CN102241867B - 一种具有高表面硬度的pmma/abs合金材料及制备方法 - Google Patents
一种具有高表面硬度的pmma/abs合金材料及制备方法 Download PDFInfo
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- CN102241867B CN102241867B CN 201010500369 CN201010500369A CN102241867B CN 102241867 B CN102241867 B CN 102241867B CN 201010500369 CN201010500369 CN 201010500369 CN 201010500369 A CN201010500369 A CN 201010500369A CN 102241867 B CN102241867 B CN 102241867B
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- pmma
- abs
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- surface hardness
- high surface
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- 229920003229 poly(methyl methacrylate) Polymers 0.000 title claims abstract description 47
- 239000004926 polymethyl methacrylate Substances 0.000 title claims abstract description 47
- 239000000956 alloy Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title abstract description 9
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 49
- 239000011347 resin Substances 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 230000002902 bimodal effect Effects 0.000 claims abstract description 3
- 238000002844 melting Methods 0.000 claims abstract description 3
- 230000008018 melting Effects 0.000 claims abstract description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 230000003078 antioxidant effect Effects 0.000 claims description 2
- 239000011324 bead Substances 0.000 claims description 2
- 238000012662 bulk polymerization Methods 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 abstract description 29
- 238000002156 mixing Methods 0.000 abstract description 7
- 229910045601 alloy Inorganic materials 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 4
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 abstract 4
- 235000019589 hardness Nutrition 0.000 description 16
- 239000002994 raw material Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 5
- 238000005453 pelletization Methods 0.000 description 5
- 229920009204 Methacrylate-butadiene-styrene Polymers 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010500369 CN102241867B (zh) | 2010-09-30 | 2010-09-30 | 一种具有高表面硬度的pmma/abs合金材料及制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010500369 CN102241867B (zh) | 2010-09-30 | 2010-09-30 | 一种具有高表面硬度的pmma/abs合金材料及制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102241867A CN102241867A (zh) | 2011-11-16 |
| CN102241867B true CN102241867B (zh) | 2013-05-15 |
Family
ID=44960126
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010500369 Expired - Fee Related CN102241867B (zh) | 2010-09-30 | 2010-09-30 | 一种具有高表面硬度的pmma/abs合金材料及制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102241867B (zh) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102827453B (zh) * | 2012-09-20 | 2014-04-02 | 南华大学 | 一种防尘耐老化黑色高光abs合金及制备方法 |
| CN103351572B (zh) * | 2013-07-14 | 2015-11-18 | 上海秋橙新材料科技有限公司 | 抗老化abs-pmma塑料合金 |
| CN104629246A (zh) * | 2013-11-11 | 2015-05-20 | 黑龙江鑫达企业集团有限公司 | 一种增韧耐磨合金材料及制备方法 |
| CN104177764A (zh) * | 2014-08-18 | 2014-12-03 | 合肥华凌股份有限公司 | 抗腐蚀型abs组合物、外观件及其制造方法 |
| CN106009476A (zh) * | 2016-07-25 | 2016-10-12 | 金田集团（桐城）塑业有限公司 | 一种高硬度抗冲击pmma/abs复合板材 |
| CN106398094A (zh) * | 2016-08-31 | 2017-02-15 | 佛山市顺德区美的洗涤电器制造有限公司 | Abs树脂材料、用途以及家用电器 |
| CN106751408A (zh) * | 2016-12-27 | 2017-05-31 | 浙江普利特新材料有限公司 | 一种高表面硬度abs美学树脂复合材料及其制备方法 |
| CN114957908A (zh) * | 2022-06-14 | 2022-08-30 | 山东亿科化学有限责任公司 | 一种abs/pmma改性合金及其制备方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1986634A (zh) * | 2005-12-22 | 2007-06-27 | 佛山市顺德区汉达精密电子科技有限公司 | 提高abs与聚甲基丙烯酸甲酯相容性的方法 |
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- 2010-09-30 CN CN 201010500369 patent/CN102241867B/zh not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1986634A (zh) * | 2005-12-22 | 2007-06-27 | 佛山市顺德区汉达精密电子科技有限公司 | 提高abs与聚甲基丙烯酸甲酯相容性的方法 |
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| Publication number | Publication date |
|---|---|
| CN102241867A (zh) | 2011-11-16 |
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Denomination of invention: PMMA/ABS alloy material with high surface hardness and preparation method thereof Effective date of registration: 20150817 Granted publication date: 20130515 Pledgee: China Everbright Bank Shenzhen branch Pledgor: Shenzhen Keju New Material Co., Ltd. Registration number: 2015990000679 |
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Date of cancellation: 20161202 Granted publication date: 20130515 Pledgee: China Everbright Bank Shenzhen branch Pledgor: Shenzhen Keju New Material Co., Ltd. Registration number: 2015990000679 |
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Denomination of invention: PMMA/ABS alloy material with high surface hardness and preparation method thereof Effective date of registration: 20170106 Granted publication date: 20130515 Pledgee: Bank of Shizuishan Limited by Share Ltd Yinchuan branch Pledgor: Anhui science and Technology Co., Ltd.|Shenzhen branch poly new materials Co., Ltd.|Xu Dong Registration number: 2016990001133 |
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Date of cancellation: 20180904 Granted publication date: 20130515 Pledgee: Bank of Shizuishan Limited by Share Ltd Yinchuan branch Pledgor: Polymer Science (Anhui) New Material Co., Ltd.|Shenzhen Keju New Material Co., Ltd.|Xu Dong Registration number: 2016990001133 |
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Denomination of invention: PMMA/ABS alloy material with high surface hardness and preparation method thereof Effective date of registration: 20180912 Granted publication date: 20130515 Pledgee: Bank of Shizuishan Limited by Share Ltd Yinchuan branch Pledgor: Polymer Science (Anhui) New Material Co., Ltd.|Shenzhen Keju New Material Co., Ltd. Registration number: 2018440020055 |
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