CN102103071A - On-site absorption spectrum gas analysis system - Google Patents
On-site absorption spectrum gas analysis system Download PDFInfo
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- CN102103071A CN102103071A CN2010106100109A CN201010610010A CN102103071A CN 102103071 A CN102103071 A CN 102103071A CN 2010106100109 A CN2010106100109 A CN 2010106100109A CN 201010610010 A CN201010610010 A CN 201010610010A CN 102103071 A CN102103071 A CN 102103071A
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Abstract
The invention discloses an on-site absorption spectrum gas analysis system. The system comprises a light transmitting unit, a light receiving unit and a signal analysis unit, wherein the light transmitting unit comprises a light source and a converging lens. The system is characterized in that: one end of the converging lens back to the light source is provided with an arc surface; the arc surface end of the converging lens is provided with a calibration chamber of which one end is provided with an opening and the other end is closed; the opening end is hermetically connected with the converging lens; an A-A section on the middle part of the converging lens is in any geometrical shape; and light emitted by the light source passes through the converging lens and the calibration chamber and enters a medium to be measured. The system has the advantages of real-time on-line calibration, high measuring accuracy and measuring sensitivity, simple and reliable structure, easily realized explosion isolation function, no need of blowing, low sealing requirement and the like, and is convenient to manufacture.
Description
Technical field
The present invention relates to spectral analysis, particularly a kind of formula absorption spectrum gas analysis on the throne system.
Background technology
Formula gas analysis system on the throne is different with traditional sampling mode gas analysis system, it does not need sampling and preprocessing process, overcome a lot of defectives of traditional sampling mode gas analysis system, it is simple to have system, the reliability height, the measurement response speed is fast, the analysis precision height, advantage such as concentration that can measurement gas and speed is at modern industry, scientific research, fields such as environmental protection have obtained application more and more widely.Formula gas analysis system on the throne can adopt multiple absorption spectrum technology to realize, as Non-Dispersive Infra-red (NDIR) spectrum (NDIR) technology, and differential optical absorption spectrum (DOAS) technology, tunable semiconductor laser absorption spectrum (TDLAS) technology.
As shown in Figure 1, a kind of semi-conductor laser absorption spectrum gas analyzing system comprises Optical Transmit Unit 1, light receiving unit 2 and signal analysis unit 3, and described Optical Transmit Unit 1 and light receiving unit 2 are installed in the both sides of tested gas 4.Described Optical Transmit Unit comprises semiconductor laser 11, convergent lens 12 and glass window 13; Described light receiving unit 2 comprises convergent lens 20, light receiving element 21 and glass window 22.When described analytic system needs were explosion-proof, described glass window 13,22 used tempered glass, and in order to satisfy the needs of explosion suppresion surface size, the diameter of tempered glass 13,22 is bigger; Simultaneously a lot of on-position measures are used also needs wide-aperture light beam to reduce the inhomogeneous decay that the particle scattering produces measuring light in the tested gas, so the diameter of convergent lens 12 and convergent lens 20 is bigger.
The course of work of described analytic system is as follows: described semiconductor laser 11 is luminous, be converged to directional light through the convergent lens 12 in the Optical Transmit Unit 1, pass tested gas 4 through glass window 13 afterwards, assemble through convergent lens 20 again after passing the glass window 22 of light in passing light receiving unit 2 of tested gas 4, received by described light receiving element 21 afterwards, and received signal feed signals analytic unit 3 is analyzed, thereby obtains the concentration etc. of tested gas 4.
In a lot of application scenarios, analytic system need be installed in the inflammable and explosive environment, as contains in the workspace of hazardous gases such as carbon monoxide or hydrogen.Just need carry out explosion-proof design in these occasions, and obtain explosion-proof authentication analytic system.Explosion-proof design has multiple mode, as positive-pressure explosion-proof, flame proof, intrinsic safe explosion-proof etc.Because flame proof has the reliability height, uses superiority such as convenient, obtains to use very widely.
After laser is launched by semiconductor laser 11, through each optical components such as convergent lens 12, glass window 13, glass window 22, convergent lens 20 surperficial the time, although most laser energy refraction passing through optical device, but the sub-fraction laser energy can be received by light receiving element after interflection or scattering by the surface of above-mentioned optical device again, therefore, can there be phase differential between each secondary reflection of arrival light receiving element, the scattering laser bundle, produces multiple-beam interference (etalon) phenomenon.This multiple-beam interference phenomenon can exert an influence to the transmitance of measuring beam, thereby changes the light signal that light receiving element receives.Because the absorption spectroanalysis technology is to come analytical gas concentration by the light signal that the analysis light receiving element receives, above-mentioned multiple-beam interference phenomenon can produce the gas concentration analysis and disturb, and this interference is commonly called the etalon noise.In the process of the scanned absorption line of optical maser wavelength, phase differential constantly changes with optical maser wavelength between the multiple beam; That is to say that the transmitance of light beam changes in the process of the scanned absorption line of optical maser wavelength, therefore, the etalon noise changes with the variation of light frequency, and Fig. 2 has provided the relation of a kind of etalon noise and light frequency.In addition, be subjected to the influence of various environmental factors (temperature variation, mechanical vibration etc.), small variation often takes place in the distance between each optical component surface; Because optical maser wavelength is shorter, small variation will cause the obvious change of phase differential between the multiple beam, thereby significantly change the transmitance variation that above-mentioned multiple-beam interference produces, that is to say that the etalon noise can be changed by various Effect of Environmental with the distribution of light frequency, and then bring difficulty for accurate gas parameter analysis.Fig. 3 has provided is not having the gas single line absorption spectrum that analytic system records under the etalon noise situation, can significantly descend in the signal to noise ratio (S/N ratio) that the gas single line absorption spectrum that records under the etalon noise situation is arranged, as shown in Figure 4.For the fixed wave length measuring method, the small drift of wavelength or the variation of environmental factor also all can cause the variation of the apparent transmitance of optical system, thereby influence measuring accuracy.
Above-mentioned analytic system comes with some shortcomings: 1) structure relative complex, adopt convergent lens to come converging and diverging light, and also need tempered glass to realize flame proof simultaneously; Owing to adopt a plurality of optical components, increased the reflecting surface number, increased the etalon optical noise, reduce measuring accuracy and measured sensitivity; 2) when measuring some concentration of medium, as when measuring trace water and concentration of oxygen, because between semiconductor laser, convergent lens, the flame proof slide, light receiving element, all there are many spaces between convergent lens and the flame proof slide,, will exert an influence measurement if there is tested gas composition in gas in these spaces, current approach is or adopts nitrogen purging, perhaps adopts the method for nitrogen embedding to avoid existing in these spaces these tested gases; But purge the complexity that has increased system, encapsulating method can produce bigger measurement inaccuracy when taking place to leak in addition, especially when measured medium concentration is low, ppm magnitude for example, therefore, Optical Transmit Unit 1, light receiving unit 2 all need strict seal, and anti-leak requires high, and this has further increased the complicacy of system design and manufacturing.
In the use of above-mentioned analytic system, the aging meeting of light source and electronic devices and components etc. causes the slow drift of analytic system parameter, and therefore the accuracy that influence is measured need periodically demarcate formula gas analysis system on the throne.
As shown in Figure 5, U.S. Pat 5517314 discloses a kind of gas analysis system on the throne, and this system has calibrating function on the throne, specifically comprises light emitting devices, demarcates and measuring channel optical pickup apparatus, analytical equipment; Principle of work is as follows: the light that light source sends is reflected into two bundle directional lights through two concave mirrors, passes through closed conduct and measuring channel respectively, enters into optical pickup apparatus, reflects into optical receiver through two concave mirrors, send the analytical equipment analysis by optical fiber afterwards.On demarcating light path, outside the tested gas pipeline marked gas chamber is arranged, chamber also can be placed in the tested process gas pipeline and allow the demarcation light beam pass through, the tested gas of zero gas or concentration known charges into chamber by valve control, and purge gas feeds measuring channel by ventilating joint; When the needs timing signal, the computer control motor is seated in block body and measures on the light path, opens valve, charges into the tested gas of zero gas or concentration known at chamber, demarcates the light of light path and sends into analytical equipment by receiver.During measurement, the computer control motor is seated in block body and demarcates on the light path, and measuring beam is sent into analytical equipment by receiver.
This system can realize demarcation on the throne, but complex structure, such as: in the Optical Transmit Unit the inside, the light that light source sends becomes two bundle directional lights through the concave mirror back reflection, reflect into a receiver by concave mirror again, this exigent machining and assembly precision at this two bundles directional light of light receiving unit; Have, demarcate and measure and need independently carry out in two pipelines, can not effectively utilize measuring channel and demarcate, causing increases difficulty when installing and debug; Also have,, block body well to block measuring beam, enter optical receiver, reduce stated accuracy otherwise have measuring beam at timing signal.
Summary of the invention
In order to solve above shortcomings in the prior art, the invention provides a kind of can real-time online demarcation, measuring accuracy and measurement sensitivity higher, simple and reliable for structure, be easy to realize the flame proof function, need not to purge, seal request is low and easily manufactured formula absorption spectrum gas analysis on the throne system.
For achieving the above object, the present invention is by the following technical solutions:
A kind of formula absorption spectrum gas analysis on the throne system comprises Optical Transmit Unit, light receiving unit and signal analysis unit; Described Optical Transmit Unit comprises light source, convergent lens; Characteristics are:
Described convergent lens is a cambered surface back to an end of light source; At the cambered surface end of convergent lens the demarcation chamber of one end opening, end sealing is set, openend and convergent lens are tightly connected; The A-A cross section of the center section of described convergent lens is a random geometry; The light that described light source sends enters measured medium by described convergent lens, after demarcating chamber.
As preferably, light beam chief ray light path is less than or equal to 7mm between described light source and the described convergent lens.
As preferably, an end of the relative light source of described convergent lens is the inclined-plane.
The invention allows for another formula absorption spectrum gas analysis on the throne system, comprise Optical Transmit Unit, light receiving unit and signal analysis unit, described light receiving unit comprises light receiving element, convergent lens; Characteristics are:
Described convergent lens is a cambered surface back to an end of light receiving element; At the cambered surface end of convergent lens the demarcation chamber of one end opening, end sealing is set, the cambered surface end of openend and convergent lens is tightly connected; The A-A cross section of the center section of described convergent lens is a random geometry; The light that passes from measured medium is received by light receiving element after by described demarcation chamber, convergent lens.
As preferably, light beam chief ray light path is less than or equal to 7mm between described light receiving element and the described convergent lens.
As preferably, an end of the relative light receiving element of described convergent lens is the inclined-plane.
As preferably, the thickness of above-mentioned convergent lens is more than or equal to 20mm.
As preferably, the diameter of the minimum circle-cover in above-mentioned A-A cross section is more than or equal to 25mm.
As preferably, the A-A cross section of the center section of above-mentioned convergent lens is circle, rectangle, regular polygon, in irregularly shaped any one.
Further, the front end of above-mentioned convergent lens is installed securing member.
As preferably, the blind end of described demarcation chamber is the inclined-plane.
As preferably, described demarcation chamber comprises cartridge, diaphragm.
As preferably, described diaphragm has the angle of wedge.
The minimum circle-cover in above-mentioned cross section is defined as: the circle that can surround the diameter minimum in this cross section.
Compared with prior art, the beneficial effect that has of the present invention is:
1, the end at convergent lens has fixedly mounted the demarcation chamber, is filled with the gas that substitutes demarcation usefulness in chamber, thereby has realized real-time, the on-line proving of analytic system.
2, improved measuring accuracy.
A, demarcate the sealing of chamber one end, an end opening, and openend and convergent lens be tightly connected, reduced optical reflection face quantity, lowered the optics etalon noise of analytic system.
B, lens not only have the effect of assembling collimation emission light beam, can also realize the effect of system's flame proof, have reduced the number of system optics components and parts, have reduced optical reflection face quantity, and then have reduced the optics etalon noise of analytic system.
C, owing to reduced between light source (as laser instrument) and convergent lens 14 and sensor and the convergent lens 23 apart from (the etalon noise that produces between the above-mentioned optical element face in system is the most obvious), the FSR of etalon noise (Free Spectral Range) obviously increases, and just the etalon noise is slower with the variation of light frequency; Because of more easily adopting background correct algorithms such as background match to remove the influence of the etalon noise background of slow variation, can improve measuring accuracy preferably.
D, convergent lens all are the inclined-plane near an end of light source (as laser instrument) or sensor, an end of demarcation chamber, avoided with light source (as laser instrument) and sensor in semiconductor wafer surface be parallel to each other, also reduced the optics etalon noise of system effectively.
3, need not to purge and seal request low.Medium absorbs with the light path of light in medium and is directly proportional, owing to reduced optics, the distance between each parts is all nearer simultaneously, and air significantly reduces for the influence of measurement result between parts, can need not to purge or sealing.
4, simple in structure, reliability is better.The thick convergent lens that uses is not only realized converging action, can also realize the function of flame proof simultaneously, has reduced optics, and is simple in structure.
5, big clear aperature can more easily realize flame proof and improve the performance of in site measurement.
6, thermal insulation effect is better, owing to used thicker convergent lens, extraneous heat is difficult for being delivered to the light source (as laser instrument) in the Optical Transmit Unit, thus make analytic system can be under the higher occasion of tested gas temperature operate as normal.
Description of drawings
Fig. 1 is the structural representation of semi-conductor laser absorption spectrum gas analyzing system in the prior art;
Fig. 2 is the synoptic diagram that concerns of a kind of etalon noise and light frequency;
Fig. 3 is the single line absorption spectrum synoptic diagram at a gas absorption spectrum line that does not have to record under the etalon noise situation;
Fig. 4 is having the single line absorption spectrum synoptic diagram of a gas absorption spectrum line that records under the etalon noise situation;
Fig. 5 is the structural representation that has the gas analysis system of calibrating function on the throne in the prior art;
Fig. 6 is a semi-conductor laser absorption spectrum water microanalysis system architecture synoptic diagram among the embodiment 1;
Fig. 7 is a semi-conductor laser absorption spectrum trace hydrogen sulfide analytic system structural representation among the embodiment 2;
Fig. 8 is convergent lens among the embodiment, the structural representation of demarcating chamber;
Fig. 9 is the A-A sectional view of the center section of convergent lens among the embodiment 2;
Figure 10 is a semi-conductor laser absorption spectrum water microanalysis system architecture synoptic diagram among the embodiment 3;
Figure 11 is the A-A sectional view of the center section of convergent lens among the embodiment 3;
Figure 12 is the A-A sectional view of the center section of convergent lens among the embodiment 4.
Embodiment
Below in conjunction with drawings and Examples, the present invention is done further detailed description.
Embodiment 1:
As shown in Figure 6, a kind of semi-conductor laser absorption spectrum micro-moisture analysis system is used for detecting the concentration of tested gas 4 minor amount of water, also satisfies the flame proof requirement simultaneously.Described analytic system comprises Optical Transmit Unit 1, light receiving unit 2 and signal analysis unit 3, and described Optical Transmit Unit 1 and light receiving unit 2 are installed in the both sides of tested gas 4.
Described Optical Transmit Unit 1 comprises housing, semiconductor laser 11 and driving circuit 10, first convergent lens 14 and sleeve 5, the described semiconductor laser 11 and first convergent lens 14 are installed in the described sleeve 5, and wherein semiconductor laser 11 is installed on the laser socket 15.Described semiconductor laser 11 driving circuits 10 are installed in the described housing.14 of described sleeve and described first convergent lenses enclose 16 by seal such as O shape and seal, and the front end of first convergent lens 14 is also installed lens securing member 17 simultaneously.
As shown in Figure 8, described first convergent lens 14 is thick oblique-convex lens, and an end is the inclined-plane, and the other end is a sphere, and the radius-of-curvature of its sphere is 13.66mm.Be connected with at the sphere end of convergent lens and demarcate chamber 7, this demarcates the sealing of chamber 7 one ends, is the inclined-plane, other end opening, and be tightly connected with the sphere end of convergent lens.Described demarcation chamber 7 is made up of the diaphragm 72 of the cartridge 71 and the band angle of wedge.Demarcating chamber 7 inner sealings has the carbon dioxide of concentration known.
The A-A cross section of the center section of described first convergent lens 14 is circular, diameter is 35mm, the first convergent lens thickness (the chief ray light path of laser beam in first convergent lens, be the spacing of center, inclined-plane and sphere centre) be 31mm, the angle of inclined-plane and face of cylinder longest bus-bar is 76 °, semiconductor laser 11 emitted laser are not entered in the laser instrument 11 after the inclined-plane reflection, reduce the optical noise of system.The meaning on described inclined-plane is: both can be plane inclined, also can be the cambered surface that tilts.The luminous point of described semiconductor laser 11 and inclined-plane center distance are 5.6mm.Laser beam chief ray and face of cylinder central axis angle are 7.49 °, guarantee that the laser beam chief ray is from the sphere centre outgoing.First convergent lens 14 and the sleeve 5 common flame proof functions that realize, flameproof joint between the two is the inclined-plane of lens 14 and the composition surface, inclined-plane of sleeve 5.According to GB GB3836.2-2000, in 9.5mm～15.8mm scope, the face composition surface of making even is 10mm at the width requirement on the volume conditions lower plane composition surface of Optical Transmit Unit 1; If the effective clear aperature that requires first convergent lens 14 is greater than 13mm, the face of cylinder diameter of then described first convergent lens 14 be 2 times of plane engaging surface width to add clear aperature be 33mm, present embodiment is got 35mm.
Described light receiving unit 2 comprises second convergent lens 23, photoelectric sensor 21.The size of described second convergent lens 23 is with first convergent lens 14.23 of lens mount on the described light receiving unit 2 and described second convergent lenses enclose 24 by seal such as O shape and seal, and the front end of second convergent lens 23 is also installed lens securing member 25 simultaneously.
The course of work of above-mentioned analytic system is:
Laser enters in the tested gas after passing convergent lens, and the laser after being absorbed by water vapor passes and demarcates chamber, (carbon dioxide of demarcating in the chamber does not absorb v=6963.17cm to second convergent lens
-1Laser), be detected device at last and receive and be converted to electric signal;
Analytic unit utilizes Beer-Lambert law to handle above-said current signal, thereby draws the concentration of water vapor, and computing formula is as follows:
Wherein, C is a concentration value, and V is a peak-to-peak value, b
0Be the coefficient at zero point, K is a calibration coefficient, and P is a pressure, and L is a light path, and S (T) is that line is strong, and (P T) is the temperature and pressure compensation matrix to B.
When described analytic system needs timing signal, with the emission wavelength of semiconductor laser be tuned to the characteristic absorption spectrum spectral line v=6963.94cm of carbon dioxide
-1
Laser enters in the tested gas after passing convergent lens, and tested gas not absorption frequency is v=6963.94cm
-1Light, laser passes and demarcates chamber afterwards, second convergent lens (is demarcated the carbon dioxide absorption v=6963.94cm in the chamber
-1Laser), be detected device at last and receive and be converted to electric signal;
Analytic unit utilizes Beer-Lambert law to handle above-said current signal, thereby draws the calibration coefficient K of carbon dioxide
i, computing formula is as follows:
Wherein, C
iBe the concentration of carbon dioxide value, V
iBe the peak-to-peak value of carbon dioxide absorption, L
iBe light path, S
i(T) be that line is strong.
Utilize the calibration coefficient K of above-mentioned carbon dioxide
iDraw the calibration coefficient K of water vapor:
K＝m·K
i
M is a conversion coefficient.
Embodiment 2:
As shown in Figure 7, a kind of semi-conductor laser absorption spectrum trace hydrogen sulfide analytic system is used to detect the concentration of trace hydrogen sulfide, also satisfies the flame proof requirement simultaneously.As different from Example 1:
1, as shown in Figure 8, be provided with at the sphere end of second convergent lens and demarcate chamber 6, this demarcates the sealing of chamber 6 one ends, is the inclined-plane, other end opening, and be tightly connected with the sphere end of second convergent lens.Demarcating chamber 6 inner sealings has the CO gas of concentration known.
2, the A-A cross section of the center section of described first and second convergent lenses is squares, and as shown in Figure 9, the diameter of described square minimum circle-cover is 40mm.
3, demarcate the CO gas that is filled with concentration known in the chamber.
4, use the center wave number to be 6290.25cm
-1The characteristic absorption spectrum spectral line 31 of sulfuretted hydrogen measure sulfuretted hydrogen, the center wave number of selected carbon monoxide is 6292.32cm
-1The characteristic absorption spectrum spectral line, above-mentioned optic spectrum line is in the wavelength tuning range of semiconductor laser.
Embodiment 3:
A kind of semi-conductor laser absorption spectrum micro-moisture analysis system is used to detect the concentration of micro-vaporous water, also satisfies the flame proof requirement simultaneously.As different from Example 1:
1, as shown in figure 10, Optical Transmit Unit 1 and light receiving unit are in the same side of tested gas 4, the light that Optical Transmit Unit 1 sends passes convergent lens 14, demarcates chamber 7, mirror 30,31 reflections are reflected after the tested gas 4, pass tested gas 4, convergent lens 23 afterwards again, received by photoelectric sensor 21 at last.
2, the A-A cross section of the center section of described first and second convergent lenses is oval, as shown in figure 11, the diameter of described oval-shaped minimum circle-cover is 45mm, first, second convergent lens thickness (the chief ray light path of laser beam in first, second convergent lens, the i.e. spacing of center, inclined-plane and sphere centre) is 20mm.
Embodiment 4:
A kind of semi-conductor laser absorption spectrum micro-moisture analysis system is used to detect the concentration of micro-vaporous water, also satisfies the flame proof requirement simultaneously.As different from Example 1:
The A-A cross section of the center section of described first and second convergent lenses is irregular figures, as shown in figure 12, the diameter of the minimum circle-cover of described irregular figure is 25mm, first, second convergent lens thickness (the chief ray light path of laser beam in first, second convergent lens, the i.e. spacing of center, inclined-plane and sphere centre) is 31mm.
It is pointed out that above-mentioned embodiment should not be construed as limiting the scope of the invention.Adopting semiconductor laser among the embodiment, can also be other light source certainly, as LED, ultraviolet source etc., according to actual needs this and to change Different Light be the state of the art.Key of the present invention is, at the cambered surface end of convergent lens the demarcation chamber of one end opening, end sealing is set, and openend and convergent lens are tightly connected.Under the situation that does not break away from spirit of the present invention, any type of change that the present invention is made all should fall within protection scope of the present invention.
Claims (13)
1. a formula absorption spectrum gas analysis on the throne system comprises Optical Transmit Unit, light receiving unit and signal analysis unit; Described Optical Transmit Unit comprises light source, convergent lens; It is characterized in that:
Described convergent lens is a cambered surface back to an end of light source; At the cambered surface end of convergent lens the demarcation chamber of one end opening, end sealing is set, openend and convergent lens are tightly connected; The A-A cross section of the center section of described convergent lens is a random geometry; The light that described light source sends enters measured medium by described convergent lens, after demarcating chamber.
2. a formula absorption spectrum gas analysis on the throne system comprises Optical Transmit Unit, light receiving unit and signal analysis unit, and described light receiving unit comprises light receiving element, convergent lens; It is characterized in that:
Described convergent lens is a cambered surface back to an end of light receiving element; At the cambered surface end of convergent lens the demarcation chamber of one end opening, end sealing is set, openend and convergent lens are tightly connected; The A-A cross section of the center section of described convergent lens is a random geometry; The light that passes from measured medium is received by light receiving element after by described demarcation chamber, convergent lens.
3. analytic system according to claim 1 is characterized in that: light beam chief ray light path is less than or equal to 7mm between described light source and the described convergent lens.
4. analytic system according to claim 1 is characterized in that: an end of the relative light source of described convergent lens is the inclined-plane.
5. analytic system according to claim 2 is characterized in that: light beam chief ray light path is less than or equal to 7mm between described light receiving element and the described convergent lens.
6. analytic system according to claim 2 is characterized in that: an end of the relative light receiving element of described convergent lens is the inclined-plane.
7. analytic system according to claim 1 and 2 is characterized in that: the thickness of described convergent lens is more than or equal to 20mm.
8. analytic system according to claim 1 and 2 is characterized in that: the diameter of the minimum circle-cover in described A-A cross section is more than or equal to 25mm.
9. analytic system according to claim 1 and 2 is characterized in that: the A-A cross section of the center section of described convergent lens is circle, rectangle, regular polygon, in irregularly shaped any one.
10. analytic system according to claim 1 and 2 is characterized in that: the cambered surface end of the openend of described demarcation chamber and convergent lens is tightly connected.
11. analytic system according to claim 1 and 2 is characterized in that: the blind end of described demarcation chamber is the inclined-plane.
12. analytic system according to claim 1 and 2 is characterized in that: described demarcation chamber comprises cartridge, diaphragm.
13. analytic system according to claim 12 is characterized in that: described diaphragm has the angle of wedge.
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| CN102749138A (en) * | 2012-06-11 | 2012-10-24 | 中国科学院安徽光学精密机械研究所 | Spectrum calibration method based on sun and atmosphere characteristic spectrum in hyperspectral remote sensor flight |
| CN102749138B (en) * | 2012-06-11 | 2014-03-26 | 中国科学院安徽光学精密机械研究所 | Spectrum calibration method based on sun and atmosphere characteristic spectrum in hyperspectral remote sensor flight |
| CN105300905A (en) * | 2015-11-10 | 2016-02-03 | 上海禾赛光电科技有限公司 | Machine-mounted gas telemetering system and method |
| CN105300905B (en) * | 2015-11-10 | 2018-12-07 | 上海禾赛光电科技有限公司 | Machine-carried type gas remote measurement system and method |
| CN105466872A (en) * | 2015-12-30 | 2016-04-06 | 聚光科技(杭州)股份有限公司 | Calibration method for in-situ gas analyzer |
| CN110036278A (en) * | 2016-12-12 | 2019-07-19 | 黑拉有限责任两合公司 | The measuring device and method for micronic dust measurement for motor vehicle |
| CN109143418A (en) * | 2018-11-12 | 2019-01-04 | 北京敏视达雷达有限公司 | A kind of caliberating device of laser raindrop spectrograph |
| CN109143418B (en) * | 2018-11-12 | 2024-05-03 | 华云敏视达雷达(北京)有限公司 | Calibration device of laser raindrop spectrometer |
| CN110554002A (en) * | 2019-09-30 | 2019-12-10 | 大连艾科科技开发有限公司 | Hydrogen sulfide concentration detection module, hydrogen sulfide concentration telemeter and application |
| CN116223135A (en) * | 2023-05-05 | 2023-06-06 | 南京科力赛克安全设备有限公司 | Integrated sampling equipment convenient to operate and sampling method thereof |
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