A kind of steel alloy manganese element additive and preparation method thereof
Technical field
The present invention relates to manganese element additive that uses in a kind of steel alloy smelting process and preparation method thereof.
Background technology
Manganese is a kind of important interpolation element in the steel alloy.The adding of manganese can improve the intensity and the plasticity of steel alloy, improves the work hardening capacity and the wear resistance of steel alloy, effectively improves the hardening capacity of steel alloy, and the intensity that improves low-carbon (LC) and middle carbon perlitic steel is had significant effect, improves the high temperature instantaneous strength of steel.
The existing manganese addition method of steel alloy in smelting mostly is the interpolation manganeseirom.This technology generally is to add ferromanganese in decarburization II phase and III phase, because carbon content is higher in the manganeseirom, the concentration that this can improve Mn and C in the molten metal has reduced the temperature of molten metal simultaneously.Lower in blowing molten metal temperature in early stage, Mn to the avidity of O greater than C, when molten metal temperature during greater than 1400 ℃, the avidity of C and O just surpasses Mn, so this kind manganese addition method can increase the Mn amount of oxidation, prolong and take off C tap to tap time, not only the rate of recovery of Mn is on the low side, increases the control difficulty of decarburization difficulty and carbon content, and prolongs the time that converter is on average smelted, also have influence on the life-span of furnace lining, increased ton steel cost.For some high tensile steel alloys,, can not adopt this kind addition manner because its requirement to C content is very strict.
Summary of the invention
In order to overcome the above-mentioned deficiency of manganese addition mode in the steel alloy smelting process, the invention provides a kind of molten alloy steel manganese additive, it is easy that this additive has addition manner, and tap to tap time is short, the characteristics that manganese recovery ratio is high.
For achieving the above object, the present invention takes following technical scheme: the manganese element additive that uses in a kind of steel alloy smelting process, and it is by manganese powder, and iron powder and binding agent are formed, and it consists of (calculating by weight percentage, down together):
(1) 0 ~ 30% iron powder;
(2) 0.5 ~ 5% binding agent;
(3) surplus is a manganese powder.
The summation of each component is 100% in its additive.
Described manganese powder and iron powder satisfy:
(1) manganese powder purity is not less than 98%, and the powder median size is between 0.01 ~ 0.5mm;
(2) iron powder purity is not less than 95%, and the powder median size is between 0.01 ~ 0.5mm.
Wherein iron powder is preferably 7 ~ 27%; Binding agent is preferably 0.5% ~ 4%; Manganese powder is preferably 70 ~ 97%.
Described binding agent is carbon containing not, and it is selected from alkali metal silicate binder, phosphate binders, ferrosilicate binding agent, the silicon dioxide gel one or more.
Steel alloy of the present invention comprises the steps: with the preparation method of manganese element additive
In manganese powder, add 0 ~ 30% iron powder and 0.5 ~ 5% binding agent, with the raw material thorough mixing evenly after, be pressed into briquetting through weighing with pressing machine, through overcuring, pack after the drying.
Wherein the briquetting quality is 50 ~ 500g.
The manganese element additive that uses in a kind of steel alloy smelting process, described additive is made according to above-mentioned preparation method.
The purposes of above-mentioned manganese element additive, described additive are used for steel alloy and smelt.
Adopt steel alloy of the present invention to have following advantage with the manganese element additive:
1. adding mode is simple, and fusing is rapid, casting yield height, stable content and control easily;
2. do not improve the concentration of C in the molten metal, reduce and take off the C difficulty;
3. reduce the time that converter is on average smelted.
Description of drawings
Fig. 1 is a steel alloy of the present invention manganese element additive preparation process flow sheet.
Embodiment
Operational path of the present invention is as shown in Figure 1: with manganese powder, binding agent and iron powder mixing → weighing → compression moulding → curing → drying → check → encapsulation → wrapped product.
Concrete processing step is as described below:
1. the preparation of manganese powder and iron powder
Adopt known method to prepare manganese powder and iron powder
2. the preparation of additive
In manganese powder, add 0 ~ 30% iron powder and 0.5 ~ 5% binding agent, thorough mixing evenly after, be pressed into the briquetting of 50 ~ 500g through weighing with pressing machine, through curing process, pack after the drying.
Describe the specific embodiment of the present invention in detail below in conjunction with embodiment, but embodiments of the invention are not limited to following embodiment.
Embodiment 1
(1) adopt known method to prepare purity and be not less than 98%, manganese powder and the purity of powder median size between 0.01 ~ 0.5mm is not less than 95%, the iron powder of powder median size between 0.01 ~ 0.5mm;
(2) press the 90wt% iron powder, the 7wt% iron powder, the silicate ratio of 3wt% is even in stirrer for mixing with raw material;
(3) thorough mixing evenly after, be pressed into the briquetting of 500g with pressing machine through weighing;
(4) through after curing in 24 hours and the drying, pack.
Embodiment 2
(1) adopt known method to prepare purity and be not less than 98%, manganese powder and the purity of powder median size between 0.01 ~ 0.5mm is not less than 95%, the iron powder of powder median size between 0.01 ~ 0.5mm;
(2) press the 97wt% manganese powder, the silicate ratio of 3wt% is even in stirrer for mixing with raw material;
(3) thorough mixing evenly after, be pressed into the briquetting of 200g with pressing machine through weighing;
(4) through after curing in 48 hours and the drying, pack.
Embodiment 3
(1) adopt known method to prepare purity and be not less than 98%, manganese powder and the purity of powder median size between 0.01 ~ 0.5mm is not less than 95%, the iron powder of powder median size between 0.01 ~ 0.5mm;
(2) press the 80wt% manganese powder, the 18wt% iron powder, the phosphate binders proportioning of 2wt% is even in stirrer for mixing with raw material;
(3) thorough mixing evenly after, be pressed into the briquetting of 300g with pressing machine through weighing;
(4) through after curing in 10 hours and the drying, pack.
Embodiment 4
(1) adopt known method to prepare purity and be not less than 98%, manganese powder and the purity of powder median size between 0.01 ~ 0.5mm is not less than 95%, the iron powder of powder median size between 0.01 ~ 0.5mm;
(2) press the 75wt% manganese powder, the 20wt% iron powder, the proportioning of the ferrosilicate binding agent of 5wt% is even in stirrer for mixing with raw material;
(3) thorough mixing evenly after, be pressed into the briquetting of 100g with pressing machine through weighing;
(4) through after curing in 24 hours and the drying, pack.
Embodiment 5
(1) adopt known method to prepare purity and be not less than 98%, manganese powder and the purity of powder median size between 0.01 ~ 0.5mm is not less than 95%, the iron powder of powder median size between 0.01 ~ 0.5mm;
(2) press the 70wt% manganese powder, the 27wt% iron powder, the proportioning of the silicon dioxide gel of 3wt% is even in stirrer for mixing with raw material;
(3) thorough mixing evenly after, be pressed into the briquetting of 50g with pressing machine through weighing;
(4) through after curing in 20 hours and the drying, pack.