CN1022682C - Process for preparing mosaic of glass-ceramic composite material - Google Patents
Process for preparing mosaic of glass-ceramic composite material Download PDFInfo
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- CN1022682C CN1022682C CN 90104449 CN90104449A CN1022682C CN 1022682 C CN1022682 C CN 1022682C CN 90104449 CN90104449 CN 90104449 CN 90104449 A CN90104449 A CN 90104449A CN 1022682 C CN1022682 C CN 1022682C
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- glass
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- composite material
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- 239000002131 composite material Substances 0.000 title claims abstract description 13
- 239000002241 glass-ceramic Substances 0.000 title abstract description 3
- 238000004519 manufacturing process Methods 0.000 title description 9
- 239000011521 glass Substances 0.000 claims abstract description 27
- 239000000919 ceramic Substances 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 238000000748 compression moulding Methods 0.000 claims abstract description 9
- 239000002699 waste material Substances 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- 238000010304 firing Methods 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000006063 cullet Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 238000003672 processing method Methods 0.000 claims description 7
- 238000005245 sintering Methods 0.000 claims description 7
- 239000011468 face brick Substances 0.000 claims description 6
- 235000019580 granularity Nutrition 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 5
- 239000002893 slag Substances 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 239000003292 glue Substances 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- 238000012216 screening Methods 0.000 claims description 3
- 150000004760 silicates Chemical class 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims 1
- 239000011259 mixed solution Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 5
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 238000005286 illumination Methods 0.000 abstract 1
- 230000001953 sensory effect Effects 0.000 abstract 1
- 239000000843 powder Substances 0.000 description 16
- 238000005303 weighing Methods 0.000 description 6
- 229910052573 porcelain Inorganic materials 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 239000011398 Portland cement Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 235000013405 beer Nutrition 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 235000015067 sauces Nutrition 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- 241000707825 Argyrosomus regius Species 0.000 description 1
- 241001233914 Chelidonium majus Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000001458 anti-acid effect Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000010977 jade Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000010819 recyclable waste Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Landscapes
- Compositions Of Oxide Ceramics (AREA)
- Glass Compositions (AREA)
Abstract
The invention relates to a process method for preparing a glass-ceramic composite mosaic, which takes waste silicate clinker such as waste glass, waste ceramic and the like as raw materials, mixes the raw materials according to a certain component proportion after crushing, then carries out one-step compression molding, and then sends the mixture into a kiln to be fired for 6 to 12 minutes to obtain a novel composite material. The cost of the composite material finished product is reduced by 1/4 to 1/3 compared with the finished product on the market, the physical and chemical properties and the mechanical strength of the composite material finished product are higher than those of the existing finished product, and the composite material finished product can generate the sensory effect of starlight flash under the illumination.
Description
The present invention relates to a kind of processing method for preparing glass～ceramic composite mosaic, this technology is to utilize the cullet and other silicates waste material that reclaim to be raw material, through the classification crushing screening, mixes the compacting sintering moulding by proportioning.
As mosaic, the face brick of External building finishing material use within doors, comparatively general at present.Existing known mosaic, face brick production technology all are to make finished product with single glass body or single ceramic body.Finished product condemnation factor as the processing of single ceramic raw material is higher, and in case what scrapped is to melt down regeneration, this is determined by ceramic self property.
The technical scheme of utilizing cullet to make glass Mosaic again behind powder has many.The disclosed CN86101532A of Chinese patent communique is an example.It is raw material binding agent and inorganic colourant and compacting sintering becomes the glass Mosaic processing method of single material in addition with cullet that this part patent application document provides a kind of.This processing method firing time needs 1～2 hour, and production efficiency is lower, and performance is limited to by the single glass body.
The objective of the invention is: overcome the deficiency of prior art, a kind of processing method that is feedstock production glass～ceramic composite mosaic with multiple useless portland cement clinker is provided.
Implementation of the present invention is as follows: described glass～ceramic composite be the useless pottery porcelain that utilize to reclaim, cullet, slag slag, and silica mine tailing class be raw material, through the classification crushing screening, mix the compacting sintering moulding by proportioning, its feed composition proportioning can be selected for use from following several groups: set of dispense is than 1: pottery: 10～40%, glass: 50～80%, tinting material: 0.05～10%; Set of dispense is than 2: glass: 40～60%, slag class: 20～30%, pottery class: 15～20%, zinc oxide: 0.1～0.5%, tinting material: 0.05～10%; Set of dispense is than 3: glass: 50～80%, silica mine tailing material: 10～30%, pottery class: 5～15%, zinc oxide: 0.1～0.5%, tinting material: 0.05～10%.Can add an amount of binding agent than raw material when the compression moulding to above-mentioned each assembly, binding agent can be used: 100% water glass: 3～7%, glue: 5～8%, water: 85～90% mutual uniform mixing are made.
Required various raw material granularities are broken to 24 orders～250 orders, select different grain size for use, various raw materials uniformly mixed mutually according to product, then with 120kg～380kg/cm by the said components proportioning
2A compression moulding of forming pressure, molded blank can directly be sent in the kiln of gap and fire under 720 ℃～900 ℃ temperature, firing time is 6～12 minutes.For the waste product that occurs in producing, still can be with the compacting sintering moulding once more of same production technique after the pulverizing.
Realizing when of the present invention, various glass classification color separations such as the cullet middle plateform that reclaims, Bottle ﹠ Can vessel, electrician's goods should used, testing with preceding sampling analysis and the sintering temperature of needing.Pottery can be hard porcelain such as electrical equipment, chemical porcelain, tableware porcelain etc., also can be soft porcelain, as ceramic tile etc.Pottery waste material such as kylix, flowerpot, cylinder jar altar class.The available portland cement clinker also has steel slag etc. and silica mine tailing.During production, it is broken separately with it with crusher to need that above-mentioned materials is cleaned the back, granularity is controlled at 5mm～20mm, then sending into disc type whirlwind pulverizer or ball mill, to carry out fine powder broken, it is a class, 150 orders～be a class more than 250 orders that granularity can be divided into a class, 64 orders～150 orders by 24 orders～64 purposes, and all kinds of underproof screen overflows are still got back to the pulverizer powder to qualified; With qualified powder, after weighing by the set of dispense ratio, send into blending machine blending mixing in the lump, require to add an amount of binding agent, the aqueous solution according to product performance more thereupon together with the tinting material of aequum, concocted 5～7 minutes, at this moment the composition moisture content of compound all reaches best degree of mixing again.If the north of china in winter operation then need take the corresponding measure of heating to guarantee that the blending stock temperature is more than 10 ℃.The material that mixes up is delivered to the pressure next time pressed compact moulding of press room in regulation, if repeatedly compression moulding will cause defectives such as finished product top layer aliquation, inherent interlayer.The base substrate of forming is placed on the special light-weight refractory screen brick plate, burns till in kiln car is sent into kiln.Used kiln can be the gap kiln, also tunnel kiln.The leading portion of this kind tunnel furnace is for giving 8 meters long in the torrid zone, and the stage casing is that 3 meters of middle temperature clinkering zones are long, and back segment is that 7 meters of annealing zones are long.In this kiln, fire temperature that product need control clinkering zone between 750 ℃～900 ℃, specifically will decide according to the softened zone viscosity test of used cullet." half-cooked " can appear in vitreous imperfection when base substrate is lower than 750 ℃; If temperature is crossed and is higher than and can overbates, lose due physical dimension.Except that need control firing temperature, also want the whole firing time of strict control base substrate should be not less than 6 minutes.Accurately firing time will be decided by base substrate thickness size.
Principle of the present invention is: after glass is heated, be to be a plastic viscosity gradually to change along with the rising of temperature.As mentioned before, various powders are evenly to concoct by weight ratio, can guarantee that like this glass powder is to be enclosed in equably around the ceramic-like powder particulate, when temperature reaches more than 750 ℃, the glass powder is tending towards softening and shrinks flowing gradually, all the time be in according to the proportioning glass content and be rich in state, so form a vitreum network, ceramic powder particle then is embedded in therebetween firmly.From the microlithofacies analysis, because making pottery, glass all belongs to the silicates material, so they also exist meagre soakage layer mutually in sintering process, this just is combined into a New-type compounded Portland class material.Also just because its textural association, make product physical strength height provided by the invention, wear-resisting, antiacid caustic corrosion performance good, color and luster is stable.
Glass provided by the present invention～the mosaic of Ceramic Composite material, the performance index of face brick are:
Water-intake rate: 0.5～2%
Resistance to acid attack rate :≤0.2%(soaks 24 hours weight loss in 10% hydrochloric acid)
Caustic corrosion resistance rate :≤0.02%(is 24 hours weight loss of dip in NaOH solution)
Anti-chilling thermal test flawless: in 150 ℃ of baking ovens, take out and fastly go into 19 ℃ of water flawless.
The present invention's advantage compared with prior art is:
1. not only recyclable cullet, also multiple useless portland cement clinker such as recyclable waste ceramic can be saved relevant Mineral resources in a large number as raw materials for production again; Its processing condition, production cycle shorten; Reduced production cost.Material provided by the present invention is made mosaic, face brick hangs down 1/4th to 1/3rd than the cost of existing like product.
2. because glass and pottery formed matrix material institute inherent characteristic in firing, all the similar finished product than single glass or pottery is good to make thing, voltinism energy and the physical strength of its finished product.
3. because this kind composite structure is similar to the jade class, its finished product shines the photosensitive effect that the asterism color break-up is arranged down at light.
4. make finished product with matrix material, in use be more convenient for laying bonding than glasswork.
5. owing to reclaim the materials recycling product, a large amount of silicate waste materials of handling the life of industry have been protected environment, and this also is the most difficult part in the domestic and international waste material.
Below by embodiment the present invention is done further narration:
Example one
Light green glass pottery mosaic: green beer air water bottle, powder to 150 order takes by weighing 100 grams, white pottery china bowl powder to 150 order, take by weighing 35 grams, zinc oxide is crossed 200 mesh sieves, takes by weighing 5～8 grams, add 7～8 gram aqueous solution, (this aqueous fusion liquid is 100% water glass, 4 grams, and glue 7 grams add in the 100 gram water) blending was evenly placed 15 minutes, the entrance pressure mould is with 200kg/cm
2Compression moulding is directly sent in 880 ℃ of stoves and was burnt 8 minutes, and coming out of the stove is chilled to room temperature.Product is 25 * 25 * 4.5mm light green mosaic.But wall is pasted in this mosaic floor file.
Implement two
Light gray green glass veneer brick 75 * 150 * 7mm; Get blue look beer air water bottle 100 grams, powder to 100～64 orders mix granularity; Take by weighing the ceramics powder (white) of the mixed grain of 40 grams, 64～100 orders, add 6 grams, 200 order zinc oxide, add the 8 gram aqueous solution, with 240kg/cm
2Compression moulding is sent in 880 ℃ of stoves and was fired 9 minutes, come out of the stove to room temperature, just the celandine green face brick, this product is rich in sparkle effect, for decoration of exterior wall, under the irradiation of sunlight and light, makes eye that the star effect that sparkles be arranged, and has increased outward appearance U.S. of buildings.
Embodiment three
Red sauce floor tile 300 * 300 * 18mm, plate window glass powder to 100～150 orders of making even, 5kg, white ceramics powder to 150 order of 1.2kg, the purple pottery powder to 150 of 1.2g order～250 orders takes by weighing 0.037kgZnO granularity 200 orders, mixes and transfers evenly, adds the 0.45kg aqueous solution.With 280kgf/cm
2The 18M tunnel furnace is sent in compression moulding, and burnt till in 12 minutes in 900 ℃ of districts of middle warm area, and kiln discharge just obtains serious and bright-coloured red sauce floor tile to room temperature.
Claims (3)
1, the processing method of preparation glass～ceramic composite mosaic, it is to utilize the cullet and other silicates waste material that reclaim to be raw material, through the classification crushing screening, mixes the compacting sintering moulding by proportioning, it is characterized in that:
A, set of dispense than 1 (accounting for total amount per-cent) are:
Pottery: 10～40%
Glass: 50～80%
Tinting material: 0.05～10%
B, set of dispense than 2 are:
Glass: 40～60%
Slag class: 20～30%
Pottery class: 15～20%
Zinc oxide: 0.1～0.5%
Tinting material: 0.05～10%
C, set of dispense than 3 are:
Glass: 50～80%
Silica mine tailing class: 10～30%
Pottery class: 5～15%
Zinc oxide: 0.1～0.5%
Tinting material: 0.05～10%
D, can add an amount of binding agent than raw material when the compression moulding to above-mentioned each set of dispense.
E. various raw material granularities are broken to 24 orders～250 orders, according to product select different grain size for use, by the set of dispense ratio that provides in the claim 1, with the mutual mixing of various raw materials, then with 120kg～380kg/cm
2Forming pressure, a compression moulding, molded blank can directly be sent in the gap kiln of firing temperature and fire, firing temperature is 720 ℃～900 ℃, firing time is 6～12 minutes.
2, processing method according to claim 1 is characterized in that: institute's adding additives is the mixed solution of following set of dispense ratio:
100% water glass: 3～7%
Glue: 5～8%
Water: 85～90%.
3, processing method according to claim 1 and 2 is characterized in that: burnt the glass～Ceramic Composite mosaic that, the unacceptable product in the face brick with this method, after it can being pulverized again with this method technological forming, fire.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 90104449 CN1022682C (en) | 1990-06-12 | 1990-06-12 | Process for preparing mosaic of glass-ceramic composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 90104449 CN1022682C (en) | 1990-06-12 | 1990-06-12 | Process for preparing mosaic of glass-ceramic composite material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1057246A CN1057246A (en) | 1991-12-25 |
| CN1022682C true CN1022682C (en) | 1993-11-10 |
Family
ID=4878562
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 90104449 Expired - Fee Related CN1022682C (en) | 1990-06-12 | 1990-06-12 | Process for preparing mosaic of glass-ceramic composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1022682C (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1057748C (en) * | 1996-11-08 | 2000-10-25 | 建平县平板玻璃厂 | Glass mosaic and tile made of pearlite tail sand |
| WO2013163807A1 (en) * | 2012-05-03 | 2013-11-07 | Kao Chin Fa | Construction method for wall surface with glazed layer, wall surface structure and brick structure |
| CN107827355A (en) * | 2017-10-24 | 2018-03-23 | 佛山市唯格装饰建材有限公司 | A kind of preparation technology of mosaic glass base substrate |
| CN110423003A (en) * | 2019-09-09 | 2019-11-08 | 安徽法莱科技有限公司 | With the manufacturing method of spatter glass particle production decorative building material |
| CN113387576A (en) * | 2021-06-09 | 2021-09-14 | 湖南仙凤瓷业有限公司 | Preparation method for recycling finished porcelain and glass into glaze |
-
1990
- 1990-06-12 CN CN 90104449 patent/CN1022682C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1057246A (en) | 1991-12-25 |
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