CN102162059A - Manganese element additive for alloy steel and preparation method thereof - Google Patents

Manganese element additive for alloy steel and preparation method thereof Download PDF

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Publication number
CN102162059A
CN102162059A CN 201110077778 CN201110077778A CN102162059A CN 102162059 A CN102162059 A CN 102162059A CN 201110077778 CN201110077778 CN 201110077778 CN 201110077778 A CN201110077778 A CN 201110077778A CN 102162059 A CN102162059 A CN 102162059A
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China
Prior art keywords
manganese
powder
additive
steel alloy
smelting process
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CN 201110077778
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Chinese (zh)
Inventor
曾克里
张淑婷
王磊
许根国
侯玉柏
孙建刚
解峰
占佳
张康
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Bgrimm Advanced Materials Science & Technology Co Ltd
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Beijing General Research Institute of Mining and Metallurgy
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Publication of CN102162059A publication Critical patent/CN102162059A/en
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Abstract

The invention relates to a manganese element additive used in an alloy steel smelting process and a preparation method thereof. The additive comprises manganese powder, iron powder and a binder, and comprises the following components in percentage by weight: 0-30% of iron powder; 0.5-5% of a binder; the balance being manganese powder. The sum of all the components in the additive is 100 percent. The additive has the characteristics of simple and convenient addition mode, short smelting time and high manganese recovery rate.

Description

A kind of steel alloy manganese element additive and preparation method thereof
Technical field
The present invention relates to manganese element additive that uses in a kind of steel alloy smelting process and preparation method thereof.
Background technology
Manganese is a kind of important interpolation element in the steel alloy.The adding of manganese can improve the intensity and the plasticity of steel alloy, improves the work hardening capacity and the wear resistance of steel alloy, effectively improves the hardening capacity of steel alloy, and the intensity that improves low-carbon (LC) and middle carbon perlitic steel is had significant effect, improves the high temperature instantaneous strength of steel.
The existing manganese addition method of steel alloy in smelting mostly is the interpolation manganeseirom.This technology generally is to add ferromanganese in decarburization II phase and III phase, because carbon content is higher in the manganeseirom, the concentration that this can improve Mn and C in the molten metal has reduced the temperature of molten metal simultaneously.Lower in blowing molten metal temperature in early stage, Mn to the avidity of O greater than C, when molten metal temperature during greater than 1400 ℃, the avidity of C and O just surpasses Mn, so this kind manganese addition method can increase the Mn amount of oxidation, prolong and take off C tap to tap time, not only the rate of recovery of Mn is on the low side, increases the control difficulty of decarburization difficulty and carbon content, and prolongs the time that converter is on average smelted, also have influence on the life-span of furnace lining, increased ton steel cost.For some high tensile steel alloys,, can not adopt this kind addition manner because its requirement to C content is very strict.
Summary of the invention
In order to overcome the above-mentioned deficiency of manganese addition mode in the steel alloy smelting process, the invention provides a kind of molten alloy steel manganese additive, it is easy that this additive has addition manner, and tap to tap time is short, the characteristics that manganese recovery ratio is high.
For achieving the above object, the present invention takes following technical scheme: the manganese element additive that uses in a kind of steel alloy smelting process, and it is by manganese powder, and iron powder and binding agent are formed, and it consists of (calculating by weight percentage, down together):
(1) 0 ~ 30% iron powder;
(2) 0.5 ~ 5% binding agent;
(3) surplus is a manganese powder.
The summation of each component is 100% in its additive.
Described manganese powder and iron powder satisfy:
(1) manganese powder purity is not less than 98%, and the powder median size is between 0.01 ~ 0.5mm;
(2) iron powder purity is not less than 95%, and the powder median size is between 0.01 ~ 0.5mm.
Wherein iron powder is preferably 7 ~ 27%; Binding agent is preferably 0.5% ~ 4%; Manganese powder is preferably 70 ~ 97%.
Described binding agent is carbon containing not, and it is selected from alkali metal silicate binder, phosphate binders, ferrosilicate binding agent, the silicon dioxide gel one or more.
Steel alloy of the present invention comprises the steps: with the preparation method of manganese element additive
In manganese powder, add 0 ~ 30% iron powder and 0.5 ~ 5% binding agent, with the raw material thorough mixing evenly after, be pressed into briquetting through weighing with pressing machine, through overcuring, pack after the drying.
Wherein the briquetting quality is 50 ~ 500g.
The manganese element additive that uses in a kind of steel alloy smelting process, described additive is made according to above-mentioned preparation method.
The purposes of above-mentioned manganese element additive, described additive are used for steel alloy and smelt.
Adopt steel alloy of the present invention to have following advantage with the manganese element additive:
1. adding mode is simple, and fusing is rapid, casting yield height, stable content and control easily;
2. do not improve the concentration of C in the molten metal, reduce and take off the C difficulty;
3. reduce the time that converter is on average smelted.
Description of drawings
Fig. 1 is a steel alloy of the present invention manganese element additive preparation process flow sheet.
Embodiment
Operational path of the present invention is as shown in Figure 1: with manganese powder, binding agent and iron powder mixing → weighing → compression moulding → curing → drying → check → encapsulation → wrapped product.
Concrete processing step is as described below:
1. the preparation of manganese powder and iron powder
Adopt known method to prepare manganese powder and iron powder
2. the preparation of additive
In manganese powder, add 0 ~ 30% iron powder and 0.5 ~ 5% binding agent, thorough mixing evenly after, be pressed into the briquetting of 50 ~ 500g through weighing with pressing machine, through curing process, pack after the drying.
Describe the specific embodiment of the present invention in detail below in conjunction with embodiment, but embodiments of the invention are not limited to following embodiment.
Embodiment 1
(1) adopt known method to prepare purity and be not less than 98%, manganese powder and the purity of powder median size between 0.01 ~ 0.5mm is not less than 95%, the iron powder of powder median size between 0.01 ~ 0.5mm;
(2) press the 90wt% iron powder, the 7wt% iron powder, the silicate ratio of 3wt% is even in stirrer for mixing with raw material;
(3) thorough mixing evenly after, be pressed into the briquetting of 500g with pressing machine through weighing;
(4) through after curing in 24 hours and the drying, pack.
Embodiment 2
(1) adopt known method to prepare purity and be not less than 98%, manganese powder and the purity of powder median size between 0.01 ~ 0.5mm is not less than 95%, the iron powder of powder median size between 0.01 ~ 0.5mm;
(2) press the 97wt% manganese powder, the silicate ratio of 3wt% is even in stirrer for mixing with raw material;
(3) thorough mixing evenly after, be pressed into the briquetting of 200g with pressing machine through weighing;
(4) through after curing in 48 hours and the drying, pack.
Embodiment 3
(1) adopt known method to prepare purity and be not less than 98%, manganese powder and the purity of powder median size between 0.01 ~ 0.5mm is not less than 95%, the iron powder of powder median size between 0.01 ~ 0.5mm;
(2) press the 80wt% manganese powder, the 18wt% iron powder, the phosphate binders proportioning of 2wt% is even in stirrer for mixing with raw material;
(3) thorough mixing evenly after, be pressed into the briquetting of 300g with pressing machine through weighing;
(4) through after curing in 10 hours and the drying, pack.
Embodiment 4
(1) adopt known method to prepare purity and be not less than 98%, manganese powder and the purity of powder median size between 0.01 ~ 0.5mm is not less than 95%, the iron powder of powder median size between 0.01 ~ 0.5mm;
(2) press the 75wt% manganese powder, the 20wt% iron powder, the proportioning of the ferrosilicate binding agent of 5wt% is even in stirrer for mixing with raw material;
(3) thorough mixing evenly after, be pressed into the briquetting of 100g with pressing machine through weighing;
(4) through after curing in 24 hours and the drying, pack.
Embodiment 5
(1) adopt known method to prepare purity and be not less than 98%, manganese powder and the purity of powder median size between 0.01 ~ 0.5mm is not less than 95%, the iron powder of powder median size between 0.01 ~ 0.5mm;
(2) press the 70wt% manganese powder, the 27wt% iron powder, the proportioning of the silicon dioxide gel of 3wt% is even in stirrer for mixing with raw material;
(3) thorough mixing evenly after, be pressed into the briquetting of 50g with pressing machine through weighing;
(4) through after curing in 20 hours and the drying, pack.

Claims (10)

1. the manganese element additive that uses in the steel alloy smelting process, it is characterized in that: described additive is made up of manganese powder, iron powder and binding agent, and its composition is by weight percentage:
(1) 0 ~ 30% iron powder;
(2) 0.5 ~ 5% binding agent;
(3) surplus is a manganese powder,
The summation of each component is 100% in its additive.
2. the manganese element additive that uses in the steel alloy smelting process according to claim 1 is characterized in that described manganese powder and iron powder satisfy:
(1) manganese powder purity is not less than 98%, and the powder median size is between 0.01 ~ 0.5mm;
(2) iron powder purity is not less than 95%, and the powder median size is between 0.01 ~ 0.5mm.
3. the manganese element additive that uses in the steel alloy smelting process according to claim 1 and 2, wherein iron powder is 7 ~ 27%.
4. the manganese element additive that uses in the steel alloy smelting process according to claim 1 and 2, wherein binding agent is 0.5 ~ 4%.
5. the manganese element additive that uses in the steel alloy smelting process according to claim 1 and 2, wherein manganese powder is 70 ~ 97%.
6. the manganese element additive that uses in the steel alloy smelting process according to claim 1 and 2, it is characterized in that not carbon containing of described binding agent, it is selected from alkali metal silicate binder, phosphate binders, ferrosilicate binding agent, the silicon dioxide gel one or more.
7. according to the preparation method of the manganese element additive that uses in each described steel alloy smelting process of claim 1-6, it is characterized in that, this method comprise the steps: with the raw material thorough mixing evenly after, be pressed into briquetting through weighing with pressing machine, through overcuring, pack after the drying.
8. the preparation method of the manganese element additive that uses in the steel alloy smelting process according to claim 7 is characterized in that the briquetting quality is 50 ~ 500g.
9. the manganese element additive that uses in the steel alloy smelting process is characterized in that described additive is made according to claim 4 or 5 described preparation methods.
10. according to the purposes of each described manganese element additive of claim 1-3, it is characterized in that described additive is used for steel alloy and smelts.
CN 201110077778 2011-03-30 2011-03-30 Manganese element additive for alloy steel and preparation method thereof Pending CN102162059A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105039814A (en) * 2015-08-28 2015-11-11 重庆润际远东新材料科技有限公司 Manganese additive for aluminum alloy and preparing method of manganese additive
CN105087974A (en) * 2015-08-28 2015-11-25 重庆润际远东新材料科技有限公司 Aluminum alloy manganese additive and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1046193A (en) * 1989-04-03 1990-10-17 中国科学院金属研究所 The additive that a kind of smelting aluminium alloy is used
CN1270236A (en) * 2000-05-11 2000-10-18 武进市昌盛合金制品有限公司 Ultra-low-C low-P MnFe alloy
CN1928137A (en) * 2005-09-05 2007-03-14 湖南华菱涟源钢铁有限公司 Mn-Fe alloy production process
CN101381821A (en) * 2008-09-26 2009-03-11 北京矿冶研究总院 Flux-free aluminum alloy additive and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1046193A (en) * 1989-04-03 1990-10-17 中国科学院金属研究所 The additive that a kind of smelting aluminium alloy is used
CN1270236A (en) * 2000-05-11 2000-10-18 武进市昌盛合金制品有限公司 Ultra-low-C low-P MnFe alloy
CN1928137A (en) * 2005-09-05 2007-03-14 湖南华菱涟源钢铁有限公司 Mn-Fe alloy production process
CN101381821A (en) * 2008-09-26 2009-03-11 北京矿冶研究总院 Flux-free aluminum alloy additive and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105039814A (en) * 2015-08-28 2015-11-11 重庆润际远东新材料科技有限公司 Manganese additive for aluminum alloy and preparing method of manganese additive
CN105087974A (en) * 2015-08-28 2015-11-25 重庆润际远东新材料科技有限公司 Aluminum alloy manganese additive and preparation method thereof

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Application publication date: 20110824