CN102174292B - Resin paint surface nursing emulsion and preparation method thereof - Google Patents
Resin paint surface nursing emulsion and preparation method thereof Download PDFInfo
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- CN102174292B CN102174292B CN 201110060655 CN201110060655A CN102174292B CN 102174292 B CN102174292 B CN 102174292B CN 201110060655 CN201110060655 CN 201110060655 CN 201110060655 A CN201110060655 A CN 201110060655A CN 102174292 B CN102174292 B CN 102174292B
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- resin paint
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Abstract
The invention discloses resin paint surface nursing emulsion, which consists of the following components in part by weight: 10 to 50 parts of stearic acid, 20 to 80 parts of ester, 90 to 150 parts of polyol, 80 to 100 parts of alcohol amine, 50 to 80 parts of solvent oil, 30 to 60 parts of wax and 400 to 500 parts of distilled water. A preparation method comprises the following steps of: uniformly mixing the polyol, the alcohol amine and the distilled water to obtain a component A; heating and stirring the stearic acid, the ester, the solvent oil and the wax at the temperature of between 85 and 95 DEG C, and mixing for 30 to 40 minutes to obtain a component B; and uniformly mixing the component A and the component B. The emulsion can completely remove oil dirt, glue stain and asphalt on the surface of a resin paint, has high varnishing performance, can nurse a glass steel die, and is convenient to use; and the three wastes (waste gas, waste water and waste residue) are not generated in the production process, and the method is environment-friendly.
Description
Technical field
The present invention relates to a kind of resin paint surface nursing emulsion that is applicable to automobile, furniture, floor and leather surface scrubbing, waxing, cleaning, glazing and daily nursing and preparation method thereof, metal surface nursing technique field.
Background technology
At present, common floor wax mostly is solid or liquid wax, is generally the oil extract, and needing to add essence increases its fragrance to hide the taste of wax work itself, and the aerial oil extract that volatilizees affects HUMAN HEALTH.Chinese patent application 88102840.1,88105538.7 and 95101730.6 all uses paraffin to be raw material, and its fusing point is low, consumption between 2-6%, product glazing poor-performing.
Often produce the waste water that contains organic solvent in the nursing materials production processes such as automobile, furniture, floor and leather surface scrubbing, waxing, cleaning, glazing, production process not only causes Health hazard to operator, also causes environmental pollution.
Summary of the invention
It is good, nonflammable, nontoxic, inexpensive that the object of the invention provides a kind of luminance brightness, widely used water-base emulsion type resin paint surface nursing emulsion.
Another object of the present invention provides the preparation method of above-mentioned water-base emulsion type resin paint surface nursing emulsion.
Implementation procedure of the present invention is as follows:
Resin paint surface nursing emulsion, its composition and weight part are as follows:
Stearic acid 10-50 esters 20-80 polyvalent alcohols 90-150 hydramine 80-100 solvent oils 50-80
Wax 30-60 distilled water 400-500;
Described ester is selected from lacquer tree fat, glyceryl monostearate, Tego-stearate, propylene glycol monostearate; Facts have proved that use lacquer tree fat and glyceryl monostearate mixed ester, effect is better, the lacquer tree fat add-on accounts for the weight percent 25-35% of ester, and total weight parts is 20-40.
Above-mentioned resin paint surface nursing emulsion, it forms and weight part is preferably:
Stearic acid 20-40 esters 20-60 polyvalent alcohols 100-130 hydramine 85-100 solvent oils 60-80
Wax 30-50 distilled water 410-460.
Also contain emulsifying agent in the above-mentioned resin paint surface nursing emulsion, emulsifying agent is selected from peregal, paregal O, class of department 60, fatty alcohol-polyoxyethylene ether, polyoxyethylene nonylphenol ether, and parts by weight are 30-50.Preferred paregal O, paregal O is a kind of nonionic surface active agent, its molecular formula is RO (CH
2CH
2O) n-CH
2CH
2OH, main component is polyoxyethylene aliphatic alcohol ether, R is C in the formula
12～C
18Alkyl, n is the ethylene oxide of 15～16 molecules, it adds weight part is 30-50.
Polyvalent alcohol is selected from glycerol, propylene glycol, ethylene glycol in the above-mentioned resin paint surface nursing emulsion, preferred glycerol, and its performance of keeping humidity is good, and add-on is 100-130; Hydramine is selected from thanomin, diethanolamine, trolamine, and preferably with diethanolamine and trolamine mixing hydramine, its diethanolamine accounts for 4-32% of total add-on, and its add-on is 85-100; Solvent oil is selected from turps, Viscotrol C, lacquer tree kernel oil, and it is best selecting the mixture of turps, Viscotrol C, lacquer tree kernel oil, and its volume ratio is: (0.5 ~ 1): (1.8 ~ 2.5): (6.5 ~ 7.7); Wax is selected from the kind of natural wax, beeswax, insect wax, rice bran wax, the carnauba wax of fusing point between 60～85 ℃, select the wax of higher melt to be advisable, particularly beeswax cooperates with carnauba wax, the glazing successful is higher than single variety, the distribution of beeswax and two kinds of melting point substances of carnauba wax is so that working fluid is insensitive to temperature variation, and auxiliary with stearic acid and stearic polyol ester, auxiliary glazing, have the more excellent characteristics of upper light characteristic, wherein beeswax accounts for 35-45% of wax total amount, and add-on is 80-100.
The pH value of the nursing emulsion of aforesaid method preparation is between 8 ~ 10, and density is 1.01-1.03.
The preparation method of above-mentioned resin paint surface nursing emulsion may further comprise the steps:
(1) polyvalent alcohol, hydramine and distilled water are mixed, obtain the A component; Or emulsifying agent is dissolved in distilled water, and adding again polyvalent alcohol and hydramine and obtain the A component, described emulsifying agent is selected from peregal, paregal O, class of department 60, fatty alcohol-polyoxyethylene ether, polyoxyethylene nonylphenol ether, and parts by weight are 30-50;
(2) with stearic acid, ester, solvent oil and wax 85 ℃～95 ℃ heating, stir, mixing 30～40min obtains the B component;
(3) A component and B component are mixed get final product.
Advantage of the present invention is as follows:
1. resin paint surface nursing emulsion is easy to use, the saving of labor, save time, laborsaving.
2. resin paint surface nursing emulsion directly uses, and need not water and cleans, and is without sewage discharging, free from environmental pollution.
3. the resin paint surface nursing emulsion glazing is effective, and is lasting.
4. the resin paint surface nursing emulsion production process is easy, and the production whole process is without waste gas, waste residue, discharge of wastewater, and is environmentally friendly.
5. the present invention is used for nursing, the scrubbing on the forming mould surface of epoxy glass laminate, can prolong the mold use life-span, helps the demoulding.
Embodiment
The invention will be further described below in conjunction with embodiment.
Embodiment 1
According to the resin paint surface nursing emulsion prescription of the present invention that table 1,2 provides, the preparation method of resin paint surface nursing emulsion of the present invention may further comprise the steps:
(1) polyvalent alcohol, hydramine and distilled water are mixed, obtain the A component; Or emulsifying agent is dissolved in distilled water, add again polyvalent alcohol and hydramine and obtain the A component;
(2) with stearic acid, fat, solvent oil and wax 85 ℃～95 ℃ heating, stir, mixing 30～40min obtains the B component;
(3) A component and B component are mixed get final product.
Table 1 resin paint surface nursing emulsion formula table 1 of the present invention
In the preparation of prescription 2,30 parts of paregal Os have been added;
In the preparation of prescription 5,40 parts of fatty alcohol-polyoxyethylene ether have been added;
Table 2 resin paint surface nursing emulsion formula table 2 of the present invention
In the preparation of prescription 6, added 60 30 parts in class of department;
In the preparation of prescription 10,40 parts of polyoxyethylene nonylphenol ethers have been added;
Embodiment 2 furniture, floor
The prescription 1 for preparing is applied on cotton yarn or the soft cloth, is evenly distributed, repeatedly wipe the painted surface on examination furniture, floor, effect light, clean.
Embodiment 3 leathers
With the prescription 3 for preparing and water by volume 1:1 mix, evenly be sprayed to leather surface with spraying plant, dry, with cotton yarn or soft cloth wiping leather surface, the effect light is as before.
Embodiment 4 automobiles
With the prescription 5 for preparing and water (tap water) by volume 1:3 mix, evenly be sprayed to car body surface with spraying plant, take advantage of wetly with cotton yarn or soft cloth wiping so that dirt is peeled off, slightly dried, with cotton yarn or repeatedly wiping of soft cloth, coating surface is clean, light.
Embodiment 5 fiber glass epoxies and mould
The prescription 10 for preparing is applied to the fiber glass epoxy die surface, evenly gets final product with cotton yarn or soft cloth wiping, can be effective to the demoulding.
Can find out from above example, use the present invention convenient, the saving of labor, save time, laborsaving, glazing is effective, lasting.Production process of the present invention is easy, the production whole process is without waste gas, waste residue, discharge of wastewater, the present invention can bring into play excellent properties and the effect of self cleaning, waxing, glazing aspect automobile, furniture, floor, leather, it can also be used in the nursing aspect of fiber reinforced plastic mold, its effect is that it can prolong the mold use life-span, assisted ejection is arranged, and is easy to use.
Claims (9)
1. resin paint surface nursing emulsion, its form and weight part as follows:
Stearic acid 10-50 esters 20-80 polyvalent alcohols 90-150 hydramine 80-100 solvent oils 50-80
Wax 30-60 distilled water 400-500;
Described ester is selected from lacquer tree fat, glyceryl monostearate, Tego-stearate, propylene glycol monostearate;
Described wax is selected from beeswax, insect wax, rice bran wax, carnauba wax.
2. resin paint surface nursing emulsion according to claim 1, its form and weight part as follows:
Stearic acid 20-40 esters 20-60 polyvalent alcohols 100-130 hydramine 85-100 solvent oils 60-80
Wax 30-50 distilled water 410-460.
3. resin paint surface nursing emulsion according to claim 1, it is characterized in that: also contain emulsifying agent in the nursing emulsion, emulsifying agent is selected from peregal, paregal O, class of department 60, fatty alcohol-polyoxyethylene ether, polyoxyethylene nonylphenol ether, and parts by weight are 30-50.
4. according to claim 1 to 3 one of any described resin paint surface nursing emulsions, it is characterized in that: described polyvalent alcohol is selected from glycerol, propylene glycol, ethylene glycol.
5. according to claim 1 to 3 one of any described resin lacquer painting nursing emulsions, it is characterized in that: described hydramine is selected from thanomin, diethanolamine, trolamine.
6. according to claim 1 to 3 one of any described resin lacquer painting nursing emulsions, it is characterized in that: described solvent oil is selected from turps, Viscotrol C, lacquer tree kernel oil.
7. according to claim 1 to 3 one of any described resin lacquer painting nursing emulsions, it is characterized in that: the pH value of nursing emulsion is between 8 ~ 10, and density is 1.01-1.03.
8. the preparation method of resin paint surface nursing emulsion claimed in claim 1 may further comprise the steps:
(1) polyvalent alcohol, hydramine and distilled water are mixed, obtain the A component;
(2) with stearic acid, ester, solvent oil and wax 85 ℃～95 ℃ heating, stir, mixing 30～40min obtains the B component;
(3) A component and B component are mixed get final product.
9. the preparation method of resin paint surface nursing emulsion according to claim 8, it is characterized in that: step (1) is that emulsifying agent is dissolved in distilled water, add again polyvalent alcohol and hydramine, described emulsifying agent is selected from peregal, paregal O, class of department 60, fatty alcohol-polyoxyethylene ether, polyoxyethylene nonylphenol ether, and parts by weight are 30-50.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110060655 CN102174292B (en) | 2011-03-15 | 2011-03-15 | Resin paint surface nursing emulsion and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110060655 CN102174292B (en) | 2011-03-15 | 2011-03-15 | Resin paint surface nursing emulsion and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN102174292A CN102174292A (en) | 2011-09-07 |
| CN102174292B true CN102174292B (en) | 2013-03-27 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110060655 Expired - Fee Related CN102174292B (en) | 2011-03-15 | 2011-03-15 | Resin paint surface nursing emulsion and preparation method thereof |
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Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103881587B (en) * | 2012-12-19 | 2015-09-09 | 齐河力厚化工有限公司 | A kind of leather finishing agent and preparation method thereof |
| CN104531398A (en) * | 2014-12-01 | 2015-04-22 | 苏州东邦家具有限公司 | Preparation method of solid wood furniture cleaning agent |
| CN104531373A (en) * | 2014-12-01 | 2015-04-22 | 苏州东邦家具有限公司 | Solid wood furniture cleaning agent |
| CN104974672A (en) * | 2014-12-02 | 2015-10-14 | 肖哲西 | Environment-friendly floor polishing agent |
| CN106118493B (en) * | 2016-06-19 | 2018-01-05 | 上犹京禾纳米科技有限公司 | Button conditioning liquid and preparation method thereof |
| CN108913384A (en) * | 2018-08-07 | 2018-11-30 | 湖北天喜达生物科技有限公司 | A kind of long acting antibiotic multifunctional floor cleaning wax and preparation method thereof |
| CN111471532A (en) * | 2020-05-28 | 2020-07-31 | 西安车利宝环保科技有限公司 | Micro-water environment-friendly automobile cleaning agent and preparation method thereof |
| CN113563805A (en) * | 2021-08-05 | 2021-10-29 | 皇宇奢汇(上海)技术有限公司 | High-gloss wax water based on modified rice bran wax and preparation method thereof |
| CN113480943A (en) * | 2021-08-05 | 2021-10-08 | 皇宇奢汇(上海)技术有限公司 | Polishing wax oil based on modified rice bran wax and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1068349A (en) * | 1991-07-10 | 1993-01-27 | 张增光 | Special shoe cream for high-grade sports shoes and preparation method thereof |
| CN1224763A (en) * | 1998-12-17 | 1999-08-04 | 葛东 | Multifunctional leather protecting and grooming aerosol and its production process |
| CN101921490A (en) * | 2010-01-07 | 2010-12-22 | 浙江吉利汽车研究院有限公司 | Multifunctional automobile protective wax and preparation method thereof |
-
2011
- 2011-03-15 CN CN 201110060655 patent/CN102174292B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1068349A (en) * | 1991-07-10 | 1993-01-27 | 张增光 | Special shoe cream for high-grade sports shoes and preparation method thereof |
| CN1224763A (en) * | 1998-12-17 | 1999-08-04 | 葛东 | Multifunctional leather protecting and grooming aerosol and its production process |
| CN101921490A (en) * | 2010-01-07 | 2010-12-22 | 浙江吉利汽车研究院有限公司 | Multifunctional automobile protective wax and preparation method thereof |
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| CN102174292A (en) | 2011-09-07 |
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Granted publication date: 20130327 Termination date: 20140315 |