized in that: described seal is O-ring seal, potted line or sealing gasket.
7. test pool according to claim 4 is characterized in that: be provided with the sealing wire casing that is used to place O-ring seal around the slot opening end of last anchor clamps (1) and lower clamp (2), be placed with O-ring seal in the sealing wire casing.
8. test pool according to claim 4 is characterized in that: offer screw accordingly on the wallboard in the last anchor clamps (1) and lower clamp (2) the groove outside, last lower clamp is fixed through the screw place by screw bolt and nut.
9. the proving installation of the described membrane electrode air penetrability test of a claim 1, it is characterized in that: comprise control pressurer system, moisture control system, flow control system, tested gas source of the gas and inert gas source of the gas, the described test pool of claim 4, gas chromatograph;
Tested gas source of the gas links to each other by the gas feed of anchor clamps (1) on the described test pool of pipeline and claim 4 and lower clamp (2) respectively with the inert gas source of the gas, the inert gas outlet of lower clamp (2) links to each other with the injection port of gas chromatograph, and the tested gas vent of last anchor clamps (1) communicates with atmosphere;
Be respectively equipped with switch valve, reduction valve, precision pressure gauge or pressure transducer, gas meter, humidification jar humidification or dew point humidifier on the connecting line between tested gas source of the gas and inert gas source of the gas and test pool, constitute control pressurer system, flow control system, moisture control system respectively.
10. proving installation according to claim 9 is characterized in that: gas flow is counted mass flowmeter, soap-foam flowmeter, rotary drum flowmeter or flow sensor.
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