CN102219626B - Additive used for fireworks medicament pelletizing process and adding method thereof - Google Patents
Additive used for fireworks medicament pelletizing process and adding method thereof Download PDFInfo
- Publication number
- CN102219626B CN102219626B CN201110095202A CN201110095202A CN102219626B CN 102219626 B CN102219626 B CN 102219626B CN 201110095202 A CN201110095202 A CN 201110095202A CN 201110095202 A CN201110095202 A CN 201110095202A CN 102219626 B CN102219626 B CN 102219626B
- Authority
- CN
- China
- Prior art keywords
- medicament
- rice flour
- additive
- total mass
- fireworks
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The invention relates to an additive used for fireworks medicament pelletizing process and an adding method thereof, belonging to the field of fireworks and firecrackers. Potassium dichromate and cooked glutinous rice flour are taken as the additive, wherein the mass of the potassium dichromate accounts for 1%-3% of the total mass of fireworks medicament, and the particle size of the potassium dichromate is smaller than 80 meshes; and the cooked glutinous rice flour is taken as adhesion agent, and the mass of the cooked glutinous rice flour accounts for 1%-4% of the total mass of the fireworks medicament. The adding method is as follows: when mixing medicament raw material, adding potassium dichromate with the mass accounting for 1%-3% of the total mass of the medicament, and the particle size being smaller than 80 meshes, mixing uniformly; and in the bonding process, replacing the additive by the cooked glutinous rice flour accounting for 1%-4% of the total mass of the medicament, and preparing the cooked glutinous rice flour into 3%-8% of water solution. In the invention, the additive is low in cost, the using amount is little, the adding process is simple, the problem of heat accumulation in the pelletizing process of the fireworks medicament is solved, so that the temperature of the medicament is the same as that of the environment, the explosion accident is avoided, and the additive can not affect the setting-off performance of the original medicament formula.
Description
Technical field
The present invention relates to a kind of additive and addition means thereof that is used for the firework medicament granulation process, belong to the fireworks and firecrackers field.
Background technology
Firer, firework medicament in order to improve the free-running property of medicament, reduce the dust in sieve medicine, the powder charge process, and realize the accurate filling of medicament in process of production, need carry out granulation to medicament.Along with the reach of science, chemical deposition, water suspension method, electromagnetism sputtering method and high speed dispersion medical method etc. have been researched and developed.The firework medicament granulation process is general to mix medicament stock earlier, and then with sticker raw material is bonded to particulate state.But meanwhile, contain in flammable and explosive substance, the especially granulation processs such as aluminium powder, aluminium-magnesium alloy powder meeting and sticker solvent generation chemical reactions such as water or alcohol in the firework medicament; Emit heat, cause the rising of pyrotechnics composition temperature and the consumption of aluminium powder and magnesium aluminum-alloy powder, go up appreciable heat and chemical phenomenon, promptly formed chemical energy and produce macroscopic view; I.e. heating, when the chemical reaction liberated heat exceeds the heat that firework medicament distributes gradually, heat can slowly be gathered; Temperature raises gradually thereupon, and chemical reaction is sharply accelerated thereupon, and temperature also sharply rises; Thereby make it in a flash, reach the spontaneous ignition temperature of medicament, cause the combustion explosion accident at certain.And some sticker is participated in the medicament reaction, has changed the oxygen balance value of former medicament, has had a strong impact on the physical and chemical performance of firework medicament.Therefore, select the additive of the gentle cohesive action of suitable landing, the generation of blast accident is avoided in the temperature rise of strict control medicament, keeps powder performance stable, is the important step of firework medicament granulation process.
Summary of the invention
The objective of the invention is in the firework medicament granulation process because of thermal accumlation causes blast accident, and keep the stable of powder performance, additive that has been used for the cooling effect and the sticker that is complementary with it are provided, with the security of raising granulation process.
The objective of the invention is to realize through following technical scheme:
A kind of additive that is used for the firework medicament granulation process of the present invention, this additive are SRM 935a and ripe sticky rice flour; Wherein, the quality of SRM 935a accounts for 1%～3% of firework medicament total mass, and particle diameter is less than 80 orders; Ripe sticky rice flour is as sticker, and the quality of ripe sticky rice flour accounts for 1%～4% of firework medicament total mass.
A kind of addition means that is used for the additive of firework medicament granulation process of the present invention, its concrete grammar is:
Adding accounts for medicament total mass 1%～3%, particle diameter less than 80 purpose SRM 935as when medicament stock mixes, and is mixed to evenly;
In the bonding process, sticker is replaced with the ripe sticky rice flour that accounts for medicament total mass 1%～4%, and to be made into massfraction be 3%～8% the aqueous solution.
Beneficial effect:
Additive cost of the present invention is low, consumption is few, adding technology is simple; Solved the thermal accumlation problem of firework medicament in granulation process; Medicament temperature and envrionment temperature are consistent, avoid causing blast accident, and additive does not influence the performance of setting off of former reagent combination.
Embodiment
Below in conjunction with embodiment content of the present invention is further specified;
Embodiment 1
Used firework medicament prescription is:
(1) sulphur powder, aluminium powder, magnesium aluminum-alloy powder, saltpetre, nitrate of baryta and SRM 935a are taken by weighing 41.5g, 8.45g, 19.7g, 9.15g, 21.1g and 1g respectively and mix, and taking by weighing ripe sticky rice flour 2g, to be made into massfraction is 5% the aqueous solution.
(2) the mixed medicament and the ripe sticky rice flour aqueous solution that step (1) are obtained are bonded to the particulate state finished medicament.
Directly be placed on the particulate state finished medicament in the 300ml beaker; And seal with plastics film; Be inserted in the middle of the beaker medicament with a TM; And be placed on beaker apart from view-point a distance,, whenever observed a thermometer reading at a distance from ten minutes simultaneously with another thermometer measure envrionment temperature.
After adding additive of the present invention medicament temperature and environment are consistent, the medicament temperature of containing metal powder and water is had the obvious suppression effect.The firecracker product firework display effect of this particle medicament preparation is reached the requirement of GB, and (this medicament firing altitude＞20m), explain that ripe sticky rice flour has neither part nor lot in reaction, powder performance is stable.
Embodiment 2
Used firework medicament prescription is:
(1) sulphur powder, aluminium powder, magnesium aluminum-alloy powder, saltpetre, nitrate of baryta and SRM 935a are taken by weighing 41.5g, 8.45g, 19.7g, 9.15g, 21.1g and 2g respectively and mix, and taking by weighing ripe sticky rice flour 3g and water, to be made into massfraction is 5% solution.
(2) the mixed medicament and the ripe sticky rice flour aqueous solution that step (1) are obtained are bonded to the particulate state finished medicament.
Directly be placed on the particulate state finished medicament in the 300ml beaker; And seal with plastics film; Be inserted in the middle of the beaker medicament with a TM; And be placed on beaker apart from view-point a distance,, whenever observed a thermometer reading at a distance from ten minutes simultaneously with another thermometer measure envrionment temperature.
After adding additive of the present invention medicament temperature and environment are consistent, the medicament temperature of containing metal powder and water is had the obvious suppression effect.The firecracker product firework display effect of this particle medicament preparation is reached the requirement of GB, and (this medicament firing altitude＞20m), explain that ripe sticky rice flour has neither part nor lot in reaction, powder performance is stable.
Embodiment 3
Used firework medicament prescription is:
(1) sulphur powder, aluminium powder, magnesium aluminum-alloy powder, potassium perchlorate, nitrate of baryta and SRM 935a are taken by weighing 41.5g, 8.45g, 19.7g, 9.15g, 21.1g and 2g respectively and mix, taking by weighing ripe sticky rice flour 3g and water simultaneously, to be made into massfraction be 5% solution.
(2) the mixed medicament and the ripe sticky rice flour aqueous solution that step (1) are obtained are bonded to the particulate state finished medicament.
Directly be placed on the particulate state finished medicament in the 300ml beaker; And seal with plastics film; Be inserted in the middle of the beaker medicament with a TM; And be placed on beaker apart from view-point a distance,, whenever observed a thermometer reading at a distance from ten minutes simultaneously with another thermometer measure envrionment temperature.
After adding additive of the present invention medicament temperature and environment are consistent; Medicament temperature to containing metal powder and water has the obvious suppression effect; The firecracker product firework display effect of this particle medicament preparation is reached the requirement of GB, and (this medicament is an explosive; Can blow the paper shell gets final product), explain that ripe sticky rice flour has neither part nor lot in reaction, powder performance is stable.
Comparative Examples
Adopt traditional method to carry out firework medicament granulation processing, used firework medicament prescription is:
(1) sulphur powder, aluminium powder, magnesium aluminum-alloy powder, potassium perchlorate, nitrate of baryta and SRM 935a are taken by weighing 41.5g, 8.45g, 19.7g, 9.15g and 21.1g respectively and mix, and taking by weighing resol 3g and ethanol, to be made into massfraction is 15% solution.
(2) the mixed medicament and the ripe sticky rice flour aqueous solution that step (1) are obtained are bonded to the particulate state finished medicament.
Be placed on the particulate state finished medicament in the 300ml beaker; And seal with plastics film, be inserted in the middle of the beaker medicament with a TM, and be placed on beaker apart from view-point a distance; With another thermometer measure envrionment temperature, whenever observed a thermometer reading simultaneously at a distance from ten minutes.
Adopt prescription among the embodiment 3; Rapidly rise to 76 ℃ as the medicament temperature of sticker when the 40min with the ethanolic soln of resol; Contrast can be known; Adopt metal powder and the solvent in the sticker in the medicament after traditional method is carried out the processing of the firework medicament granulation working method heat that produces that reacts to make the medicament temperature rise sharply, be prone to the generation blast accident.
Claims (2)
1. additive that is used for the firework medicament granulation process, it is characterized in that: this additive is SRM 935a and ripe sticky rice flour; Wherein, the quality of SRM 935a accounts for 1%～3% of firework medicament total mass, and particle diameter is less than 80 orders; Ripe sticky rice flour is as sticker, and the quality of ripe sticky rice flour accounts for 1%～4% of firework medicament total mass.
2. addition means that is used for the additive of firework medicament granulation process is characterized in that concrete grammar is:
Adding accounts for medicament total mass 1%～3%, particle diameter less than 80 purpose SRM 935as when medicament stock mixes, and is mixed to evenly;
In the bonding process, sticker is replaced with the ripe sticky rice flour that accounts for medicament total mass 1%～4%, and to be made into massfraction be 3%～8% the aqueous solution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110095202A CN102219626B (en) | 2011-04-15 | 2011-04-15 | Additive used for fireworks medicament pelletizing process and adding method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110095202A CN102219626B (en) | 2011-04-15 | 2011-04-15 | Additive used for fireworks medicament pelletizing process and adding method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102219626A CN102219626A (en) | 2011-10-19 |
| CN102219626B true CN102219626B (en) | 2012-10-10 |
Family
ID=44776362
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110095202A Expired - Fee Related CN102219626B (en) | 2011-04-15 | 2011-04-15 | Additive used for fireworks medicament pelletizing process and adding method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102219626B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103739414B (en) * | 2013-12-17 | 2016-08-17 | 江西省李渡烟花集团有限公司 | A kind of novel firework silver color draws ripple medicine |
| CN103755502B (en) * | 2014-01-28 | 2016-01-06 | 西北大学 | Based on the explosive wastewater formulating of recipe method of dynamic measure and dynamic component dual regulation |
| CN104973998A (en) * | 2015-07-09 | 2015-10-14 | 卜继良 | Firework gunpowder composition for firework sounding beads |
| CN104945207B (en) * | 2015-07-09 | 2017-11-21 | 扬州奥巴玛科技发展有限公司 | A kind of preparation method of bright pearl |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1598474A (en) * | 2004-08-20 | 2005-03-23 | 姜锡松 | Flash star for mfg. fireworks |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000169276A (en) * | 1998-12-08 | 2000-06-20 | Nippon Kayaku Co Ltd | Gas generating agent composition |
-
2011
- 2011-04-15 CN CN201110095202A patent/CN102219626B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1598474A (en) * | 2004-08-20 | 2005-03-23 | 姜锡松 | Flash star for mfg. fireworks |
Non-Patent Citations (1)
| Title |
|---|
| JP特开2000-169276A 2000.06.20 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102219626A (en) | 2011-10-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102219626B (en) | Additive used for fireworks medicament pelletizing process and adding method thereof | |
| CN103214322A (en) | Sulfur-smoke-free powder composition and preparation method thereof | |
| CN102219621B (en) | Modularized smokeless firework propellant and preparation method thereof | |
| SE528756C2 (en) | Starting compositions for reactive compositions comprising metals and methods for forming the same | |
| CN105152824B (en) | A kind of point of safes gunpowder and preparation method | |
| CN103254026A (en) | Compact aluminum-containing explosive and preparation method thereof | |
| CN104973998A (en) | Firework gunpowder composition for firework sounding beads | |
| CN104944423B (en) | A kind of high-energy igniter charge and preparation method | |
| CN108456126B (en) | Transfer powder of gas generator, preparation method of transfer powder and gas generator for automobile safety airbag | |
| CN106565390A (en) | Electronically-controlled combustion solid propellant and preparation method thereof | |
| CN103755504B (en) | High-energy ignition agent and preparation method thereof | |
| CN100410217C (en) | Lemoncolor flash star for fireworks and its making method | |
| CN109020764A (en) | A kind of nonsulfide environment protection firework medicament | |
| CN103396275A (en) | Nanometer bismuth oxide-coated modified boron fuel and preparation methods thereof | |
| CN108424340A (en) | A kind of high explosion velocity pressed explosives and preparation method thereof | |
| US11040923B2 (en) | Explosive composition for use in telescopically expanding non-lethal training ammunition | |
| CN106631642A (en) | High-energy mixed explosive containing titanium powder and preparation method of high-energy mixed explosive | |
| CN111138236B (en) | 1,2, 4-triazole nitrate coated boron-magnesium composite metal powder fuel and preparation method thereof | |
| CN102206126B (en) | Method for safely preparing fireworks chemical by boiling granulating process | |
| CN103242113B (en) | Polyurethane coated modified potassium chlorate and preparation method and applications thereof | |
| CN108976095B (en) | C L-20 base pressure-loaded high-energy insensitive explosive and preparation method thereof | |
| CN108623424B (en) | Explosive added with high-activity Ti/2B nano powder material and preparation method thereof | |
| CN102153427A (en) | Excitation powder of flying plate type electric detonator without detonating powder | |
| CN111362768A (en) | Smokeless bud-opening medicine | |
| CN112280055A (en) | Cadmium-based energetic metal organic framework directly initiated by 1064nm laser, preparation method and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20121010 Termination date: 20150415 |
|
| EXPY | Termination of patent right or utility model |