CN102146227A - Transparent acrylic single-coating UV (Ultraviolet) radiation curing coating as well as production method and application method thereof - Google Patents
Transparent acrylic single-coating UV (Ultraviolet) radiation curing coating as well as production method and application method thereof Download PDFInfo
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- CN102146227A CN102146227A CN2011100206710A CN201110020671A CN102146227A CN 102146227 A CN102146227 A CN 102146227A CN 2011100206710 A CN2011100206710 A CN 2011100206710A CN 201110020671 A CN201110020671 A CN 201110020671A CN 102146227 A CN102146227 A CN 102146227A
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Abstract
The invention provides a transparent acrylic single-coating UV (Ultraviolet) radiation curing coating as well as a production method and an application method thereof. The transparent acrylic single-coating UV radiation curing coating is widely applicable to the coating of optical plastics with high light transmittances, such as PMMA (Polymethyl Methacrylate), PC (Polycarbonate) and the like. In the invention, the UV radiation curing coating is directly sprayed on a plastic material and provides a base material with good adhesion, in particular solves the difficulty that the optical plastic is unfavorable for the coating to adhere due to low surface tension and inert surface; and the transparent acrylic single-coating UV radiation curing coating has the advantages of high light transmittance, high fullness, high gloss, high hardness, high wear resistance, low VOC (Volatile Organic Compounds), low odor and the like. The invention also provides the production method and the application method of the product; and the production method is simple and convenient and the coating process is simple.
Description
Technical field
The present patent application relates to the chemistry painting industry technical field, is specifically related to a kind of acrylic list and is coated with transparent UV radiation curable coating and production thereof, using method.
Background technology
The PMMA chemical name is polymethylmethacrylate, popular name acryl, synthetic glass.Because it has light weight, inexpensive, advantages such as easy what moulding and high-clarity, transmittance reaches more than 92%, is the best plastics of optical property, secondly is the PC plastics.
For optical plastics, obtained using widely in recent years with advantages such as its impact resistance is good, density is low, cheap, easy machine-shapings, and wear-resisting, heat-resisting, moisture-proof, the relatively poor shortcoming of solvent resistance have seriously limited its goods to more high-grade development.The redesign molecular structure no doubt is to improve the fundamental way of performance to overcome these shortcomings, but is simple and practical method more yet the kind of existing optical plastics is carried out surface Modification.Up to now, people utilize physical coating method and dectroless plating successfully to prepare antistatic film, the film of anti-scratch the, antifogging film, antireflective coating and nesa coating, highly reflecting films etc.
The even film layer that the physics method is coated with, compactness are good, but plant and instrument complexity, conditional request strictness, the plastics thermotolerance is relatively poor in addition, so use less on the optical plastics surface modification.The method of plated film is more, and the performance of the rete that obtains also has nothing in common with each other.
Summary of the invention
The present patent application provides a kind of technology of using ultraviolet light polymerization for the hard rete of anti-scratch the on optical plastics surface, compares traditional embrane method that is hydrolyzed into, and has high-level efficiency, high transmission rate, high fullness ratio, high gloss, high rigidity, high-wearing feature, advantages such as low VOC, low smell.
The purpose of this invention is to provide a kind of acrylic list and be coated with transparent UV radiation curable coating, described acrylic list be coated with transparent UV radiation curable coating solved especially because of the surface tension of optical plastics low, the surface is inertia, the difficult point of adhering to that is unfavorable for coating is widely used in the application that PMMA (also being acrylic or polymethyl methacrylate), PC etc. require the optical plastics of high transmission rate.
Another object of the present invention provides a kind of production method and using method that the acrylic list is coated with transparent UV radiation curable coating that prepare.
The present invention can realize by following technical scheme:
The described a kind of acrylic list of the present patent application is coated with transparent UV radiation curable coating, and it is characterized in that: described coating comprises the various components of following weight percent:
1, six functional groups aliphatic urethane acrylate oligopolymer 15-20%;
2, the two aliphatic urethane acrylate oligopolymer 10-15% of functional group;
3, isodecyl acrylate 3-6%;
4, the third oxidation neopentyl glycol 5-10%;
5, trimethylolpropane trimethacrylate 5-12%;
6, Dipentaerythritol five acrylate 5-8%;
7, polyacrylate solution 1-2%;
8, polyether-modified polydimethylsiloxane 1-2%;
9, solvent 30-40%;
10,2-hydroxy-2-methyl-1-phenyl-1-acetone 1-4%;
11,1-hydroxyl-cyclohexyl-phenyl ketone 1-5%.
Described a kind of acrylic list is coated with transparent UV radiation curable coating, it is characterized in that: described solvent is a kind of solvent in methylethylketone, butylacetate, propyl carbinol or the Virahol or the mixed solvent of several solvents.
The production method that the present patent application also provides the described acrylic list of preparation to be coated with transparent UV radiation curable coating comprises the following independent step for preparing:
(1) mixed solvent preparation: solvent is mixed in proportion standby;
(2) oligopolymer monomer blending dispersion: get clean system lacquer cylinder, with six functional groups aliphatic urethane acrylate oligopolymer, two functional group's aliphatic urethane acrylate oligopolymers, isodecyl acrylate, the third oxidation neopentyl glycol, trimethylolpropane trimethacrylate, Dipentaerythritol five acrylate of described ratio, stirred 10-15 minute with the rotating speed that 1200-1500 changes per minute with high speed dispersor;
(3) flow agent premix: take by weighing polyacrylate solution, polyether-modified polydimethylsiloxane and solvent in proportion, stir 10-15 minute to mixing with the rotating speed that 600-800 changes per minute with high speed dispersor, standby;
(4) light trigger dissolving: weighing 2-hydroxy-2-methyl-1-phenyl-1-acetone, 1-hydroxyl-cyclohexyl-phenyl ketone and solvent in proportion, stirred 10-15 minute with the rotating speed that 600-800 changes per minute with high speed dispersor, to dissolving fully, after the filtration of 500 mesh filter screens, standby;
(5) with in the system lacquer cylinder in the standby material input step (2) of above-mentioned preparation, even with 10-15 minute blending dispersion of rotating speed stirring that 600-800 changes per minute with high speed dispersor, the solvent in the employing prescription carries out viscosity and is adjusted into 8.5 ± 0.5 seconds;
(6) filter and package with double-deck 400 order filter clothes.
The present patent application also provides the method for using described acrylic list to be coated with transparent UV radiation curable coating, it is characterized in that, comprises the steps: ground pre-treatment → spraying → levelling → preheating → UV curing → polishing → packing
(1) ground pre-treatment:
Suitable ground of the present invention is plastic rubber substrates such as PMMA, PC; Dip in clean cotton before the spraying and get 6# industrial naptha or 120# industrial naptha and wipe pollutent on the ground, and electrostatic precipitation, standby;
(2) spraying operation parameter setting and step:
(a) construction environment: temperature 15-35 ℃, relative humidity 45-70%
(b) application mode: aerial spraying, can adopt hand spray or time variable control machine to spray automatically.
(c) device parameter: gravity type boat davit or suct the formula spray gun; Bore 1.0-1.5mm; Air pressure 0.3-0.4mPa; Spray distance 15-20cm;
(d) working viscosity: 8.5-9.5 second;
(e) solidifying the back film thickness is 15-20 μ m;
(f) flow time: room temperature 1-2 minute;
(g) preheating: 55-60 ℃, 3-5 minute;
(h) UV solidifies: adopting linear heat generation rate is the high voltage mercury lamp (105Pa) of 80-120W/cm, and characteristic wavelength is at 250-410nm, with radiation dose 800-1200mJ/cm2 dry solidification.
The described technical scheme of the present patent application has following advantage:
1. the present invention has solved the difficult point of UV coating poor adhesive force on the PMMA of low surface tension plastic cement especially;
2. the present invention has high transmission rate, high fullness ratio, high gloss, high-wearing feature, high rigidity, advantages such as low VOC, low smell;
3. the present invention compares traditional coating process and has improved production efficiency, reduces frosting application energy consumption, reduces the VOC discharging that spraying application produces.
Embodiment
Below in conjunction with concrete embodiment; the described coating of the present patent application is described; purpose is better to understand the described technology contents of the present patent application for the public; rather than to the restriction of described technology contents; in fact; in spirit of the present invention, to the improvement of described each component of coating, and to the change of processing condition in the described making and use method with improve all within the present patent application technical scheme required for protection.
Embodiment 1
Described coating comprises the various components of following weight percent:
1, six functional groups aliphatic urethane acrylate oligopolymer 15%;
2, two functional group's aliphatic urethane acrylate oligopolymers 15%;
3, the isodecyl acrylate 3%;
4, the third oxidation neopentyl glycol 5%;
5, trimethylolpropane trimethacrylate 12%;
6, Dipentaerythritol five acrylate 8%;
7, polyacrylate solution 2%;
8, polyether-modified polydimethylsiloxane 1%;
9, solvent 33%;
10,2-hydroxy-2-methyl-1-phenyl-1-acetone 2%;
11,1-hydroxyl-cyclohexyl-phenyl ketone 4%.
Embodiment 2
Described coating comprises the various components of following weight percent:
1, six functional groups aliphatic urethane acrylate oligopolymer 16%;
2, two functional group's aliphatic urethane acrylate oligopolymers 14%;
3, the isodecyl acrylate 4%;
4, the third oxidation neopentyl glycol 6%;
5, trimethylolpropane trimethacrylate 10%;
6, Dipentaerythritol five acrylate 7%;
7, polyacrylate solution 1%;
8, polyether-modified polydimethylsiloxane 2%;
9, solvent 35%;
10,2-hydroxy-2-methyl-1-phenyl-1-acetone 3%;
11,1-hydroxyl-cyclohexyl-phenyl ketone 2%.
Embodiment 3
Described coating comprises the various components of following weight percent:
1, six functional groups aliphatic urethane acrylate oligopolymer 17%;
2, two functional group's aliphatic urethane acrylate oligopolymers 13%;
3, the isodecyl acrylate 5%;
4, the third oxidation neopentyl glycol 7%;
5, trimethylolpropane trimethacrylate 8%;
6, Dipentaerythritol five acrylate 6%;
7, polyacrylate solution 1%;
8, polyether-modified polydimethylsiloxane 1%;
9, solvent 36%;
10,2-hydroxy-2-methyl-1-phenyl-1-acetone 3%;
11,1-hydroxyl-cyclohexyl-phenyl ketone 3%.
Embodiment 4
Described coating comprises the various components of following weight percent:
1, six functional groups aliphatic urethane acrylate oligopolymer 19%;
2, two functional group's aliphatic urethane acrylate oligopolymers 11%;
3, the isodecyl acrylate 6%;
4, the third oxidation neopentyl glycol 8%;
5, trimethylolpropane trimethacrylate 7%;
6, Dipentaerythritol five acrylate 6%;
7, polyacrylate solution 1.5%;
8, polyether-modified polydimethylsiloxane 1.5%;
9, solvent 34%;
10,2-hydroxy-2-methyl-1-phenyl-1-acetone 1%;
11,1-hydroxyl-cyclohexyl-phenyl ketone 5%.
Embodiment 5
Described coating comprises the various components of following weight percent:
1, six functional groups aliphatic urethane acrylate oligopolymer 20%;
2, two functional group's aliphatic urethane acrylate oligopolymers 10%;
3, the isodecyl acrylate 5%;
4, the third oxidation neopentyl glycol 9%;
5, trimethylolpropane trimethacrylate 5%;
6, Dipentaerythritol five acrylate 5%;
7, polyacrylate solution 1.3%;
8, polyether-modified polydimethylsiloxane 1.7%;
9, solvent 38%;
10,2-hydroxy-2-methyl-1-phenyl-1-acetone 4%;
11,1-hydroxyl-cyclohexyl-phenyl ketone 1%.
Embodiment 6
Below carry out explanation with the prescription of embodiment 5 described coating to described coating making method, the making method of other prescription is identical, difference only is the difference of composition and the apolegamy difference of mixed solvent;
Specifically, the making method of described coating comprises the steps:
1. mixed solvent preparation: get methylethylketone, butylacetate, propyl carbinol and Virahol, solvent is mixed in proportion standby;
2. oligopolymer monomer blending dispersion: get clean system lacquer cylinder, with six functional groups aliphatic urethane acrylate oligopolymer, two functional group's aliphatic urethane acrylate oligopolymers, isodecyl acrylate, the third oxidation neopentyl glycol, trimethylolpropane trimethacrylate, Dipentaerythritol five acrylate of described ratio, stirred 10-15 minute with the rotating speed that 1200-1500 changes per minute with high speed dispersor;
3. flow agent premix: take by weighing polyacrylate solution, polyether-modified polydimethylsiloxane and solvent in proportion, stir 10-15 minute to mixing with the rotating speed that 600-800 changes per minute with high speed dispersor, standby;
4. light trigger dissolving: weighing 2-hydroxy-2-methyl-1-phenyl-1-acetone, 1-hydroxyl-cyclohexyl-phenyl ketone and mixed solvent in proportion, stirred 10-15 minute with the rotating speed that 600-800 changes per minute with high speed dispersor, to dissolving fully, after the filtration of 500 mesh filter screens, standby;
5. with in the system lacquer cylinder in the standby material input step 2 of above-mentioned preparation, even with 10-15 minute blending dispersion of rotating speed stirring that 600-800 changes per minute with high speed dispersor, the solvent in the employing prescription carries out viscosity and is adjusted into 8.5 ± 0.5 seconds;
6. filter and package with double-deck 400 order filter clothes.
Embodiment 7
The example construction technology
Being example below with PMMA describes the using method of the described coating of the present patent application, but described bed material is not limited to PMMA;
Embodiment 8
The technological standard of the described coating of the present patent application is as described in the following table:
Claims (5)
1. an acrylic list is coated with transparent UV radiation curable coating, it is characterized in that: described coating comprises the various components of following weight percent:
1) six functional groups aliphatic urethane acrylate oligopolymer 15-20%;
2) the two aliphatic urethane acrylate oligopolymer 10-15% of functional group;
3) isodecyl acrylate 3-6%;
4) the third oxidation neopentyl glycol 5-10%;
5) trimethylolpropane trimethacrylate 5-12%;
6) Dipentaerythritol five acrylate 5-8%;
7) polyacrylate solution 1-2%;
8) polyether-modified polydimethylsiloxane 1-2%;
9) solvent 30-40%;
10) 2-hydroxy-2-methyl-1-phenyl-1-acetone 1-4%;
11) 1-hydroxyl-cyclohexyl-phenyl ketone 1-5%.
2. a kind of acrylic list according to claim 1 is coated with transparent UV radiation curable coating, it is characterized in that: described solvent comprises a kind of solvent in methylethylketone, butylacetate, propyl carbinol or the Virahol or the mixed solvent of several solvents.
3. the described acrylic list of claim 1 is coated with the production method of transparent UV radiation curable coating, it is characterized in that: described method comprises the step of following independent preparation:
(1) mixed solvent preparation: solvent is mixed in proportion standby;
(2) oligopolymer monomer blending dispersion: get clean system lacquer cylinder, with six functional groups aliphatic urethane acrylate oligopolymer, two functional group's aliphatic urethane acrylate oligopolymers, isodecyl acrylate, the third oxidation neopentyl glycol, trimethylolpropane trimethacrylate, Dipentaerythritol five acrylate of described ratio, stirred 10-15 minute with the rotating speed that 1200-1500 changes per minute with high speed dispersor;
(3) flow agent premix: take by weighing polyacrylate solution, polyether-modified polydimethylsiloxane and solvent in proportion, stir 10-15 minute to mixing with the rotating speed that 600-800 changes per minute with high speed dispersor, standby;
(4) light trigger dissolving: weighing 2-hydroxy-2-methyl-1-phenyl-1-acetone, 1-hydroxyl-cyclohexyl-phenyl ketone and solvent in proportion, stirred 10-15 minute with the rotating speed that 600-800 changes per minute with high speed dispersor, to dissolving fully, after the filtration of 500 mesh filter screens, standby;
(5) with in the system lacquer cylinder in the standby material input step (2) of above-mentioned preparation, even with 10-15 minute blending dispersion of rotating speed stirring that 600-800 changes per minute with high speed dispersor, the solvent in the employing prescription carries out viscosity and is adjusted into 8.5 ± 0.5 seconds;
(6) filter and package with double-deck 400 order filter clothes.
4. the described acrylic list of claim 1 is coated with the using method of transparent UV radiation curable coating, it is characterized in that, described method comprises the steps: ground pre-treatment → spraying → levelling → preheating → UV curing → polishing → packing
(1) ground pre-treatment:
Dip in clean cotton before the spraying and get 6# industrial naptha or 120# industrial naptha and wipe pollutent on the ground, and electrostatic precipitation, standby;
(2) spraying operation parameter setting and step:
(a) construction environment: temperature 15-35 ℃, relative humidity 45-70%
(b) application mode: aerial spraying, can adopt hand spray or time variable control machine to spray automatically.
(c) device parameter: gravity type boat davit or suct the formula spray gun; Bore 1.0-1.5mm; Air pressure 0.3-0.4mPa; Spray distance 15-20cm;
(d) working viscosity: 8.5-9.5 second;
(e) solidifying the back film thickness is 15-20 μ m;
(f) flow time: room temperature 1-2 minute;
(g) preheating: 55-60 ℃, 3-5 minute;
(h) UV solidifies: adopting linear heat generation rate is the high voltage mercury lamp (105Pa) of 80-120W/cm, and characteristic wavelength is at 250-410nm, with radiation dose 800-1200mJ/cm2 dry solidification.
5. acrylic list according to claim 4 is coated with the using method of transparent UV radiation curable coating, it is characterized in that: described ground comprises PMMA or PC.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100206710A CN102146227A (en) | 2011-01-18 | 2011-01-18 | Transparent acrylic single-coating UV (Ultraviolet) radiation curing coating as well as production method and application method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100206710A CN102146227A (en) | 2011-01-18 | 2011-01-18 | Transparent acrylic single-coating UV (Ultraviolet) radiation curing coating as well as production method and application method thereof |
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| CN102146227A true CN102146227A (en) | 2011-08-10 |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102585690A (en) * | 2011-12-30 | 2012-07-18 | 深圳市嘉卓成科技发展有限公司 | Steel wool-resistant high-hardness ultraviolet (UV) radiation cured coating, and preparation and using methods thereof |
| CN103740261A (en) * | 2013-12-19 | 2014-04-23 | 澳达树熊涂料(惠州)有限公司 | Film-coated UV (ultraviolet) white and bright finish coat with high resistance to yellowing and preparation method thereof |
| CN103788860A (en) * | 2014-01-15 | 2014-05-14 | 中山永辉化工有限公司 | Recoatable UV radiation cured coating for plastic as well as production method and application method of coating |
| CN104937164A (en) * | 2013-01-17 | 2015-09-23 | 阿姆斯特郎世界工业公司 | Curing methods and products produced therefrom |
| CN105754130A (en) * | 2016-04-14 | 2016-07-13 | 广西柳州中嘉知识产权服务有限公司 | Plastic surface hardening treatment method |
| CN109096908A (en) * | 2017-06-21 | 2018-12-28 | 现代自动车株式会社 | The ultraviolet curing priming paint of radio wave transmissions cover for vehicle |
| CN110256951A (en) * | 2019-05-24 | 2019-09-20 | 深圳市嘉卓成科技发展有限公司 | A kind of aqueous UV curing coating and preparation method thereof and application method |
| CN111906004A (en) * | 2020-06-28 | 2020-11-10 | 佛山市三水进发模塑科技有限公司 | Production method of high-gloss UV (ultraviolet) paint spraying product |
| CN112876933A (en) * | 2021-01-21 | 2021-06-01 | 厦门三德信科技股份有限公司 | High-light-transmittance fluorine-free coating and preparation method thereof |
| CN115926609A (en) * | 2022-10-31 | 2023-04-07 | 苏州世华新材料科技股份有限公司 | UV (ultraviolet) curing coating composition with scratch-resistant and protective effects and preparation method thereof |
| CN116116684A (en) * | 2023-03-03 | 2023-05-16 | 上海史密斯品牌管理有限公司 | Acrylic dyeing process applied to logo manufacturing |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102585690A (en) * | 2011-12-30 | 2012-07-18 | 深圳市嘉卓成科技发展有限公司 | Steel wool-resistant high-hardness ultraviolet (UV) radiation cured coating, and preparation and using methods thereof |
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| CN103740261B (en) * | 2013-12-19 | 2016-08-24 | 澳达树熊涂料(惠州)有限公司 | A kind of high color inhibition overlay film UV white and bright finish coat and preparation method thereof |
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| CN103788860B (en) * | 2014-01-15 | 2016-03-30 | 中山永辉化工有限公司 | One can recoat plastic cement UV radiation curable coating and production method and using method |
| CN105754130A (en) * | 2016-04-14 | 2016-07-13 | 广西柳州中嘉知识产权服务有限公司 | Plastic surface hardening treatment method |
| CN109096908A (en) * | 2017-06-21 | 2018-12-28 | 现代自动车株式会社 | The ultraviolet curing priming paint of radio wave transmissions cover for vehicle |
| CN109096908B (en) * | 2017-06-21 | 2021-10-29 | 现代自动车株式会社 | Ultraviolet-curing primer for radio wave transmission cover of vehicle |
| CN110256951A (en) * | 2019-05-24 | 2019-09-20 | 深圳市嘉卓成科技发展有限公司 | A kind of aqueous UV curing coating and preparation method thereof and application method |
| CN111906004A (en) * | 2020-06-28 | 2020-11-10 | 佛山市三水进发模塑科技有限公司 | Production method of high-gloss UV (ultraviolet) paint spraying product |
| CN112876933A (en) * | 2021-01-21 | 2021-06-01 | 厦门三德信科技股份有限公司 | High-light-transmittance fluorine-free coating and preparation method thereof |
| CN115926609A (en) * | 2022-10-31 | 2023-04-07 | 苏州世华新材料科技股份有限公司 | UV (ultraviolet) curing coating composition with scratch-resistant and protective effects and preparation method thereof |
| CN115926609B (en) * | 2022-10-31 | 2023-08-15 | 苏州世华新材料科技股份有限公司 | UV (ultraviolet) curing coating composition with scratch resistance and protection effects and preparation method thereof |
| CN116116684A (en) * | 2023-03-03 | 2023-05-16 | 上海史密斯品牌管理有限公司 | Acrylic dyeing process applied to logo manufacturing |
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Application publication date: 20110810 |