CN102174680B - A (Ti, zr)2AlC/Al2O3solid solution composite material and its preparation method - Google Patents
A (Ti, zr)2AlC/Al2O3solid solution composite material and its preparation method Download PDFInfo
- Publication number
- CN102174680B CN102174680B CN2010106238994A CN201010623899A CN102174680B CN 102174680 B CN102174680 B CN 102174680B CN 2010106238994 A CN2010106238994 A CN 2010106238994A CN 201010623899 A CN201010623899 A CN 201010623899A CN 102174680 B CN102174680 B CN 102174680B
- Authority
- CN
- China
- Prior art keywords
- powder
- gross weight
- alc
- matrix
- matrix material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000002131 composite material Substances 0.000 title abstract description 5
- 239000000843 powder Substances 0.000 claims abstract description 91
- 239000011159 matrix material Substances 0.000 claims abstract description 74
- 239000000463 material Substances 0.000 claims abstract description 26
- 238000005245 sintering Methods 0.000 claims abstract description 13
- 238000000498 ball milling Methods 0.000 claims description 35
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 14
- 238000005516 engineering process Methods 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- 230000001476 alcoholic effect Effects 0.000 claims description 7
- 229910052786 argon Inorganic materials 0.000 claims description 7
- 239000007789 gas Substances 0.000 claims description 7
- 229910002804 graphite Inorganic materials 0.000 claims description 7
- 239000010439 graphite Substances 0.000 claims description 7
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 7
- 238000005303 weighing Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 abstract description 12
- 238000006243 chemical reaction Methods 0.000 abstract description 8
- 239000006104 solid solution Substances 0.000 abstract description 6
- 239000002245 particle Substances 0.000 abstract description 5
- 229910052782 aluminium Inorganic materials 0.000 abstract description 3
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- 238000005728 strengthening Methods 0.000 abstract description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 229910052593 corundum Inorganic materials 0.000 abstract 2
- 239000013078 crystal Substances 0.000 abstract 2
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 2
- 238000007731 hot pressing Methods 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 9
- 238000012986 modification Methods 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000003832 thermite Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000000713 high-energy ball milling Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
Abstract
The invention discloses a (Ti, Zr)2AlC/Al2O3 solid solution composite material and a preparation method thereof. The method comprises the following steps of: performing a hot-press sintering process on 39.38 to 70.08 weight percent of Ti powder, 20.11 to 22.85 weight percent of Al powder, 6.37 to 8.84 weight percent of C powder and 0.97 to 31.41 weight percent of ZrO2 powder; automatically generating a particle wild phase by using a thermit reaction in the process of generating a matrix phase to obtain an Al2O3 dispersed phase reinforced matrix phase Ti2AlC fine crystal composite material; and performing solid solution strengthening on a matrix by using Zr generated by the reaction. The material has high component adjustability, a low sintering temperature, a uniform and compact structure, lower cost and a high mechanical property, so that the application range of the composite material is widened; in addition, by the method, sintering temperatures and hot-pressing pressure are reduced, and crystal grain micritization is realized in the quick sintering process.
Description
Technical field
The invention belongs to matrix material and make the field, particularly a kind of (Ti, Zr)
2AlC/Al
2O
3. sosoloid matrix material and preparation method thereof.
Background technology
Novel lamellar stupalith Ti
2AlC has attracted lot of domestic and foreign scholar's exploration and research with its excellent properties.It had both had the performance of metal, can carry out traditional mechanical workout as having at normal temperatures under good electrical and thermal conductivity, lower Vickers' hardness, higher modulus of elasticity and shearing modulus, the room temperature, under comparatively high temps, had plasticity; This material has the performance of pottery again, like HMP, high thermal stability and good antioxidant property.But this material also exists sintering temperature high, and TR is little, and shortcoming such as hardness is low, strength ratio is less and limited its further application.
In recent years, for improving Ti
2The performance of AlC material, people utilize the means of solid solution highly malleablized and compoundization that it has been carried out study on the modification, have obtained effect preferably.Utilize the simple substance V element to carry out the solid solution study on the modification like document report (Scripta Materialia 53 (2005) 1369-1372); Its mechanical property is greatly improved; Can utilize the Zr element to carry out molten admittedly study on the modification with quadrat method; But this method raw materials cost is higher, and synthesis temperature is higher simultaneously, is unfavorable for its industrialization production; Also there is document (Scripta Materialia 50 (2004) 897-901) report to utilize Al
2O
3Particle can to Ti
2AlC has the Ti of analog structure
3AlC
2Material property carries out modification.But the present method that adopts is all more single, simultaneously, on the preparation method mainly with Al
2O
3And Ti
2Sintering is carried out in two kinds of powders mixing of AlC, perhaps with Al, C, TiO
2For raw material high temperature generates Ti through reduction reaction
2AlC/Al
2O
3Matrix material, but no matter the sort of technology all exists temperature of reaction high, and undercapacity, can't large-scale industrialized production.Patent (200910219290.8) has been reported and has been utilized high-energy ball milling to synthesize Ti
2AlC/Al
2O
3The novel method of matrix material, this method institute synthetic material is greatly improved on performance, but high-energy ball milling is difficult to suitability for industrialized production, simultaneously, matrix is not carried out the solid solution modification mutually.Therefore, how to take valid approach, utilize cheap material to synthesize Al
2O
3The solid solution type Ti of particle highly malleablized
2The AlC matrix material is a research emphasis from now on.
Summary of the invention
In order to overcome the defective of above-mentioned prior art, the object of the present invention is to provide a kind of (Ti, Zr)
2AlC/Al
2O
3Sosoloid matrix material and preparation method thereof utilizes Ti-Al-C-ZrO
2System is a raw material, prepares Al through thermite reaction reaction in technology low temperature
2O
3The Ti that strengthens
2AlC sosoloid matrix material; This method is utilized cheap oxide compound ZrO
2Substitute expensive metal simple-substance, reduced raw materials cost; Utilize the reaction heat of thermite reduction reaction self, reduced the synthesis temperature of material, simultaneously generated in-situ Al
2O
3The wild phase particle is tiny, even, and the performance of material is greatly improved; Prepared material has high-strength, fine and close, high temperature resistant, machinable performance characteristics.
In order to achieve the above object, technical scheme of the present invention is achieved in that
A kind of (Ti, Zr)
2AlC/Al
2O
3Sosoloid matrix material, its initial feed be purity more than or equal to 99%, fineness is smaller or equal to 200 purpose metal Ti powder, Al powder, C powder and MOX ZrO
2Carry out proportioning by following reaction formula:
2 (1-x) Ti+ (1+8x/3) Al+C+2xZrO
2→ (Ti
1-xZr
x)
2AlC+4x/3Al
2O
3(1) (x=0.005～0.2241), the result is Ti:39.38～70.08wt%, Al:20.11～22.85wt%, C:6.37～8.84wt%, ZrO
2: 0.97～31.41wt%.
The result is: a kind of (Ti, Zr)
2AlC/Al
2O
3The sosoloid matrix material, the raw material moity is: the Ti powder accounts for 39.38～70.08% of gross weight, and the Al powder accounts for 20.11～22.85% of gross weight, and the C powder accounts for 6.37～8.84% and ZrO of gross weight
2Powder accounts for 0.97～31.41% of gross weight.
A kind of (Ti, Zr)
2AlC/Al
2O
3The preparation technology of sosoloid matrix material the steps include:
Step 1, at first with purity more than or equal to 99%, fineness is smaller or equal to 200 purpose metal Ti powder, Al powder, C powder and MOX ZrO
2By following proportioning weighing, the Ti powder accounts for 39.38～70.08% of gross weight, and the Al powder accounts for 20.11～22.85% of gross weight, and the C powder accounts for 6.37～8.84% and ZrO of gross weight
2Powder accounts for 0.97～31.41% of gross weight;
Step 2, the batching in the step 1 is put into aluminum oxide ball milling jar on planetary ball mill, carry out mixing and ball milling; With the absolute ethyl alcohol is ball-milling medium; The rotating speed of ball mill is 600～900 rpms, material: ball: alcoholic acid mass ratio=1: 3: 1, ball milling 0.5～1.5 hour;
Step 3, the ball milling powder of step 2 gained is following dry 4～8 hours at 40～50 ℃;
Step 4, the dried powder of step 3 gained is packed in the graphite jig, under vacuum or argon gas condition, at 1100 ℃～1400 ℃, the pressure hot pressed sintering of 5.0～30MPa 1～2 hour;
Step 5, with step 4 gained material naturally cool to room temperature can obtain (Ti, Zr)
2AlC/Al
2O
3The sosoloid matrix material.
Institute of the present invention synthetic (Ti, Zr)
2AlC/Al
2O
3The sosoloid matrix material is characterized in that: it is made up of matrix phase and wild phase two portions, and matrix accounts for the 81.5-99.5% of matrix material gross weight mutually, and wild phase accounts for the 0.5-18.5% of gross weight, and matrix is (Ti mutually
1-x, Zr
x)
2AlC, wherein x gets 0.005～0.2241, and wild phase is Al
2O
3If Al in the matrix material that generates
2O
3Growing amount does not have enhancing, toughness reinforcing Ti less than 0.5% of product quality
2The effect of AlC matrix, otherwise, if Al in the product
2O
3Phasor surpasses Ti
2The content of AlC matrix phase can not be referred to as Ti
2The AlC based composites, simultaneously, Al
2O
3Growing amount will be above 18.5%, excessive Al
2O
3Not only do not have and improve Ti
2The effect of AlC can worsen its performance on the contrary.Therefore confirmed above compositional range.
The present invention utilizes Ti powder, Al powder, C powder and ZrO
2Powder is a raw material, through thermite reaction spontaneous particle wild phase Al in the process that matrix generates mutually
2O
3The metal simple-substance Zr that restores simultaneously is to Ti
2AlC carries out solution strengthening.Thereby prepared Al
2O
3The thin brilliant Ti of dispersion consolidatedization
2AlC sosoloid matrix material.Should be because this technology institute synthetic material composition adjustability be big, and firing temperature is low, even structure is fine and close, and cost is lower, and mechanical property is excellent, has widened the range of application of this matrix material.
Description of drawings
Accompanying drawing is the material phase analysis result of instance one gained sample; X-coordinate is a diffraction angle, and ordinate zou is a diffraction peak intensity, and wherein matrix is (Ti mutually
0.9576Zr
0.0424)
2AlC; Wild phase is Al
2O
3Can find out that by figure this material purity is very high, except (Ti
0.9576Zr
0.0424)
2AlC and Al
2O
3Almost there is not other impurity phase outward.
Embodiment
Embodiment one
A kind of (Ti, Zr)
2AlC/Al
2O
3The sosoloid matrix material, its raw material weight moity is: 20.38%, the 1200 purpose C powder that 63.86%, the 200 purpose Al powder that 270 purpose Ti powder account for gross weight account for gross weight account for 8.15% and ZrO of gross weight
2Powder accounts for 7.61% of gross weight.
The step of preparation process of present embodiment is following:
Step 1, at first with purity more than or equal to 99%, fineness is smaller or equal to 200 purpose metal Ti powder, Al powder, C powder and MOX ZrO
2By following proportioning weighing, 20.38%, the 1200 purpose C powder that 63.86%, the 200 purpose Al powder that 270 purpose Ti powder account for gross weight account for gross weight account for gross weight 8.15%, ZrO
2Powder accounts for 7.61% of gross weight;
Step 2, the batching in the step 1 is put into aluminum oxide ball milling jar on planetary ball mill, carrying out mixing and ball milling, is ball-milling medium with the absolute ethyl alcohol, and the rotating speed of ball mill is 800 rpms, material: ball: alcoholic acid mass ratio=1: 3: 1, ball milling 1 hour;
Step 3, the ball milling powder of step 2 gained is following dry 6 hours at 44 ℃;
Step 4, the dried powder of step 3 gained is packed in the graphite jig, under vacuum or argon gas condition, at 1350 ℃, the pressure hot pressed sintering of 16MPa 2 hours;
Step 5, with step 4 gained material naturally cool to room temperature can obtain (Ti, Zr)
2AlC/Al
2O
3The sosoloid matrix material.
Present embodiment institute synthetic (Ti, Zr)
2AlC/Al
2O
3The sosoloid matrix material is characterized in that: it is made up of matrix phase and wild phase two portions, and matrix accounts for 96% of matrix material gross weight mutually, and wild phase accounts for 4% of gross weight, and matrix is (Ti mutually
0.9576, Zr
0.0424)
2AlC, wild phase are Al
2O
3
With reference to accompanying drawing, show this material matrix by (Ti, Zr)
2The AlC phase contains the TiC phase of small amount of impurities, and wild phase is Al
2O
3Phase.
Embodiment two
A kind of (Ti, Zr)
2AlC/Al
2O
3The sosoloid matrix material, its raw material weight moity is: 21.64%, the 1200 purpose C powder that 66.08%, the 200 purpose Al powder that 270 purpose Ti powder account for gross weight account for gross weight account for 8.46% and ZrO of gross weight
2Powder accounts for 3.82% of gross weight.
The step of preparation process of present embodiment is following:
Step 1, at first with purity more than or equal to 99%, fineness is smaller or equal to 200 purpose metal Ti powder, Al powder, C powder and MOX ZrO
2By following proportioning weighing, 21.64%, the 1200 purpose C powder that 66.08%, the 200 purpose Al powder that 270 purpose Ti powder account for gross weight account for gross weight account for gross weight 8.46%, ZrO
2Powder accounts for 3.82% of gross weight;
Step 2, the batching in the step 1 is put into aluminum oxide ball milling jar on planetary ball mill, carrying out mixing and ball milling, is ball-milling medium with the absolute ethyl alcohol, and the rotating speed of ball mill is 800 rpms, material: ball: alcoholic acid mass ratio=1: 3: 1, ball milling 1 hour;
Step 3, the ball milling powder of step 2 gained is following dry 6 hours at 47 ℃;
Step 4, the dried powder of step 3 gained is packed in the graphite jig, under vacuum or argon gas condition, at 1350 ℃, the pressure hot pressed sintering of 16MPa 2 hours;
Step 5, with step 4 gained material naturally cool to room temperature can obtain (Ti, Zr)
2AlC/Al
2O
3The sosoloid matrix material.
Present embodiment institute synthetic (Ti, Zr)
2AlC/Al
2O
3The sosoloid matrix material is characterized in that: it is made up of matrix phase and wild phase two portions, and matrix accounts for 98% of matrix material gross weight mutually, and wild phase accounts for 2% of gross weight, and matrix is (Ti mutually
0.9795, Zr
0.0205)
2AlC, wild phase are Al
2O
3
Embodiment three
A kind of (Ti, Zr)
2AlC/Al
2O
3The sosoloid matrix material, its raw material weight moity is: 21.04%, the 1200 purpose C powder that 54.56%, the 200 purpose Al powder that 270 purpose Ti powder account for gross weight account for gross weight account for 7.53% and ZrO of gross weight
2Powder accounts for 16.87% of gross weight.
The step of preparation process of present embodiment is following:
Step 1, at first with purity more than or equal to 99%, fineness is smaller or equal to 200 purpose metal Ti powder, Al powder, C powder and MOX ZrO
2By following proportioning weighing, 54.56%, the 200 purpose Al powder that 270 purpose Ti powder account for gross weight account for that 21.04%, 1200 purpose C powder account for 7.53%, ZrO
2Powder accounts for 16.87;
Step 2, the batching in the step 1 is put into aluminum oxide ball milling jar on planetary ball mill, carrying out mixing and ball milling, is ball-milling medium with the absolute ethyl alcohol, and the rotating speed of ball mill is 800 rpms, material: ball: alcoholic acid mass ratio=1: 3: 1, ball milling 1 hour;
Step 3, the ball milling powder of step 2 gained is following dry 6 hours at 44 ℃;
Step 4, the dried powder of step 3 gained is packed in the graphite jig, under vacuum or argon gas condition, at 1350 ℃, the pressure hot pressed sintering of 16MPa 2 hours;
Step 5, with step 4 gained material naturally cool to room temperature can obtain (Ti, Zr)
2AlC/Al
2O
3The sosoloid matrix material.
Present embodiment institute synthetic (Ti, Zr)
2AlC/Al
2O
3The sosoloid matrix material is characterized in that: it is made up of matrix phase and wild phase two portions, and matrix accounts for 92% of matrix material gross weight mutually, and wild phase accounts for 8% of gross weight, and matrix is (Ti mutually
0.9087, Zr
0.0913)
2AlC, wild phase are Al
2O
3
Claims (6)
1. one kind (Ti, Zr)
2AlC/Al
2O
3The preparation technology of sosoloid matrix material is characterized in that, the steps include:
Step 1, at first with purity more than or equal to 99%, fineness is smaller or equal to 200 purpose metal Ti powder, Al powder, C powder and MOX ZrO
2By following proportioning weighing, the Ti powder accounts for 39.38～70.08% of gross weight, and the Al powder accounts for 20.11～22.85% of gross weight, and the C powder accounts for 6.37～8.84% and ZrO of gross weight
2Powder accounts for 0.97～31.41% of gross weight;
Step 2, the batching in the step 1 is put into aluminum oxide ball milling jar on planetary ball mill, carry out mixing and ball milling; With the absolute ethyl alcohol is ball-milling medium; The rotating speed of ball mill is 600～900 rpms, material: ball: alcoholic acid mass ratio=1:3:1, ball milling 0.5～1.5 hour;
Step 3, the ball milling powder of step 2 gained is following dry 4～8 hours at 40～50 ℃;
Step 4, the dried powder of step 3 gained is packed in the graphite jig, under vacuum or argon gas condition, at 1100 ℃～1400 ℃, the pressure hot pressed sintering of 5.0～30MPa 1～2 hour;
Step 5, with step 4 gained material naturally cool to room temperature can obtain (Ti, Zr)
2AlC/Al
2O
3The sosoloid matrix material.
2. according to claim 1 a kind of (Ti, Zr)
2AlC/Al
2O
3The preparation technology of sosoloid matrix material is characterized in that, the steps include:
Step 1, at first with purity more than or equal to 99%, fineness is smaller or equal to 200 purpose metal Ti powder, Al powder, C powder and MOX ZrO
2By following proportioning weighing, 20.38%, the 1200 purpose C powder that 63.86%, the 200 purpose Al powder that 270 purpose Ti powder account for gross weight account for gross weight account for gross weight 8.15%, ZrO
2Powder accounts for 7.61% of gross weight;
Step 2, the batching in the step 1 is put into aluminum oxide ball milling jar on planetary ball mill, carrying out mixing and ball milling, is ball-milling medium with the absolute ethyl alcohol, and the rotating speed of ball mill is 800 rpms, material: ball: alcoholic acid mass ratio=1:3:1, ball milling 1 hour;
Step 3, the ball milling powder of step 2 gained is following dry 6 hours at 44 ℃;
Step 4, the dried powder of step 3 gained is packed in the graphite jig, under vacuum or argon gas condition, at 1350 ℃, the pressure hot pressed sintering of 16MPa 2 hours;
Step 5, with step 4 gained material naturally cool to room temperature can obtain (Ti, Zr)
2AlC/Al
2O
3The sosoloid matrix material.
3. according to claim 1 a kind of (Ti, Zr)
2AlC/Al
2O
3The preparation technology of sosoloid matrix material is characterized in that, the steps include:
Step 1, at first with purity more than or equal to 99%, fineness is smaller or equal to 200 purpose metal Ti powder, Al powder, C powder and MOX ZrO
2By following proportioning weighing, 21.64%, the 1200 purpose C powder that 66.08%, the 200 purpose Al powder that 270 purpose Ti powder account for gross weight account for gross weight account for gross weight 8.46%, ZrO
2Powder accounts for 3.82% of gross weight;
Step 2, the batching in the step 1 is put into aluminum oxide ball milling jar on planetary ball mill, carrying out mixing and ball milling, is ball-milling medium with the absolute ethyl alcohol, and the rotating speed of ball mill is 800 rpms, material: ball: alcoholic acid mass ratio=1:3:1, ball milling 1 hour;
Step 3, the ball milling powder of step 2 gained is following dry 6 hours at 47 ℃;
Step 4, the dried powder of step 3 gained is packed in the graphite jig, under vacuum or argon gas condition, at 1350 ℃, the pressure hot pressed sintering of 16MPa 2 hours;
Step 5, with step 4 gained material naturally cool to room temperature can obtain (Ti, Zr)
2AlC/Al
2O
3The sosoloid matrix material.
4. according to claim 1 a kind of (Ti, Zr)
2AlC/Al
2O
3The preparation technology of sosoloid matrix material is characterized in that, gained (Ti, Zr)
2AlC/Al
2O
3The sosoloid matrix material, it is made up of matrix phase and wild phase two portions, and matrix accounts for the 81.5-99.5% of matrix material gross weight mutually, and wild phase accounts for the 0.5-18.5% of gross weight, and matrix is (Ti mutually
1-x, Zr
x)
2AlC, wherein x gets 0.005～0.2241, and wild phase is Al
2O
3
5. according to claim 2 a kind of (Ti, Zr)
2AlC/Al
2O
3The preparation technology of sosoloid matrix material is characterized in that, gained (Ti, Zr)
2AlC/Al
2O
3The sosoloid matrix material, it is made up of matrix phase and wild phase two portions, and matrix accounts for 96% of matrix material gross weight mutually, and wild phase accounts for 4% of gross weight, and matrix is (Ti mutually
0.9576, Zr
0.0424)
2AlC, wild phase are Al
2O
3
6. according to claim 3 a kind of (Ti, Zr)
2AlC/Al
2O
3The preparation technology of sosoloid matrix material is characterized in that, gained (Ti, Zr)
2AlC/Al
2O
3The sosoloid matrix material, it is made up of matrix phase and wild phase two portions, and matrix accounts for 98% of matrix material gross weight mutually, and wild phase accounts for 2% of gross weight, and matrix is (Ti mutually
0.9795, Zr
0.0205)
2AlC, wild phase are Al
2O
3
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010106238994A CN102174680B (en) | 2010-12-31 | 2010-12-31 | A (Ti, zr)2AlC/Al2O3solid solution composite material and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010106238994A CN102174680B (en) | 2010-12-31 | 2010-12-31 | A (Ti, zr)2AlC/Al2O3solid solution composite material and its preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102174680A CN102174680A (en) | 2011-09-07 |
| CN102174680B true CN102174680B (en) | 2012-11-14 |
Family
ID=44517915
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010106238994A Active CN102174680B (en) | 2010-12-31 | 2010-12-31 | A (Ti, zr)2AlC/Al2O3solid solution composite material and its preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102174680B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103820695B (en) * | 2014-03-19 | 2016-02-10 | 成都理工大学 | Based on the Al of liquid sintering process 2o 3/ TiC coated carbides preparation method |
| CN108441912B (en) * | 2018-03-16 | 2019-10-08 | 南京理工大学 | Aluminum alloy surface Al3C4-Al2O3-ZrO2The preparation method of wear-resisting composite coating |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1804068A (en) * | 2006-01-18 | 2006-07-19 | 陕西科技大学 | Preparation method of highly dispersed AI2O3 particle reinforced Ti-Al based composite material |
| CN101245428A (en) * | 2008-03-13 | 2008-08-20 | 哈尔滨工程大学 | Modified TiC/Ti6Al4V composite material and manufacture method thereof |
| CN101717253A (en) * | 2009-12-03 | 2010-06-02 | 陕西科技大学 | Al2O3/Ti2AlC ceramic composite material and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1715070B1 (en) * | 2003-11-25 | 2012-11-07 | Fundacion Tecnalia Research & Innovation | Method of producing titanium composite parts by means of casting |
-
2010
- 2010-12-31 CN CN2010106238994A patent/CN102174680B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1804068A (en) * | 2006-01-18 | 2006-07-19 | 陕西科技大学 | Preparation method of highly dispersed AI2O3 particle reinforced Ti-Al based composite material |
| CN101245428A (en) * | 2008-03-13 | 2008-08-20 | 哈尔滨工程大学 | Modified TiC/Ti6Al4V composite material and manufacture method thereof |
| CN101717253A (en) * | 2009-12-03 | 2010-06-02 | 陕西科技大学 | Al2O3/Ti2AlC ceramic composite material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102174680A (en) | 2011-09-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101717252B (en) | Ti3AlC2/Al2O3 compound material and preparation method thereof | |
| CN100396650C (en) | Method for preparing Ti2AlC ceramic material | |
| CN101100383A (en) | Manufacture method for titanium-aluminum-carbon ternary layered processable ceramics material | |
| CN104496477A (en) | Method for preparing high-purity Cr2AlC ceramic powder | |
| CN101423413B (en) | Method for preparing ZrB2-Al2O3 composite powder | |
| CN101717253A (en) | Al2O3/Ti2AlC ceramic composite material and preparation method thereof | |
| CN102174680B (en) | A (Ti, zr)2AlC/Al2O3solid solution composite material and its preparation method | |
| CN102181766B (en) | A (Ti, cr)2AlC solid solution composite material and its prepn | |
| CN102174679B (en) | A (Ti, mo)3AlC2/Al2O3solid solution composite material and its preparation method | |
| CN101050116A (en) | Powder body of solid solution among interlayer of titanium, silicon, aluminum, carbon, and preparation method | |
| CN102041425B (en) | (Ti, Nb) 3AlC2/Al2O3 solid solution composite material and preparation method thereof | |
| CN102174681B (en) | High-purity Ti2AlNxC1-x solid solution material and preparation method thereof | |
| CN101376931A (en) | Preparation of cemented carbide containing block tabular tungsten carbide crystal grain | |
| CN1948220A (en) | Method of thermo press preparing high purity aluminium titanium carbide block material | |
| CN102181765B (en) | A (Ti, cr)3AlC2/Al2O3composite material and its preparation method | |
| CN1259279C (en) | Titanium silicon carbon block material using aluminium as additive and its preparing method | |
| CN102181767B (en) | (Ti, Mo)2AlC/Al2O3 solid solution composite material and preparation method thereof | |
| CN102174682A (en) | A (Ti, V)2AlC/Al2O3solid solution composite material and its preparation method | |
| CN100404465C (en) | Method for preparing TiN/Al2O3 composite materials | |
| CN101531514A (en) | Method for preparing zirconium-aluminum-silicon-carbon ceramic block material by in-situ reaction under hot pressure | |
| CN100450970C (en) | Atmospheric synthetic method for high purity titamum aluminum carbide ceramic powder | |
| CN102181769A (en) | (Ti, V)3AlC2/Al2O3 solid solution composite material and preparation method thereof | |
| CN101100382A (en) | Manufacture method for Ti3AlC2 processable ceramics material | |
| CN105218100A (en) | A kind of low-temperature growth Ti 2the method of AlC stupalith | |
| CN101289222A (en) | Method for preparing high-pure and superfine titanium-aluminum-nitrogen powder |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170516 Address after: Caotan economic and Technological Development Zone of Shaanxi Province, Xi'an city ecological park 710021 Yuan Lu is No. 3669 Patentee after: PHENOM INNOVATIONS (XI'AN) Co.,Ltd. Address before: 710021 Shaanxi province Xi'an Weiyang university campus of Shaanxi University of Science and Technology Patentee before: SHAANXI University OF SCIENCE & TECHNOLOGY |
|
| TR01 | Transfer of patent right | ||
| CP03 | Change of name, title or address |
Address after: 712046 A2, Channel 1, Building 1, No. 2, Enterprise Road, Shanglin Road Street Office, Fengdong New City, Xi'an City, Shaanxi Province Patentee after: Phenom Innovations (Xi''an) Co.,Ltd. Address before: 710021 No. 3669 Shangyuan Road, Caotan Ecological Park, Economic and Technological Development Zone, Xi'an City, Shaanxi Province Patentee before: PHENOM INNOVATIONS (XI'AN) Co.,Ltd. |
|
| CP03 | Change of name, title or address |