CN102295805A - Loudspeaker diaphragm made from polypropylene blend - Google Patents

Loudspeaker diaphragm made from polypropylene blend Download PDF

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Publication number
CN102295805A
CN102295805A CN 201110189771 CN201110189771A CN102295805A CN 102295805 A CN102295805 A CN 102295805A CN 201110189771 CN201110189771 CN 201110189771 CN 201110189771 A CN201110189771 A CN 201110189771A CN 102295805 A CN102295805 A CN 102295805A
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China
Prior art keywords
diaphragm
matrix
described device
loudspeaker
blank
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CN 201110189771
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Chinese (zh)
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CN102295805B (en
Inventor
马春彪
耿云瑶
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JILIN SHENYUN ELECTRONIC TECHNOLOGY DEVELOPMENT Co Ltd
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Publication of CN102295805A publication Critical patent/CN102295805A/en
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Abstract

The invention relates to a loudspeaker diaphragm made from polypropylene blend, and belongs to the field of electroacoustic device and audio product manufacturing. The loudspeaker diaphragm provided by the invention comprises the following raw materials of: by weight, 68%-75% of a polypropylene resin; 18%-25% of a high-density polyethylene resin with the density being 0.94-0.96g/cm<3>; 6%-9% of powdered steatile or an ethene-propylene-diene rubber; and 1%-3% of nanometer silica particles with the diameter being 25-40nm. The beneficial effects are as follows: the supply of the adopted raw materials is sufficient; the cost is low; the density is greatly reduced in comparison with that of solid materials with the same dimension; the rigidity is markedly raised; the loudspeaker diaphragm provided by the invention is applicable to large batch production and performance parameter control.

Description

The diaphragm of loudspeaker that polypropylene blend is made
Technical field
The invention belongs to electro-acoustic element and acoustic product and make the field, be specifically related to a kind of diaphragm of loudspeaker, especially a kind of thickness that adopts polypropylene blend to make is ultra-thin, the diaphragm of loudspeaker of light weight.
Background technology
The performance of the diaphragm of loudspeaker has crucial influence to the tonequality of loud speaker.After the size shape of vibrating diaphragm was determined, material that vibrating diaphragm is selected and moulding process just had very important influence to the performance and the tonequality of loud speaker.At present, the material of the diaphragm of loudspeaker is mainly used wood fibre or is the main cone made from the wood fibre, needs to consume a large amount of forest reserves, is unfavorable for the trend of environmental protection and sustainable development.
In addition, traditional loud speaker adopts awl benzvalene form vibrating diaphragm, and the occupation of land space is big, is difficult to satisfy consumption electronic product, as " panelized ", the trend of " lightening " of flat panel TV, computer, multi-media audiovisual product etc.Though reducing the height of awl benzvalene form vibrating diaphragm can be so that the attenuation of loud speaker integral thickness, the bass effect of loud speaker and tonequality reductive are cashed variation thereupon.
Guarantee excellent tonequality simultaneously in order to satisfy the loud speaker slimming, need the loudspeaker diaphragm materials of development of new.
Summary of the invention
The invention provides the diaphragm of loudspeaker that a kind of polypropylene blend is made ,To solve the audio variation of loud speaker, the problem that distortion increases.The thickness that adopts polypropylene blend to make is ultra-thin, light weight, Hz-KHz is wide, inside has the honeycomb cavernous structure the diaphragm of loudspeaker.
The technical solution used in the present invention is: be made up of the raw material of following mass percent:
Acrylic resin: 68% ~ 75%;
High-density polyethylene resin, density are 0.94 ~ 0.96g/cm 3: 18% ~ 25%;
Talcum powder or ethylene-propylene-dience rubber: 6% ~ 9%;
Nano-silicon dioxide particle, diameter are 25 ~ 40nm, 1% ~ 3%.
The manufacture method of the diaphragm of loudspeaker that polypropylene blend of the present invention is made comprises the following steps:
(1), according to formula rate starting material are sent into mixing roll and mix, be pressed into the blank of desired shape through press-forming machine,
(2), blank is put into the honeycomb hole foaming and forming apparatus, described device is heated to 120 ℃ ~ 160 ℃ and rotate the inner screw rod of described device, the plasticizing of blank melted by heating forms the matrix of described vibrating diaphragm, it is inner that high-pressure carbon dioxide gas is injected into described device, described carbon dioxide gas pressure is 15 ~ 20Mpa, form polymkeric substance/gas homogeneous system with matrix, subsequently, open pressure release valve removal carbon dioxide gas pressure, thereby at the equally distributed honeycomb hole of the inner acquisition of matrix, after described device is cooled to 20 ℃ ~ 25 ℃, take out matrix;
(3), utilize laser cutting or blanking method to make the vibrating diaphragm of desired shape and size at last.
The internal structure of described vibrating diaphragm is the honeycomb cavernous structure, and the honeycomb hole diameter is between 10 μ m ~ 100 μ m, and honeycomb cell densities range is greater than 10 8Individual/cm 3
A kind of diaphragm of loudspeaker that adopts polypropylene blend to make is made the raw material of described vibrating diaphragm and is made up of acrylic resin (the English PP of abbreviation), high-density polyethylene resin (the English HDPE of abbreviation), modified additive.
Acrylic resin is the linear polymer of a kind of high-density, unprotected side chain, high crystalline, has excellent comprehensive performances, numerous industries such as widespread use electronic apparatus, household electrical appliances, automobile, packing, food, its raw material supply abundance, with low cost is a kind of comparatively ideal diaphragm of loudspeaker starting material.The diaphragm of loudspeaker inherent damping that adopts the PP resin to make is good, is not subjected to the influence of ambient moisture, processes and be controlled to the molded dimension error easily.The internal structure of described vibrating diaphragm is the honeycomb cavernous structure, and the honeycomb hole diameter is between 10 μ m ~ 100 μ m, and honeycomb cell densities range is greater than 10 8Individual/cm 3, have that quality alleviates significantly, good rigidity, than advantages such as spring rate significantly improve.But because the PP resin is linear, crystalline polymer, during molten state, the intensity of melt is low; In order to guarantee to obtain equally distributed honeycomb porous structure, need to add other raw materials so that improve the melt strength of PP resin.
The beneficial effect that the present invention is compared with prior art brought is:
1, the raw material supply abundance that is adopted, with low cost is not destroyed the forest reserves;
2, the inside of described vibrating diaphragm is the honeycomb cavernous structure, so the solid material of the same size of density greatly reduces, but its rigidity significantly improves.Test shows, compares the low-frequency cut-off frequency F of vibrating diaphragm of the present invention with the conventional paper cone material 0Reduced by 10% ~ 15%;
3, described vibrating diaphragm can adopt injection moulding, plastics molding process processing such as extrude, and is easy to produce in enormous quantities and performance perameter is controlled.
Embodiment
Acrylic resin (the English PP of abbreviation), high-density polyethylene resin (the English HDPE of abbreviation), ethylene-propylene-dience rubber (the English EPDM that is called for short)
Embodiment 1
Form by the raw material of following mass percent:
Acrylic resin: 68%;
High-density polyethylene resin, density are 0.94g/cm 3: 20%;
Talcum powder: 9%;
Nano-silicon dioxide particle, diameter are 25nm, 3%.
The manufacture method of the diaphragm of loudspeaker that polypropylene blend of the present invention is made comprises the following steps:
(1), according to formula rate starting material are sent into mixing roll and mix, be pressed into the blank of desired shape through press-forming machine,
(2), blank is put into the honeycomb hole foaming and forming apparatus, described device is heated to 120 ℃ and rotate the inner screw rod of described device, the plasticizing of blank melted by heating forms the matrix of described vibrating diaphragm, it is inner that high-pressure carbon dioxide gas is injected into described device, described carbon dioxide gas pressure is 15Mpa, form polymkeric substance/gas homogeneous system with matrix, subsequently, open pressure release valve removal carbon dioxide gas pressure, thereby at the equally distributed honeycomb hole of the inner acquisition of matrix, after described device is cooled to 20 ℃, take out matrix;
(3), utilize laser cutting or blanking method to make the vibrating diaphragm of desired shape and size at last.
The internal structure of described vibrating diaphragm is the honeycomb cavernous structure, and the honeycomb hole diameter is between 10 μ m ~ 100 μ m, and honeycomb cell densities range is greater than 10 8Individual/cm 3
Embodiment 2
Form by the raw material of following mass percent:
Acrylic resin: 71.5%;
High-density polyethylene resin, density are 0.95g/cm 3: 21.5%;
Talcum powder: 5.0%;
Nano-silicon dioxide particle, diameter are 35nm, 2%.
The manufacture method of the diaphragm of loudspeaker that polypropylene blend of the present invention is made comprises the following steps:
(1), according to formula rate starting material are sent into mixing roll and mix, be pressed into the blank of desired shape through press-forming machine,
(2), blank is put into the honeycomb hole foaming and forming apparatus, described device is heated to 140 ℃ and rotate the inner screw rod of described device, the plasticizing of blank melted by heating forms the matrix of described vibrating diaphragm, it is inner that high-pressure carbon dioxide gas is injected into described device, described carbon dioxide gas pressure is 17Mpa, form polymkeric substance/gas homogeneous system with matrix, subsequently, open pressure release valve removal carbon dioxide gas pressure, thereby at the equally distributed honeycomb hole of the inner acquisition of matrix, after described device is cooled to 22 ℃, take out matrix;
(3), utilize laser cutting or blanking method to make the vibrating diaphragm of desired shape and size at last.
Embodiment 3
Form by the raw material of following mass percent:
Acrylic resin: 75%;
High-density polyethylene resin, density are 0.96g/cm 3: 18%;
Talcum powder: 6%;
Nano-silicon dioxide particle, diameter are 40nm, 1%.
The manufacture method of the diaphragm of loudspeaker that polypropylene blend of the present invention is made comprises the following steps:
(1), according to formula rate starting material are sent into mixing roll and mix, be pressed into the blank of desired shape through press-forming machine,
(2), blank is put into the honeycomb hole foaming and forming apparatus, described device is heated to 160 ℃ and rotate the inner screw rod of described device, the plasticizing of blank melted by heating forms the matrix of described vibrating diaphragm, it is inner that high-pressure carbon dioxide gas is injected into described device, described carbon dioxide gas pressure is 20Mpa, form polymkeric substance/gas homogeneous system with matrix, subsequently, open pressure release valve removal carbon dioxide gas pressure, thereby at the equally distributed honeycomb hole of the inner acquisition of matrix, after described device is cooled to 25 ℃, take out matrix;
(3), utilize laser cutting or blanking method to make the vibrating diaphragm of desired shape and size at last.
Embodiment 4
Form by the raw material of following mass percent:
Acrylic resin: 68%;
High-density polyethylene resin, density are 0.94g/cm 3: 25%;
Ethylene-propylene-dience rubber: 6%;
Nano-silicon dioxide particle, diameter are 25nm, 1%.
The manufacture method of the diaphragm of loudspeaker that polypropylene blend of the present invention is made comprises the following steps:
(1), according to formula rate starting material are sent into mixing roll and mix, be pressed into the blank of desired shape through press-forming machine,
(2), blank is put into the honeycomb hole foaming and forming apparatus, described device is heated to 120 ℃ and rotate the inner screw rod of described device, the plasticizing of blank melted by heating forms the matrix of described vibrating diaphragm, it is inner that high-pressure carbon dioxide gas is injected into described device, described carbon dioxide gas pressure is 18Mpa, form polymkeric substance/gas homogeneous system with matrix, subsequently, open pressure release valve removal carbon dioxide gas pressure, thereby at the equally distributed honeycomb hole of the inner acquisition of matrix, after described device is cooled to 23 ℃, take out matrix;
(3), utilize laser cutting or blanking method to make the vibrating diaphragm of desired shape and size at last.
Embodiment 5
Form by the raw material of following mass percent:
Acrylic resin: 69%;
High-density polyethylene resin, density are 0.95g/cm 3: 21.5%;
Ethylene-propylene-dience rubber: 7.5%;
Nano-silicon dioxide particle, diameter are 32nm, 2%.
The manufacture method of the diaphragm of loudspeaker that polypropylene blend of the present invention is made comprises the following steps:
(1), according to formula rate starting material are sent into mixing roll and mix, be pressed into the blank of desired shape through press-forming machine,
(2), blank is put into the honeycomb hole foaming and forming apparatus, described device is heated to 140 ℃ and rotate the inner screw rod of described device, the plasticizing of blank melted by heating forms the matrix of described vibrating diaphragm, it is inner that high-pressure carbon dioxide gas is injected into described device, described carbon dioxide gas pressure is 17.5Mpa, form polymkeric substance/gas homogeneous system with matrix, subsequently, open pressure release valve removal carbon dioxide gas pressure, thereby at the equally distributed honeycomb hole of the inner acquisition of matrix, after described device is cooled to 22.5 ℃, take out matrix;
(3), utilize laser cutting or blanking method to make the vibrating diaphragm of desired shape and size at last.
Embodiment 6
Form by the raw material of following mass percent:
Acrylic resin: 75%;
High-density polyethylene resin, density are 0.96g/cm 3: 18%;
Ethylene-propylene-dience rubber: 6%;
Nano-silicon dioxide particle, diameter are 40nm, 1%.
The manufacture method of the diaphragm of loudspeaker that polypropylene blend of the present invention is made comprises the following steps:
(1), according to formula rate starting material are sent into mixing roll and mix, be pressed into the blank of desired shape through press-forming machine,
(2), blank is put into the honeycomb hole foaming and forming apparatus, described device is heated to 160 ℃ and rotate the inner screw rod of described device, the plasticizing of blank melted by heating forms the matrix of described vibrating diaphragm, it is inner that high-pressure carbon dioxide gas is injected into described device, described carbon dioxide gas pressure is 20Mpa, form polymkeric substance/gas homogeneous system with matrix, subsequently, open pressure release valve removal carbon dioxide gas pressure, thereby at the equally distributed honeycomb hole of the inner acquisition of matrix, after described device is cooled to 25 ℃, take out matrix;
(3), utilize laser cutting or blanking method to make the vibrating diaphragm of desired shape and size at last.

Claims (3)

1. the diaphragm of loudspeaker made of a polypropylene blend is characterized in that being made up of the raw material of following mass percent:
Acrylic resin: 68% ~ 75%;
High-density polyethylene resin, density are 0.94 ~ 0.96g/cm 3: 18% ~ 25%;
Talcum powder or ethylene-propylene-dience rubber: 6% ~ 9%;
Nano-silicon dioxide particle, diameter are 25 ~ 40nm, 1% ~ 3%.
2. the diaphragm of loudspeaker that polypropylene blend according to claim 1 is made, it is characterized in that: internal structure is the honeycomb cavernous structure, and the honeycomb hole diameter is between 10 μ m ~ 100 μ m, and honeycomb cell densities range is greater than 10 8Individual/cm 3
3. the manufacture method of the diaphragm of loudspeaker that polypropylene blend as claimed in claim 1 is made comprises the following steps:
(1), according to formula rate starting material are sent into mixing roll and mix, be pressed into the blank of desired shape through press-forming machine,
(2), blank is put into the honeycomb hole foaming and forming apparatus, described device is heated to 120 ℃ ~ 160 ℃ and rotate the inner screw rod of described device, the plasticizing of blank melted by heating forms the matrix of described vibrating diaphragm, it is inner that high-pressure carbon dioxide gas is injected into described device, described carbon dioxide gas pressure is 15 ~ 20Mpa, form polymkeric substance/gas homogeneous system with matrix, subsequently, open pressure release valve removal carbon dioxide gas pressure, thereby at the equally distributed honeycomb hole of the inner acquisition of matrix, after described device is cooled to 20 ℃ ~ 25 ℃, take out matrix;
(3), utilize laser cutting or blanking method to make the vibrating diaphragm of desired shape and size at last.
CN201110189771A 2011-07-07 2011-07-07 Loudspeaker diaphragm made from polypropylene blend Expired - Fee Related CN102295805B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201110189771A CN102295805B (en) 2011-07-07 2011-07-07 Loudspeaker diaphragm made from polypropylene blend

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201110189771A CN102295805B (en) 2011-07-07 2011-07-07 Loudspeaker diaphragm made from polypropylene blend

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CN102295805A true CN102295805A (en) 2011-12-28
CN102295805B CN102295805B (en) 2012-10-10

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103929710A (en) * 2014-04-25 2014-07-16 瑞声光电科技(常州)有限公司 Preparation method of composite vibrating diaphragm
CN104125530A (en) * 2014-06-20 2014-10-29 宁波兴隆电子有限公司 High-signal to noise ratio curve double-down microphone
CN107454546A (en) * 2017-08-16 2017-12-08 东莞涌韵音膜有限公司 Speaker film production process
CN107484099A (en) * 2017-08-16 2017-12-15 东莞涌韵音膜有限公司 The production method that air-permeable material and sound film is made using the material of earphone sound film
CN107501590A (en) * 2017-09-14 2017-12-22 黄建伟 The method that the diaphragm of loudspeaker is prepared using radiation modification
CN111787466A (en) * 2020-07-08 2020-10-16 深圳市时商创展科技有限公司 Sound box vibrating diaphragm and sound box

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1986627A (en) * 2005-12-22 2007-06-27 吴永刚 Composite polypropylene material and its preparing method
CN101288336A (en) * 2005-10-14 2008-10-15 Kh化学有限公司 Acoustic diaphragm and speakers having the same
CN101304622A (en) * 2007-05-09 2008-11-12 富准精密工业(深圳)有限公司 Audio film structure of electroacoustic apparatus and preparation method thereof
CN101552943A (en) * 2009-05-18 2009-10-07 毛丛敏 A sheet material for producing loudspeaker cone and its processing technique

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101288336A (en) * 2005-10-14 2008-10-15 Kh化学有限公司 Acoustic diaphragm and speakers having the same
CN1986627A (en) * 2005-12-22 2007-06-27 吴永刚 Composite polypropylene material and its preparing method
CN101304622A (en) * 2007-05-09 2008-11-12 富准精密工业(深圳)有限公司 Audio film structure of electroacoustic apparatus and preparation method thereof
CN101552943A (en) * 2009-05-18 2009-10-07 毛丛敏 A sheet material for producing loudspeaker cone and its processing technique

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103929710A (en) * 2014-04-25 2014-07-16 瑞声光电科技(常州)有限公司 Preparation method of composite vibrating diaphragm
CN104125530A (en) * 2014-06-20 2014-10-29 宁波兴隆电子有限公司 High-signal to noise ratio curve double-down microphone
CN107454546A (en) * 2017-08-16 2017-12-08 东莞涌韵音膜有限公司 Speaker film production process
CN107484099A (en) * 2017-08-16 2017-12-15 东莞涌韵音膜有限公司 The production method that air-permeable material and sound film is made using the material of earphone sound film
CN107501590A (en) * 2017-09-14 2017-12-22 黄建伟 The method that the diaphragm of loudspeaker is prepared using radiation modification
CN111787466A (en) * 2020-07-08 2020-10-16 深圳市时商创展科技有限公司 Sound box vibrating diaphragm and sound box

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Owner name: GENG YUNYAO

Effective date: 20120130

Owner name: MA CHUNBIAO

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Address after: 136001 3128, economic development zone, Siping City, Jilin Province

Applicant after: Ma Chunbiao

Co-applicant after: Geng Yunyao

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Applicant before: Jilin Shenyun Electronic Technology Development Co., Ltd.

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