CN102205769A - Method for endowing surface of object with three-dimensional pattern - Google Patents
Method for endowing surface of object with three-dimensional pattern Download PDFInfo
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- CN102205769A CN102205769A CN2010101583409A CN201010158340A CN102205769A CN 102205769 A CN102205769 A CN 102205769A CN 2010101583409 A CN2010101583409 A CN 2010101583409A CN 201010158340 A CN201010158340 A CN 201010158340A CN 102205769 A CN102205769 A CN 102205769A
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Abstract
The invention relates to a method for endowing a surface of an object with a three-dimensional pattern, in particular to the method for endowing the surface of the object with a concave-convex pattern by using a hydraulic transfer-printing method. The invention provides the hydraulic transfer-printing method, which comprises the following steps of: forming a pattern layer on a water-soluble film according to a required pattern by using a first coating; covering a fixed plate layer which is formed by a second coating on the whole pattern layer to form a hydraulic transfer-printing film; coating an activating agent on the fixed plate layer; placing the hydraulic transfer-printing film which is coated with the activating agent on a water surface to make the hydraulic transfer-printing film unfolded; and placing the object to be transfer-printed on the hydraulic transfer-printing film, and pressing into water to make the hydraulic transfer-printing film cover the object so as to form the pattern on the surface of the object, wherein the activating agent can dissolve the fixed plate layer but cannot dissolve the pattern layer.
Description
Technical field
The present invention relates to object surface is given the method for space pattern, particularly, relate to and use method of hydraulic transfer object surface to be given the method for patterning of the concavo-convex sense of touch of tool.
Background technology
Known method of hydraulic transfer as shown in Figure 1, coated pattern layer 12 and form the hydraulic-transfer film on water-soluble films such as PVA 11 normally, on patterned layer 12, be coated with active agent layer 13 again, after making the coating activation, make on this hydraulic-transfer film that is coated with activator bubbles through the water column in patterned layer 12 mode up, then, object 14 to be transferred is pressed in the water 15, makes patterned layer be transferred to the surface of object 14 to be transferred thus.Utilize the mode of UV or heating to make patterned layer 12 and active agent layer 13 solidify adherence (combination) (Figure 1 shows that the situation that UV solidifies) then,, can obtain the figuratum object of transfer printing at last with water-soluble film 11 flush awaies.
In recent years, utilize method of hydraulic transfer to carry out the content spare etc. that technology that article surface modifies has been widely used in automobile-used, family expenses, but the technology of concavo-convex sense of touch is still expected to give object surface simultaneously in transfer printing in this area.
In the disclosed method of hydraulic transfer of Japanese patent laid-open 6-040198 communique, in coating, add wood powder, on object surface, cause the concave-convex effect of pattern thus.The formed relief pattern shape of this kind method is limited, and wood powder may influence the quality of pattern transferring.
In the disclosed method of hydraulic transfer of Japanese patent laid-open 7-276899 communique, form top coat (top coating) on the pattern transferring or on object to be transferred, forming priming coat (base coating), make top coat or priming coat form state, make the object surface after banding present concavo-convex sense of touch thus with jog.But this method only is fit to have the object of top coat, priming coat, and needs extra procedure of processing.
Disclosed method of hydraulic transfer in international open WO2009/054482 number, main purpose is for to form concavo-convex sense of touch at object surface.It has on transfer film by formed zone of patterned layer and the zone that do not have patterned layer, to this transfer film coating activator, when carrying out hydraulic-transfer, utilize the cohesiveness of activator itself and the repulsive interaction between coating and the activator, make unnecessary activator concentrate on the zone that transfer film does not have patterned layer, cause the activator effect more more protruding thus, to obtain the concavo-convex sense of touch of object surface than patterned layer.
Summary of the invention
Main purpose of the present invention is, under the prerequisite that does not increase unnecessary operating procedure, provides a kind of method of hydraulic transfer that can form concavo-convex sense of touch at the transfer printing object surface.
Method of hydraulic transfer of the present invention is to utilize first coating to form patterned layer according to required pattern on water-soluble film, follow whole solid flaggy that covering is made of second coating on patterned layer, and formation hydraulic-transfer film, on this hydraulic-transfer film, be coated with activator, and place and make its expansion on the water surface, place the object of desiring transfer printing on this hydraulic-transfer film that is coated with activator and be pressed into water, make this hydraulic-transfer film be coated on this object so that form pattern at object surface; Wherein, this activator solubilized is somebody's turn to do solid flaggy but can't be dissolved this patterned layer.
The method that forms above-mentioned patterned layer, solid flaggy or be coated with above-mentioned activator comprises printing, spraying, roller coat.
Between above-mentioned patterned layer and the solid flaggy, also can be dissolvable in water above-mentioned activator in order to this decoration that forms this decorative layer with coating as required further to decorate with the decorative layer more than coating formation one deck.
Above-mentioned activator is preferably the ray curing activator, more preferably ultraviolet hardening activator or electronic beam solidified activator.
In addition, above-mentioned " solubilized " among the present invention and the definition of " can't dissolve " see the aftermentioned explanation for details.
The present invention also provides and has utilized above-mentioned method of hydraulic transfer to band the object on surface, and the picture on surface of this object has concavo-convex sense of touch.
(invention effect)
According to the present invention, can be under the prerequisite that does not increase unnecessary operating procedure, utilize method of hydraulic transfer and form pattern at object surface with concavo-convex sense of touch.In addition, owing to do not need other special device or step, can be identical with cost control with known method of hydraulic transfer.Utilize the present invention, can be according to the step identical with known method of hydraulic transfer, give the pattern of the concavo-convex sense of touch of tool to object surface, and be applied to aspects such as the content spare of automobile-used, family expenses or electronic product shell, increase the attractive in appearance and ornamental of these content spares or electronic product.
Description of drawings
Fig. 1 is the technology of known method of hydraulic transfer.
Fig. 2 is the technology of method of hydraulic transfer of the present invention.
Fig. 3 is the schematic diagram of ongoing object of method of hydraulic transfer of the present invention and hydraulic-transfer film.
Fig. 4 is for before carrying out method of hydraulic transfer of the present invention, the schematic diagram of object and hydraulic-transfer film.
Fig. 5 is the pattern photo of embodiment 1 gained object surface, and this pattern scanned the figure (part only is shown) of drawing as the longitudinal axis as the height of projection (μ m) of transverse axis (mm), hydraulic-transfer object surface pattern with the part that is parallel to the hydraulic-transfer object surface with Alpha-step.
The specific embodiment
Below further describe method of hydraulic transfer of the present invention.
Method of hydraulic transfer of the present invention comprises following steps:
(1) prepares a water-soluble film;
(2) utilize first coating, on water-soluble film, form patterned layer according to required pattern;
(3) on above-mentioned patterned layer, utilize to decorate the decorative layer that forms with coating more than one deck as required;
(4) whole solid flaggy that covering is made of second coating on above-mentioned patterned layer or decorative layer;
(5) go up the coating activator and be deployed on the water surface at the water-soluble film of handling through above-mentioned steps (below be sometimes referred to as " hydraulic-transfer film ");
(6) object that will desire transfer printing places on this hydraulic-transfer film that is coated with activator and is pressed into water, makes this hydraulic-transfer film be coated on this object surface;
(7) for form figuratum above-mentioned object on the surface, use rays such as ultraviolet rays or electron beam to handle, this pattern and activator are solidified;
(8) above-mentioned water-soluble film is removed with water-washing method.
Among the present invention, by selecting the first suitable coating, second coating and activator (to make first coating be not dissolved in activator, and second coating is dissolvable in water activator), utilize the dissolubility difference between two kinds of coating and the activator, after hydraulic-transfer technology, can form the pattern of the concavo-convex sense of touch of tool at object surface.
Between patterned layer and solid flaggy, have under the situation of the decorative layer more than one deck, be dissolvable in water above-mentioned activator with coating in order to the decoration that forms this decorative layer.This decorative layer mainly with so that the pattern of object surface has more variation, therefore can form in the mode of figure, also can form in the mode of whole covering, decides on the demand of object surface pattern complexity.By the existence of decorative layer, can make the more object of horn of plenty of picture on surface and color change.
" dissolving " of indication of the present invention is defined as follows.The coating of printing or coating individual layer on blank PVA film, its thickness is about 1-2 μ m, is coated with 20g/ more thereon
M2Activator, carry out hydraulic-transfer technology.After if object is pressed into water, the hydraulic-transfer film that its surface can have been activated fully coats, then claim this activator " solubilized " this coating, otherwise, if object surface produces the folding line of hydraulic-transfer film, be that the hydraulic-transfer film can't complete coating object surface, then claim this activator " can't dissolve " this coating.
Followingly describe the present invention in detail with reference to Fig. 2.
Fig. 2 is the detailed process of method of hydraulic transfer of the present invention, is the simplified illustration content, and Fig. 2 only illustrates the hydraulic-transfer film and has most important " patterned layer " and " Gu flaggy ", and do not have also can exist can non-existent " decorative layer " situation.In addition, shown in Figure 2 is the example of ultraviolet ray (UV) curing type activator.Among Fig. 2, hydraulic-transfer film 1 comprises the solid flaggy 4 that patterned layer 3 that water-soluble film 2, first coating constituted and second coating are constituted.The hydraulic-transfer film forms patterned layer 3 according to required pattern on water-soluble film 2, then, whole ground forms solid flaggy 4 on patterned layer 3.When carrying out hydraulic-transfer, at first, whole coating activator on the solid flaggy 4 of hydraulic-transfer film 1, and formation active agent layer 5, then, object 6 is pressed in the water 7 across the hydraulic-transfer film 1 that is coated with active agent layer 5, makes the hydraulic-transfer film in water-soluble film 2 mode outwardly, be coated on the surface of object 6, with the surface of pattern transfer to object 6.Then, according to the kind of above-mentioned activator, object 6 is suitably handled (for example irradiation ultraviolet radiation or electron beam, Figure 2 shows that the situation of irradiation ultraviolet radiation), with activator and pattern cured, the last above-mentioned water-soluble film 2 of water flush away is finished the transfer printing of object.
Among the present invention, mainly utilize patterned layer 3 insoluble respectively with solid flaggy 4 and dissolve in the activator, hydraulic-transfer technology is finished after, only have the part of patterned layer to be raised in object surface, thereby form the concavo-convex sense of touch of object surface pattern.The reason of concavo-convex sense of touch that can realize the object surface pattern about method of hydraulic transfer of the present invention is as follows.
Fig. 3 is the schematic diagram when utilizing method of hydraulic transfer of the present invention to give pattern to object 6, and Fig. 4 then is the schematic diagram before being pressed into object in the water.Patterned layer 3 in the hydraulic-transfer film 1 of Fig. 4, solid flaggy 4 and the active agent layer 5 that was coated with afterwards when carrying out hydraulic-transfer, can roughly be mixed into one deck (part of representing with " A " among Fig. 3).Can't be dissolved in the activator owing to constitute first coating of patterned layer 3, therefore first coating keeps its original state in the A layer, only has second coating that constitutes solid flaggy can be dissolved in activator and form mixed solution.So, can become the state that contains " first coating " and " activator solution of second coating " in the A layer.Afterwards, first coating may be because object presses down the hydraulic pressure that is produced and embeds in the water-soluble film 2 (protrude from the interface of water-soluble film 2 and A layer, represent this interface with " B " among Fig. 3) during hydraulic-transfer.Utilize proper method to be solidified the mixed solution of solid flaggy 4 and active agent layer 5, so that patterned layer 3 is fixing, and behind the flush away water-soluble film 2, then can obtain the effect that pattern that patterned layer 3 constituted protrudes from object 6 surfaces.
Among the present invention, there is no particular restriction for the kind of water-soluble film 2, can use the water-soluble film that generally is used for hydraulic-transfer technology, for example polyvinyl alcohol (PVA) film etc.
There is no particular restriction for first coating and second coating, so long as can be used in the coating of hydraulic-transfer, and and activator between relation can above-mentioned qualification according to the invention, all can use.In addition, can add other outward appearance modifying agent in first coating and second coating according to demand, for example pearlite slurry etc.
Activator is mainly suitably selected according to employed first coating, second coating, so long as can be used in hydraulic-transfer and meet and first coating, second coating between the dissolubility relation, all can use.
The method that activator is solidified decide according to the kind of activator, preferably the use activator that can solidify via ray such as irradiation ultraviolet radiation or electron beam.
When utilizing the present invention to carry out hydraulic-transfer, the coating weight of activator does not have special restriction yet, is coated with according to the use amount of general technology to get final product, and for example can be 15～40g/m
2
The coating method of first coating, second coating and activator is not particularly limited, on the general industry employed coating process all can, for example can exemplify print process, spraying process, rolling method etc.
Among the present invention, when between patterned layer and solid flaggy, having under the situation of decorative layer, as long as after coating first coating, the decorative layer that earlier is coated with the required number of plies in the mode of figure or whole covering (as mentioned above as required, the employed coating of decorative layer (decorate and use coating) is dissolvable in water activator), whole more at last coating second coating gets final product, and all the other steps all need not change., also be not particularly limited with the coating method of coating as for applied decorative, on the general industry employed coating process all can, for example can exemplify print process, spraying process, rolling method etc.
Below enumerate embodiment, be described more specifically the present invention, but the present invention is not subjected to the restriction of following embodiment, variation, improvement that the technical staff of any the technical field of the invention can know by inference from content of the present invention all are covered by in the scope of the invention.
[embodiment]
(dissolubility of coating)
Printing or coating single layer coating on blank PVA film, its thickness is about 1-2 μ m, is coated with 20g/m more thereon
2Activator, put it in the water, carry out hydraulic-transfer technology.After if object is pressed into water, the hydraulic-transfer film that its surface can have been activated fully coats, then claim this activator " solubilized " this coating, otherwise, if object surface produces the folding line of hydraulic-transfer film, be that the hydraulic-transfer film can't complete coating object surface, then claim this activator " can't dissolve " this coating.
Use following printing ink and activator to carry out hydraulic-transfer.Employed printing ink is the coating of the commodity of Dongguan transfer printing Science and Technology Ltd. of wide section production HR-AA, HR-APB by name, HR-BA, HR-BPB, employed activator then is the product of the commodity HR-UAc by name of Dongguan transfer printing Science and Technology Ltd. of wide section production, wherein, by above-mentioned deliquescent test, judge HR-AA and HR-APB (outward appearance of coating is for being with blue pearly-lustre) coating " solubilized " in activator HR-UAc, HR-BA and HR-BPB (outward appearance of coating is for being with blue pearly-lustre) coating then " can't dissolve " in activator HR-UAc.
(embodiment 1)
On blank PVA film, utilize print process to form pattern,, utilize whole of rolling method to apply HR-AA coating more thereon, form solid flaggy, be prepared into a volume hydraulic-transfer glued membrane thus as patterned layer with HR-BA coating.Utilize spraying process coating one deck activator HR-UAc on this hydraulic-transfer glued membrane, coating weight is 30g/m
2, the material object with acrylonitrile-butadiene-styrene (ABS) (ABS) material, Merlon (PC) material or ABS and PC blend carries out hydraulic-transfer technology afterwards, obtains the hydraulic-transfer object of tool watermark printed patterns.
Utilize Canon EOS7D camera that the pattern of this hydraulic-transfer object surface is taken pictures, and Alpha-step instrument (model Dektak 150) with the Veeco corporate system, hydraulic-transfer pattern to object surface scans, and obtains about the pattern actual height data on the object surface everywhere.Utilize above-mentioned data, with the direction that is parallel to object surface as the height (μ m) of transverse axis (mm), hydraulic-transfer object surface pattern as the longitudinal axis, the graphics of gained is shown in Fig. 5 (part only is shown) together.Calculate the height flat average of the bossing of whole of hydraulic-transfer object surface pattern, the result is 11 μ m.
(embodiment 2)
On blank PVA film, utilize print process to form pattern,, utilize whole of rolling method to apply HR-AA coating more thereon, form solid flaggy, be prepared into a volume hydraulic-transfer glued membrane thus as patterned layer with HR-BPB coating.Utilize spraying process coating one deck activator HR-UAc on this hydraulic-transfer glued membrane, coating weight is 30g/m
2, the material object with acrylonitrile-butadiene-styrene (ABS) (ABS) material or Merlon (PC) material or ABS and PC blend carries out hydraulic-transfer technology afterwards, obtains the hydraulic-transfer object of the printed patterns of tool projection.Calculate the height flat average of the bossing of whole of hydraulic-transfer object surface pattern in mode similarly to Example 1, the result is 8 μ m.
(comparative example 1)
On blank PVA film, utilize print process to form pattern,, utilize whole of rolling method to apply HR-AA coating more thereon, form solid flaggy, be prepared into a volume hydraulic-transfer glued membrane thus as patterned layer with HR-APB coating.Utilize spraying process coating one deck activator HR-UAc on this hydraulic-transfer glued membrane, coating weight is 30g/m
2, the material object with acrylonitrile-butadiene-styrene (ABS) (ABS) material or Merlon (PC) material or ABS and PC blend carries out hydraulic-transfer technology afterwards, obtains the hydraulic-transfer object of the tool planographic pattern similar to the traditional water transfer printing.Calculate the height flat average of the bossing of whole of hydraulic-transfer object surface pattern in mode similarly to Example 1, the result is 1 μ m.
(comparative example 2)
On blank PVA film, utilize print process to form pattern,, utilize whole of rolling method to apply HR-BA coating more thereon, form solid flaggy, be prepared into a volume hydraulic-transfer glued membrane thus as patterned layer with HR-BPB coating.Utilize spraying process coating one deck activator HR-UAc on this hydraulic-transfer glued membrane, coating weight is 30g/m
2, the material object with acrylonitrile-butadiene-styrene (ABS) (ABS) material or Merlon (PC) material or ABS and PC blend carries out hydraulic-transfer technology afterwards, and glued membrane can't be activated, and can't finish hydraulic-transfer technology.
Result's arrangement of embodiment 1,2 and comparative example 1,2 is shown in table 1.
(table 1)
| Numbering | Patterned layer coating | Gu flaggy coating | The transfer printing effect | Average height of projection (μ m) |
| Embodiment 1 | HR-BA | HR-AA | The printing line projection of patterned layer has the 3-D effect of watermark | ?11 |
| |
HR-BPB | HR-AA | The printing line projection of patterned layer produces 3-D effect | ?8 |
| Comparative example 1 | HR-APB | HR-AA | Though the printing lines is arranged, does not have 3-D effect | ?1 |
| Comparative example 2 | HR-BPB | HR-BA | Can't carry out transfer printing | ?- |
Can more clearly find out by table 1, have only use can't be dissolved in the HR-BA of activator or HR-BPB coating as patterned layer and use the HR-AA that is dissolvable in water activator, carry out just can obtaining behind the hydraulic-transfer the concavo-convex sense of touch of pattern at object surface as solid flaggy.In other words, the embodiment 1 and 2 that meets the dissolubility relation of this case invention regulation between patterned layer coating and solid flaggy coating and the activator, just can obtain the concavo-convex sense of touch of hydraulic-transfer object surface pattern, and the comparative example 1 and 2 that the dissolubility that does not meet this case invention regulation between patterned layer coating and solid flaggy coating and the activator concerns, then can't obtain the concave-convex effect of hydraulic-transfer pattern, even can't carry out hydraulic-transfer.
(utilizability on the industry)
Method of hydraulic transfer of the present invention can be given concavo-convex sense of touch to the hydraulic-transfer object surface, can be applicable to the aspects such as the in-built object of automobile-used, family expenses or electronic product casing, increases the attractive in appearance and ornamental of these in-built objects or electronic product. Method of hydraulic transfer of the present invention does not need extra step, do not need special material and device yet, can give concavo-convex sense of touch to object surface, can not cause the hydraulic-transfer cost to increase, and can obtain object more attractive in appearance, the figuratum concavo-convex sense of touch of while tool, the industry purposes is extremely wide.
The primary clustering symbol description
1 hydraulic-transfer film
2,11 water-soluble films
3,12 patterned layer
4 solid flaggies
5,13 active agent layer
6,14 objects
7,15 water
A patterned layer, solid flaggy mix the layer that constitutes with active agent layer
The interface of B water-soluble film and A layer.
Claims (8)
1. method of hydraulic transfer, utilize first coating on water-soluble film, to form patterned layer according to required pattern, follow whole solid flaggy that covering is made of second coating on patterned layer, form the hydraulic-transfer film, on described solid flaggy, be coated with activator, the described hydraulic-transfer film that is coated with activator placed make its expansion on the water surface, place the object of desiring transfer printing on the described hydraulic-transfer film and be pressed into water, make described hydraulic-transfer film be coated on described object so that form pattern at object surface; Wherein, the described solid flaggy of described activator solubilized but can't dissolve described patterned layer.
2. method of hydraulic transfer according to claim 1 wherein, between above-mentioned patterned layer and above-mentioned solid flaggy, further has to decorate with the decorative layer more than the formed one deck of coating, and described decoration is dissolvable in water above-mentioned activator with coating.
3. method of hydraulic transfer according to claim 1 and 2, wherein, the method that forms above-mentioned patterned layer, solid flaggy, decorative layer or be coated with above-mentioned activator is print process, spraying process or rolling method.
4. method of hydraulic transfer according to claim 1 and 2, wherein, the ray curing activator that above-mentioned activator solidifies for utilizing ray.
5. method of hydraulic transfer according to claim 4, wherein, above-mentioned ray curing activator is ultraviolet hardening activator or electronic beam solidified activator.
6. according to each described method of hydraulic transfer in the claim 1,2 or 5, wherein, through the above-mentioned object that above-mentioned hydraulic-transfer film coats, its surface has concavo-convex sense of touch.
7. method of hydraulic transfer according to claim 3, wherein, through the above-mentioned object that above-mentioned hydraulic-transfer film coats, its surface has concavo-convex sense of touch.
8. method of hydraulic transfer according to claim 4, wherein, through the above-mentioned object that above-mentioned hydraulic-transfer film coats, its surface has concavo-convex sense of touch.
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201010158340 CN102205769B (en) | 2010-03-30 | 2010-03-30 | Method for endowing surface of object with three-dimensional pattern |
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| CN 201010158340 CN102205769B (en) | 2010-03-30 | 2010-03-30 | Method for endowing surface of object with three-dimensional pattern |
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| CN102205769A true CN102205769A (en) | 2011-10-05 |
| CN102205769B CN102205769B (en) | 2013-07-17 |
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| CN103862904A (en) * | 2012-12-11 | 2014-06-18 | 黄北江 | Surface coating film |
| CN103950308A (en) * | 2014-04-29 | 2014-07-30 | 中山市东鹰包装制品有限公司 | Preparation method of free-spraying water gage |
| CN104078762A (en) * | 2014-06-27 | 2014-10-01 | 航天特种材料及工艺技术研究所 | Method for forming frequency selective surface structure on folding-unavailable curved surface |
| CN113910798A (en) * | 2021-09-16 | 2022-01-11 | 美盈森集团股份有限公司 | Paper pulp molding water transfer printing method |
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| CN1860036A (en) * | 2003-09-30 | 2006-11-08 | 大日本油墨化学工业株式会社 | Hydraulic transfer film and hydraulic transfer body |
| CN1918009A (en) * | 2004-02-18 | 2007-02-21 | 泰卡株式会社 | Hydraulic transfer product |
| CN101112837A (en) * | 2007-09-12 | 2008-01-30 | 吕海萍 | Process for water transferring on the surface of large workpiece and equipment thereof |
| CN101125736A (en) * | 2006-08-15 | 2008-02-20 | 刘松坡 | Method for manufacturing wood grain and marble glass |
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| JP2004034393A (en) * | 2002-07-01 | 2004-02-05 | Dainippon Ink & Chem Inc | Film for hydraulic transfer and manufacturing method for hydraulic transfer body using the same |
| JP2004358681A (en) * | 2003-06-02 | 2004-12-24 | Cubic:Kk | Method for forming ultraviolet-curable surface protecting layer on article and product obtained by this method |
| CN1860036A (en) * | 2003-09-30 | 2006-11-08 | 大日本油墨化学工业株式会社 | Hydraulic transfer film and hydraulic transfer body |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103862904A (en) * | 2012-12-11 | 2014-06-18 | 黄北江 | Surface coating film |
| CN103862904B (en) * | 2012-12-11 | 2016-12-21 | 黄北江 | A kind of water transfer surface coating thin film |
| CN103950308A (en) * | 2014-04-29 | 2014-07-30 | 中山市东鹰包装制品有限公司 | Preparation method of free-spraying water gage |
| CN104078762A (en) * | 2014-06-27 | 2014-10-01 | 航天特种材料及工艺技术研究所 | Method for forming frequency selective surface structure on folding-unavailable curved surface |
| CN104078762B (en) * | 2014-06-27 | 2017-02-22 | 航天特种材料及工艺技术研究所 | Method for forming frequency selective surface structure on folding-unavailable curved surface |
| CN113910798A (en) * | 2021-09-16 | 2022-01-11 | 美盈森集团股份有限公司 | Paper pulp molding water transfer printing method |
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| Publication number | Publication date |
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| CN102205769B (en) | 2013-07-17 |
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