CN102140225A - Transparent thermoplastic elastomer in injection adhering with polypropylene - Google Patents
Transparent thermoplastic elastomer in injection adhering with polypropylene Download PDFInfo
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- CN102140225A CN102140225A CN 201010611887 CN201010611887A CN102140225A CN 102140225 A CN102140225 A CN 102140225A CN 201010611887 CN201010611887 CN 201010611887 CN 201010611887 A CN201010611887 A CN 201010611887A CN 102140225 A CN102140225 A CN 102140225A
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Abstract
The invention relates to a transparent thermoplastic elastomer in injection adhering with polypropylene; the transparent thermoplastic elastomer comprises a polypropylene elastomer, a hydrogenated styrene elastomer, an antioxidant and a mineral extending oil, wherein the weight percentage of the polypropylene elastomer is 8% to 23%, the weight percentage of the hydrogenated styrene elastomer is 35 to 45%, the weight percentage of the antioxidant is 0.1% to 0.2% , and the weight percentage of the mineral extending oil is 40% to 55%. Therefore, the transparent thermoplastic elastomer has high transparency and can be used for products requiring high transparency.
Description
Technical field
The present invention relates to a kind of being used for penetrates sticking transparent thermoplastic elastomer with polypropylene.
Background technology
The existing material that is used to produce bonding PP generally needs to add the PP prescription, and polypropylene (PP) is lighter a kind of in the common plastics, and its electrical property excellence can be used as the hot high-frequency insulation material of moisture-proof and uses.PP belongs to crystalline polymer, presents than shrinking percentage (1.0%-1.5%) greatly because of specific volume changes greatly, degree of molecular orientation is high during the melt condensation.Yet this bonding PP material has following shortcoming: its transparency is not high, need can not be used to the product of highly transparent.
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Summary of the invention
The technical problem to be solved in the present invention provides high being used for of a kind of transparency and penetrates sticking transparent thermoplastic elastomer with polypropylene.The present invention is achieved through the following technical solutions:
A kind of being used for of the present invention penetrated sticking transparent thermoplastic elastomer with polypropylene, comprises polypropylene elastomer, hydrogenated styrene elastomerics, antioxidant, mineral-filled oil; Wherein, to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be 40%-55% for 0.1%-0.2%, mineral-filled oil for 35%-45%, antioxidant for 8%-23%, hydrogenated styrene elastomerics to polypropylene elastomer.
As improvement, wherein, polypropylene elastomer accounts for that weight percent is 23%, the hydrogenated styrene elastomerics accounts for that weight percent is 36%, antioxidant accounts for that weight percent is 0.1%, to account for weight percent be 40.9% to mineral-filled oil.
As improvement, wherein, polypropylene elastomer accounts for that weight percent is 13%, the hydrogenated styrene elastomerics accounts for that weight percent is 37%, antioxidant accounts for that weight percent is 0.15%, to account for weight percent be 49.85% to mineral-filled oil.
As improvement, wherein, polypropylene elastomer accounts for that weight percent is 8%, the hydrogenated styrene elastomerics accounts for that weight percent is 41.8%, antioxidant accounts for that weight percent is 0.2%, to account for weight percent be 50% to mineral-filled oil.
As improvement, described hydrogenated styrene elastomerics is SEBS, SEBS is to be end segment with the polystyrene, the ethylene-butene copolymer that obtains with the polyhutadiene hydrogenation is the triblock copolymer of middle elastomeric block, SEBS does not contain unsaturated double-bond, therefore have satisfactory stability and ageing resistance, model that the present invention adopts is one or any mixed multiple among SEBS G1650, SEBS G1651, SEBS G6933, SEBS 4033, the SEBS 4055.
As improvement, described mineral-filled oil is paraffin-base alkanes oil, and its flash-point is more than 200 ℃, and under 25 ℃, viscosity is 15～20Cps.
As improvement, described antioxidant is anti-oxidant 1010 and anti-oxidant 168 mixtures by 1:1～2 mixed.
A kind of being used for of the present invention penetrated sticking transparent thermoplastic elastomer with polypropylene, owing to comprise polypropylene elastomer, hydrogenated styrene elastomerics, antioxidant, mineral-filled oil, therefore, it has the high benefit of transparency, need can be used to the product of highly transparent.
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Embodiment
A kind of being used for of the present invention penetrated sticking transparent thermoplastic elastomer with polypropylene, comprises polypropylene elastomer, hydrogenated styrene elastomerics, antioxidant, mineral-filled oil; Wherein, to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be 40%-55% for 0.1%-0.2%, mineral-filled oil for 35%-45%, antioxidant for 8%-23%, hydrogenated styrene elastomerics to polypropylene elastomer.Therefore, it has the high benefit of transparency, need can be used to the product of highly transparent.
Embodiment one: wherein, polypropylene elastomer accounts for that weight percent is 23%, the hydrogenated styrene elastomerics accounts for that weight percent is 36%, antioxidant accounts for that weight percent is 0.1%, to account for weight percent be 40.9% to mineral-filled oil.
Embodiment two: wherein, polypropylene elastomer accounts for that weight percent is 13%, the hydrogenated styrene elastomerics accounts for that weight percent is 37%, antioxidant accounts for that weight percent is 0.15%, to account for weight percent be 49.85% to mineral-filled oil.
Embodiment three: wherein, polypropylene elastomer accounts for that weight percent is 8%, the hydrogenated styrene elastomerics accounts for that weight percent is 41.8%, antioxidant accounts for that weight percent is 0.2%, to account for weight percent be 50% to mineral-filled oil.
In the foregoing description, described hydrogenated styrene elastomerics is SEBS, SEBS is to be end segment with the polystyrene, the ethylene-butene copolymer that obtains with the polyhutadiene hydrogenation is the triblock copolymer of middle elastomeric block, SEBS does not contain unsaturated double-bond, therefore have satisfactory stability and ageing resistance, model that the present invention adopts is one or any mixed multiple among SEBS G1650, SEBS G1651, SEBS G6933, SEBS 4033, the SEBS 4055.Described mineral-filled oil is paraffin-base alkanes oil, and its flash-point is more than 200 ℃, and under 25 ℃, viscosity is 15～20Cps.Described antioxidant is anti-oxidant 1010 and anti-oxidant 168 mixtures by 1:1～2 mixed.
A kind of being used for of the present invention penetrated sticking transparent thermoplastic elastomer with polypropylene, owing to comprise polypropylene elastomer, hydrogenated styrene elastomerics, antioxidant, mineral-filled oil, therefore, it has the high benefit of transparency, need can be used to the product of highly transparent.
Claims (7)
1. one kind is used for penetrating sticking transparent thermoplastic elastomer with polypropylene, comprises polypropylene elastomer, hydrogenated styrene elastomerics, antioxidant, mineral-filled oil; Wherein, to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be 40%-55% for 0.1%-0.2%, mineral-filled oil for 35%-45%, antioxidant for 8%-23%, hydrogenated styrene elastomerics to polypropylene elastomer.
2. according to claim 1 being used for penetrated sticking transparent thermoplastic elastomer with polypropylene, it is characterized in that: wherein, polypropylene elastomer accounts for that weight percent is 23%, the hydrogenated styrene elastomerics accounts for that weight percent is 36%, antioxidant accounts for that weight percent is 0.1%, to account for weight percent be 40.9% to mineral-filled oil.
3. according to claim 1 being used for penetrated sticking transparent thermoplastic elastomer with polypropylene, it is characterized in that: wherein, polypropylene elastomer accounts for that weight percent is 13%, the hydrogenated styrene elastomerics accounts for that weight percent is 37%, antioxidant accounts for that weight percent is 0.15%, to account for weight percent be 49.85% to mineral-filled oil.
4. according to claim 1 being used for penetrated sticking transparent thermoplastic elastomer with polypropylene, it is characterized in that: wherein, polypropylene elastomer accounts for that weight percent is 8%, the hydrogenated styrene elastomerics accounts for that weight percent is 41.8%, antioxidant accounts for that weight percent is 0.2%, to account for weight percent be 50% to mineral-filled oil.
5. according to claim 1 being used for penetrated sticking transparent thermoplastic elastomer with polypropylene, it is characterized in that: described hydrogenated styrene elastomerics is SEBS, SEBS is to be end segment with the polystyrene, the ethylene-butene copolymer that obtains with the polyhutadiene hydrogenation is the triblock copolymer of middle elastomeric block, SEBS does not contain unsaturated double-bond, therefore have satisfactory stability and ageing resistance, model that the present invention adopts is one or any mixed multiple among SEBS G1650, SEBS G1651, SEBS G6933, SEBS 4033, the SEBS 4055.
6. according to claim 1 being used for penetrated sticking transparent thermoplastic elastomer with polypropylene, it is characterized in that: described mineral-filled oil is paraffin-base alkanes oil, and its flash-point is more than 200 ℃, and under 25 ℃, viscosity is 15～20Cps.
7. according to claim 1 being used for penetrated sticking transparent thermoplastic elastomer with polypropylene, it is characterized in that: described antioxidant is anti-oxidant 1010 and anti-oxidant 168 mixtures by 1:1～2 mixed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010611887 CN102140225A (en) | 2010-12-29 | 2010-12-29 | Transparent thermoplastic elastomer in injection adhering with polypropylene |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010611887 CN102140225A (en) | 2010-12-29 | 2010-12-29 | Transparent thermoplastic elastomer in injection adhering with polypropylene |
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| CN102140225A true CN102140225A (en) | 2011-08-03 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 201010611887 Pending CN102140225A (en) | 2010-12-29 | 2010-12-29 | Transparent thermoplastic elastomer in injection adhering with polypropylene |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103102584A (en) * | 2011-11-11 | 2013-05-15 | 中国石油化工股份有限公司 | Hydrogenated block polymer elastomer-polypropylene blend |
| CN103172963A (en) * | 2011-12-22 | 2013-06-26 | 中纺投资发展股份有限公司 | High-weld-strength thermoplastic elastomer material and preparation method thereof |
| CN105175977A (en) * | 2015-09-29 | 2015-12-23 | 广东波斯科技股份有限公司 | Low-exhalation-rate transparent TPE elastomer and preparation method thereof |
| WO2017084216A1 (en) * | 2015-11-18 | 2017-05-26 | 南通普力马弹性体技术有限公司 | Wear-resistant and high-resilience-rate tpe caster material used for bonding pp, and preparation method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050014891A1 (en) * | 2003-07-16 | 2005-01-20 | Quinn Thomas H. | Low odor, light color, disposable article construction adhesive |
| CN1931919A (en) * | 2006-09-07 | 2007-03-21 | 浙江俊尔新材料有限公司 | Thermoplastic elastomer for injection adhering nylon material |
| CN101676327A (en) * | 2008-09-17 | 2010-03-24 | 东莞市卡帝德塑胶原料有限公司 | Thermoplastic elastomer for sucking with polypropylene material |
-
2010
- 2010-12-29 CN CN 201010611887 patent/CN102140225A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050014891A1 (en) * | 2003-07-16 | 2005-01-20 | Quinn Thomas H. | Low odor, light color, disposable article construction adhesive |
| CN1931919A (en) * | 2006-09-07 | 2007-03-21 | 浙江俊尔新材料有限公司 | Thermoplastic elastomer for injection adhering nylon material |
| CN101676327A (en) * | 2008-09-17 | 2010-03-24 | 东莞市卡帝德塑胶原料有限公司 | Thermoplastic elastomer for sucking with polypropylene material |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103102584A (en) * | 2011-11-11 | 2013-05-15 | 中国石油化工股份有限公司 | Hydrogenated block polymer elastomer-polypropylene blend |
| CN103102584B (en) * | 2011-11-11 | 2015-07-01 | 中国石油化工股份有限公司 | Hydrogenated block polymer elastomer-polypropylene blend |
| CN103172963A (en) * | 2011-12-22 | 2013-06-26 | 中纺投资发展股份有限公司 | High-weld-strength thermoplastic elastomer material and preparation method thereof |
| CN103172963B (en) * | 2011-12-22 | 2015-07-29 | 中纺投资发展股份有限公司 | Thermoplastic elastic material of a kind of high welding strength and preparation method thereof |
| CN105175977A (en) * | 2015-09-29 | 2015-12-23 | 广东波斯科技股份有限公司 | Low-exhalation-rate transparent TPE elastomer and preparation method thereof |
| CN105175977B (en) * | 2015-09-29 | 2018-03-06 | 广东波斯科技股份有限公司 | A kind of low transparent TPE elastomer of precipitation and preparation method thereof |
| WO2017084216A1 (en) * | 2015-11-18 | 2017-05-26 | 南通普力马弹性体技术有限公司 | Wear-resistant and high-resilience-rate tpe caster material used for bonding pp, and preparation method |
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Application publication date: 20110803 |