CN102153821A - Modified polystyrene material - Google Patents
Modified polystyrene material Download PDFInfo
- Publication number
- CN102153821A CN102153821A CN 201110039395 CN201110039395A CN102153821A CN 102153821 A CN102153821 A CN 102153821A CN 201110039395 CN201110039395 CN 201110039395 CN 201110039395 A CN201110039395 A CN 201110039395A CN 102153821 A CN102153821 A CN 102153821A
- Authority
- CN
- China
- Prior art keywords
- district
- gpps
- injection moulding
- raw materials
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
The invention discloses a modified polystyrene material which comprises the following raw materials in percentage by weight: 65-90% of polystyrene resin, 8-30% of styrene-butadiene copolymer and 1-5% of liquid paraffin. The raw materials according to the formula are proportionally added, and a mixer is started to mix the raw materials for 5 minutes; and the mixture can be directly put into a common injection molding machine for production without drying the raw materials. The transparency of the modified GPPS (general purpose polystyrene) material disclosed by the invention remains the transparency of the original GPPS material, the elongation at break is enhanced from 2% to 5%, and the impact strength can be enhanced from 3KJ/m<2> to 15KJ/m<2>.
Description
Technical field:
The present invention relates to a kind of transparent material, the modified polystyrene material on the transparent plastic articles such as being applied in the refrigerator lampshade of more specifically saying so.
Background technology:
At present, the lampshade material that is applied on the refrigerator is that PC (polycarbonate) material is injection molded substantially, later stage is because PC is on the high side, change into and use PCTA (copolyester) material substitution PC, but under precondition, PC and PCTA material price are all higher, consider for the angle that reduces cost, and need seek the injection moulding that new material substitution PC and PCTA material are used for lampshade.Common GPPS material because shock strength is poor, when injection moulding and later stage assembling, the cracking situation can occur when producing baroque Transparent Parts such as lampshade.
Summary of the invention:
For overcoming the defective of prior art, the object of the present invention is to provide a kind of method of modifying that can improve GPPS toughness and not influence the material transparency, make modification GPPS material can successfully substitute PC material and copolyester material.
Technical solution problem of the present invention adopts following technical scheme:
Modified polystyrene material comprises following raw materials by weight percent:
Polystyrene resin (GPPS): 65-90%
Styrene-butadiene copolymer (K resin): 8-30%
Whiteruss (white oil): 1-5%
It is low-cost that the present invention mainly provides a kind of use, and the modification GPPS material of high impact strength, high-clarity is applied in the refrigerator lampshade.Use the common plastic mixer required various raw materials of will filling a prescription to add in proportion, start and get final product after stirrer stirs 5min, stirred materials can directly drop into common injection moulding machine and can produce, and need not starting material are carried out drying treatment.If the dispersiveness to raw material has higher requirement, need that then above material is dropped into homogenizer in proportion and stir, stir by the cooling and stirring machine then, after dropping into dual-screw pelletizer again and carrying out granulation, can carry out ordinary production dropping into injection moulding machine.The adding proportion of control styrene-butadiene copolymer (K resin) is the difficult point in the process, if ratio is improper, because the influence of the specific refraction of two kinds of materials can make transparency of products descend significantly.
Compared with the prior art, beneficial effect of the present invention is embodied in:
Material of the present invention is a major ingredient with common GPPS material, in the GPPS material, add a certain proportion of K resin (styrene-butadiene copolymer) and improve its toughness, the purpose of adding toner (optional raw material) mainly is that material is dyeed, and the purpose of adding white oil is to improve dispersiveness.Above material is by after the twin screw granulation, and the modification GPPS material transparency that processes can keep the transparency of original GPPS material, and elongation at break brings up to 5% from 2%, and shock strength is from 3KJ/m
2Can bring up to 15KJ/m
2
1, reduces material cost, comprise unit price, manufacturing expense, weight etc.Attached cost analysis:
The price of K resin: 18000 yuan/ton
GPPS price: 10500 yuan/ton
The price of modification GPPS material: 11250 yuan/ton
The price of PC and copolyester: 20000 yuan/ton
After using the GPPS material, material is per ton to reduce cost 8750 yuan.
The proportion of modification GPPS is: 1.03g/cm3
The proportion of PC and copolyester is: 1.20g/cm3
After using the GPPS material, product weight can reduce by the 16.5% (density of modification GPPS material: 1.03g/cm
3, the density of PC material is 1.20g/cm
3).
Drying-free when producing behind the use GPPS material, PC and copolyester must 120 ℃ of dry 4h.
2, materials procurement channel of the present invention is simple, the modifying process stable performance.
3, the modification GPPS materials processing performance of the present invention's generation is better than original material, and feed back is easy to reuse.PC and copolyester are owing to the flavescence of being heated easily, and feed back can not reuse.
4, moulding good fluidity, technology is simple, and processing temperature is low, drying-free.And the difficult moulding of PC material, the processing temperature height, time of drying is long.
Below by embodiment, the invention will be further described.
Embodiment:
Embodiment 1:
GPPS (raising the sub-143E of BASF AG): 65 parts
K resin (KK38 of Chevron Corporation): 30 parts
White oil: 5 parts
1, use electronic scale that above raw material is carried out weighing in proportion,
2, then GPPS and K resin are put into homogenizer mixing stirring, behind the stirring 2min, add white oil, stir 3min once more,
3, the mixing raw material that stirs be put in the homogenizer carry out cooling and stirring in the cooling and stirring machine, stir 10min after, mixing raw material is emitted stirrer, prepare to carry out granulation.
4, the raw material that stirs is added the feed bin of dual-screw pelletizer, the barrel technological temperature of tablets press is provided with as follows:
One district: 185 ℃ of two district: 195 ℃ of three district: 200 ℃ of four district: 200 ℃ of five district: 210 ℃
Six districts: 210 ℃ of mouth moulds: 210 ℃
5, in granulation process, after will cooling off by cooling trough from the tie rod that extrude mouth mould position,, use dicing machine that billot is processed into pellet then using hot air dryer to carry out moisture oven dry processing.
6, granulation is good raw material adds the injection moulding machine feed bin by suction feeder, and the Shooting Technique temperature of injection moulding machine is provided with as follows:
One district: 185 ℃ of two district: 200 ℃ of three district: 210 ℃ of four district: 215 ℃ of five district: 220 ℃
Mouth mould: 225 ℃
7, the temperature of each heating zone of injection moulding machine is raised to after the set(ting)value, starts injection moulding machine, and raw material is processed into plastic component by the injection moulding machine injection moulding, after the moulding passed examination, tests and packs, and send final assembly to use.
Embodiment 2:
GPPS (raising the sub-143E of BASF AG): 90 parts
K resin (KK38 of Chevron Corporation): 8 parts
White oil: 2 parts
1, use electronic scale that above raw material is carried out weighing in proportion,
2, then GPPS and K resin are put into homogenizer mixing stirring, behind the stirring 2min, add white oil, stir 3min once more,
3, the mixing raw material that stirs be put in the homogenizer carry out cooling and stirring in the cooling and stirring machine, stir 10min after, mixing raw material is emitted stirrer, prepare to carry out granulation.
4, the raw material that stirs is added the feed bin of dual-screw pelletizer, the barrel technological temperature of tablets press is provided with as follows:
One district: 185 ℃ of two district: 195 ℃ of three district: 200 ℃ of four district: 200 ℃ of five district: 210 ℃
Six districts: 210 ℃ of mouth moulds: 210 ℃
5, in granulation process, after will cooling off by cooling trough from the tie rod that extrude mouth mould position,, use dicing machine that billot is processed into pellet then using hot air dryer to carry out moisture oven dry processing.
6, granulation is good raw material adds the injection moulding machine feed bin by suction feeder, and the Shooting Technique temperature of injection moulding machine is provided with as follows:
One district: 185 ℃ of two district: 200 ℃ of three district: 210 ℃ of four district: 215 ℃ of five district: 220 ℃
Mouth mould: 225 ℃
7, the temperature of each heating zone of injection moulding machine is raised to after the set(ting)value, starts injection moulding machine, and raw material is processed into plastic component by the injection moulding machine injection moulding, after the moulding passed examination, tests and packs, and send final assembly to use.
Embodiment 3:
GPPS (raising the sub-143E of BASF AG): 80 parts
K resin (KK38 of Chevron Corporation): 18 parts
White oil: 2 parts
1, use electronic scale that above raw material is carried out weighing in proportion,
2, then GPPS and K resin are put into homogenizer mixing stirring, behind the stirring 2min, add white oil, stir 3min once more,
3, the mixing raw material that stirs be put in the homogenizer carry out cooling and stirring in the cooling and stirring machine, stir 10min after, mixing raw material is emitted stirrer, prepare to carry out granulation.
4, the raw material that stirs is added the feed bin of dual-screw pelletizer, the barrel technological temperature of tablets press is provided with as follows:
One district: 185 ℃ of two district: 195 ℃ of three district: 200 ℃ of four district: 200 ℃ of five district: 210 ℃
Six districts: 210 ℃ of mouth moulds: 210 ℃
5, in granulation process, after will cooling off by cooling trough from the tie rod that extrude mouth mould position,, use dicing machine that billot is processed into pellet then using hot air dryer to carry out moisture oven dry processing.
6, granulation is good raw material adds the injection moulding machine feed bin by suction feeder, and the Shooting Technique temperature of injection moulding machine is provided with as follows:
One district: 185 ℃ of two district: 200 ℃ of three district: 210 ℃ of four district: 215 ℃ of five district: 220 ℃
Mouth mould: 225 ℃
7, the temperature of each heating zone of injection moulding machine is raised to after the set(ting)value, starts injection moulding machine, and raw material is processed into plastic component by the injection moulding machine injection moulding, after the moulding passed examination, tests and packs, and send final assembly to use.
Embodiment 4:
GPPS (raising the sub-143E of BASF AG): 70 parts
K resin (KK38 of Chevron Corporation): 28 parts
White oil: 2 parts
1, use electronic scale that above raw material is carried out weighing in proportion,
2, then GPPS and K resin are put into homogenizer mixing stirring, behind the stirring 2min, add white oil, stir 3min once more,
3, the mixing raw material that stirs be put in the homogenizer carry out cooling and stirring in the cooling and stirring machine, stir 10min after, mixing raw material is emitted stirrer, prepare to carry out granulation.
4, the raw material that stirs is added the feed bin of dual-screw pelletizer, the barrel technological temperature of tablets press is provided with as follows:
One district: 185 ℃ of two district: 195 ℃ of three district: 200 ℃ of four district: 200 ℃ of five district: 210 ℃
Six districts: 210 ℃ of mouth moulds: 210 ℃
5, in granulation process, after will cooling off by cooling trough from the tie rod that extrude mouth mould position,, use dicing machine that billot is processed into pellet then using hot air dryer to carry out moisture oven dry processing.
6, granulation is good raw material adds the injection moulding machine feed bin by suction feeder, and the Shooting Technique temperature of injection moulding machine is provided with as follows:
One district: 185 ℃ of two district: 200 ℃ of three district: 210 ℃ of four district: 215 ℃ of five district: 220 ℃
Mouth mould: 225 ℃
7, the temperature of each heating zone of injection moulding machine is raised to after the set(ting)value, starts injection moulding machine, and raw material is processed into plastic component by the injection moulding machine injection moulding, after the moulding passed examination, tests and packs, and send final assembly to use.
Claims (2)
1. modified polystyrene material is characterized in that comprising following raw materials by weight percent:
Polystyrene resin: 65-90%;
Styrene-butadiene copolymer: 8-30%;
Whiteruss: 1-5%.
2. modified polystyrene material according to claim 1 is characterized in that comprising following raw materials by weight percent:
Polystyrene resin: 70-85%;
Styrene-butadiene copolymer: 10-25%;
Whiteruss: 2-5%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110039395 CN102153821A (en) | 2011-02-17 | 2011-02-17 | Modified polystyrene material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110039395 CN102153821A (en) | 2011-02-17 | 2011-02-17 | Modified polystyrene material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102153821A true CN102153821A (en) | 2011-08-17 |
Family
ID=44435517
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110039395 Pending CN102153821A (en) | 2011-02-17 | 2011-02-17 | Modified polystyrene material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102153821A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102922837A (en) * | 2012-11-05 | 2013-02-13 | 浦江亿通塑胶电子有限公司 | Composite sheet used for manufacturing antistatic bearing belt and processing method of composite sheet |
| CN103044797A (en) * | 2013-01-22 | 2013-04-17 | 贵州省复合改性聚合物材料工程技术研究中心 | Transparent K glue composite AS (Acrylonitrile-Styrene Copolymers) alloy material and preparation method thereof |
| CN103073805A (en) * | 2013-01-21 | 2013-05-01 | 东莞市欣隆光电材料有限公司 | High impact strength photodiffusion polystyrene material and preparation method thereof |
| CN103756173A (en) * | 2014-01-20 | 2014-04-30 | 苏州新区特氟龙塑料制品厂 | Improved GPPS (General Purpose Polystyrene) formula |
| CN104262884A (en) * | 2014-10-16 | 2015-01-07 | 佛山市南海美之彩塑化有限公司 | High-strength HIPS (high impact polystyrene) prepared by GPPS (general purpose polystyrene) return material and preparation method of HIPS |
| CN104927220A (en) * | 2015-06-26 | 2015-09-23 | 苏州云舒新材料科技有限公司 | Preparing method of PS (polystyrene) composite |
| CN105037989A (en) * | 2015-08-04 | 2015-11-11 | 金宝丽科技（苏州）有限公司 | Modified poly styrene (PS) composite material and preparation process thereof |
| CN105237901A (en) * | 2015-11-13 | 2016-01-13 | 广州洁特生物过滤股份有限公司 | Transparent polystyrene linear material for 3D printing and preparation method thereof |
| CN106633454A (en) * | 2016-12-07 | 2017-05-10 | 南京创维家用电器有限公司 | GPPS high-gloss refrigerator inner liner, refrigerator and preparation method |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1405229A (en) * | 2002-10-21 | 2003-03-26 | 浙江大学 | High-toughness polystyrene alloy and its preparation process |
-
2011
- 2011-02-17 CN CN 201110039395 patent/CN102153821A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1405229A (en) * | 2002-10-21 | 2003-03-26 | 浙江大学 | High-toughness polystyrene alloy and its preparation process |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102922837A (en) * | 2012-11-05 | 2013-02-13 | 浦江亿通塑胶电子有限公司 | Composite sheet used for manufacturing antistatic bearing belt and processing method of composite sheet |
| CN102922837B (en) * | 2012-11-05 | 2015-07-29 | 浦江亿通塑胶电子有限公司 | For making composite sheet and the processing method thereof of antistatic carrying belt |
| CN103073805A (en) * | 2013-01-21 | 2013-05-01 | 东莞市欣隆光电材料有限公司 | High impact strength photodiffusion polystyrene material and preparation method thereof |
| CN103044797A (en) * | 2013-01-22 | 2013-04-17 | 贵州省复合改性聚合物材料工程技术研究中心 | Transparent K glue composite AS (Acrylonitrile-Styrene Copolymers) alloy material and preparation method thereof |
| CN103756173A (en) * | 2014-01-20 | 2014-04-30 | 苏州新区特氟龙塑料制品厂 | Improved GPPS (General Purpose Polystyrene) formula |
| CN104262884A (en) * | 2014-10-16 | 2015-01-07 | 佛山市南海美之彩塑化有限公司 | High-strength HIPS (high impact polystyrene) prepared by GPPS (general purpose polystyrene) return material and preparation method of HIPS |
| CN104262884B (en) * | 2014-10-16 | 2016-10-26 | 中山市瑞邦红利塑料工业有限公司 | High-strength impact-resistant HIPS and preparation method thereof prepared by a kind of GPPS feed back |
| CN104927220A (en) * | 2015-06-26 | 2015-09-23 | 苏州云舒新材料科技有限公司 | Preparing method of PS (polystyrene) composite |
| CN105037989A (en) * | 2015-08-04 | 2015-11-11 | 金宝丽科技（苏州）有限公司 | Modified poly styrene (PS) composite material and preparation process thereof |
| CN105237901A (en) * | 2015-11-13 | 2016-01-13 | 广州洁特生物过滤股份有限公司 | Transparent polystyrene linear material for 3D printing and preparation method thereof |
| CN106633454A (en) * | 2016-12-07 | 2017-05-10 | 南京创维家用电器有限公司 | GPPS high-gloss refrigerator inner liner, refrigerator and preparation method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102153821A (en) | Modified polystyrene material | |
| CN103571039A (en) | High-melt index polypropylene composition and preparation method thereof | |
| CN101906234A (en) | Polymethylmethacrylate composition and preparation method thereof | |
| CN101418101B (en) | Polypropylene wood-plastic slab and preparation method thereof | |
| CN107932820A (en) | One kind injection control panel and its Shooting Technique | |
| CN103224706A (en) | Polyphenylene sulfide composite material, preparation method and molding method thereof | |
| CN104130508A (en) | Low-oriented extrusion grade polypropylene material and preparation method thereof | |
| CN109130046A (en) | A kind of preparation method of Wood-plastic mould pressing pallet | |
| CN105131542B (en) | A kind of bamboo powder handled through lactide surface grafting and polylactic acid blend composite and preparation method and application | |
| CN102250454A (en) | Low-cost fully-degradable high-flexibility polylactic acid composite material and preparation method thereof | |
| CN103087480A (en) | High-toughness low-warping low-mold temperature glass fiber-reinforced PET/PA6 alloy and preparation method thereof | |
| CN102952332A (en) | High temperature-resistant PP (polypropylene) lunch box and manufacturing process thereof | |
| CN113185809A (en) | Heat-resistant full-biodegradable composite material for thin-wall injection molding product and preparation method thereof | |
| CN102627829A (en) | Composite fiberboard prepared with waste acrylonitrile-butadiene-styrene (ABS) plastics and preparation method thereof | |
| CN101007893A (en) | PC/PET alloy material production method | |
| CN113150566B (en) | High-melt-index high-modulus asphalt mixture additive and preparation method and application thereof | |
| CN111673997A (en) | Injection molding process of plastic material air purifier shell | |
| CN107686637A (en) | High pressure resistant high temperature resistant composite and preparation method thereof | |
| CN104448558A (en) | Highly-toughened light-diffusion PP composition and preparation method thereof | |
| CN105176021A (en) | Preparation method of high-impact-resistance polyethylene terephthalate particles | |
| CN101845165A (en) | Method for preparing flame-retardant wood-flour composite macromolecular thermoplastic resin material | |
| CN105440723A (en) | Preparation method of carrier-free precipitated barium sulfate transparent master batch | |
| CN115011080B (en) | Full-biodegradable composite material and preparation method thereof | |
| CN108530853B (en) | PLA/HBP derivative blend and preparation method thereof | |
| CN114752145A (en) | Special master batch for hot-press forming transparent polypropylene and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20110817 |