CN102283224B - Wheatland weeding composition and preparation thereof - Google Patents

Wheatland weeding composition and preparation thereof Download PDF

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CN102283224B
CN102283224B CN201110287257.6A CN201110287257A CN102283224B CN 102283224 B CN102283224 B CN 102283224B CN 201110287257 A CN201110287257 A CN 201110287257A CN 102283224 B CN102283224 B CN 102283224B
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weed killer
flumetsulam
killer herbicide
tralkoxydim
weeding composition
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CN102283224A (en
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俞远凯
王龙
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Hefei Xingyu Chemical Co Ltd
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Hefei Xingyu Chemical Co Ltd
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Abstract

The invention relates to the field of pesticide preparations, and discloses a wheatland weeding composition. The wheatland weeding composition comprises tralkoxydim and flumetsulam. The invention also discloses a wheatland weed killer which comprises the weeding composition and auxiliary materials acceptable in agriculture, and the weeding composition accounts for 1-85 percent by weight of the weed killer. The weed preventing effect of the weeding composition and the preparation thereof disclosed by the invention is obviously improved, the synergistic effect is obvious, the dosage of active ingredients is reduced, the generation of drug resistance of weeds is delayed, environmental pollution is reduced, and the wheatland weeding composition and the preparation thereof can be widely applied in the agricultural field.

Description

A kind of Wheat field weeding composition and preparation thereof
Technical field
The present invention relates to pesticidal preparations field, relate to specifically a kind of Wheat field weeding composition and preparation thereof.
Background technology
Wheat is the general designation of Triticum plant, it is a kind of gramineous plants extensively planting all over the world, being rich in starch, protein, fat, mineral matter, calcium, iron, thiamine, vitamin b3, nicotinic acid and vitamin A etc., is the cereal crops of gross yield second in the world.In China, wheat is one of Three major grain crops, occupies the basic of critical role ,Shi China agricultural in all cereal crops.But, the most of wheat paddock of China always has crop smothering in various degree to occur, the most serious with grassy weed crop smotherings such as the broad leaved weed crop smotherings such as lamb's-quarters, acalypha copperleaf and lady's-grass, herba setariae viridis grass, this two classes weeds kind is many, distributes wide, growing power is vigorous, individual plant area coverage is large, fights in a large number moisture, nutriment, space, a little less than causing wheat growth gesture with wheat, directly affect the yield and quality of wheat, directly affect China's cereal crops reserves.Therefore, domestic wheat paddock is widely used weed killer herbicide, avoids wheat because of the weeds underproduction.
At present, the domestic weed killer herbicide that is usually used in preventing and treating weeds of wheat is Flumetsulam, and its active component is Flumetsulam, chemical name be 2 ', 6 '-bis-fluoro-5-methyl (1,2,4)-triazols (1,5-a) pyrimidine-2-sulfonanilide.Flumetsulam is interior suction conductivity weed killer herbicide, by root system and blade absorption, xylem and the phloem of weeds, is conducted, and in weeds meristematic tissue, accumulates, by suppressing acetolactate synthestase in weeds body, make protein biosynthesis block, weeds stop growing, and finally cause death.But the broad leaved weed herbicidal effect of Flumetsulam is still not fully up to expectations.Meanwhile, its preventive effect to grassy weed is poor, can not effectively prevent and treat wheat paddock main weeds.
Summary of the invention
In view of this, the object of the invention is to provide a kind of Wheat field weeding composition and preparation thereof, can improve the preventive effect of broad leaved weed and grassy weed and reduce dosage.
For realizing object of the present invention, the present invention adopts following technical scheme:
A Wheat field weeding composition, is comprised of tralkoxydim and Flumetsulam.
Wherein, the mass ratio of described tralkoxydim and Flumetsulam is preferably 1: 45-60: 1, more preferably 1: 15-15: 1, most preferably be 1: 3-3: 1.
Flumetsulam, chemical name is 2 ', 6 '-bis-fluoro-5-methyl (1,2,4)-triazol (1,5-a) pyrimidine-2-sulfonanilide, belonging to triazolopyrimidine sulfonamides, is typical inhibitor of acetolactate synthetase, is the agent of a kind of low toxicity broad spectrum weeding.Flumetsulam can be prevented and kill off most of annual and perennial broadleaf weeds, as lamb's-quarters, dayflower, huge three-coloured amaranth, field thistle, Amaranthus retroflexus, recessed amaranth, acalypha copperleaf, clearvers, common vetch etc., soluble in water, in the situation that soil is more arid, also can reach herbicidal effect.
Tralkoxydim, chemical name is 2-[1-(ethoxy imino) propyl group]-3-hydroxyl-5-(2,4,6-trimethylphenyl) cyclohexene-2-ketone, belong to oximes weed killer herbicide, be applicable to wheat, barley.Mainly prevent and kill off grassy weed, to wild oat, straw, yard grass, fescue, amur foxtail, lady's-grass and herba setariae viridis grass etc. all has control efficiency.
The present invention also provides a kind of wheat paddock weed killer herbicide, can accept auxiliary material be comprised of Herbicidal combinations of the present invention and pesticidal preparations.
Wherein, the mass percent that described Herbicidal combinations accounts for described weed killer herbicide is 1-85%, is preferably 10-62%, more preferably 20%.
According to method known in those skilled in the art, the present invention can be made into the upper any formulation of acceptable of agricultural, and preferred formulation formulation is oil-suspending agent, water dispersible granules and wetting powder.Auxiliary material of the present invention can form by a kind of and surfactant in solid carrier, liquid diluent, and wherein said solid carrier, liquid diluent and surfactant are at least a kind of.According to auxiliary material known in those skilled in the art, surfactant can be selected from alkylsulfonate, fatty alcohol sulfonate, alkylphenol polyoxyethylene, lauryl sodium sulfate, calcium dodecyl benzene sulfonate, sodium lauryl sulfate, lignosulfonates, carboxymethyl cellulose, agriculture breast 500#, agriculture breast 600#, Nongru-700 #, agriculture breast 2201, agriculture breast 8209, agriculture breast 8312, agriculture breast 8210, agriculture breast NP-10, agriculture breast 0425, agriculture breast 0408, agriculture breast 3517, agriculture breast 8220, agriculture breast 8210, NNO BX LS etc.; Solid carrier can be selected from bentonite, white carbon, high clay, potter's clay, diatomite, kaolin, precipitated calcium carbonate etc.; Liquid diluent can be selected from cyclohexanone, acetone, dimethylacetylamide, methyl alcohol, methyl oleate, dimethyl sulfoxide (DMSO), water etc.
Different herbicidal activity components are mixed rear each active component due to the difference of composition, structure, physicochemical property, make the synergy between each active component be typically expressed as synergistic effect, summation action or antagonism.So-called synergistic effect is exactly the mutual synergism between different material, and the effect of its generation is greater than the sum total of each composition effect; And the effect that summation action is exactly its generation equals the sum total of each composition effect; Antagonism refers to that when two kinds of materials act on living organism, a kind of material disturbs the effect of another kind of material, or the effect of interfering with an opponent each other, the phenomenon that general effect is declined.
Weed killer herbicide of the present invention and each single dose have been carried out weeds of wheat control test, result shows, in weed killer herbicide effective ingredient consumption of the present invention, be less than under the prerequisite of each single dose effective ingredient consumption, the present invention prevents and treats the drug effect of broad leaved weed and grassy weed higher than each single dose, show that in weed killer herbicide of the present invention, each active component is without cross tolerance, control efficiency has synergistic effect.
From above technical scheme, the weeds preventive effect of Herbicidal combinations of the present invention and preparation thereof significantly improves, and has notable synergistic effect, and reduce the consumption of active ingredient, delay the generation of herbicide resistance, reduce the pollution to environment, can be widely used in agriculture field.
Embodiment
The embodiment of the invention discloses a kind of Wheat field weeding composition and preparation thereof.Those skilled in the art can use for reference content herein, suitably improve technological parameter and realize.Special needs to be pointed out is, all similar replacements and change apparent to those skilled in the artly, they are all deemed to be included in the present invention.Product of the present invention is described by preferred embodiment, and related personnel obviously can change product as herein described or suitably change and combination within not departing from content of the present invention, spirit and scope, realizes and apply the technology of the present invention.
In order further to understand the present invention, below in conjunction with embodiment, a kind of Wheat field weeding composition provided by the invention and preparation thereof are elaborated.
Embodiment 1:6.1% tralkoxydim Flumetsulam water dispersible granules
6% tralkoxydim, 0.1% Flumetsulam, 4% calcium lignosulfonate, 3% carboxymethyl cellulose, 1%BX, 4% urea, diatomite supplies 100%, each material is once added to wet mixing in reactor, under stirring condition, it is fully mixed, and carry out wet pulverizing and carry out spray congealing moulding and spray drying granulation after certain fineness, obtain product.
Embodiment 2:62% tralkoxydim Flumetsulam oil wetting powder
60% tralkoxydim, 2% Flumetsulam, 4% methylcellulose, 2%JFC, kaolin supplies 100%, makes it fully mix above each material under stirring condition, pulverizes certain fineness, obtains wetting powder.
Embodiment 3:48% tralkoxydim Flumetsulam oil-suspending agent
45% tralkoxydim, 3% Flumetsulam, 6% white carbon, 10% agriculture breast 0408, oleic acid grease supplies 100%, by after each mixing of materials, by case of wet attrition, makes average grain diameter below 5 μ m, just obtains oil suspending agent.
Embodiment 4:20% tralkoxydim Flumetsulam water dispersible granules
15% tralkoxydim, 5% Flumetsulam, 5% sodium carboxymethylcellulose, 5% lauryl sodium sulfate, 16% lignin sodium sulphate, 2% soluble starch, kaolin supplies 100%, each material is once added to wet mixing in reactor, under stirring condition, it is fully mixed, and carry out wet pulverizing and carry out spray congealing moulding and spray drying granulation after certain fineness, obtain product.
Embodiment 5:20% tralkoxydim Flumetsulam water dispersible granules
5% tralkoxydim, 15% Flumetsulam, 5% sodium carboxymethylcellulose, 5% lauryl sodium sulfate, 16% lignin sodium sulphate, 2% soluble starch, kaolin supplies 100%, each material is once added to wet mixing in reactor, under stirring condition, it is fully mixed, and carry out wet pulverizing and carry out spray congealing moulding and spray drying granulation after certain fineness, obtain product.
Embodiment 6:48% tralkoxydim Flumetsulam oil-suspending agent
3% tralkoxydim, 45% Flumetsulam, 6% white carbon, 10% agriculture breast 0408, oleic acid grease supplies 100%, by after each mixing of materials, by case of wet attrition, makes average grain diameter below 5 μ m, just obtains oil suspending agent.
Embodiment 7:62% tralkoxydim Flumetsulam wetting powder
2% tralkoxydim, 60% Flumetsulam, 4% methylcellulose, 2%JFC, kaolin supplies 100%, makes it fully mix above each material under stirring condition, pulverizes certain fineness, obtains wetting powder.
Embodiment 8:82.8% tralkoxydim Flumetsulam water dispersible granules
1.8% tralkoxydim, 81% Flumetsulam, 4% sodium carboxymethylcellulose, 3%NNO, 3% lignin sodium sulphate, 1% soluble starch, kaolin supplies 100%, each material is once added to wet mixing in reactor, under stirring condition, it is fully mixed, and carry out wet pulverizing and carry out spray congealing moulding and spray drying granulation after certain fineness, obtain product.
Embodiment 9: control of weeds test
The weed killer herbicide of embodiment 1-8 and commercially available 10% tralkoxydim OF, 80% Flumetsulam WDG are carried out to the control test of weeds, and together, in the wheat 2-4 leaf phase, weeds 2-5 leaf phase dispenser, investigates strain preventive effect, the results are shown in Table 1 for after medicine 30 days for experimental condition, environment facies.
The test of table 1 control of weeds
Figure BDA0000093871720000051
As shown in Table 1, in weed killer herbicide effective ingredient consumption of the present invention, be less than under the prerequisite of each single dose effective ingredient consumption, the present invention prevents and treats the drug effect of broad leaved weed and grassy weed higher than each single dose, show that weed killer herbicide control efficiency of the present invention has synergistic effect, can reduce dosage, reduce cost, to succession crop safety.
The explanation of above embodiment is just for helping to understand method of the present invention and core concept thereof.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also carry out some improvement and modification to the present invention, these improvement and modification also fall in the protection domain of the claims in the present invention.

Claims (9)

1. for a Herbicidal combinations for wheat paddock broad leaved weed and grassy weed, it is characterized in that, tralkoxydim and Flumetsulam, consist of, the mass ratio of described tralkoxydim and Flumetsulam is 1:45-60:1.
2. Herbicidal combinations according to claim 1, is characterized in that, the mass ratio of described tralkoxydim and Flumetsulam is 1:15-15:1.
3. Herbicidal combinations according to claim 2, is characterized in that, the mass ratio of described tralkoxydim and Flumetsulam is 1:3-3:1.
4. a wheat paddock weed killer herbicide, is characterized in that, acceptable auxiliary material on Herbicidal combinations described in claim 1 and pesticidal preparations, consists of, and the mass percent that described Herbicidal combinations accounts for described weed killer herbicide is 1-85%.
5. weed killer herbicide according to claim 4, is characterized in that, the mass percent that described Herbicidal combinations accounts for described weed killer herbicide is 10-62%.
6. weed killer herbicide according to claim 5, is characterized in that, the mass percent that described Herbicidal combinations accounts for described weed killer herbicide is 20%.
7. according to weed killer herbicide described in claim 4-6 any one, it is characterized in that, it is oil-suspending agent.
8. according to weed killer herbicide described in claim 4-6 any one, it is characterized in that, it is wetting powder.
9. according to weed killer herbicide described in claim 4-6 any one, it is characterized in that, it is water dispersible granules.
CN201110287257.6A 2011-09-23 2011-09-23 Wheatland weeding composition and preparation thereof Active CN102283224B (en)

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CN102835405A (en) * 2012-09-28 2012-12-26 江苏省农用激素工程技术研究中心有限公司 Weed killing composition containing tralkoxydim and florasulam
CN103548825B (en) * 2013-11-14 2015-10-28 联保作物科技有限公司 A kind of Herbicidal combinations and preparation thereof
CN105851009A (en) * 2016-04-18 2016-08-17 泰安市农业科学研究院 Synergistic weeding composition containing biscarfentrazone and tralkoxydim and application of synergistic weeding composition

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CN101292655A (en) * 2007-04-28 2008-10-29 江苏辉丰农化股份有限公司 Cornfield herbicidal composition containing tralkoxydim

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