CN102191144B - Microemulsion spraying agent - Google Patents
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- CN102191144B CN102191144B CN 201010127825 CN201010127825A CN102191144B CN 102191144 B CN102191144 B CN 102191144B CN 201010127825 CN201010127825 CN 201010127825 CN 201010127825 A CN201010127825 A CN 201010127825A CN 102191144 B CN102191144 B CN 102191144B
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Abstract
The invention relates to a microemulsion spraying agent applicable to the daily washing industry. Technically, the microemulsion spraying agent is characterized by spraying agent in form and cleaning compositions of the microemulsion system in content. The agent, as a transparent microemulsion, mainly comprises a fatty alcohol polyethylene oxide nonionic surfactant or a fatty alcohol ethylene oxide-propylene oxide block polyether nonionic surfactant, one or several polyol nonionic surfactants, one or several alkane solvents, one or several ether solvents, one or several alcohol cosurfactants, a builder, water and a composite corrosion inhibitor. The invention is characterized in that application of the microemulsion system serving as the aerosol content for local decontamination of fabrics enjoys strong permeability. The agent, containing enzyme preparation added therein, has an enhanced decontamination effect. In the invention, propyl butane or dimethyl ether as the propellent, is completely soluble in the microemulsion system. Therefore, the aerosol can be guaranteed with stable using effect and quality.
Description
Technical field:
The present invention relates to the local pollution-removing spraying agent of microemulsion type fabric and feed liquid composition thereof, be applied to daily washing industry, said composition is the transparent micro emulsion that contains alkane solvent and kinds of surface promoting agent mixture.
Technical background
Local decontamination often at be the stupid dirt that common washing composition is difficult to remove, so to the having relatively high expectations of the detersive power of this class purposes product, particularly at the oils spot, most modes that adopt dissolution with solvents.But solvent is directly exposed in the air, can pollute environment, the people is known from experience damage.The present invention adopts microemulsion system to carry out decontamination, when having strengthened detersive efficiency, has the advantage of environmental protection and safety.The adoption of innovation aerosol form makes system form countless tiny dispersion microemulsions under atomize simultaneously, greatly strengthens its penetrating power, makes decontamination more thorough.
Microemulsion is the thermodynamic stable system of spontaneous formation under each component appropriate proportioning, normally mixed with tensio-active agent and medium chain alcohol by water, oil, can spontaneously form transparent and translucent dispersion system, also can utilize the polarity nonionogenic tenside under the condition that does not add alcohol, to obtain.Microemulsion is compared with common milk sap, and have special nature: interfacial tension is little, is generally 10
-5N/m～10
-9N/m; The micella particle is very little, and diameter is about 10nm～100nm; Thermodynamics is more stable, can spontaneously form, and does not need the external world that energy is provided, and separates through high speed centrifugation demixing phenomenon does not take place; Appearance transparent or intimate transparent.Just because of the microemulsion special nature, the performance of its cleaning aspect very outstanding (progress of microemulsion and application, household chemicals science, Hu Lili etc., 2007,30).
Because microemulsion has ultra low interfacial tension and stronger emulsification, solubilising, dispersion, foaming, lubricated and flexibility etc., therefore can be applicable to industry such as tertiary oil recovery, detergents and cosmetic, food, agricultural chemicals, environment protection and be used for multiple fields such as assay determination, the material of material is synthetic, micro emulsion polymerization, biochemical reaction as reaction medium.So, in household chemicals field, the use of microemulsion in the local decontamination of fabric is extremely poor, and introduces zymin and yet there are no report with the application of spray form in microemulsion.
In the local decontamination of fabric many patent reports are arranged, for example the collar cleaner of aerosol for dry cleaning, difference in functionality, bar-shaped collar cleaner etc.According to present application state, we find that there is scarce limit in various degree in all kinds of products, as having reported a kind of cleaning liquid aerosol among the CN1143108A, so it has adopted a large amount of volatile solvents, can have bad consequence to environment and HUMAN HEALTH like this; A kind of solvent-borne type pre-cleaning agent of reporting among the CN 1354232A, solvent is big, and environmental pollution is serious, and in addition, several spots of suitable limitation only can be effectively removed in this invention; And in the prior art, many researchists point out that adding enzyme auxiliary agent in existing system is that a cost is higher, unstable products, the actually operating difficulty, be not suitable for suitability for industrialized production, a kind of emulsion fabric decontaminating aerosol as the CN101643689 report, its content is ordinary emulsion type composition, the micella particle is very big, is 10～1000 times of microemulsion micella material for making clothes diameter, and is stable poor, under the influence of propellent, this defective is more outstanding, is difficult to keep homogeneous to disperse, and the quality weighing apparatus in the whole process that guarantees to use is fixed.And its excellent Environmental Safety of microemulsion and cleaning performance be allowed to condition at seem in all kinds of systems that comparatively outstanding H-D Dorr husband reins in, A Ge Luosi, moral Leix step on (moral) (Zhou Jingyi, Xing Yingzhan translate in " micro emulsion is as the application of cleaning medium ", the 2nd phase of household chemicals science, in April, 1998) discussed microemulsion enhancement to decontamination in fabric washing in.
The invention solves the influence of each set of dispense comparison system formation microemulsion of prescription, can make system in wideer water oil ratio interval, form the microemulsion of stable transparent.And microemulsion system mixes the energy good dispersion mutually with propellent, the stability of new system after the assurance adding propellent.Owing to contain water solvent, make the washing composition that the contains organic solvent environmental friendliness more that becomes, softer with skin contact, also strengthened the security of aerosol jar simultaneously.The adding of auxiliary agents such as enzyme more can make clean effect better.
Summary of the invention
The present invention relates to a kind of daily washing industry that is applied to, the local pollution-removing spraying agent of the enzyme-added fabric of the microemulsion type that designs at the various stains of fabric, the present invention has stronger perviousness, the adoption of innovation microemulsion system has solved the fabric part and has removed to steep solvent height in the aerosol, is unfavorable for the shortcoming of safety and environmental protection; And solved (as adopting the form of aerosol) under normal conditions, propellent can exert an influence to the stability of feed liquid system, destroys this problem of original balance, makes the microemulsion system of feed liquid form even dispersion with propellent liquid in aerosol jar high pressure; In addition, also solved in the aerosol system, be difficult to add the problem of zymin.Its technical characterictic is for adopting spray form, content is the cleaning based composition of microemulsion system, it mainly contains 5%～40% poly alkyl alcohol ethylene oxide nonionogenic tenside or Fatty Alcohol(C12-C14 and C12-C18) oxyethane propylene oxide block polymerization ethers nonionogenic tenside, 4%～35% polyalcohols nonionogenic tenside, 5%～60% alkane solvents, the pure ether solvent of 0%-30%, 5%～40% alcohols cosurfactant, 0.001%～20% washing assistant, the transparent micro emulsion of 1%～80% water and 0.01%～0.5% composite corrosion-proof erosion agent.The present invention is applicable to the Local treatment of each kind fabric, and fuller closing or the not removal of saturated fat, alkanes or other oil-dirt and the removal of some protein spots is such as sebum, edible oil, shoe polish, lipstick, grass juice factor etc.
Except the propellent consumption was 10%～30% this quantity of sprays feed liquid total amount, the many fingers of indication content of the present invention did not comprise the weight percent content of the microemulsion feed liquid of propellent.The present invention attempts to prepare the daily product of environmental protection more and safety, so tensio-active agent that does not adopt the good alkylphenol-polyethenoxy class of various aspects of performance to be difficult to degrade, for the preferred higher alkane solvents of boiling point of choosing yet of solvent, such selection is not to decide for itself the performance of filling a prescription.
Microemulsion exists three kinds of phase: O/W, co-continuous phase, W/O phase, because the feature of microemulsion, when microemulsion is in the co-continuous phase time, the situation that exists system viscosity to increase fast when oil is had bigger solubilizing amount, when implementing the preparation microemulsion composition, should note regulating each set of dispense ratio and consumption, do not make microemulsion viscosity surpass certain limit as far as possible, can normally spray use to guarantee the aerosol jar.
The tensio-active agent that the present invention adopts is mainly two classes, and the one, poly alkyl alcohol ethylene oxide nonionogenic tenside or Fatty Alcohol(C12-C14 and C12-C18) oxyethane propylene oxide block polymerization ethers nonionogenic tenside, the one, polyalcohols nonionogenic tenside.Owing to be microemulsion system, also can partly add anion surfactant, non-limiting example of the present invention comprises C11～18 alkylbenzene sulfonates, the vitriol of C10～20 primary alkyls, branched-chain alkyl and any alkyl, C10～18 alkyl alkoxy sulfates.Poly alkyl alcohol ethylene oxide nonionogenic tenside can be primary alkyl or C4～16 that contain side chain, the poly alkyl alcohol ethylene oxide nonionogenic tenside of 3～13 ethoxylation numbers, the compound nonionogenic tenside of preferred employing, be more preferably and contain two or more ethoxylation number and differ 5～7 poly alkyl alcohol ethylene oxide nonionogenic tenside mixture, more preferably contain the poly alkyl alcohol ethylene oxide nonionogenic tenside that carbonatoms on average differs 6～8 carbon atoms in addition.Can add C4～16, block ethoxylation number and propoxylation number in addition and add up to 4～20 polyethers nonionogenic tenside.These two kinds non-polyalcohols nonionogenic tensides consumption altogether are 5～40%.
Polyalcohols nonionogenic tenside of the present invention is characterized by one or more this type of nonionogenic tensides.Selectable but be not limited to glycerol mono fatty acid ester arranged, dialycerides fat acid esters, fatty acid triglyceride, the glycerine monopalmitate, glycerine palm fibre two palmitic acid acid esters, glycerine list myristic acid, glycerine two myristinates, glyceryl monolaurate, Lauric acid, diester with glycerol, xylitan monostearate, sorbitan mono-laurate, the anhydrous sorbitol monopalmitate, sorbitan monooleate, sorbitan monostearate, Witconol AL 69-66 and anhydrous sorbitol tristearate, polyoxyethylene 20 sorbitan monolaurate, polyoxyethylene 20 sorbitan monolaurate, polyoxyethylene 20 sorbitan monopalmitate, polyoxyethylene 20 sorbitan monostearate, polyoxyethylene 20 sorbitan monostearate, polyoxyethylene 20 sorbitan tristearate, polyoxyethylene 20 sorbitan monooleate, polyoxyethylene 20 sorbitan monooleate, polyoxyethylene 20 sorbitan trioleate, Surfhope SE Cosme C 1216, Surfhope SE Cosme C 1616, Sugar Ester O 1570, sucrose stearate, the sucrose monoricinolein, Polyglycerine poly monoricinoleins etc., its consumption is 4%～35%.
The alkane solvents that uses among the present invention is the oil phase in the system, itself has the good solvency action of deoiling simultaneously, and is on-consumable ozonosphere material, in system important effect is played in decontamination.Selectedly can be the mixture of the alkane derivative that contains 8 to 22 carbon atoms of positive structure or isomery, be preferably boiling point and be the alkane derivative more than 180 ℃, preferred purpose mainly not exclusively is because the demand of prescription own, but for the volatile organic compounds (VOC) that makes prescription itself drops to minimumly, and make the environmental friendliness more of filling a prescription.The low-carbon alkanes solvent has stronger solubility property as a rule, also might be more conducive to the raising of the whole detergency ability of system, but can produce detrimentally affect to environment.The present invention can make the high boiling alkane kind solvent bring into play the effect of its maximum in system by adjusting selection and the consumption of each component raw material.The alkane solvents consumption be in the claim 1 total composition 5～60%.
The present invention alcohol ether solvent can use a kind of, two or more or do not use with the variation of other component in the system, its feature is exemplified as butyl glycol ether, propylene glycol propyl ether, ethylene glycol ethanol, diethylene glycol ether, Diethylene Glycol propyl ether, propylene glycol butyl ether, diethylene glycol methyl ether, butyl carbitol, triglycol methyl ether, triglycol ether, triglycol propyl ether etc., be preferably the arbitrary solvent with the system no-float, in the view volume system other set of dispense than and decide, more preferably volatile organic compounds (VOC) is low, and with the pure ether solvent of system no-float.Preferred purpose is environmentally friendly for component, and is not to be entirely component prescription consideration itself.Alcohol ether solvents also plays an important role in cleaning as coupling agent and the solvent of excellent property, can be to a certain extent the effective intermiscibility of each system in the blending component, pure ether solvent consumption be in the claim 1 total composition 0～30%.
Pure analog assistant is characterized as one or more alcohol compounds among the present invention, selectable but be not limited to have 1,2～propylene glycol, 1, ammediol, Virahol, butanols, dipropylene glycol, amylalcohol, n-hexyl alcohol, n-Heptyl alcohol, 2,4-dimethylbutadio, primary isoamyl alcohol, monohydroxy-alcohols such as isohexyl alcohol, hexylene glycol, dibasic alcohol or trivalent alcohol.Play a role in system as cosurfactant.This type of alcohols auxiliary dosage be in the claim 1 total composition 5%～40%.
Added zymin among the present invention, expansion has promoted decontamination scope and usefulness.Optional enzyme can comprise following one or more enzymes: proteolytic enzyme, amylase, cellulase, at, lipase, carbohydrase and their prozyme.Be not limited to add various enzyme stabilizers, selectable stabiliser system has calcium or magnesium compound, boron compound, aromatic boric acid ester, peptide and peptide derivant, polyvalent alcohol, Fatty Alcohol(C12-C14 and C12-C18), low molecular weight carboxylic acid's salt, relative hydrophobic organic compound (as the alcoxylates of dialkyl group glycol ether, alcohol), alkyl ether carboxy acid salt, benzamidine hypochlorite, methacrylic acid methyl acrylate copolymer, lignin compound, polyamide oligomer as well as, oxyacetic acid, N, the mixture of N-two-3-aminopropyl lauryl amine or its salt and above compound etc.Also can select the product of the marketization, as the Sai Wei of Novozymes Company, wave power, beautiful ripple, beautiful group etc., the major part in them has all added stablizer simultaneously.The add-on of enzyme can be regarded as market zymin finished product among the present invention, also can be regarded as zymin and enzyme stabilizers total amount, and concrete consumption is decided as circumstances require.
Composite spray of the present invention can add white dyes or SYNTHETIC OPTICAL WHITNER in order further to improve whiteness.Wherein white dyes is known and fluorescent agent can be in commercial acquisition.Usually, these fluorescent agents with its an alkali metal salt for example the form of sodium salt be supplied and use.The white dyes of preferred classes is distyryl biphenyl compound, diamines stilbene disulfonic acid compound and pyrazoline compounds.Wherein, SYNTHETIC OPTICAL WHITNER can be peroxy bleaching agent compound such as inorganic tartaric acid salt or organic peroxide acid.
Composite spray of the present invention can add perfume compound in order further to improve aroma effect.Useful fragrance components comprises the material in natural and synthetic source.They comprise simplification compound and mixture.
Composite spray of the present invention is the migration that prevents dyestuff, has used the typical polymkeric substance of modern detergent compositions as dying transfer inhibitor.These dyestuff inhibitor comprise polyvinylpyrrolidonepolymers polymers, polyamine N-oxide pllymers, the multipolymer of N-vinyl pyrrolidone and N-vinyl imidazole, manganese phthalocyanine, peroxidase etc.
The present invention also can add a small amount of anion surfactant and chlorate, vitriol or silicates.
Owing to be aerosol, aerosol adopts materials such as tinplate, aluminium to make usually, so moisture product has to consider etching problem, though the component of stating among the present invention prescription pH value levels off to 7, the degree that corrosion takes place under the condition of sealing fully is lower, but for safety, still need add corrosion inhibitor.Used among the present invention that composite corrosion-proof erosion agent is selectable a potassium bichromate, sulfonate (calcium sulphonate, sodium sulfonate and barium sulfonate), carboxylic acid and its esters (dodecenylsuccinic acid, zinc naphthenate, n-oleoyl sarcosine stearylamine salt), trolamine, monoethanolamine, triethanolamine oleate, phenylformic acid amine, hexamethylenetetramine, benzotriazole, organic phosphate, imidazoline salt, volatile salt and amine, organic amine, mercaptan, thiocarbamide, pyridine derivate, anils compounds or directly select the composite corrosion inhibitor of the marketization.
Composition of the present invention can form transparent or semitransparent washing liq after 100 to 500 times of water dilutions.
The local decontamination of the described fabric of this explanation claim does not comprise all proportioning compositions entirely with composite spray, only comprises forming the composition that homogeneous disperses the transparence microemulsion.This illustrates that the local pollution-removing spraying agent composition of described fabric uses tinplate, aluminum or other metal or matrix material aerosol jar processed canned, also can adopt other canned form.The present invention is applicable to the Local treatment of each kind fabric, fuller closing or the not removal of saturated fat, alkanes or other oil-dirt and the removal of some protein spots, such as sebum, edible oil, shoe polish, lipstick, grass juice factor etc., has outstanding washing effect.Using method for the aerosol that is fit to composition feed liquid and propellent carry out canned after, use aerosol to be sprayed onto the not dirty place of fabric of adhesional wetting, several minutes post-flush or hand-launder to greasiness removal, also can be used as the preceding pre-washing agent of laundry machine washing, after hydrojet is placed as previously mentioned, put normal washing in the washing machine.
Specific embodiment:
Embodiment one:
Fatty alcohol-polyoxyethylene ether (C4～6, ethoxylation number are 5～15): 1
Fatty alcohol-polyoxyethylene ether (C12～14, ethoxylation number are 3): 6
Fatty alcohol-polyoxyethylene ether (C12～14, ethoxylation number are 7): 18
Aliphatic alcohol polyethenoxy gathers the third ethylene block condensation polymerization (C4～10, block ethoxylation and propylated number add up to 5～15): 1
The alkanes mixture (C8～C20): 16
Glycol ether: 9
Propylene glycol: 6
Butyl glycol ether: 11
Sugar Ester O 1570: 4
Proteolytic enzyme: 0.25
Composite corrosion-proof erosion agent: 0.2
Water: surplus
Above each component is mixed, stir the back a little and wait for very bell one-tenth clear solution, use can, (wherein propane is 16%～20% to charge into 18% third butane gas of above each component gross weight, Trimethylmethane is 80%～84%), namely get the enzyme-added microemulsion aerosol of the local pre-treatment of fabric.
Embodiment two:
Fatty alcohol-polyoxyethylene ether (C4～6, ethoxylation number are 5～15): 3.2
Fatty alcohol-polyoxyethylene ether (C12～14, ethoxylation number are 3): 9.2
Fatty alcohol-polyoxyethylene ether (C12～14, ethoxylation number are 7): 4
Glyceryl monolaurate: 6
The alkanes mixture (C8～C20): 13
Propylene glycol: 10
Triglycol propyl ether: 2
White dyes (2-(4-styryl-3-sulfo group phenyl)-2H-naphtho-[1,2-d] triazole sodium): 0.13
Enzyme (Sai Wei): 0.25
Composite corrosion-proof erosion agent: 0.2
Water: surplus
Above each component is mixed, stir the back a little and wait for very bell one-tenth clear solution, use can, (wherein propane is 16%～20% to charge into 18% third butane gas of above each component gross weight, Trimethylmethane is 80%～84%), namely get the enzyme-added microemulsion aerosol of the local pre-treatment of fabric.
Embodiment three:
Fatty alcohol-polyoxyethylene ether (C4～6, ethoxylation number are 5～15): 4
Fatty alcohol-polyoxyethylene ether (C12～14, ethoxylation number are 3): 15
Fatty alcohol-polyoxyethylene ether (C12～14, ethoxylation number are 9): 6
Aliphatic alcohol polyethenoxy gathers the third ethylene block condensation polymerization (C6～15, block ethoxylation and propylated number add up to 4～9): 5
The alkanes mixture (C8～C20): 30
Dibasic alcohol (2,4-dimethylbutadio): 16
Polyoxyethylene 20 sorbitan monolaurate: 8
Enzyme (beautiful group): 0.25
Composite corrosion-proof erosion agent; 0.2
Water: surplus
Above each component is mixed, stir the back a little and wait for very bell one-tenth clear solution, use can, (wherein propane is 16%～20% to charge into 18% third butane gas of above each component gross weight, Trimethylmethane is 80%～84%), namely get the enzyme-added microemulsion aerosol of the local pre-treatment of fabric.
Claims (17)
1. microemulsion type sprays is characterized in that weight percent concentration by each component of the following weight percent concentration that does not comprise propellent and sprays feed liquid total amount is that the propellent of 10%-30% is formed:
A, the composition of one or more in 5%～40% poly alkyl alcohol ethylene oxide nonionogenic tenside, the Fatty Alcohol(C12-C14 and C12-C18) oxyethane propylene oxide block polymerization ethers nonionogenic tenside
B, one or more polyalcohols nonionogenic tensides of 4%～35%
C, one or more alkane solvents of 5%～60%
D, the pure ether solvent of one or more of 2%～30%
E, one or more alcohols cosurfactants of 5%～40%
F, 0.001%～20% washing assistant
G, 0.01%～0.5% composite corrosion-proof erosion agent
H, 1%～80% water
Wherein, a-h component sum is 100%, washing assistant is the mixture of zymin and other washing assistant, and other washing assistant is one or more the composition in whitening agent, perfume compound, sequestrant, antiseptic-germicide, anti-dyestuff transfer inhibitor, suds suppressor, anion surfactant, chlorate, vitriol, the silicate.
2. microemulsion type sprays is characterized in that weight percent concentration by each component of the following weight percent concentration that does not comprise propellent and sprays feed liquid total amount is that the propellent of 10%-30% is formed:
A, the composition of one or more in 5%～40% poly alkyl alcohol ethylene oxide nonionogenic tenside, the Fatty Alcohol(C12-C14 and C12-C18) oxyethane propylene oxide block polymerization ethers nonionogenic tenside
B, one or more polyalcohols nonionogenic tensides of 4%～35%
C, one or more alkane solvents of 5%～60%
D, one or more alcohols cosurfactants of 5%～40%
E, 0.001%～20% washing assistant
F, 0.01%～0.5% composite corrosion-proof erosion agent
G, 1%～80% water
Wherein, a-g component sum is 100%, washing assistant is the mixture of zymin and other washing assistant, and other washing assistant is one or more the composition in whitening agent, perfume compound, sequestrant, antiseptic-germicide, anti-dyestuff transfer inhibitor, suds suppressor, anion surfactant, chlorate, vitriol, the silicate.
3. a kind of microemulsion type sprays as claimed in claim 1 or 2, it is characterized in that described poly alkyl alcohol ethylene oxide nonionogenic tenside is 4～16 carbonatomss, one or more in the poly alkyl alcohol ethylene oxide nonionogenic tenside of 3～13 ethoxylation numbers.
4. a kind of microemulsion type sprays as claimed in claim 1 or 2 is characterized in that described Fatty Alcohol(C12-C14 and C12-C18) oxyethane propylene oxide block polymerization ethers nonionogenic tenside is that 4～16 carbonatomss, block ethoxylation number and propoxylation number add up to one or more in 4～20 the polyethers nonionogenic tenside.
5. a kind of microemulsion type sprays as claimed in claim 1 or 2 is characterized in that described poly alkyl alcohol ethylene oxide nonionogenic tenside accounts for more than 50% of a class constituent total amount.
6. a kind of microemulsion type sprays as claimed in claim 1 or 2 is characterized in that described poly alkyl alcohol ethylene oxide nonionogenic tenside differs 5～7 poly alkyl alcohol ethylene oxide nonionogenic tenside mixture for two or more ethoxylation number.
7. a kind of microemulsion type sprays as claimed in claim 1 or 2 is characterized in that described poly alkyl alcohol ethylene oxide nonionogenic tenside is for containing the poly alkyl alcohol ethylene oxide nonionogenic tenside that carbonatoms on average differs 6～8 carbon atoms in addition.
8. a kind of microemulsion type sprays as claimed in claim 1 or 2, it is characterized in that described polyalcohols nonionogenic tenside is glycerol mono fatty acid ester, dialycerides fat acid esters, fatty acid triglyceride, the glycerine monopalmitate, glycerine palm fibre two palmitic acid acid esters, glycerine list myristic acid, glycerine two myristinates, glyceryl monolaurate, Lauric acid, diester with glycerol, xylitan monostearate, sorbitan mono-laurate, the anhydrous sorbitol monopalmitate, sorbitan monooleate, sorbitan monostearate, Witconol AL 69-66 and anhydrous sorbitol tristearate, polyoxyethylene 20 sorbitan monolaurate, polyoxyethylene 20 sorbitan monolaurate, polyoxyethylene 20 sorbitan monopalmitate, polyoxyethylene 20 sorbitan monostearate, polyoxyethylene 20 sorbitan monostearate, polyoxyethylene 20 sorbitan tristearate, polyoxyethylene 20 sorbitan monooleate, polyoxyethylene 20 sorbitan monooleate, polyoxyethylene 20 sorbitan trioleate, Surfhope SE Cosme C 1216, Surfhope SE Cosme C 1616, Sugar Ester O 1570, sucrose stearate, the sucrose monoricinolein, in the Polyglycerine poly monoricinolein one or several.
9. a kind of microemulsion type sprays as claimed in claim 1 or 2 is characterized in that described alkane solvents is the mixture of the alkane derivative that contains 8 to 22 carbon atoms of positive structure or isomery.
10. a kind of microemulsion type sprays as claimed in claim 1 is characterized in that described pure ether solvent is one or more in butyl glycol ether, propylene glycol propyl ether, ethylene glycol ethanol, diethylene glycol ether, Diethylene Glycol propyl ether, propylene glycol butyl ether, diethylene glycol methyl ether, butyl carbitol, triglycol methyl ether, triglycol ether, the triglycol propyl ether alcohol ether compound.
11. a kind of microemulsion type sprays as claimed in claim 1 or 2, it is characterized in that described alcohols cosurfactant is the composition of one or more alcohol compounds, selectable pure analog assistant has 1,2-propylene glycol, 1, ammediol, Virahol, butanols, dipropylene glycol, amylalcohol, n-hexyl alcohol, n-Heptyl alcohol, 2,4-dimethylbutadio, primary isoamyl alcohol, one or more in isohexyl alcohol, the hexylene glycol.
12. a kind of microemulsion type sprays as claimed in claim 1 or 2 is characterized in that described composite corrosion-proof erosion agent is one or several in potassium bichromate, calcium sulphonate, sodium sulfonate and barium sulfonate, dodecenylsuccinic acid, zinc naphthenate, n-oleoyl sarcosine stearylamine salt, trolamine, monoethanolamine, triethanolamine oleate, phenylformic acid amine, hexamethylenetetramine, benzotriazole, organic phosphate, imidazoline salt, volatile salt and mercaptan, the thiocarbamide.
13. a kind of microemulsion type sprays as claimed in claim 1 or 2 is characterized in that described propellent is one or more composition in propane, butane, the dme.
14. a kind of microemulsion type sprays as claimed in claim 1 or 2, feed liquid is the microemulsion that W/O, O/W or co-continuous phase are transparence to it is characterized in that dissolving each other each component afterwards.
15. a kind of microemulsion type sprays as claimed in claim 1 or 2 is characterized in that still keeping homodisperse after each component and propellent mix mutually.
16. a kind of microemulsion type sprays as claimed in claim 1 or 2 is characterized in that described composition can form transparent or semitransparent washing liq after 100 to 500 times of water dilutions.
17. a kind of microemulsion type sprays as claimed in claim 1 or 2 is characterized in that described composition uses the canned form of tinplate, aluminum or matrix material aerosol jar processed.
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| CN 201010127825 CN102191144B (en) | 2010-03-19 | 2010-03-19 | Microemulsion spraying agent |
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| CN 201010127825 CN102191144B (en) | 2010-03-19 | 2010-03-19 | Microemulsion spraying agent |
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| CN102191144B true CN102191144B (en) | 2013-08-14 |
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| CN102191144A (en) | 2011-09-21 |
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