Embodiment
Below in conjunction with example, the present invention will be described in detail.
The present invention is take the principle of material and energy balance as theoretical basis, take the many principle comprehensive coordinations of gas, liquid, solid " tri-state separation " materialization, biochemical reaction as mechanism, to recover and to bring into play water body self purification function as means, take the water ecological setting of creating a natural circulation as object, system has in depth been explored low thing energy balance fine molecular material mechanism, has set up new materialization, biochemical running balance reaction system.The fine molecular of the inventive method, over-saturation dissolved oxygen, superpower magnetization technology, the difficult points such as in traditional method, water body oxygen level is low, microbial biochemical reaction is incomplete are overcome, not only can be by super-saturated oxygen soluble in water, and can make aerobic microbiological amount reproduction, thereby organic decomposition in acceleration water, the nutrition source of minimizing algae.The present invention refers to above-mentioned technology in the lake water processing of river, for the solution of this world-famous puzzle of water bodies of rivers and lakes eutrophication provides brand-new improvement thinking.
The overall schematic of water magnetizing device as shown in Figure 1, magnetizing assembly comprises magnetization passage 1 and flange 2, and flange 2 is positioned at the two ends of magnetization passage 1, and wherein flange 2 plays the convenient effect connecting.Magnetization passage 1 is circular, the inner circumferential direction along magnetization passage 1 of magnetization passage 1 has high magnetic flux density magnetic field, water body when passage 1 carries out magnetic force line cutting along the axis direction of magnetization passage 1 by magnetization with certain flow rate, the water body that flows through magnetization passage 1 is magnetized, and changes because cutting magnetic line makes the character of water.
Fig. 2 is the A-A sectional view of magnetizing assembly, magnetization passage 1 comprises inner ring 4 and outer wall 5, the cross section of inner ring 4 and outer wall 5 is circle, and inner ring 4 and outer wall 5 coaxial lines, between the inner ring 4 of described magnetization passage 1 and outer wall 5, permanent magnet 3 is set, for convenience of placing, permanent magnet 3 is fan-shaped, and permanent magnet 3 can be fitted with inner ring 4; Circumferential direction and axis direction along magnetization passage 1 arrange several piece permanent magnet 3, permanent magnet 3 in magnetization in passage 1 and with it permanent magnet 3 in relative position be close to and inner ring 4 by magneticaction, between outer wall 5 and permanent magnet 3, magnetic shielding material 6 is set, the magnetic permeability of magnetic shielding material 6 is determined according to the magneticstrength of magnetizing assembly.
Fig. 3 is combination unit overall schematic, and described combination unit comprises water pump 7, magnetizing assembly 8, fine molecular device 9 and oxygenerator 10.Each device is arranged by annexation shown in Fig. 3, be put near that need to administer water body, oxygenerator 10 is connected with fine molecular device 9, while making water certain speed flow through through fine molecular device 9 by water pump 7, oxygen is dissolved in water body by fine molecular device 9, and water body is carried out to fine molecular over-saturation dissolved oxygen, through the water body of over-saturation dissolved oxygen with the certain flow rate magnetizing assembly 8 of flowing through, and carrying out magnetic force line cutting, the water body of the magnetizing assembly 8 of flowing through becomes magnetized water; Process the water body after being purified through fine molecular device 9 and magnetizing assembly 8.
Embodiment 1: fine molecular over-saturation dissolved oxygen
Fine molecular over-saturation oxygen-dissolving apparatus is to utilize physical action, make the large water clusters associating disperse to become independently individual molecule, increased the voidage between water molecules, simultaneously by after same oxygen molecule refinement, be added in the space between water molecules, make that oxygen is super-saturated to be dissolved in the water.Sewage is after this device refinement, activity, vigor and the activation capacity of material in water, G&W are improved, increase contact area, gas, solid, liquid intimate mixing and mass transfer velocity are improved, change substance reaction environment, improve interface free energy and concentration diffusion transmitting thrust, thereby effectively improved the dissolving power of various materials in water, for microbial growth and breeding provide adapt circumstance.
Water body also can reach following effect after fine molecular:
More than the concentration of oxygen in water can reach 50mg/L, tap water oxygen content can only reach 4-6mg/L, so water body oxygen concn after fine molecular is processed significantly improves, becomes over-saturation dissolved oxygen water.Water body after fine molecular over-saturation dissolved oxygen is after 1 year, the concentration of measuring residue oxygen is original more than 60%, the utilization ratio of oxygen can reach more than 95%, and conventional aeration is difficult to accomplish, as: the utilization ratio of boring aeration dissolved oxygen only can reach 5%~10%, and micro-pore aeration dissolved oxygen utilization ratio also only can reach 20%~40% left and right.This device can by oxygen over-saturation be dissolved in water, to water body create a sufficient aerobic environment, aerobic microbiological amount reproduction is conducive to the removal of various pollutents in water, is conducive to improve the ecotope of water body.
The effect of oxygen in water may be summarized as follows:
(1) the aerobic katabolism of organism
Aerobic katabolism refers under the participation of aerobic microbiological and aerobic-anaerobic microbe (heterotroph bacterium) in water, under the condition of dissolved oxygen abundance, the organism in water (representing with COD) is decomposed into CO
2and H
2o, and the metabolic process giving off energy.
(2) ammonification of organonitrogen and the nitrification of ammonia nitrogen
The in the situation that of dissolved oxygen abundance, organonitrogen ammonifying bacteria under effect, there is " aminating reaction " and be decomposed and be converted into ammonia-state nitrogen; There is again " nitration reaction " and be converted into nitrous acid nitrogen, nitrate nitrogen in ammonia-state nitrogen, then by anti-nitration reaction, nitrate nitrogen, nitrous acid nitrogen are reduced into gaseous nitrogen discharge water body under the effect of nitrifier, thereby reach the object of denitrogenation.
(3) biological phosphate-eliminating
In waste water, the form of common phosphorus is phosphoric acid salt (H
2pO
4 -, HPO
4 2-, PO
4 3-), poly-phosphate and organophosphorus.In general waste water, the phosphorus of 90% left and right exists with phos-phate forms.
PolyP bacteria absorbs the low fatty acids such as acetic acid and synthesizes a kind of salt (PHB) in cell under anaerobic state, and the decomposition of needed energy derive poly-phosphorus in thalline, has so also just caused phosphatic release.In aerobic zone, polyP bacteria is take free oxygen as electron acceptor(EA), by aerobic the PHB storing in body decomposition, and utilize and decompose the energy producing, phosphoric acid salt in excessive picked-up water body is converted into poly-phosphorus, like this in cell, aerobic phosphorous accumulating amount is greater than anaerobic phosphorus release amount, just can realize by precipitating action the object of biological phosphate-eliminating.
In a word, to the super-saturated oxygen that dissolves in the water body of eutrophication, under the acting in conjunction of above-mentioned several effects, will progressively recover the balance of nature of water body, improve the self-purification capacity of water body.
Embodiment 2: superpower magnetization
Super-strong magnetic gasifying device utilizes high magnetic flux density magnetic field, and its magnetism intensity is tens times of common ferrite magnet, and work-ing life is up to more than 10 years; And the power of unique needs allows water flow through magnetic field to be not less than necessary speed exactly when water is magnetized, does not need to increase too much energy consumption again, super-strong magnetic gasifying device does not generally need repairing, adjusts and maintains.Through putting into practice this device, the water of human body and the device of flowing through is not all worked the mischief to hydrobiont.
After magnetization is processed, there is variation because the magnetization in magnetic field makes the water molecules of macromolecular mass in water body.Micropartical polarity strengthens, and cohesive force weakens, and original longer associated molecule chain in water is truncated as shorter associated molecule chain and the distortion of charged ion, has destroyed interionic electrostatic attraction.Adsorptive power between water molecules is little, and the macromolecular mass that water is formed by 13~18 water molecules set has become the subset or the single water molecules that are assembled by 5~6 water moleculess, and the activity of water is improved greatly; The surface tension of water molecules strengthens; Water molecules seepage force strengthens, and has interfacial energy; There is the variation of angle and length in water molecules key, hydrogen bond angle reduces to 103 ° of left and right from 105 ° simultaneously; Make the potential of hydrogen of water that variation occur, pH value approximately rises 0.4~1.0.
Water body can reach following effect after magnetization:
(1) heavy-oxygen-enriched water is passed through continuously from inducedmagnetic field, in water, produce 5 × 10
-5the H of %
2o
2, this is a kind of very strong oxygenant, can make the organism direct oxidation in water decompose, thereby reduce the COD in sewage;
(2) utilize the paramagnetic field property of oxygen and the counter field of nitrogen, the nitric nitrogen existing in water is decomposed, make the form effusion water body of nitrogen element with nitrogen, thereby reduced the nutrient nitrogen of algae;
(3) ultrastrong magnetic field, in the mode of cutting magnetic line in mobile water body, makes the cell walls attenuation of algae in water, causes enchylema to run off, and causes the death of algae, thereby has reached the function except algae;
(4) sewage magnetization has very strong selecting bacteria effect, and directly sterilization rate can reach 70%~80%, but can not make all microbial deaths, especially functional microorganism, and the meeting surviving improves water body self-purification ability;
(5) mobile water forms electric current after being magnetized in water, and the existence of electric current makes the oxygen in water become active oxygen;
(6) magnetization can promote high aquatic organism growth, is conducive to ecosystem restoration, improves water body self-purification ability.
Embodiment 3: the removal of nitrogen, phosphorus
The principal element that affects lake, river algal grown is the nutrition such as nitrogen, phosphorus, and the method for the invention can be removed by following approach the nutrition such as nitrogen, phosphorus:
(1) removal of nitrogen
A. the effect of fine molecular over-saturation oxygen-dissolving apparatus
This device, in over-saturation dissolved oxygen, has reduced NH
3-N the pressure of fluid surface and with the avidity of water, thereby reduced NH
3the dissolving power of-N in water, has strengthened it and has discharged diffusibility, so just makes part NH
3-N is transferred to gas phase and is discharged from water body from liquid phase.
B. the effect of super-strong magnetic gasifying device
This device utilizes the paramagnetic field property of oxygen and the counter field of nitrogen, and the nitrate nitrogen existing in water is decomposed, and makes the form effusion water body of nitrogen element with nitrogen, thereby has reduced the nutrient nitrogen of algae.
C. the effect of aerobic microbiological
Water body, after fine molecular over-saturation dissolved oxygen, makes dissolved oxygen better be absorbed and to utilize by aerobic microbiological, has increased the quantity of aerobic microbiological, has strengthened vigor, the activity of aerobic microbiological; Improve the ability of aerobic microbiological conversion nitrogen.
(2) removal of phosphorus
A. chemical dephosphorization effect (Fe
3+and Al
3+)
In the situation that containing compared with high-solubility oxygen, be conducive to the Fe in water
2+be oxidized to Fe
3+, Fe
3+be combined with phosphoric acid salt and form the tertiary iron phosphate of indissoluble and be deposited in the middle of bed mud, the soluble phosphate in water is reduced.And Fe
3+under neutrallty condition or alkaline condition, the free state phosphorus of the ferric hydroxide colloid of generation in also can planar water, forms large flco and is deposited to the bottom.Aluminum ion (Al
3+) etc. other metal ions also have above-mentioned coagulative precipitation effect.
B. microorganism dephosphorization
The in the situation that of dissolved oxygen abundance, polyP bacteria huge uptake phosphorus, is stored in phosphorus in thalline with the form of polymerization, thereby reaches the object that phosphorus is removed from water.
(3) hydrobiont is for the removal of nitrogen, phosphorus
Because fine molecular and magnetization can promote high hydrobiological growth, increase the activity of fish body endoenzyme, thereby can increase the removal of hydrobiont for nitrogen, phosphorus.
A. food chain restructuring
---planktonic organism---food planktonic organism fish---the ichthyophagy fish that in river, have following food chain: algae.
Algophagous fish can be removed the nutritive element such as nitrogen, phosphorus in water effectively.River snail, freshwater mussel etc., also can cut down the nutritive salt such as nitrogen, phosphorus in bed mud.
B. waterplant
In treated river, waterplant ramp, its process of growth can consume the nutritive salt such as nitrogen, phosphorus a large amount of in water.
(4) removal of other pollutents
The water that contains dissolved oxygen passes through continuously from inducedmagnetic field, produces the H of 5 × 10-5% in water
2o
2, can make the organism direct oxidation in water decompose, thereby reduce the COD in sewage.After rich oxygen containing magnetic water, the activity of water oxygen increases greatly simultaneously, the degraded of COD and BOD in promotion water.
Embodiment 4:
Adopt the inventive method to process north gate, Beihai park water body, between 7 dates of June in-2011 on May 26th, 2011, use combination unit to process water body, water body sample before and after processing is sent to environmental quality inspection center of Tsing-Hua University and detects, and before processing, water sample detection report number is: CEQT-BG (W)-11052603; After processing, water sample detection report number is: CEQT-BG (W)-11060703.Test item in examining report comprises: COD, BOD
5, total phosphorus, total nitrogen, ammonia nitrogen, chlorophyll a;
Wherein the detection of every test item is according to being:
COD: rapid-digestion spectrophotometry, HJ/T399-2007;
BOD
5: water quality five-day BOD (BOD
5) mensuration dilution and inoculation method, GB/T7488-1987;
Total phosphorus: the mensuration of total phosphorus, ammonium molybdate spectrophotometry, GB/T11893-1989;
Total nitrogen: the mensuration of total nitrogen, alkaline alkaline potassium per-sulfate digestion ultraviolet spectrophotometry, GB/T11894-1989;
Ammonia nitrogen: the mensuration of ammonium, Whitfield's ointment spectrophotometry, GB/T7481-1987;
Chlorophyll a: " water and effluent monitoring analytical procedure " 2002 (the 4th edition) ultraviolet-visible spectrophotometry;
North gate, North Sea water body sampling projects test result is referring to table 1.
Table 1
Test item |
Detected value before processing |
Detected value after processing |
COD(mg/L) |
28.6 |
27.3 |
BOD
5(mg/L)
|
4.1 |
3.9 |
Total phosphorus (mg/L) |
0.28 |
0.02 |
Total nitrogen (mg/L) |
1.42 |
0.70 |
Ammonia nitrogen (mg/L) |
0.39 |
0.11 |
Chlorophyll a (mg/L) |
Do not detect |
Do not detect |
Before improvement, (on May 26th, 2011), improvement rear (on June 7th, 2011) are at north gate, the North Sea and 2, marina sampling spot sample examination.Water quality data analysis contrast before and after administering:
1. the clearance of TP is 93%, brings up to I class standard by original IV class;
2. the clearance of TN is 50.8%, more than bringing up to III class by original V class;
3. NH
3the clearance of-N is about 71.8%, brings up to I class standard by original II class;
4. chlorophyll a also has obvious removal;
Data presentation in table 1, after administering, water body obviously improves, more than water quality is brought up to III class by original V class, wherein TP, NH
3the content of-N is only 0.01mg/L, and 0.13mg/L can reach surface water environment quality I class standard.
Embodiment 5:
Adopt the inventive method to process three coaster gate upstream water quality, the treatment time is on June 21st, 1 2011 on May 25th, 2011, and table 2 is that three coaster gate upstream water correction pilot project visibilities detect data.Water turbidity refers to the obstruction degree occurring when suspended substance sees through light in water.Suspended substance in water is generally earth, sand grains, fine organism and inorganics, planktonic organism, microorganism and colloidalmaterial etc.The turbidity of water is not only relevant with the content of suspended matter in water, and relevant with their size, shape and specific refraction etc.The present invention adopts turbidimetry for Determination water turbidity, and turbidity and visibility are converted, and draws data in table 2.
Table 2
Data presentation in table:
1. water distributor place water body visibility is increased to 0.7m by original 0.55m, clear seeing the bottom after administering;
2. submersible pump place water body visibility is increased to 1.7m by original 0.45m, after improvement, substantially sees the bottom;
3. lotus ship place water body visibility is increased to the 0.8m after improvement by original 0.35m;
4. marina place water body visibility is increased to the 0.8m after improvement by original 0.4m.
Above data presentation, this region water body visibility after administering obviously improves, and all can reach water distributor and reach to the water body visibility within the scope of the 150m of downstream the expection management goal of 800mm.
In sum, by the effective control to N, P in water body, activated water molecules and oxygen molecule continue to supplement simultaneously, improve the DO content in water, for water body provides an aerobic environment, prevent algal bloom, avoid middle lower floor water body generation anaerobic digestion, Comprehensive Control indices, makes whole water body present good sense organ effect, free from extraneous odour in water, transparency obviously improves, and has contained the generation of wawter bloom, and progressively recovers the self-purification capacity of water body, improve the micro of water body, make water body keep a good order and condition steady in a long-term.
Embodiment 6:
Adopt the inventive method to process Yuyuan Lake oriental cherry Lake Water Body, between 25 dates of May in-2009 on May 15th, 2009, use combination unit to process water body, the former water water body of water body sample after treatment and oriental cherry lake sample is sent to environmental quality inspection center of Tsing-Hua University and detects, and water sample detection report number is: CEQT-BG (W)-09052504; Test item in examining report comprises: COD, BOD
5, total phosphorus, total nitrogen, ammonia nitrogen; Wherein projects detect foundation with embodiment 4, and detected result is listed in table 3.
Table 3
The data presentation of table 3, after administering, water body obviously improves.
According to specific exemplary embodiment, invention has been described herein.It will be apparent under not departing from the scope of the present invention, carrying out to one skilled in the art suitable replacement or revise.Exemplary embodiment is only illustrative, rather than restriction to scope of the present invention, and scope of the present invention is defined by appended claim.