CN102241960B - Antifog bactericide for automobile window - Google Patents

Antifog bactericide for automobile window Download PDF

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Publication number
CN102241960B
CN102241960B CN 201110123207 CN201110123207A CN102241960B CN 102241960 B CN102241960 B CN 102241960B CN 201110123207 CN201110123207 CN 201110123207 CN 201110123207 A CN201110123207 A CN 201110123207A CN 102241960 B CN102241960 B CN 102241960B
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China
Prior art keywords
antifog
bactericide
automobile window
polyvinylpyrrolidone
propylene glycol
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Expired - Fee Related
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CN 201110123207
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CN102241960A (en
Inventor
刘洋
李杨
赵甜静
陈捷
戴燕华
顾艳
徐珊
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University of Shanghai for Science and Technology
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University of Shanghai for Science and Technology
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Abstract

The invention provides an antifog bactericide for an automobile window, which has a long-time effective antifog function on the automobile window and a rearview mirror and a bactericidal function of purifying air in an automobile to fulfill the aim of safely and healthily driving. The antifog bactericide is prepared by uniformly mixing absolute ethanol, propylene glycol, isopropanol, an alkylolamide nonionic surfactant of which the oleophylic end contains 11 to 14 carbon atoms, deionized water, polyvinylpyrrolidone, and a water soluble nanometer titanium dioxide in a certain ratio according to a certain order. The antifog bactericide is filled in a spray bottle and is sprayed. The antifog bactericide is easy to prepare, economical and practical, and convenient to use.

Description

A kind of Antifog bactericide for automobile window
Technical field
The present invention relates to a kind of Antifog bactericide for automobile window, belong to vehicle window antifogging agent and sterilant preparing technical field.
Background technology
Windshield and rearview mirror all can produce mist vapour and affect sight line in winter or the rainy day of cold, cause serious traffic safety hidden danger, in car, water vapor is met cold meeting and condense into many droplets on sheet glass, these globules are shrunk to semisphere or spherical under capillary effect, make light scatter, driven to cause very important driving dangerous to the driver.Because automobile usually travels under the state of sealing, the atmosphere draught-free in car except being easy to haze, also can cause spreading of bacterium in car, causes the infection of some disease.Therefore, solve vehicle window and rearview mirror haze and car in the purifying problem of air, driving is most important for ensuring safety.
The present invention is intended to design a kind of safe, economic, effective, green existing anti-fog function, the multi-functional antifogging agent of sterilization functions is arranged again, to improve the security of driving.
At present, the antifog method of vehicle window mainly contains following several both at home and abroad:
(1) the bad glass of exploitation thermal conduction or blow hot blast at the glass inner face, purpose is that the temperature of glass inner face is dropped to below dew point;
(2) reduce indoor humidity with dehydrating unit;
(3) a kind of anti-fog thin film of coating on glass;
(4) on glassly smear one deck antifogging agent, even water vapour in the glass surface dewfall, does not also allow it exist with drops, but make it be transformed into the high moisture film of transparency.
First, second kind method is install an air-conditioner in the medium and high classes automobile and use antifog property windshield glass preferably, but to most of popular automobiles, as truck, motorbus, motor bus etc., this method is too expensive.The third method must be used in glass manufacturing process, its complex process, and to finished glass processing inconvenience.The 4th kind of method as the antifogging agent of glass, is to form coating by lyophobic dusts such as metallic soap, silicon, zirconium compounds, alkyl pyridine halogenide, urea.As general method, by the top coat that lyophobic dust forms, from anchorage and persistence, fail to obtain satisfied effect.
And it is very few for the research of car inner air-cleaning sterilization both at home and abroad, although the patent of current existing many vehicle window antifogging agents, as anti-fog agent for wind-screen of automobile CN101108960, anti-fog agent for wind-screen of automobile CN1632037, agent for dirt-removing and antifogging CN1418787 etc., but the vehicle window antifogging agent that has good sterilizing function concurrently is also unprecedented.
Summary of the invention
The object of the invention is to overcome above-mentioned deficiency of the prior art, a kind of comparatively desirable multi-functional antifogging agent is provided.
A kind of Antifog bactericide for automobile window of the present invention is characterized in that having following moiety and weight percent thereof:
Dehydrated alcohol 20~25%; ,
Propylene glycol 12~15%,
Virahol 12~15%,
Alkylol amide 7~9%,
Polyvinylpyrrolidone 0.3~0.5%,
Deionized water 45~48%;
Water soluble nano titanium dioxide is counted 10mg/L with bulking value concentration; Be to contain 10mg titanium dioxide in every liter of solution;
Described alkylol amide is the nonionogenic tenside that a kind of hydrophobic end contains 11-14 C; Described dehydrated alcohol, propylene glycol, Virahol are solvent, and described polyvinylpyrrolidone is dispersion agent.
The preparation method of a kind of Antifog bactericide for automobile window of the present invention is characterized in that having following preparation process and step:
A. by said components formula weigh batching;
B. add successively sequentially dehydrated alcohol, propylene glycol, Virahol, deionized water, alkylol amide; Add polyvinylpyrrolidone, water soluble nano titanium dioxide after stirring; Adopt sonic oscillation to make Solution Dispersion even;
C. pack in opaque spray bottle.
The invention has the advantages that:
(1) preparation technology is simple, raw materials cost economy;
(2) effectively, antifog lastingly, stable performance;
(3) absorb the ultraviolet catalytic sterilization, purifying in-vehicle air, green non-poisonous.
Embodiment
After now specific embodiments of the invention being described in.
Embodiment 1 and embodiment 2 component formula such as following table 1:
The component formula of table 1 embodiment 1 and embodiment 2
Figure 282038DEST_PATH_IMAGE001
Data in above form are all to be obtained by round.
Preparation method in the present embodiment: at first by certain quality percentage composition feeding, then add successively dehydrated alcohol, propylene glycol, Virahol, deionized water, alkylol amide, add polyvinylpyrrolidone, water soluble nano titanium dioxide after stirring, method by sonic oscillation is evenly distributed solution, can use in the opaque spray bottle of packing at last.
During use, on vehicle window, then using cloth to wipe with to wipe away evenly gets final product on a small quantity in ejection from spray bottle.
In January, 2011, done antifog and bactericidal assay to this invention:
Antifog test: spraying antifogging agent of the present invention on the vehicle window of the left side of dickey seats, the right side does not spray, 20 days afterwards discovery do not spray on the vehicle window of antifogging agent of the present invention and hazed obviously, and sprayed on the vehicle window of antifogging agent without hazing phenomenon, and sight line can be not influenced when seeing through this window and outwards seeing.
Bactericidal assay: take 9 gram nutrient agar mediums and be dissolved in 250 milliliters of 50 ℃ of distilled water and be mixed with substratum; Get 10 milliliters of sewage conducts and contain the bacterium inoculation liquid, and dilute 1000 times with sterilized water.The instruments such as culture dish, transfer pipet are put into 120 ℃ of sterilizations of electric-heating steam pressure sterilizer 15 minutes.
Under aseptic condition, inject respectively 20 milliliters of substratum in four culture dish, after substratum is cooling, add respectively 1 milliliter to contain the bacterium inoculation liquid in four culture dish, then add respectively 1 milliliter of self-control Antifog bactericide of spending 2 hours through solar radiation in two culture dish wherein; And do not add Antifog bactericide in two other culture dish; Make blank simultaneous test; Use spreading rod respectively that the liquid spreading on substratum in four culture dish is even.Use covers above-mentioned four culture dish respectively through the large size culture dish of disinfecting action, after congealed solid total condensation wherein, culture dish is inverted in the incubator of 38 degrees centigrade.After 48 hours, take out culture dish and observe to find: the colony number that was coated with on two congealed soliies of Antifog bactericide of the present invention is respectively 2 and 1, and the colony number that was not coated with on two congealed soliies of the Antifog bactericide of invention not is respectively 19 and 21.

Claims (2)

1. Antifog bactericide for automobile window is characterized in that having following moiety:
Dehydrated alcohol 20~25%,
Propylene glycol 12~15%,
Virahol 12~15%,
Alkylol amide 7~9%,
Polyvinylpyrrolidone 0.3~0.5%,
Deionized water 45~48%; Above ratio is weight percentage;
Water soluble nano titanium dioxide is counted 10mg/L with bulking value concentration; Be to contain 10mg titanium dioxide in every liter of solution;
Described alkylol amide is the nonionogenic tenside that a kind of hydrophobic end contains 11-14 C; Described dehydrated alcohol, propylene glycol, Virahol are solvent, and described polyvinylpyrrolidone is dispersion agent.
2. preparation method who prepares Antifog bactericide for automobile window according to claim 1 is characterized in that having following preparation process and step:
A. by said components formula weigh batching;
B. add successively sequentially dehydrated alcohol, propylene glycol, Virahol, deionized water, alkylol amide; Add polyvinylpyrrolidone, water soluble nano titanium dioxide after stirring; Adopt sonic oscillation to make Solution Dispersion even;
C. pack in opaque spray bottle.
CN 201110123207 2011-05-13 2011-05-13 Antifog bactericide for automobile window Expired - Fee Related CN102241960B (en)

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Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102850997B (en) * 2012-08-30 2014-05-14 苏州市德莱尔建材科技有限公司 Long-acting antifogging agent for glass
CN103060136A (en) * 2012-12-28 2013-04-24 青岛润鑫伟业科贸有限公司 Glass cleaning agent
CN103555274A (en) * 2013-10-29 2014-02-05 大连创达技术交易市场有限公司 Mist remover
CN103549918A (en) * 2013-10-29 2014-02-05 大连创达技术交易市场有限公司 Wet tissue with defogging function
CN104762064B (en) * 2015-04-14 2018-06-19 合肥学院 A kind of preparation method of antimicrobial form glass antidimmer and its wet tissue
CN106497518A (en) * 2016-11-01 2017-03-15 重庆返璞科技有限公司 A kind of nano-glass antifoggant and preparation method thereof
CN107541190A (en) * 2017-09-06 2018-01-05 苏州纽东精密制造科技有限公司 A kind of anti-fog agent for wind-screen of automobile and preparation method thereof
CN108070460B (en) * 2017-11-03 2020-08-04 浙江工业大学温州科学技术研究院 Special cleaning fluid for non-aqueous crystal lamp and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1057284A (en) * 1990-06-09 1991-12-25 北京铁路局北京科学技术研究所 Antifreezer for water-bearing particles
KR20020092781A (en) * 2002-01-10 2002-12-12 백순기 Frost-melting and frost-preventing composition
CN1418787A (en) * 2001-11-13 2003-05-21 崔长安 Agent for dirt-removing and antifogging
CN1632037A (en) * 2004-11-09 2005-06-29 林侠 Antifogging agent for automobile glasses
CN101220257A (en) * 2007-01-09 2008-07-16 青岛大学 Process for producing vehicle glass antifogging agent

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7852954B2 (en) * 2004-09-30 2010-12-14 Lg Electronics, Inc. Method of transmitting data and estimating channel information in OFDM/OFDMA mobile communications system

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1057284A (en) * 1990-06-09 1991-12-25 北京铁路局北京科学技术研究所 Antifreezer for water-bearing particles
CN1418787A (en) * 2001-11-13 2003-05-21 崔长安 Agent for dirt-removing and antifogging
KR20020092781A (en) * 2002-01-10 2002-12-12 백순기 Frost-melting and frost-preventing composition
CN1632037A (en) * 2004-11-09 2005-06-29 林侠 Antifogging agent for automobile glasses
CN101220257A (en) * 2007-01-09 2008-07-16 青岛大学 Process for producing vehicle glass antifogging agent

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