CN102226316B - Environmentally-friendly digital inkjet textile printing ink with reactive dye and preparation method thereof - Google Patents
Environmentally-friendly digital inkjet textile printing ink with reactive dye and preparation method thereof Download PDFInfo
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- CN102226316B CN102226316B CN 201110103190 CN201110103190A CN102226316B CN 102226316 B CN102226316 B CN 102226316B CN 201110103190 CN201110103190 CN 201110103190 CN 201110103190 A CN201110103190 A CN 201110103190A CN 102226316 B CN102226316 B CN 102226316B
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- 239000004753 textile Substances 0.000 title claims abstract description 55
- 238000007639 printing Methods 0.000 title claims abstract description 53
- 239000000985 reactive dye Substances 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 239000012528 membrane Substances 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004094 surface-active agent Substances 0.000 claims abstract description 17
- 239000008367 deionised water Substances 0.000 claims abstract description 16
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 9
- 239000000080 wetting agent Substances 0.000 claims abstract description 6
- 238000001914 filtration Methods 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims abstract description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 28
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 20
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 10
- 235000011187 glycerol Nutrition 0.000 claims description 10
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims description 8
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 8
- KXXFHLLUPUAVRY-UHFFFAOYSA-J [Na+].[Na+].[Na+].[Cu++].[O-]C(=O)C1=CC=C(C=C1N=N[C-](N=NC1=C([O-])C(NC2=NC(F)=NC(NCCOCCS(=O)(=O)C=C)=N2)=CC(=C1)S([O-])(=O)=O)C1=CC=CC=C1)S([O-])(=O)=O Chemical compound [Na+].[Na+].[Na+].[Cu++].[O-]C(=O)C1=CC=C(C=C1N=N[C-](N=NC1=C([O-])C(NC2=NC(F)=NC(NCCOCCS(=O)(=O)C=C)=N2)=CC(=C1)S([O-])(=O)=O)C1=CC=CC=C1)S([O-])(=O)=O KXXFHLLUPUAVRY-UHFFFAOYSA-J 0.000 claims description 8
- 229960002887 deanol Drugs 0.000 claims description 8
- 239000012972 dimethylethanolamine Substances 0.000 claims description 8
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims description 7
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 6
- 229960001124 trientine Drugs 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 4
- 230000000844 anti-bacterial effect Effects 0.000 claims description 4
- 239000003899 bactericide agent Substances 0.000 claims description 4
- 230000003750 conditioning effect Effects 0.000 claims description 4
- ASDREVVGQFYRTH-UHFFFAOYSA-N 3-[[2-acetamido-4-[(4-amino-6-chloro-1,3,5-triazin-2-yl)amino]phenyl]diazenyl]naphthalene-1,5-disulfonic acid Chemical compound C=1C=C(N=NC=2C=C3C(=CC=CC3=C(C=2)S(O)(=O)=O)S(O)(=O)=O)C(NC(=O)C)=CC=1NC1=NC(N)=NC(Cl)=N1 ASDREVVGQFYRTH-UHFFFAOYSA-N 0.000 claims description 2
- QQLRAOUUQHSXIJ-UHFFFAOYSA-N 3b1-009110 Chemical compound C1=C(S(O)(=O)=O)C=C2C=C(S(O)(=O)=O)C(N=NC3=CC=C(NC=4N=C(NC=5C=C(C(C=6C(=CC(NC=7N=C(NC=8C=C(NC(N)=O)C(N=NC=9C(=CC%10=CC(=CC(=C%10C=9)S(O)(=O)=O)S(O)(=O)=O)S(O)(=O)=O)=CC=8)N=C(Cl)N=7)=CC=6)S(O)(=O)=O)=CC=5)S(O)(=O)=O)N=C(Cl)N=4)C=C3NC(=O)N)=CC2=C1S(O)(=O)=O QQLRAOUUQHSXIJ-UHFFFAOYSA-N 0.000 claims description 2
- INOIOAWTVPHTCJ-UHFFFAOYSA-N 6-acetamido-4-hydroxy-3-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]naphthalene-2-sulfonic acid Chemical compound CC(=O)NC1=CC=C2C=C(C(N=NC3=CC=C(C=C3)S(=O)(=O)CCOS(O)(=O)=O)=C(O)C2=C1)S(O)(=O)=O INOIOAWTVPHTCJ-UHFFFAOYSA-N 0.000 claims description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 2
- OVSNDJXCFPSPDZ-UHFFFAOYSA-N Reactive red 120 Chemical compound OS(=O)(=O)C1=CC2=CC(S(O)(=O)=O)=CC(NC=3N=C(NC=4C=CC(NC=5N=C(NC=6C7=C(O)C(N=NC=8C(=CC=CC=8)S(O)(=O)=O)=C(C=C7C=C(C=6)S(O)(=O)=O)S(O)(=O)=O)N=C(Cl)N=5)=CC=4)N=C(Cl)N=3)=C2C(O)=C1N=NC1=CC=CC=C1S(O)(=O)=O OVSNDJXCFPSPDZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000003139 biocide Substances 0.000 claims description 2
- YRPZCUJHDXAQRR-UHFFFAOYSA-H hexasodium 4-amino-3,6-bis[[5-[[4-chloro-6-(3-sulfonatoanilino)-1,3,5-triazin-2-yl]amino]-2-sulfonatophenyl]diazenyl]-5-oxido-7-sulfonaphthalene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].Nc1c(N=Nc2cc(Nc3nc(Cl)nc(Nc4cccc(c4)S([O-])(=O)=O)n3)ccc2S([O-])(=O)=O)c(cc2cc(c(N=Nc3cc(Nc4nc(Cl)nc(Nc5cccc(c5)S([O-])(=O)=O)n4)ccc3S([O-])(=O)=O)c(O)c12)S([O-])(=O)=O)S([O-])(=O)=O YRPZCUJHDXAQRR-UHFFFAOYSA-H 0.000 claims description 2
- GCFAQSYBSUQUPL-UHFFFAOYSA-I pentasodium 5-[[4-chloro-6-[3-(2-sulfonatooxyethylsulfonyl)anilino]-1,3,5-triazin-2-yl]amino]-3-[(1,5-disulfonatonaphthalen-2-yl)diazenyl]-4-hydroxynaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].Oc1c(N=Nc2ccc3c(cccc3c2S([O-])(=O)=O)S([O-])(=O)=O)c(cc2cc(cc(Nc3nc(Cl)nc(Nc4cccc(c4)S(=O)(=O)CCOS([O-])(=O)=O)n3)c12)S([O-])(=O)=O)S([O-])(=O)=O GCFAQSYBSUQUPL-UHFFFAOYSA-I 0.000 claims description 2
- 239000012257 stirred material Substances 0.000 claims description 2
- RGGWIBHAZTZHMR-UHFFFAOYSA-J tetrasodium 5-[[4-chloro-6-[4-(2-sulfooxyethylsulfonyl)anilino]-1,3,5-triazin-2-yl]amino]-4-oxido-3-[(2-sulfonatophenyl)diazenyl]naphthalene-2,7-disulfonate Chemical compound C1=CC=C(C(=C1)N=NC2=C(C3=C(C=C(C=C3C=C2S(=O)(=O)[O-])S(=O)(=O)[O-])NC4=NC(=NC(=N4)NC5=CC=C(C=C5)S(=O)(=O)CCOS(=O)(=O)O)Cl)[O-])S(=O)(=O)[O-].[Na+].[Na+].[Na+].[Na+] RGGWIBHAZTZHMR-UHFFFAOYSA-J 0.000 claims description 2
- UIEBGVDTKLYGTN-UHFFFAOYSA-J tetrasodium;7-[[2-(carbamoylamino)-4-[[4-chloro-6-[3-(2-sulfonatooxyethylsulfonyl)anilino]-1,3,5-triazin-2-yl]amino]phenyl]diazenyl]naphthalene-1,3,6-trisulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].C=1C=C(N=NC=2C(=CC3=CC(=CC(=C3C=2)S([O-])(=O)=O)S([O-])(=O)=O)S([O-])(=O)=O)C(NC(=O)N)=CC=1NC(N=1)=NC(Cl)=NC=1NC1=CC=CC(S(=O)(=O)CCOS([O-])(=O)=O)=C1 UIEBGVDTKLYGTN-UHFFFAOYSA-J 0.000 claims description 2
- IHVXOVVDYSKGMH-UHFFFAOYSA-K trisodium 2-[[6-[(4-amino-6-chloro-1,3,5-triazin-2-yl)-methylamino]-1-hydroxy-3-sulfonatonaphthalen-2-yl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].CN(c1ccc2c(O)c(N=Nc3ccc4c(cccc4c3S([O-])(=O)=O)S([O-])(=O)=O)c(cc2c1)S([O-])(=O)=O)c1nc(N)nc(Cl)n1 IHVXOVVDYSKGMH-UHFFFAOYSA-K 0.000 claims description 2
- MBAYVHBJJXOOIY-UHFFFAOYSA-K trisodium 7-[[4-chloro-6-(3-sulfonatoanilino)-1,3,5-triazin-2-yl]-methylamino]-4-hydroxy-3-[(2-sulfonatophenyl)diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].CN(c1ccc2c(O)c(N=Nc3ccccc3S([O-])(=O)=O)c(cc2c1)S([O-])(=O)=O)c1nc(Cl)nc(Nc2cccc(c2)S([O-])(=O)=O)n1 MBAYVHBJJXOOIY-UHFFFAOYSA-K 0.000 claims description 2
- ZUCXUTRTSQLRCV-UHFFFAOYSA-K trisodium;1-amino-4-[3-[[4-chloro-6-(3-sulfonatoanilino)-1,3,5-triazin-2-yl]amino]-2,4,6-trimethyl-5-sulfonatoanilino]-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].CC1=C(S([O-])(=O)=O)C(C)=C(NC=2C=3C(=O)C4=CC=CC=C4C(=O)C=3C(N)=C(C=2)S([O-])(=O)=O)C(C)=C1NC(N=1)=NC(Cl)=NC=1NC1=CC=CC(S([O-])(=O)=O)=C1 ZUCXUTRTSQLRCV-UHFFFAOYSA-K 0.000 claims description 2
- WTPOYMNMKZIOGO-UHFFFAOYSA-K trisodium;2,5-dichloro-4-[4-[[5-[[4-chloro-6-(4-sulfonatoanilino)-1,3,5-triazin-2-yl]amino]-2-sulfonatophenyl]diazenyl]-3-methyl-5-oxo-4h-pyrazol-1-yl]benzenesulfonate Chemical compound [Na+].[Na+].[Na+].CC1=NN(C=2C(=CC(=C(Cl)C=2)S([O-])(=O)=O)Cl)C(=O)C1N=NC(C(=CC=1)S([O-])(=O)=O)=CC=1NC(N=1)=NC(Cl)=NC=1NC1=CC=C(S([O-])(=O)=O)C=C1 WTPOYMNMKZIOGO-UHFFFAOYSA-K 0.000 claims description 2
- 239000000975 dye Substances 0.000 abstract description 24
- 238000004043 dyeing Methods 0.000 abstract description 8
- 230000008569 process Effects 0.000 abstract description 7
- 238000003860 storage Methods 0.000 abstract description 6
- 239000002351 wastewater Substances 0.000 abstract description 3
- 229920000742 Cotton Polymers 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract description 2
- 239000000645 desinfectant Substances 0.000 abstract 1
- 238000004381 surface treatment Methods 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
- 239000000047 product Substances 0.000 description 14
- 238000005516 engineering process Methods 0.000 description 8
- -1 Diethylenetriamine 3 Isothiazolinone Chemical compound 0.000 description 6
- 230000007062 hydrolysis Effects 0.000 description 6
- 238000006460 hydrolysis reaction Methods 0.000 description 6
- 238000012805 post-processing Methods 0.000 description 4
- 238000002203 pretreatment Methods 0.000 description 4
- 241001062009 Indigofera Species 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 238000003911 water pollution Methods 0.000 description 2
- JUCNRWYKMOYMOP-UHFFFAOYSA-N 2h-1,2-thiazol-5-one Chemical compound O=C1C=CNS1 JUCNRWYKMOYMOP-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention relates to environmentally-friendly digital inkjet textile printing ink with reactive dye and a preparation method thereof, and the ink is a composition formed by the following components by weight percent: 12-90.6% of deionized water, 5-40% of wetting agent, 0.2-5% of surface active agent, 0.1-2% of pH regulator, 0.1-1% of disinfectant, 1-10% of softener and 3-30% of the reactive dye. The preparation method comprises the following steps: placing all the components into a stirring container sequentially, stirring, and then using a filter membrane to perform filtration many timesso as to prepare an ink finished product. The ink can be combined with cotton, wool and silk textiles without surface treatment under the conditions of being salt-free and alkali-free completely, thereactive dye is not hydrolyzed completely during the dyeing process and the storage process, the dyeing rate is high, the ink can be stably stored for a long time, the dyeing without waste water emission is realized, and the water consumption and the pollution of printing with the reactive dye are reduced.
Description
[technical field]
The present invention relates to the digital ink-jet textile printing ink, particularly relate to a kind of environment-friendly digital ink-jet textile printing ink with REACTIVE DYES and preparation method thereof.
[background technology]
In traditional textile printing technology, stamp all needs to make a plate in advance on textiles, and some printing technology needs pre-treatment and post processing, and all can produce water pollution problems in the process of plate-making or pre-treatment, post processing.In addition, traditional textiles printing technology need carry out in batches, and feasible production technology and end product quality to stamp all has high requirement.
Digital ink-jet printed technology is a kind of new textile printing technology, and it is that dedicated dye ink or paint ink are passed through the direct spray printing of ink-jet printer on textiles.Use reactive dye ink ink-jet printed at enterprising line number sign indicating numbers of textiles such as cotton, fiber crops, can obtain outstanding colour vividness, washing fastness and soft degree.But traditional reactive dye ink exists defectives such as easy hydrolysis, dye-uptake be low, can not satisfy the stability of digital ink-jet textile printing ink long term storage, and in ink-jet printed process, need to make a plate in advance, and some printing technology needs pre-treatment and post processing, and all can produce water pollution problems in the process of plate-making or pre-treatment, post processing.
[summary of the invention]
The present invention is intended to solve that traditional easy hydrolysis, dye-uptake with REACTIVE DYES ink-jet textile printing ink are low, the stability problem of long term storage, and provide REACTIVE DYES not hydrolysis fully in a kind of dyeing and the storage process, the dye-uptake height, the ink storage-stable time is long, the dyeing of realization non-wastewater discharge greatly reduces the water consumption of printing with reactive dye and the environment-friendly digital ink-jet textile printing ink with REACTIVE DYES that pollutes.
The present invention also aims to provide the preparation method of this environment-friendly digital ink-jet textile printing ink with REACTIVE DYES.
For achieving the above object, the invention provides a kind of environment-friendly digital ink-jet textile printing ink with REACTIVE DYES, this ink is the mixture of the following component calculated by weight percentage:
Environment-friendly digital ink-jet textile printing ink optimum ratio with REACTIVE DYES of the present invention is:
Specifically, REACTIVE DYES is selected from modification C.I. reactive black 8, C.I. reactive yellow 2, C.I. reactive yellow 3, C.I. REACTIVE YELLOW 18, C.I. reactive yellow 81, C.I. reactive yellow 84, C.I. reactive yellow 86, C.I. REACTIVE Yellow 145, C.I. reactive red 120, C.I. reactive red 141, C.I. Reactive Red 194, C.I. REACTIVE Red 195, C.I. reactive red 240, C.I. reactive blue 5, C.I. reactive blue 14, C.I. reactive blue 49, C.I. reactive blue 72, C.I. reactive blue 74, C.I. reactive blue 171, C.I. active blue 19 4, C.I. reactive orange 2, C.I. reactive orange 5, C.I. REACTIVE ORANGE 13, C.I. the combination of one or more in active green 19;
Wetting agent is selected from one or more in propylene glycol, glycerine, the diethylene glycol (DEG), and described wetting agent is used for preventing that ink is dried at the shower nozzle place of printer, guarantees that ink has outstanding stability when the printer closed condition, and does not stop up shower nozzle;
Glass or plastic containers can be the low foam surface activity agent of nonionic, and its surface tension that is used for the control ink makes ink have desirable diffusivity at 20-50dyn/cm, thereby guarantees the quality of printing;
The pH conditioning agent is triethanolamine or dimethylethanolamine, and it is used for keeping the pH value of ink in the scope of 6-9, guarantees the stability of ink;
Bactericide is the isothiazolinone biocide agent, and it is used for suppressing growing of bacterium;
Softener is selected from one or more in ethylenediamine, diethylenetriamine, the triethylene tetramine.Described softener can make color pigments have good washing fastness, light resistance at textiles, and soft;
Deionized water in the ink is the carrier of ink, and the purity that it be used for to guarantee ink makes ink can not produce the phenomenon of crystallization and plug nozzle.
The present invention also provides the preparation method of this environment-friendly digital ink-jet textile printing ink with REACTIVE DYES, and this method comprises the steps:
A, the deionized water with described ratio, wetting agent, surfactant, pH conditioning agent, bactericide, softener and REACTIVE DYES are thrown in the stirred vessel sequentially, stir 30～120 minutes with 500～3000rpm speed;
B, stirred materials is carried out filtration treatment, first pass filters for the 1um filter membrane with the aperture, is the 0.5um filter membrane filters, the 3rd time obtains have REACTIVE DYES for the 0.22um filter membrane after filtering with the aperture environment-friendly digital ink-jet textile printing ink finished product with the aperture second time.
Contribution of the present invention is that the easy hydrolysis of REACTIVE DYES, dye-uptake that it efficiently solves in the existing digital ink-jet textile printing ink are low, the stability problem of long term storage, and it has the following advantages:
One, the environment-friendly digital ink-jet textile printing ink with REACTIVE DYES of the present invention can directly carry out digit printing to textiles, need not plate-making, incalculability and restriction in batches, avoid producing in enormous quantities the inventory problem that causes, can select pattern that the single-piece clothes is carried out stamp flexibly, thereby demand that can satisfying personalized product.
Two, the environment-friendly digital ink-jet textile printing ink with REACTIVE DYES of the present invention can directly carry out stamp at textiles by digital ink-jet printed printer; need not that textiles is printed front surface handles; the textiles of having printed cures under 100-180 ℃ of condition or decatize 1-20 minute; washing fastness reaches the 4-5 level; dyeing condition need not salt or alkali fully; dyestuff is not hydrolysis fully in dyeing course, realizes non-wastewater discharge dyeing, is of value to environmental protection.
Three, REACTIVE DYES not hydrolysis fully in the ink storage process can storage-stable 2 years, improves the stability problem of REACTIVE DYES ink-jet printing ink.
Four, the environment-friendly digital ink-jet textile printing ink that uses the present invention the to have REACTIVE DYES pattern that carries out stamp is compared with traditional stamp, pattern color bright-coloured meticulous, the transition color abundant, soft.
[specific embodiment]
The following example is that the present invention is further explained and explanation, and the present invention is not constituted any limitation.
Example 1
1, the environment-friendly digital ink-jet textile printing ink with REACTIVE DYES is prepared by following proportioning, referring to table 1.
Table 1
| Component | Content (weight %) |
| Deionized water | 72.7 |
| Glycerine | 5 |
| Diethylene glycol (DEG) | 10 |
| Triethanolamine | 0.5 |
| Non-ionic surface active agent | 2.5 |
| Ethylenediamine | 1 |
| Isothiazolinone | 0.3 |
| Environment-friendly active dye black 8 | 8 |
| Add up to | 100 |
2, preparation method:
Throw in above component in the stirred vessel sequentially, stirred 30～120 minutes with 500～3000rpm speed, use the aperture to filter step by step as the filter membrane of 1um, 0.5um, 0.22um then, obtain having the environment-friendly digital ink-jet textile printing ink finished product of black and active dye.
Example 2
1, the environment-friendly digital ink-jet textile printing ink with REACTIVE DYES is prepared by following proportioning, referring to table 2.
Table 2
| Component | Content (weight %) |
| Deionized water | 35.5 |
| Propylene glycol | 16 |
| Diethylene glycol (DEG) | 15 |
| Dimethylethanolamine | 0.2 |
| Non-ionic surface active agent | 1.8 |
| Diethylenetriamine | 3 |
| Isothiazolinone | 0.5 |
| Environment-friendly active dye black 8 | 28 |
| Add up to | 100 |
2, preparation method:
Throw in above component in the stirred vessel sequentially, stirred 30～120 minutes with 500～3000rpm speed, use the aperture to filter step by step as the filter membrane of 1um, 0.5um, 0.22um then, obtain having the environment-friendly digital ink-jet textile printing ink finished product of black and active dye.
Example 3
1, the environment-friendly digital ink-jet textile printing ink with REACTIVE DYES is prepared by following proportioning, referring to table 3.
Table 3
| Component | Content (weight %) |
| Deionized water | 60.7 |
| Glycerine | 10 |
| Propylene glycol | 10 |
| Triethanolamine | 0.1 |
| Non-ionic surface active agent | 1 |
| Triethylene tetramine | 3 |
| Isothiazolinone | 0.2 |
| Environment-friendly active dye black 8 | 15 |
| Add up to | 100 |
2, preparation method:
Throw in above component in the stirred vessel sequentially, stirred 30～120 minutes with 500～3000rpm speed, use the aperture to filter step by step as the filter membrane of 1um, 0.5um, 0.22um then, obtain having the environment-friendly digital ink-jet textile printing ink finished product of black and active dye.
Example 4
1, the environment-friendly digital ink-jet textile printing ink with REACTIVE DYES is prepared by following proportioning, referring to table 4.
Table 4
| Component | Content (weight %) |
| Deionized water | 40.3 |
| Glycerine | 15 |
| Diethylene glycol (DEG) | 15 |
| Dimethylethanolamine | 0.1 |
| Non-ionic surface active agent | 1.6 |
| Ethylenediamine | 2 |
| Isothiazolinone | 1 |
| Environment-friendly active dye indigo plant 72 | 25 |
| Add up to | 100 |
2, preparation method:
Throw in above component in the stirred vessel sequentially, stirred 30～120 minutes with 500～3000rpm speed, use the aperture to filter step by step as the filter membrane of 1um, 0.5um, 0.22um then, obtain having the environment-friendly digital ink-jet textile printing ink finished product of blue active dye.
Example 5
1, the environment-friendly digital ink-jet textile printing ink with REACTIVE DYES is prepared by following proportioning, referring to table 5.
Table 5
| Component | Content (weight %) |
| Deionized water | 70.5 |
| Propylene glycol | 7 |
| Diethylene glycol (DEG) | 7 |
| Triethanolamine | 0.5 |
| Non-ionic surface active agent | 1 |
| Diethylenetriamine | 5 |
| Isothiazolinone | 1 |
| Environment-friendly active dye indigo plant 72 | 8 |
| Add up to | 100 |
2, preparation method:
Throw in above component in the stirred vessel sequentially, stirred 30～120 minutes with 500～3000rpm speed, use the aperture to filter step by step as the filter membrane of 1um, 0.5um, 0.22um then, obtain having the environment-friendly digital ink-jet textile printing ink finished product of blue active dye.
Example 6
1, the environment-friendly digital ink-jet textile printing ink with REACTIVE DYES is prepared by following proportioning, referring to table 6.
Table 6
| Component | Content (weight %) |
| Deionized water | 55 |
| Glycerine | 11 |
| Propylene glycol | 10 |
| Dimethylethanolamine | 0.5 |
| Non-ionic surface active agent | 1 |
| Triethylene tetramine | 6 |
| Isothiazolinone | 0.5 |
| Environment-friendly active dye indigo plant 72 | 16 |
| Add up to | 100 |
2, preparation method:
Throw in above component in the stirred vessel sequentially, stirred 30～120 minutes with 500～3000rpm speed, use the aperture to filter step by step as the filter membrane of 1um, 0.5um, 0.22um then, obtain having the environment-friendly digital ink-jet textile printing ink finished product of blue active dye.
Example 7
1, the environment-friendly digital ink-jet textile printing ink with REACTIVE DYES is prepared by following proportioning, referring to table 7.
Table 7
| Component | Content (weight %) |
| Deionized water | 45.6 |
| Glycerine | 13 |
| Diethylene glycol (DEG) | 10 |
| Triethanolamine | 0.2 |
| Non-ionic surface active agent | 1 |
| Ethylenediamine | 2 |
| Isothiazolinone | 0.2 |
| Environment-friendly active dye red 141 | 28 |
| Add up to | 100 |
2, preparation method:
Throw in above component in the stirred vessel sequentially, stirred 30～120 minutes with 500～3000rpm speed, use the aperture to filter step by step as the filter membrane of 1um, 0.5um, 0.22um then, obtain having the environment-friendly digital ink-jet textile printing ink finished product of red reactive dyes.
Example 8
1, the environment-friendly digital ink-jet textile printing ink with REACTIVE DYES is prepared by following proportioning, referring to table 8.
Table 8
| Component | Content (weight %) |
| Deionized water | 79.6 |
| Propylene glycol | 5 |
| Diethylene glycol (DEG) | 7 |
| Dimethylethanolamine | 0.2 |
| Non-ionic surface active agent | 1 |
| Diethylenetriamine | 2 |
| Isothiazolinone | 0.2 |
| Environment-friendly active dye red 141 | 5 |
| Add up to | 100 |
2, preparation method:
Throw in above component in the stirred vessel sequentially, stirred 30～120 minutes with 500～3000rpm speed, use the aperture to filter step by step as the filter membrane of 1um, 0.5um, 0.22um then, obtain having the environment-friendly digital ink-jet textile printing ink finished product of red reactive dyes.
Example 9
1, the environment-friendly digital ink-jet textile printing ink with REACTIVE DYES is prepared by following proportioning, referring to table 9.
Table 9
| Component | Content (weight %) |
| Deionized water | 53 |
| Glycerine | 11 |
| Propylene glycol | 12 |
| Triethanolamine | 0.5 |
| Non-ionic surface active agent | 1 |
| Triethylene tetramine | 5 |
| Isothiazolinone | 0.5 |
| Environment-friendly active dye red 141 | 17 |
| Add up to | 100 |
2, preparation method:
Throw in above component in the stirred vessel sequentially, stirred 30～120 minutes with 500～3000rpm speed, use the aperture to filter step by step as the filter membrane of 1um, 0.5um, 0.22um then, obtain having the environment-friendly digital ink-jet textile printing ink finished product of red reactive dyes.
Example 10
1, the environment-friendly digital ink-jet textile printing ink with REACTIVE DYES is prepared by following proportioning, referring to table 10.
Table 10
| Component | Content (weight %) |
| Deionized water | 41.1 |
| Glycerine | 10 |
| Diethylene glycol (DEG) | 12 |
| Dimethylethanolamine | 0.2 |
| Non-ionic surface active agent | 1.5 |
| Ethylenediamine | 10 |
| Isothiazolinone | 0.2 |
| Environment-friendly active dye Huang 86 | 25 |
| Add up to | 100 |
2, preparation method:
Throw in above component in the stirred vessel sequentially, stirred 30～120 minutes with 500～3000rpm speed, use the aperture to filter step by step as the filter membrane of 1um, 0.5um, 0.22um then, obtain having the environment-friendly digital ink-jet textile printing ink finished product of Yellow active dye.
Example 11
1, the environment-friendly digital ink-jet textile printing ink with REACTIVE DYES is prepared by following proportioning, referring to table 11.
Table 11
| Component | Content (weight %) |
| Deionized water | 70.1 |
| Propylene glycol | 10 |
| Diethylene glycol (DEG) | 12 |
| Triethanolamine | 0.2 |
| Non-ionic surface active agent | 1.5 |
| Diethylenetriamine | 2 |
| Isothiazolinone | 0.2 |
| Environment-friendly active dye Huang 86 | 4 |
| Add up to | 100 |
2, preparation method:
Throw in above component in the stirred vessel sequentially, stirred 30～120 minutes with 500～3000rpm speed, use the aperture to filter step by step as the filter membrane of 1um, 0.5um, 0.22um then, obtain having the environment-friendly digital ink-jet textile printing ink finished product of Yellow active dye.
Example 12
1, the environment-friendly digital ink-jet textile printing ink with REACTIVE DYES is prepared by following proportioning, referring to table 12.
Table 12
| Component | Content (weight %) |
| Deionized water | 58.4 |
| Glycerine | 11 |
| Propylene glycol | 10 |
| Dimethylethanolamine | 0.1 |
| Non-ionic surface active agent | 1 |
| Triethylene tetramine | 5 |
| Isothiazolinone | 0.5 |
| Environment-friendly active dye Huang 86 | 14 |
| Add up to | 100 |
2, preparation method:
Throw in above component in the stirred vessel sequentially, stirred 30～120 minutes with 500～3000rpm speed, use the aperture to filter step by step as the filter membrane of 1um, 0.5um, 0.22um then, obtain having the environment-friendly digital ink-jet textile printing ink finished product of Yellow active dye.
More than embodiments of the invention are had been described in detail, but described content only is preferred embodiment of the present invention, can not be considered to for limiting practical range of the present invention.All equalizations of doing according to the present patent application scope change and improve etc., all should still belong within the patent covering scope of the present invention.
Claims (8)
1. the environment-friendly digital ink-jet textile printing ink with REACTIVE DYES is characterized in that,
This ink comprises following component by weight percentage:
Described REACTIVE DYES is selected from C.I. reactive black 8, C.I. reactive yellow 2, C.I. reactive yellow 3, C.I. REACTIVE YELLOW 18, C.I. reactive yellow 81, C.I. reactive yellow 84, C.I. reactive yellow 86, C.I. REACTIVE Yellow 145, C.I. reactive red 120, C.I. reactive red 141, C.I. Reactive Red 194, C.I. REACTIVE Red 195, C.I. reactive red 240, C.I. reactive blue 5, C.I. reactive blue 14, C.I. reactive blue 49, C.I. reactive blue 72, C.I. reactive blue 74, C.I. reactive blue 171, C.I. active blue 19 4, C.I. reactive orange 2, C.I. reactive orange 5, C.I. REACTIVE ORANGE 13, C.I. one or more in active green 19.
2. ink according to claim 1 is characterized in that this ink comprises following component by weight percentage:
3. ink as claimed in claim 1 or 2 is characterized in that described wetting agent is selected from one or more in propylene glycol, glycerine, the diethylene glycol (DEG).
4. ink as claimed in claim 1 or 2 is characterized in that described surfactant is non-ionic surface active agent.
5. ink as claimed in claim 1 or 2 is characterized in that, described pH conditioning agent is a kind of in triethanolamine or the dimethylethanolamine.
6. ink as claimed in claim 1 or 2 is characterized in that described bactericide is the isothiazolinone biocide agent.
7. ink as claimed in claim 1 or 2 is characterized in that described softener is selected from one or more in ethylenediamine, diethylenetriamine, the triethylene tetramine.
8. the preparation method of ink as claimed in claim 1 or 2, this method comprises the steps:
A, the deionized water with described ratio, wetting agent, surfactant, pH conditioning agent, bactericide, softener and REACTIVE DYES are thrown in the stirred vessel sequentially, stir 30～120 minutes with 500～3000rpm speed;
B, stirred materials is carried out filtration treatment, first pass is that 1 μ m filter membrane filters with the aperture, and second time is that 0.5 μ m filter membrane filters, is the environment-friendly digital ink-jet textile printing ink finished product that obtains having REACTIVE DYES after 0.22 μ m filter membrane filters with the aperture the 3rd time with the aperture.
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| CN102558959B (en) * | 2011-12-16 | 2013-09-11 | 广州市联印数码科技有限公司 | Starching-free direct injection reactive dye ink |
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| CN104790227A (en) * | 2015-04-07 | 2015-07-22 | 山东黄河三角洲纺织科技研究院有限公司 | Reactive dye ink for inkjet printing and preparation method thereof |
| CN105803827A (en) * | 2016-04-01 | 2016-07-27 | 华南师范大学 | Ink-jet ink and application thereof |
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| CN107740289A (en) * | 2017-10-19 | 2018-02-27 | 无锡嘉加科技有限公司 | A kind of anhydrous printing with reactive dye ink and preparation method thereof |
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| CN107904987B (en) * | 2017-11-13 | 2020-11-03 | 珠海市东昌颜料有限公司 | Water-based active direct-injection printing ink suitable for Beijing porcelain sprayer and preparation method thereof |
| CN107956172B (en) * | 2017-11-13 | 2020-11-03 | 珠海市东昌颜料有限公司 | Nano water-based heat transfer ink suitable for high-speed printing in Beijing porcelain sprayer |
| CN108221407A (en) * | 2018-02-10 | 2018-06-29 | 无锡蓝莹数码技术有限公司 | A kind of digit printing active ink and preparation method thereof |
| JP7234578B2 (en) * | 2018-10-31 | 2023-03-08 | セイコーエプソン株式会社 | Textile inkjet ink, ink set and textile printing method |
| CN110306360A (en) * | 2019-07-19 | 2019-10-08 | 浙江海印数码科技有限公司 | A kind of digit printing high stable reactive dye ink and preparation method thereof |
| CN114753165A (en) * | 2022-04-29 | 2022-07-15 | 珠海天威新材料股份有限公司 | Environment-friendly reactive dye ink and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1010802A2 (en) * | 1998-12-17 | 2000-06-21 | Seiko Epson Corporation | Ink compositions for ink jet textile printing |
| CN1786331A (en) * | 2005-12-16 | 2006-06-14 | 上海印能数码科技有限公司 | Ink-jet ink of digit printing active dye for textiles and production Tech. thereof |
| CN101531848A (en) * | 2009-03-24 | 2009-09-16 | 深圳市墨库数码耗材有限公司 | An environment-friendly digital ink-jet direct printing textile ink and method for preparing same |
| CN101760078A (en) * | 2010-01-04 | 2010-06-30 | 广东鸿昌服饰创意股份有限公司 | Reactive ink for printing and dyeing and method for carrying out jet printing on denim fabric by adopting same |
-
2011
- 2011-04-25 CN CN 201110103190 patent/CN102226316B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1010802A2 (en) * | 1998-12-17 | 2000-06-21 | Seiko Epson Corporation | Ink compositions for ink jet textile printing |
| CN1786331A (en) * | 2005-12-16 | 2006-06-14 | 上海印能数码科技有限公司 | Ink-jet ink of digit printing active dye for textiles and production Tech. thereof |
| CN101531848A (en) * | 2009-03-24 | 2009-09-16 | 深圳市墨库数码耗材有限公司 | An environment-friendly digital ink-jet direct printing textile ink and method for preparing same |
| CN101760078A (en) * | 2010-01-04 | 2010-06-30 | 广东鸿昌服饰创意股份有限公司 | Reactive ink for printing and dyeing and method for carrying out jet printing on denim fabric by adopting same |
Non-Patent Citations (2)
| Title |
|---|
| 张伟等.喷墨印花墨水及其发展.《针织工业》.2009,(第6期),第63-68页. * |
| 簧健等.织物喷墨印花用色素及发展趋势.《染料与染色》.2004,第41卷(第6期),第334-336页. * |
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