CN102211890A - High-property inorganic environment-friendly waterproof powder for mortar concrete and preparation method thereof - Google Patents

High-property inorganic environment-friendly waterproof powder for mortar concrete and preparation method thereof Download PDF

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Publication number
CN102211890A
CN102211890A CN2011100964817A CN201110096481A CN102211890A CN 102211890 A CN102211890 A CN 102211890A CN 2011100964817 A CN2011100964817 A CN 2011100964817A CN 201110096481 A CN201110096481 A CN 201110096481A CN 102211890 A CN102211890 A CN 102211890A
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China
Prior art keywords
powder
sulfate
mortar concrete
sodium
high performance
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CN2011100964817A
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CN102211890B (en
Inventor
王福刚
汪永安
王传成
袁诗林
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Wang Fugang
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HENGYANG SHANWANG BUILDING MATERIALS CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a high-property inorganic environment-friendly waterproof powder for mortar concrete and a preparation method thereof. The waterproof powder comprises the following components by weight percent: 1.5-2.0% of aluminum sulfate, 42-48% of aluminum potassium sulfate, 12-16% of ferrous sulfate, 1.5-2.5% of sodium chloride, 1.5-2.5% of urea, 1.5-2.5% of anhydrous sodium sulfate, 0.1-0.5% of glue powder and 30-35% of coal ash, wherein the glue powder is dispersible latex powder or re-dispersible latex powder, and aluminum potassium sulfate is dehydrated aluminum potassium sulfate. The preparation method comprises the steps of making the prepared raw materials to powder of 100-150 meshes, mixing the powder and evenly stirring so as to prepare the high-property inorganic environment-friendly waterproof powder for the mortar concrete. By using the waterproof powder, the mortar concrete has the functions of waterproofness, seepage resistance, crack resistance, frost resistance, corrosion resistance, micro expansion compensation shrinkage and the like, has no toxicity and is environment-friendly.

Description

High Performance Mortar concrete inorganic environment-friendly water-proofing powder and preparation method thereof
Technical field
The present invention relates to a kind of mortar concrete waterproof additive and preparation method thereof, particularly a kind of High Performance Mortar concrete inorganic environment-friendly water-proofing powder and preparation method thereof.
Background technology
At present, thousands of kinds of architectural waterproof materials mainly are with coiled material, ointment, JS polymerizable compound waterproof paint, polyurethane coating etc., these all are to belong to surperficial dash, though have flexibility characteristics, weather resistance is a little less than basal plane concrete binding power, especially moist or have under the situation of infiltration at basal plane, can not make the waterproof of the back side and moist basal plane, can not reach mortar concrete, and poison gas is heavy from waterproof, do not have environment protecting, it is also very complicated to construct.
Summary of the invention
The objective of the invention is to overcome the above-mentioned deficiency of prior art and a kind of High Performance Mortar concrete inorganic environment-friendly water-proofing powder is provided, it can make mortar concrete have functions such as waterproof, impervious, cracking resistance, freeze proof, anti-corrosion, microdilatancy compensate for shrinkage, and environment-protecting asepsis, its easy construction, saves time at the saving of labor.
Another object of the present invention provides a kind of preparation method of High Performance Mortar concrete inorganic environment-friendly water-proofing powder, and its operation row are simple, and processing condition require low, the efficient height, and cost is low.
Technical scheme of the present invention is: a kind of High Performance Mortar concrete inorganic environment-friendly water-proofing powder, and it comprises following component by mass percent: Tai-Ace S 150 1.5~2.0%, potassium aluminium sulfate 42~48%, ferrous sulfate 12~16%, sodium-chlor 1.5~2.5%, urea 1.5~2.5%, Sodium sulfate anhydrous.min(99) 1.5~2.5%, rubber powder 0.1~0.5%, flyash 30~35%; Described rubber powder is dispersibility latex powder or redispersible latex powder.
The further technical scheme of the present invention is: it comprises following component by mass percent: Tai-Ace S 150 1.9%, potassium aluminium sulfate 45%, ferrous sulfate 15%, sodium-chlor 2%, urea 2%, Sodium sulfate anhydrous.min(99) 2%, rubber powder 0.1%, flyash 32%.
The present invention further technical scheme is: it comprises following component by mass percent: Tai-Ace S 150 2%, potassium aluminium sulfate 42%, ferrous sulfate 15%, sodium-chlor 2%, urea 2.5%, Sodium sulfate anhydrous.min(99) 2.5%, rubber powder 0.5%, flyash 33.5%.
The also further technical scheme of the present invention is: described potassium aluminium sulfate is the dehydration potassium aluminium sulfate, and described flyash is I level flyash, and described rubber powder is a redispersible latex powder.
Another technical scheme of the present invention is: a kind of preparation method of High Performance Mortar concrete inorganic environment-friendly water-proofing powder, and it comprises that following technology is rapid step by step:
One, gets raw material
Obtain raw material according to following mass percent: Tai-Ace S 150 1.5~2.0%, potassium aluminium sulfate 42~48%, ferrous sulfate 12~16%, sodium-chlor 1.5~2.5%, urea 1.5~2.5%, Sodium sulfate anhydrous.min(99) 1.5~2.5%, rubber powder 0.1~0.5%, flyash 30~35%;
Two, the raw material of obtaining is made powder;
Three, raw material powder is mixed, stirs, make High Performance Mortar concrete inorganic environment-friendly water-proofing powder.
The present invention further another technical scheme is: second step, the described particles of powder degree of making was 100~150 orders.
The present invention further another technical scheme is: the raw materials quality per-cent that the first step obtains is: Tai-Ace S 150 1.9%, potassium aluminium sulfate 45%, ferrous sulfate 15%, sodium-chlor 2%, urea 2%, Sodium sulfate anhydrous.min(99) 2%, rubber powder 0.1%, flyash 32%.
Further again another technical scheme of the present invention is: the raw materials quality per-cent that the first step obtains is: Tai-Ace S 150 2%, potassium aluminium sulfate 42%, ferrous sulfate 15%, sodium-chlor 2%, urea 2.5%, Sodium sulfate anhydrous.min(99) 2.5%, rubber powder 0.5%, flyash 33.5%.
Main symbol and name resolving that the present invention uses are as follows:
Urea: another name carbonyl diamine, carboxamide, urea; By the organic compound that carbon, nitrogen, oxygen and hydrogen are formed, claim urea (with the urine unisonance) again; Its chemical formula is CON 2H 4, (NH 2) 2CO or CN 2H 4O.
Sodium sulfate anhydrous.min(99): sodium sulfate, mineral compound has another name called thenardite, and white, odorless, the crystallization that bitter taste is arranged or powder have water absorbability; Chemical Chinese: sodium sulfate; Chemical formula is Na 2SO 4
Rubber powder: be dispersibility latex powder or redispersible latex powder, be the multipolymer of ethylene/vinyl acetate, vinyl acetate between to for plastic/tertiary monocarboxylic acid ethylene copolymer, acrylic acid multipolymer or the like, with polyvinyl alcohol as protective colloid; For example, the TC-2016 that Mei Da Chemical Industry Science Co., Ltd in Henan produces is water-soluble redispersion powders, is the multipolymer of ethene, vinyl acetate, with polyvinyl alcohol as protective colloid; The polymer dispersion powder that the rich special architecture engineering material of Changsha company limited produces.
The waterproof principle of the present invention and characteristics: High Performance Mortar concrete inorganic environment-friendly water-proofing powder of the present invention is made by Tai-Ace S 150, potassium aluminium sulfate, ferrous sulfate, sodium-chlor, urea, Sodium sulfate anhydrous.min(99), rubber powder, flyash, ferrous sulfate has the expansion function, make open structure become compact structure, compensated the contraction of cement concrete, stopped up pore, filled fine pore, water molecules can't have been infiltrated pass through; Urea has the frost resistance effect to cement; Rubber powder has the cement dispersiveness, has strengthened the flowability to cement; After High Performance Mortar concrete inorganic environment-friendly water-proofing powder of the present invention mixed concrete mortar, can promote the aquation of cement granules, generate AL (OH) with the cement reaction 3(aluminium glue), C-S-H, a large amount of ettringite crystal etc. are crystalloid, colloidalmaterial, aluminium itself has anti-ultraviolet function and reflex action, mix the inorganic compounding effect that plays simultaneously by the crystal doping effect, reach connected effect, crystal growth is grown up, extruding towards periphery, the expansion that stops and offset the Cement Concrete fine fisssure, and by colloid associating one, colloid has entered in pore and the microfracture, thoroughly forms permanent firm waterproof construction in cement concrete, after producing microdilatancy, a large amount of filament structures disappear in the cement, and small discrete particle condenses into piece, wrong overlapping adding, produce in the water thing by the weak link of gathering materials one by one transitional zone obtained basic improvement; So, High Performance Mortar concrete inorganic environment-friendly water-proofing powder of the present invention is compound formulated by high-quality inorganic powders such as density component, expansion component and other additive, its water-proof function is remarkable, and has impervious, cracking resistance, freeze proof, anti-corrosion, functions such as workability is good, microdilatancy compensate for shrinkage; Its easy construction, cost is low.
In order to be illustrated more clearly in the present invention, enumerate following examples, but it there is not any restriction to scope of invention.
Embodiment
Embodiment 1
Get 1.9 kilograms in Tai-Ace S 150,45 kilograms of potassium aluminium sulfates, 15 kilograms in ferrous sulfate, 2 kilograms in sodium-chlor, 2 kilograms in urea, 2 kilograms of Sodium sulfate anhydrous.min(99), 0.1 kilogram of rubber powder, 32 kilograms in flyash; It is 100~150 purpose powder that these raw materials are worn into granularity; Successively raw material powder is mixed, stirs, make High Performance Mortar concrete inorganic environment-friendly water-proofing powder.
With the High Performance Mortar concrete inorganic environment-friendly water-proofing powder that makes, 3 quality % by cement mixing content in the mortar concrete are incorporated in the mortar concrete, and stir, make test block again, 10 test blocks are detected, the average behaviour index of each test block that obtains detecting is: the bleeding rate ratio is 35%, presetting period be 73min (minute), compressive strength rate is 3d 130%, 7d 109%, 28d 102%, the permeated height ratio is 38%, water demand ratio is 66%, and shrinkage ratio is 125%; Detected result meets JC474-2008 " mortar concrete water-resisting agent " standard.
Embodiment 2-7
Employed raw material of embodiment 2-7 and quality are shown in following table 1, and its preparation method and detection method are identical with embodiment 1; Following table 1 shows employed concrete raw material of embodiment 1-7 and quality; Wherein the potassium aluminium sulfate described in the embodiment 4-7 is the dehydration potassium aluminium sulfate, and described flyash is I level flyash (according to GB/T 1596-2005 national standard); Following table 2 shows the detection data of High Performance Mortar concrete inorganic environment-friendly water-proofing powder after use that embodiment 1-7 obtains, from the data that detect as can be seen, High Performance Mortar concrete inorganic environment-friendly water-proofing powder of the present invention has functions such as waterproof, impervious, cracking resistance, freeze proof, anti-corrosion, microdilatancy compensate for shrinkage.
Table 1
Table 2
Show from above detected result: embodiment 6 effects are best, all meet or exceed the requirement of GB acceptable end product.

Claims (8)

1. High Performance Mortar concrete inorganic environment-friendly water-proofing powder, it is characterized in that: it comprises following component by mass percent: Tai-Ace S 150 1.5~2.0%, potassium aluminium sulfate 42~48%, ferrous sulfate 12~16%, sodium-chlor 1.5~2.5%, urea 1.5~2.5%, Sodium sulfate anhydrous.min(99) 1.5~2.5%, rubber powder 0.1~0.5%, flyash 30~35%; Described rubber powder is dispersibility latex powder or redispersible latex powder.
2. High Performance Mortar concrete inorganic environment-friendly water-proofing powder according to claim 1, it is characterized in that: it comprises following component by mass percent: Tai-Ace S 150 1.9%, potassium aluminium sulfate 45%, ferrous sulfate 15%, sodium-chlor 2%, urea 2%, Sodium sulfate anhydrous.min(99) 2%, rubber powder 0.1%, flyash 32%.
3. High Performance Mortar concrete inorganic environment-friendly water-proofing powder according to claim 1, it is characterized in that: it comprises following component by mass percent: Tai-Ace S 150 2%, potassium aluminium sulfate 42%, ferrous sulfate 15%, sodium-chlor 2%, urea 2.5%, Sodium sulfate anhydrous.min(99) 2.5%, rubber powder 0.5%, flyash 33.5%.
4. according to claim 1 or 2 or 3 described High Performance Mortar concrete inorganic environment-friendly water-proofing powder, it is characterized in that: described potassium aluminium sulfate is the dehydration potassium aluminium sulfate; Described rubber powder is a redispersible latex powder.
5. the preparation method of a High Performance Mortar concrete inorganic environment-friendly water-proofing powder, it is characterized in that: it comprises that following technology is rapid step by step:
One, gets raw material
Obtain raw material according to following mass percent: Tai-Ace S 150 1.5~2.0%, potassium aluminium sulfate 42~48%, ferrous sulfate 12~16%, sodium-chlor 1.5~2.5%, urea 1.5~2.5%, Sodium sulfate anhydrous.min(99) 1.5~2.5%, rubber powder 0.1~0.5%, flyash 30~35%;
Two, the raw material of obtaining is made powder;
Three, raw material powder is mixed, stirs, make High Performance Mortar concrete inorganic environment-friendly water-proofing powder.
6. the preparation method of High Performance Mortar concrete inorganic environment-friendly water-proofing powder according to claim 5 is characterized in that: second step, the described particles of powder degree of making was 100~150 orders.
7. according to the preparation method of claim 5 or 6 described High Performance Mortar concrete inorganic environment-friendly water-proofing powder, it is characterized in that: the raw materials quality per-cent that the first step obtains is: Tai-Ace S 150 1.9%, potassium aluminium sulfate 45%, ferrous sulfate 15%, sodium-chlor 2%, urea 2%, Sodium sulfate anhydrous.min(99) 2%, rubber powder 0.1%, flyash 32%.
8. according to the preparation method of claim 5 or 6 described High Performance Mortar concrete inorganic environment-friendly water-proofing powder, it is characterized in that: the raw materials quality per-cent that the first step obtains is: Tai-Ace S 150 2%, potassium aluminium sulfate 42%, ferrous sulfate 15%, sodium-chlor 2%, urea 2.5%, Sodium sulfate anhydrous.min(99) 2.5%, rubber powder 0.5%, flyash 33.5%.
CN2011100964817A 2011-04-08 2011-04-08 High-property inorganic environment-friendly waterproof powder for mortar concrete and preparation method thereof Expired - Fee Related CN102211890B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112358225A (en) * 2020-10-21 2021-02-12 肖剑波 Composite waterproof agent and preparation method and application thereof
CN112851191A (en) * 2021-01-13 2021-05-28 武汉源锦建材科技有限公司 Compact anti-cracking waterproof agent for inhibiting early cracking of concrete and preparation method thereof
CN113278314A (en) * 2021-06-03 2021-08-20 何志刚 Wall surface decorative coating and preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1068803A (en) * 1992-07-25 1993-02-10 陈国忠 Mortar, concrete antiseeping waterproofing agent and method for making and application
CN1125703A (en) * 1994-12-29 1996-07-03 丁吉东 Fiuing material for building waterproofing powder
CN1634792A (en) * 2003-12-30 2005-07-06 陈晓光 Waterproof additives for building materials and method for making same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1068803A (en) * 1992-07-25 1993-02-10 陈国忠 Mortar, concrete antiseeping waterproofing agent and method for making and application
CN1125703A (en) * 1994-12-29 1996-07-03 丁吉东 Fiuing material for building waterproofing powder
CN1634792A (en) * 2003-12-30 2005-07-06 陈晓光 Waterproof additives for building materials and method for making same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
史美东: "混凝土抗裂防水剂ASA的试验研究", 《合肥工业大学学报(自然科学版)》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112358225A (en) * 2020-10-21 2021-02-12 肖剑波 Composite waterproof agent and preparation method and application thereof
CN112851191A (en) * 2021-01-13 2021-05-28 武汉源锦建材科技有限公司 Compact anti-cracking waterproof agent for inhibiting early cracking of concrete and preparation method thereof
CN113278314A (en) * 2021-06-03 2021-08-20 何志刚 Wall surface decorative coating and preparation method and application thereof

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