CN102217642A - Flusilazole-azoxystrobin compounded bactericide suspending agent and preparation method thereof - Google Patents
Flusilazole-azoxystrobin compounded bactericide suspending agent and preparation method thereof Download PDFInfo
- Publication number
- CN102217642A CN102217642A CN2011101166034A CN201110116603A CN102217642A CN 102217642 A CN102217642 A CN 102217642A CN 2011101166034 A CN2011101166034 A CN 2011101166034A CN 201110116603 A CN201110116603 A CN 201110116603A CN 102217642 A CN102217642 A CN 102217642A
- Authority
- CN
- China
- Prior art keywords
- agent
- flusilazole
- percentage
- weight
- ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a flusilazole-azoxystrobin compounded bactericide suspending agent and a preparation method thereof, belonging to the technical field of the pesticides. The flusilazole-azoxystrobin compounded bactericide suspending agent is prepared from the following components in weight percentage: in a case where the content of the flusilazole is 95% and the content of the azoxystrobin is 98%, 0.1-40% flusilazole, 0.1-40% azoxystrobin, 0.1-2% defoaming agent, 0.5-20% wetting agent, 0.5-20% dispersant, 0.1-4% antifreeze, 0.1-5% thickening agent, 0.1-4% PH value regulator, 0.1-10% stabilizer, 0.1-5% penetrant, and rest being de-ionized water. The flusilazole-azoxystrobin compounded bactericide suspending agent has the advantages of high efficiency, low toxicity, no pollution, and safety for the environment, the human and the animals, and the resistance of pathogenic bacteria is not easy to be induced.
Description
Technical field
The present invention relates to bactericide suspending agent of a kind of Flusilazole and azoxystrobin compound and preparation method thereof, belong to technical field of pesticides.
Background technology
Pesticidal preparations is progressively to safe, environmental protectionization, water baseization development, and 1. agricultural chemicals suspension agent does not have dust harzard owing to have the following advantages, to operator and Environmental security; 2. be dispersion medium with water, do not have the inflammable and drug injury problem that produces by organic solvent; 3. compare with wetting powder, allow to select for use the former medicine of different-grain diameter, so that make the biological effect of preparation and physical stability reach best; 4. liquid suspension spreads in water well, can directly make spray liquid and use; 5. than great, packaging volume is little.6. the dispersiveness of suspending agent and plate-out ability are all relatively good, the suspensibility height, and the ability that sticks to the plant corpus surface is more intense, resistance of rainwater washing against, thereby drug effect significantly and also compares lastingly than wetting powder.7. have that particle is little, active surface is big, penetration is strong, do not have dust when making up a prescription, characteristics such as cost is low, drug effect height.And have the advantage of wetting powder and missible oil concurrently, and can be moistening by water, suspension is good behind the thin up.Agricultural chemicals suspension agent be after a kind of formulation of large usage quantity in the formulations of pesticide utilizations.
Flusilazole, two (4-fluorophenyl) methyl (1H-1,2, the 4-triazol-1-yl methylene) silane of chemical name belong to low-toxin farm chemicals.Absorption sterilization in belonging to suppresses the sterol demethylation.Mainly can be used for preventing and treating Ascomycetes, Basidiomycetes and Fungi Imperfecti fungi are effective, as venturia inaequalis, white powder germ, and the wheat class nuclear cavity bacteria of cereal class, Septoria bacterium, snag shell bacterium etc., the various pathogens on Guignardia and the sweet Lay, leaf spot of peanut.Triazole bactericidal agent destroys and stops the biosynthesis of ergosterol, causes cell membrane not form, and makes germ death.Effective to disease due to sac fungi, basidiomycetes and the imperfect fungus, invalid to oomycetes, pear scab there is special efficacy.Prevent and treat pear scab, send out initial stage spray medicine in disease, every 7～10d spray 1 time, continuous 4～6 times, use 40% missible oil effective dose, 40～50mg/L (8000～10000 times of liquid) at every turn, can effectively prevent and treat pear scab, and the double effect of controlling the pears rust is arranged.When the disease occurrence in peak period, the spray medicine can suitably shorten at interval.Also can be used for the black star of apple and rectify and powdery mildew grape powdery mildew, leaf spot of peanut, powdery mildem of cereals and eye spot disease, wheat glume blight, leaf rust and yellow rust, Folium Hordei Vulgaris pinta etc.
The Flusilazole preparation of present domestic registration mainly be single agent emulsifiable solution, single agent suspending agent, single agent aqueous emulsion, single agent microemulsion and with suspending agent, aqueous emulsion, microemulsion and the dispersive granule of Prochloraz, oxazole bacterium ketone, carbendazim etc., do not see the bactericide suspending agent composite with Flusilazole.
Fluoxastrobin; chemical name is: (E)-[2-[6-(2-cyano-benzene oxygen) pyrimidine-4-base oxygen] phenyl]-the 3-methoxy-methyl acrylate; it is first commercial methoxy acrylic bactericide that Syngenta Co.,Ltd succeeds in developing; efficiently, wide spectrum; have protection, treat, root out, permeate and interior absorption, nearly all mycota (Ascomycotina, Basidiomycotina, Mastigomycotina and Deuteromycotina) disease such as powdery mildew, rust, glume blight, net blotch, downy mildew, rice blast etc. are all had good activity.Can be used for cauline leaf spraying, seed treatment, also can carry out soil treatment, be mainly used in cereal, paddy rice, peanut, grape, potato, fruit tree, vegetables, coffee, lawn etc.
The azoxystrobin formulations of present domestic registration mainly be single agent suspending agent, single agent dispersive granule and with the suspending agent and the dispersive granule of other agricultural chemicals, do not see bactericide suspending agent with azoxystrobin compound.
Single agent product of above-mentioned two kinds of agricultural chemicals in use develops immunity to drugs at present, and drug effect descends much than before, and the control cost also obviously increases.
Summary of the invention
The objective of the invention is to overcome the defective of Flusilazole and Fluoxastrobin list agent product, the little Flusilazole of a kind of good drug efficacy, pesticide resistance and bactericide suspending agent of azoxystrobin compound and preparation method thereof are provided.
For achieving the above object, the technical solution adopted in the present invention is:
The bactericide suspending agent of a kind of Flusilazole and azoxystrobin compound, formulated by following components in weight percentage: as to be 95% at the content of Flusilazole, the content of Fluoxastrobin is under 98% the situation, Flusilazole 0.1%～40%, Fluoxastrobin 0.1%～40%, defoamer 0.1%～2%, wetting agent 0.5%～20%, dispersant 0.5%～20%, antifreezing agent 0.1%～4%, thickener 0.1%～5%, pH value conditioning agent 0.1%～4%, stabilizing agent 0.1%～10%, bleeding agent 0.1%～5%, surplus are deionized water.
The ratio of the percentage by weight of described Flusilazole is 10%～40%, and the ratio of the percentage by weight of Fluoxastrobin is 10%～40%.
The ratio of the percentage by weight of described defoamer is 0.2%～1.5%, and defoamer is organic silicone, silicone oil, polyethers, C
10～20Saturated fat acids, C
8～10In the aliphatic alcohols any one or multiple mixture are as AntifoamTS, Tegomer V-Si 4042, ZBH-305B, lauric acid, 16 carbonic acid etc.AntifoamTS is the product of Shanghai rising sun trade Co., Ltd.Tegomer V-Si 4042 fills in the product of company admittedly for German moral.ZBH-305B is the product of precious chemical industry Co., Ltd in the Qingdao.
The ratio of the percentage by weight of described wetting agent is 0.5%～4%; wetting agent is one or more in alkylnaphthalene sulfonate, fatty acid amide N methyl taurine salt, alkylsulfonate, alkylaryl polyoxyethylene ether sulfate, the fat fatty alcohol-polyoxyethylene ether etc., as lauryl sodium sulfate, draw back powder, dodecyl sulphate barium, MorwetEFW, TERWET1004 etc.MorwetEFW is the product of Akzo Nobel (AKZO NOBEL) company.TERWET1004 selects the deliver a letter product of chemical industry Co., Ltd of Shanghai for use.
The ratio of the percentage by weight of described dispersant is 0.5%～4%, dispersant is one or more in alkyl sodium salt, lignosulfonates and derivative thereof, naphthalenesulfonic acid-formaldehyde condensate, alkylphenol-polyethenoxy and formaldehyde condensation products sulphate, polycarboxylate and derivative thereof, cresols-formaldehyde and sodium sulphite condensation product, alkylaryl sulfonates phenethyl phenol polyethenoxy ether and the derivative thereof etc., as wooden sodium sulfonate, MorwetD-425, MorwetD-110, TERSPENSE2425, TERSPENSE2700 etc.MorwetD-425, MorwetD-110 are the product of Akzo Nobel (AKZO NOBEL) company.
The ratio of the percentage by weight of described antifreezing agent is 0.5%～2%, and antifreezing agent is any one or the multiple mixture in ethylene glycol, propane diols, urea, the glycerine.
The ratio of the percentage by weight of described thickener is 0.5%～2%, and thickener is any one or the multiple mixture in xanthans, sodium carboxymethylcellulose, starch, pectin, the Magnesiumaluminumsilicate.The product that sodium carboxymethylcellulose selects for use Xinfeng, Dacheng County, Hebei province cellulose factory to produce.
The ratio of the percentage by weight of described pH value conditioning agent is 0.5%～2%, and the pH value conditioning agent is any one or the multiple mixture in citric acid, malic acid, the sodium bicarbonate.
The ratio of the percentage by weight of described stabilizing agent is 0.5%～2%, and stabilizing agent is 1,2-benzisothiazole-3-ketone, tributyl phosphate, 2,5-dimethyl-2, any one in the 4-hexadiene or multiple mixture; The ratio of the percentage by weight of described bleeding agent is 0.5%～2%, and bleeding agent is any one or the multiple mixture that draws back in powder, bleeding agent LS, the lauryl sodium sulfate.Bleeding agent LS is the product that the Suzhou connection wins chemical Co., Ltd.
The preparation method of the bactericide suspending agent of a kind of Flusilazole and azoxystrobin compound may further comprise the steps:
1) earlier wetting agent, dispersant, pH value conditioning agent, bleeding agent, defoamer, stabilizing agent, antifreezing agent are proportionally joined in the deionized water, stir;
2) in the material of step 1) gained, add Flusilazole and Fluoxastrobin again, continue to stir;
3) with step 2) material of gained carries out sand milling, and the particle diameter of Flusilazole and Fluoxastrobin is reached below 2.5 microns;
4) add thickener, stir.
The present invention have produce to store and safe in utilization, environmental pollution is little, low cost and other advantages.
The invention provides a kind of efficient, low toxicity, pollution-free, environment, people, animal safety and germ are difficult for producing the Flusilazole of resistance and bactericide suspending agent of azoxystrobin compound and preparation method thereof, said preparation is with water to replace organic solvent, physics peptizaiton by high shear dispersion machine and horizontal sand mill, make Flusilazole and Fluoxastrobin with the particle size dispersion below 2.5 microns in water, form milky suspension formulation.The preparation of this technology is simple, production cost is low.
Technical indicator of the present invention is:
The project indicator
Flusilazole content 0.1%-40%;
Fluoxastrobin content 0.1%-40%;
Particle diameter (98%) 1-2 micron;
Suspensibility 〉=95%;
PH value
Heat storage stability (54 ± 2 ℃, 14 days)
Flusilazole resolution ratio≤2%,
Fluoxastrobin resolution ratio≤1.5%.
Embodiment
The invention will be further described below by specific embodiment, but the present invention is not limited by following examples.
Embodiment 1
The bactericide suspending agent of a kind of Flusilazole and azoxystrobin compound, formulated by following components in weight percentage: as to be 95% at the content of Flusilazole, the content of Fluoxastrobin is under 98% the situation, Flusilazole 40%, Fluoxastrobin 20%, defoamer 1.5%, wetting agent 5%, dispersant 5%, antifreezing agent 0.6%, thickener 5%, pH value conditioning agent 0.3%, stabilizing agent 10%, bleeding agent 0.35%, surplus are deionized water.
Wherein, defoamer is AntifoamTS, and wetting agent is MorwetEFW, and dispersant is MorwetD-425, antifreezing agent is a propane diols, and thickener is a Magnesiumaluminumsilicate, and the pH value conditioning agent is a citric acid, stabilizing agent is 1, and 2-benzisothiazole-3-ketone, bleeding agent are bleeding agent LS.
Preparation method of the present invention may further comprise the steps:
1) earlier wetting agent, dispersant, pH value conditioning agent, bleeding agent, defoamer, stabilizing agent, antifreezing agent are proportionally joined in the deionized water, stir by the high shear dispersion machine;
2) in the material of step 1) gained, add Flusilazole and Fluoxastrobin again, continue to stir;
3) with step 2) material of gained sends into horizontal sand mill and carries out sand milling, and the particle diameter of Flusilazole and Fluoxastrobin is reached below 2.5 microns;
4) add thickener, stir.
Embodiment 2
The bactericide suspending agent of a kind of Flusilazole and azoxystrobin compound, formulated by following components in weight percentage: as to be 95% at the content of Flusilazole, the content of Fluoxastrobin is under 98% the situation, Flusilazole 20%, Fluoxastrobin 20%, defoamer 0.2%, wetting agent 5%, dispersant 6%, antifreezing agent 0.3%, thickener 4%, pH value conditioning agent 0.3%, stabilizing agent 2%, bleeding agent 0.8%, surplus are deionized water.
Wherein, defoamer is Tegomer V-Si 4042, and wetting agent is MorwetEFW, and dispersant is MorwetD-425, antifreezing agent is a propane diols, and thickener is an xanthans, and the pH value conditioning agent is a citric acid, stabilizing agent is 1, the 2-benzisothiazole-3-ketone, and bleeding agent is for drawing back powder.
Preparation method of the present invention may further comprise the steps:
1) earlier wetting agent, dispersant, pH value conditioning agent, bleeding agent, defoamer, stabilizing agent, antifreezing agent are proportionally joined in the deionized water, stir by the high shear dispersion machine;
2) in the material of step 1) gained, add Flusilazole and Fluoxastrobin again, continue to stir;
3) with step 2) material of gained sends into horizontal sand mill and carries out sand milling, and the particle diameter of Flusilazole and Fluoxastrobin is reached below 2.5 microns;
4) add thickener, stir.
Embodiment 3
The bactericide suspending agent of a kind of Flusilazole and azoxystrobin compound, formulated by following components in weight percentage: as to be 95% at the content of Flusilazole, the content of Fluoxastrobin is under 98% the situation, Flusilazole 20%, Fluoxastrobin 20%, defoamer 0.2%, wetting agent 5%, dispersant 6%, antifreezing agent 0.3%, thickener 4%, pH value conditioning agent 0.3%, stabilizing agent 2%, bleeding agent 0.8%, surplus are deionized water.
Wherein, defoamer is Tegomer V-Si 4042, and wetting agent is MorwetEFW, and dispersant is MorwetD-425, antifreezing agent is a propane diols, and thickener is an xanthans, and the pH value conditioning agent is a citric acid, stabilizing agent is 1, the 2-benzisothiazole-3-ketone, and bleeding agent is for drawing back powder.
Preparation method of the present invention may further comprise the steps:
1) earlier wetting agent, dispersant, pH value conditioning agent, bleeding agent, defoamer, stabilizing agent, antifreezing agent are proportionally joined in the deionized water, stir by the high shear dispersion machine;
2) in the material of step 1) gained, add Flusilazole and Fluoxastrobin again, continue to stir;
3) with step 2) material of gained sends into horizontal sand mill and carries out sand milling, and the particle diameter of Flusilazole and Fluoxastrobin is reached below 2.5 microns;
4) add thickener, stir.
Embodiment 4
The bactericide suspending agent of a kind of Flusilazole and azoxystrobin compound, formulated by following components in weight percentage: as to be 95% at the content of Flusilazole, the content of Fluoxastrobin is under 98% the situation, Flusilazole 10%, Fluoxastrobin 40%, defoamer 2%, wetting agent 4%, dispersant 4%, antifreezing agent 0.5%, thickener 2%, pH value conditioning agent 2%, stabilizing agent 0.5%, bleeding agent 2%, surplus are deionized water.
Wherein, defoamer is ZBH-305B, and wetting agent is for drawing back powder, and dispersant is a sodium lignin sulfonate, and antifreezing agent is a urea, and thickener is a pectin, and the pH value conditioning agent is a malic acid, and stabilizing agent is a tributyl phosphate, and bleeding agent is a lauryl sodium sulfate.
Preparation method of the present invention may further comprise the steps:
1) earlier wetting agent, dispersant, pH value conditioning agent, bleeding agent, defoamer, stabilizing agent, antifreezing agent are proportionally joined in the deionized water, stir by the high shear dispersion machine;
2) in the material of step 1) gained, add Flusilazole and Fluoxastrobin again, continue to stir;
3) with step 2) material of gained sends into horizontal sand mill and carries out sand milling, and the particle diameter of Flusilazole and Fluoxastrobin is reached below 2.5 microns;
4) add thickener, stir.
Embodiment 5
The bactericide suspending agent of a kind of Flusilazole and azoxystrobin compound, formulated by following components in weight percentage: as to be 95% at the content of Flusilazole, the content of Fluoxastrobin is under 98% the situation, Flusilazole 40%, Fluoxastrobin 10%, defoamer 1.0%, wetting agent 0.5%, dispersant 0.5%, antifreezing agent 2%, thickener 0.5%, pH value conditioning agent 0.5%, stabilizing agent 1.0%, bleeding agent 4%, surplus are deionized water.
Wherein, defoamer is ZBH-305B, and wetting agent is a dodecyl sulphate barium, dispersant is a sodium lignin sulfonate, and antifreezing agent is the mixture of ethylene glycol and propane diols, and thickener is a pectin, the pH value conditioning agent is a sodium bicarbonate, and stabilizing agent is a tributyl phosphate, and bleeding agent is a lauryl sodium sulfate.
Preparation method of the present invention may further comprise the steps:
1) earlier wetting agent, dispersant, pH value conditioning agent, bleeding agent, defoamer, stabilizing agent, antifreezing agent are proportionally joined in the deionized water, stir by the high shear dispersion machine;
2) in the material of step 1) gained, add Flusilazole and Fluoxastrobin again, continue to stir;
3) with step 2) material of gained sends into horizontal sand mill and carries out sand milling, and the particle diameter of Flusilazole and Fluoxastrobin is reached below 2.5 microns;
4) add thickener, stir.
The foregoing description only is used to the inventive concept of the present invention of explaining, but not to the qualification of rights protection of the present invention, allly utilizes this design that the present invention is carried out the change of unsubstantiality, all should fall into protection scope of the present invention.
Claims (10)
1. the bactericide suspending agent of Flusilazole and azoxystrobin compound, it is characterized in that by following components in weight percentage formulated: be 95% at the content of Flusilazole, the content of Fluoxastrobin is under 98% the situation, Flusilazole 0.1%～40%, Fluoxastrobin 0.1%～40%, defoamer 0.1%～2%, wetting agent 0.5%～20%, dispersant 0.5%～20%, antifreezing agent 0.1%～4%, thickener 0.1%～5%, pH value conditioning agent 0.1%～4%, stabilizing agent 0.1%～10%, bleeding agent 0.1%～5%, surplus are deionized water.
2. the bactericide suspending agent of a kind of according to claim 1 Flusilazole and azoxystrobin compound is characterized in that: the ratio of the percentage by weight of described Flusilazole is 10%～40%, and the ratio of the percentage by weight of Fluoxastrobin is 10%～40%.
3. the bactericide suspending agent of a kind of according to claim 1 Flusilazole and azoxystrobin compound is characterized in that: the ratio of the percentage by weight of described defoamer is 0.2%～1.5%, defoamer
Be organic silicone, silicone oil, polyethers, C
10～20Saturated fat acids, C
8～10In the aliphatic alcohols any one or multiple mixture.
4. the bactericide suspending agent of a kind of according to claim 1 Flusilazole and azoxystrobin compound; it is characterized in that: the ratio of the percentage by weight of described wetting agent is 0.5%～4%, and wetting agent is one or more in alkylnaphthalene sulfonate, fatty acid amide N methyl taurine salt, alkylsulfonate, alkylaryl polyoxyethylene ether sulfate, the fat fatty alcohol-polyoxyethylene ether etc.
5. the bactericide suspending agent of a kind of according to claim 1 Flusilazole and azoxystrobin compound, it is characterized in that: the ratio of the percentage by weight of described dispersant is 0.5%～4%, and dispersant is one or more in alkyl sodium salt, lignosulfonates and derivative thereof, naphthalenesulfonic acid-formaldehyde condensate, alkylphenol-polyethenoxy and formaldehyde condensation products sulphate, polycarboxylate and derivative thereof, cresols-formaldehyde and sodium sulphite condensation product, alkylaryl sulfonates phenethyl phenol polyethenoxy ether and the derivative thereof etc.
6. the bactericide suspending agent of a kind of according to claim 1 Flusilazole and azoxystrobin compound, it is characterized in that: the ratio of the percentage by weight of described antifreezing agent is 0.5%～2%, and antifreezing agent is any one or the multiple mixture in ethylene glycol, propane diols, urea, the glycerine.
7. the bactericide suspending agent of a kind of according to claim 1 Flusilazole and azoxystrobin compound, it is characterized in that: the ratio of the percentage by weight of described thickener is 0.5%～2%, and thickener is any one or the multiple mixture in xanthans, sodium carboxymethylcellulose, starch, pectin, the Magnesiumaluminumsilicate.
8. the bactericide suspending agent of a kind of according to claim 1 Flusilazole and azoxystrobin compound, it is characterized in that: the ratio of the percentage by weight of described pH value conditioning agent is 0.5%～2%, and the pH value conditioning agent is any one or the multiple mixture in citric acid, malic acid, the sodium bicarbonate.
9. the bactericide suspending agent of a kind of according to claim 1 Flusilazole and azoxystrobin compound, it is characterized in that: the ratio of the percentage by weight of described stabilizing agent is 0.5%～2%, stabilizing agent is 1,2-benzisothiazole-3-ketone, tributyl phosphate, 2,5-dimethyl-2, any one in the 4-hexadiene or multiple mixture; The ratio of the percentage by weight of described bleeding agent is 0.5%～2%, and bleeding agent is any one or the multiple mixture that draws back in powder, bleeding agent LS, the lauryl sodium sulfate.
10. preparation method of the bactericide suspending agent of Flusilazole and azoxystrobin compound according to claim 1 is characterized in that may further comprise the steps:
1) earlier wetting agent, dispersant, pH value conditioning agent, bleeding agent, defoamer, stabilizing agent, antifreezing agent are proportionally joined in the deionized water, stir;
2) in the material of step 1) gained, add Flusilazole and Fluoxastrobin again, continue to stir;
3) with step 2) material of gained carries out sand milling, and the particle diameter of Flusilazole and Fluoxastrobin is reached below 2.5 microns;
4) add thickener, stir.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101166034A CN102217642A (en) | 2011-05-06 | 2011-05-06 | Flusilazole-azoxystrobin compounded bactericide suspending agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101166034A CN102217642A (en) | 2011-05-06 | 2011-05-06 | Flusilazole-azoxystrobin compounded bactericide suspending agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102217642A true CN102217642A (en) | 2011-10-19 |
Family
ID=44774556
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011101166034A Pending CN102217642A (en) | 2011-05-06 | 2011-05-06 | Flusilazole-azoxystrobin compounded bactericide suspending agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102217642A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112438268A (en) * | 2020-12-01 | 2021-03-05 | 广东立威化工有限公司 | Azoxystrobin additive and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1047286A (en) * | 1989-02-10 | 1990-11-28 | 帝国化学工业公司 | Sterilant |
| US20070053944A1 (en) * | 2003-09-23 | 2007-03-08 | Bayer Cropscience Aktiengesellschaft | Concentrated suspensions |
| CN101380027A (en) * | 2008-08-06 | 2009-03-11 | 张少武 | Sterilization suspension agent of flusilazole |
-
2011
- 2011-05-06 CN CN2011101166034A patent/CN102217642A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1047286A (en) * | 1989-02-10 | 1990-11-28 | 帝国化学工业公司 | Sterilant |
| US20070053944A1 (en) * | 2003-09-23 | 2007-03-08 | Bayer Cropscience Aktiengesellschaft | Concentrated suspensions |
| CN101380027A (en) * | 2008-08-06 | 2009-03-11 | 张少武 | Sterilization suspension agent of flusilazole |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112438268A (en) * | 2020-12-01 | 2021-03-05 | 广东立威化工有限公司 | Azoxystrobin additive and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102228042A (en) | Bactericide suspending agent compounded from difenoconazole and pyraclostrobin and preparation method thereof | |
| CN102379304B (en) | Pyraclostrobin-containing ultralow-volume liquid preparation | |
| CN102273443B (en) | Superlow-capacity liquid reagent containing ethofenprox | |
| CN101156627B (en) | Citrus corrosion protection antistaling agent with tea saponin | |
| CN101548677B (en) | Sterilizing compound of ethirimol and triazole | |
| CN103766353B (en) | Sterilization composition containing fluopyram | |
| CN101595883A (en) | A kind of composition pesticide and application thereof | |
| CN101653139A (en) | Compound bactericidal composition containing boscalid | |
| CN102835402A (en) | Bactericidal composition containing benziothiazolinone and chitosan oligosaccharide | |
| CN103719123A (en) | Ultra-low volume liquid containing composite of pyraclostrobin and morpholine bactericide | |
| CN102273473A (en) | bactericidal composition | |
| CN105076218B (en) | A kind of bactericidal composition | |
| CN102217643A (en) | Flusilazole and pyraclostrobin compounded suspending bactericide, and preparation method thereof | |
| CN102067881B (en) | Difenoconazole and sulfur compounded suspending agent and preparation method thereof | |
| CN101664033B (en) | Ethirimol-contained bactericide combination | |
| CN103651368A (en) | Ultra-low-volume liquid containing picoxystrobin and preparation method of ultra-low-volume liquid | |
| CN102217642A (en) | Flusilazole-azoxystrobin compounded bactericide suspending agent and preparation method thereof | |
| CN102715169A (en) | Agricultural sterilization compound composition containing dithianon | |
| CN102228024A (en) | Herbicide suspending agent compounded from fomesafen and fenoxaprop-p-ethyl and preparation method thereof | |
| CN101496522B (en) | Bactericidal composition containing Zhongshengmycin and tebuconazole as well as use thereof | |
| CN101647442B (en) | Mixed sterilization combination | |
| CN102640757A (en) | Compound pesticide sterilization composition containing trifloxystrobin | |
| CN102669161A (en) | Hot fogging concentrate containing pyraclostrobin and triazole fungicide | |
| CN103518743B (en) | Sterilizing composition containing boscalid and dimethomorph | |
| CN101849546A (en) | Pesticide composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20111019 |