CN102062507A - Flow ice making method and device based on lithium bromide absorption type refrigeration cycle - Google Patents

Flow ice making method and device based on lithium bromide absorption type refrigeration cycle Download PDF

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Publication number
CN102062507A
CN102062507A CN2011100237371A CN201110023737A CN102062507A CN 102062507 A CN102062507 A CN 102062507A CN 2011100237371 A CN2011100237371 A CN 2011100237371A CN 201110023737 A CN201110023737 A CN 201110023737A CN 102062507 A CN102062507 A CN 102062507A
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ice
freezing chamber
water
solution
evaporative freezing
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CN102062507B (en
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殷勇高
杜垲
张小松
査翔
张朋磊
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Southeast University
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Southeast University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/27Relating to heating, ventilation or air conditioning [HVAC] technologies
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]
    • Y02B30/62Absorption based systems

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Abstract

The invention relates to a flow ice making method and device based on lithium bromide absorption type refrigeration cycle. A lithium bromide concentrated solution continuously absorbs steam in an absorber for causing a low-pressure environment of an evaporated refrigerating chamber; water is continuously evaporated for absorbing self heat in the low-pressure environment of an evaporated refrigerating chamber to be partially frozen into flow ice. After the lithium bromide solution absorbs steam derived from the evaporated refrigerating chamber in the absorber and is diluted, the lithium bromide solution is conveyed to a generator by a solution pump for being heated and regenerated; the concentration of the solution is improved, and the solution has the moisture absorbing ability again; and then, the solution is cooled and conveyed to the absorber to form solution absorbing-regenerating recirculation. The steam derived from the generator is condensed into subcooled water in a condenser; and after being throttled, the subcooled water is conveyed to the evaporated refrigerating chamber for making ice. An ice making system is automatically supplemented by a water tank according to the water level of the evaporated refrigerating chamber.

Description

Fluid state ice preparation method and device based on the lithium bromide absorbing type refrigeration circulation
Technical field
What the present invention relates to a kind of evaporative freezing produces the fluid state ice new method, is the method and apparatus that fluid state ice is produced in a kind of evaporative freezing based on the lithium-bromide solution Absorption Cooling System, belongs to the technical field that heat drives refrigeration, produces fluid state ice.
Background technology
Along with showing especially of energy shortage situation, the air-conditioning system energy consumption problem that the extensive use of refrigeration air-conditioner causes has caused the common concern of current social, the energy-conservation an urgent demand that becomes in the refrigerating field more under the new situation, China also proposes the foundation strategy of sustainable development.Cold-storage has important and practical meanings and using value as a kind of important means of energy-conservation and peak load shifting, wherein ices cold-storage and has advantages such as latent heat of phase change is big, cost is low and come into one's own.Traditional ice accumulation of energy exist evaporating temperature low, produce and have deficiencies such as heat transfer temperature difference is big, coefficient of performance of refrigerating is low in the process, fluid state ice becomes the application form that the ice cold-storage has considerable prospect with its good hot rerum natura and flow behavior, therefore researchs and develops the new and effective method of producing fluid state ice and has great importance.
Summary of the invention
Technical problem:The invention provides following of a kind of energy-conservation, simple in structure, easy row based on lithium bromide absorbing type refrigeration
The fluid state ice preparation method and the device of ring.
Technical scheme:For solving the problems of the technologies described above, technical scheme provided by the invention is:
Technical scheme of the present invention is changed the evaporimeter in the circulation of traditional lithium bromide absorbing type refrigeration and be transformed into fluid state ice to produce module, and is aided with Auxiliary Functioning Unit and can realizes.
Fluid state ice device for making based on the lithium bromide absorbing type refrigeration circulation of the present invention is made up of solution circulation loop and evaporative freezing ice making module; Solution circulation loop comprises generator, absorber, solution heat exchanger, cooler, first solution pump, second solution pump, refrigerant pump; Wherein, the concentrated solution district of the bottom of absorber connects the bottom of generator respectively by first solution pump, second solution pump and solution heat exchanger, the input of cooler connects the bottom of generator by solution heat exchanger, and the output termination of cooler is positioned at the spray thrower on absorber top;
Evaporative freezing ice making module is made of condenser, water replanishing device, choke valve, evaporative freezing chamber, one-tenth ice production apparatus, frozen water separator, one-way cock, middle ice storage appts., one-way cock, ice machine bin; The concentrated solution district of condenser connects the evaporative freezing chamber by choke valve, and the output order of evaporative freezing chamber connects ice machine bin by one-way cock, middle ice storage appts., one-way cock; The output order of cooling tower bottom is got back to the input on cooling tower top by water pump, absorber, condenser.
In the evaporative freezing chamber, the concentrated solution district of bottom, evaporative freezing chamber connects the spray thrower that is positioned at top, evaporative freezing chamber by refrigerant pump, is provided with into ice production apparatus in the spray thrower bottom, is provided with the frozen water separator in the bottom that becomes ice production apparatus.
The method of producing fluid state ice of the fluid state ice device for making based on lithium bromide absorbing type refrigeration circulation of the present invention, for, the concentrated solution of absorber is delivered in the generator through solution heat exchanger by solution pump, the weak solution that takes place in the generator to end enters absorber through solution heat exchanger and cooler under the differential pressure effect between generator and absorber, form solution circulation loop; In the evaporation ice making flow process, water replanishing device is to the condenser moisturizing, the water of condenser enters evaporation evaporative freezing chamber through choke valve, becomes the mixture of ice and water that forms on the ice production apparatus to enter ice machine bin through frozen water separator, one-way cock, middle storage chamber, one-way cock in the evaporation evaporative freezing chamber and finishes the ice making flow process.
This method utilizes the concentrated solution in the absorber to absorb the steam that evaporates in the evaporative freezing chamber, is that environment under low pressure is made in evaporation evaporative freezing chamber, and water evaporates the absorption self heat therein, is becoming on the ice production apparatus to grow into fluid state ice.
The frozen water separation process of this method is to become the ice crystal that forms on the ice production apparatus to separate through the frozen water separator, uniform pressure in maintenance and the evaporation evaporative freezing chamber in the middle ice storage appts., open one-way cock and enter middle storage chamber, close one-way cock then, open the one-way cock ice crystal and enter ice machine bin, finish the frozen water separation process; Finish the frozen water after separating, middle storage chamber is vacuumized by vavuum pump.
Beneficial effect:
1, the method can utilize industrial exhaust heat, solar energy equitemperature be thermal source about 100 ℃ as the drive energy of generator, saved a large amount of electric energy, realized the sustainable development of using energy source.
2, this device can directly be formed by the lithium bromide absorption refrigeration plant modification, and simple structure is stable, can overcome machinery and bleed and make that the vacuum wearing and tearing are big, noise is big, the shortcoming of operation difficulty continuously.
3, this method and device provide a kind of feasible method and scheme for producing of fluid state ice, only need the absorption type refrigerating unit that technology is very ripe are transformed and upgrade and can realize.
Description of drawings
Fig. 1 is a structural representation of the present invention;
Wherein have: generator 1, condenser 2, water tank 3, choke valve 4, evaporative freezing chamber 5 becomes ice production apparatus 6, frozen water separator 7, middle ice storage appts. 8, ice machine bin 9, absorber 10, solution heat exchanger 11, the first one-way cocks 12, second one-way cock 13, cooling tower 14, cooler 15, the first solution pumps 16, second solution pump 17, refrigerant pump 18, water pump 19, vavuum pump 20, thermal source add hot fluid 21, moisturizing choke valve 22.
The specific embodiment
This device is made up of solution circulation loop and evaporative freezing ice making module; Solution circulation loop comprises generator 1, absorber 10, solution heat exchanger 11, cooler 15, first solution pump 16, second solution pump 17, refrigerant pump 18; Evaporative freezing ice making module by condenser 2, water replanishing device 3, choke valve 4, evaporative freezing chamber 5, connect water replanishing device 3 and evaporative freezing chamber 5 moisturizing choke valve 22, become ice production apparatus 6, frozen water separator 7, one-way cock 12, middle ice storage appts. 8, one-way cock 13, ice machine bin 9 to constitute; Condensed water in the condenser 2 connects evaporative freezing chamber 5 by choke valve 4, and the output order of evaporative freezing chamber 5 connects ice machine bin 9 by one-way cock 12, middle ice storage appts. 8, one-way cock 13.
In evaporative freezing chamber 5, the cryogen pool of 5 bottoms, evaporative freezing chamber connects the spray thrower that is positioned at 5 tops, evaporative freezing chamber by refrigerant pump 18, is provided with into ice production apparatus 6 in the spray thrower bottom, is provided with frozen water separator 7 in the bottom that becomes ice production apparatus 6.
Produce the method for fluid state ice based on the evaporative freezing of lithium-bromide solution Absorption Cooling System, comprise that solution circulation and evaporative freezing get two processes of fluid state ice.Its concrete scheme is as follows:
Solution circulation in lithium-bromide solution cyclic process and the circulation of traditional lithium bromide absorbing type refrigeration is similar, adopt solution in absorber, to absorb the steam that evaporates in the evaporative freezing chamber, to keep the state of low water vapor pressure in the evaporative freezing chamber, be lower than the saturated pressure phase transition of 622.8Pa(0 ℃ water correspondence), diluted concentration reduced after solution absorbed moisture, and bromize lithium dilute solution is heated regeneration by solution pump in generator, concentration is improved, and recovers to absorb the ability of steam again.It is that concentrated solution constantly absorbs the steam that evaporimeter comes out and causes the environment under low pressure (being lower than 622.8Pa) of evaporative freezing chamber in the absorber that the fluid state ice process is produced in evaporative freezing, subcooled water in the condenser enters the evaporative freezing chamber through after the throttling, because the evaporative freezing room pressure is lower than the pressure phase transition 622.8Pa of 0 ℃ of water correspondence, the indoor water of evaporative freezing will constantly evaporate the heat that absorbs self, temperature is reduced to 0 ℃ gradually, even be lower than 0 ℃, process is separated cold and is generated fluid state ice on the one-tenth ice production apparatus, and through the frozen water separator of a fixed structure, isolate fluid state ice, the chilled water of bottom, evaporative freezing chamber constantly is sprayed onto on the ice production apparatus, forms ice crystal or ice pellets gradually.Along with the continuous minimizing of moisture in the ice making circulation, by adding water replanishing device in evaporative freezing chamber side.
In the evaporation ice making flow process, water replanishing device 3 requires automatic water supplement in evaporative freezing chamber 5 according to the lowest water level in the evaporative freezing chamber 5, enter in the evaporative freezing chamber 5 after the normal-temperature water process moisturizing choke valve 22 throttling step-downs in the moisturizing process in the water replanishing device 3, the water of condenser enters evaporation evaporative freezing chamber 5 through choke valve 4, becomes the mixture of ice and water that forms on the ice production apparatus 6 to enter ice machine bin 9 through frozen water separator 7, one-way cock 12, middle storage chamber 8, one-way cock 13 in the evaporation evaporative freezing chamber 5 and finishes the ice making flow process.
The steam that the present invention will go out by the generator that thermal source more than 100 ℃ drives enters condenser, lithium-bromide solution concentration after the generation gets a promotion, through being sprayed onto in the absorber after heat exchanger, the water quench, absorption is from the steam in the evaporative freezing chamber, absorption process steam becomes the heat of liquid release by taking away from the cooling water in the cooling tower, absorb the lithium-bromide solution concentration that ends and reduce, deliver to through over-heat-exchanger by solution pump then and finish the solution generating process in the generator.From the steam in the generator in condenser through from the water quench of cooling tower, be condensed into subcooled water, then through being sprayed to the evaporative freezing chamber after the throttling arrangement throttling, evaporation and be frozen into ice crystal on the one-tenth ice production apparatus in the evaporative freezing chamber, the steam that evaporates is absorbed concentrated solution absorption in the device, keeps the indoor environment under low pressure of evaporative freezing.In order to prevent in this system that moisture constantly becomes after the ice pellets, the moisture in the circulation reduces, in due course by water replanishing device in condenser supplementing water to keep the water yield in the systemic circulation.When the ice crystal in the frozen water separator in the evaporative freezing chamber gather a certain amount of after, open the one-way cock between evaporative freezing chamber and middle ice storage appts., ice crystal under the gravity effect, enter in the middle of ice storage appts., close this one-way cock then.When the ice crystal in the middle ice storage appts. reach a certain amount of after, the one-way cock in the middle of opening between ice storage appts. and the ice machine bin is taken the ice crystal or the ice pellets of generation away, closes one-way cock then, open vavuum pump guarantee in the middle of the certain vacuum of ice storage appts..

Claims (5)

1. fluid state ice device for making based on lithium bromide absorbing type refrigeration circulation is characterized in that this device is made up of solution circulation loop and evaporative freezing ice making module; Solution circulation loop comprises generator (1), absorber (10), solution heat exchanger (11), cooler (15), first solution pump (16), second solution pump (17), refrigerant pump (18); Evaporative freezing ice making module by condenser (2), water replanishing device (3), choke valve (4), evaporative freezing chamber (5), connect water replanishing device (3) and evaporative freezing chamber (5) moisturizing choke valve (22), become ice production apparatus (6), frozen water separator (7), one-way cock (12), middle ice storage appts. (8), one-way cock (13), ice machine bin (9) formation; Condensed water in the condenser (2) connects evaporative freezing chamber (5) by choke valve (4), and the output of evaporative freezing chamber (5) connects ice machine bin (9) by one-way cock (12), middle ice storage appts. (8), one-way cock (13) in proper order.
2. the fluid state ice device for making based on the lithium bromide absorbing type refrigeration circulation according to claim 1, it is characterized in that, in evaporative freezing chamber (5), the cryogen pool of bottom, evaporative freezing chamber (5) connects the spray thrower that is positioned at top, evaporative freezing chamber (5) by refrigerant pump (18), be provided with into ice production apparatus (6) in the spray thrower bottom, be provided with frozen water separator (7) in the bottom that becomes ice production apparatus (6).
3. the method for producing fluid state ice of the fluid state ice device for making based on lithium bromide absorbing type refrigeration circulation as claimed in claim 1, it is characterized in that, in the evaporation ice making flow process, water replanishing device (3) requires automatic water supplement in evaporative freezing chamber (5) according to the lowest water level in evaporative freezing chamber (5), enter in the evaporative freezing chamber (5) after normal-temperature water process moisturizing choke valve (22) the throttling step-down in the water replanishing device in the moisturizing process (3), the water of condenser enters evaporation evaporative freezing chamber (5) through choke valve (4), and the mixture of ice and water that one-tenth ice production apparatus (6) upward forms in the evaporation evaporative freezing chamber (5) is through frozen water separator (7), one-way cock (12), middle storage chamber (8), one-way cock (13) enters ice machine bin (9) and finishes the ice making flow process.
4. the method for producing fluid state ice of the fluid state ice device for making based on lithium bromide absorbing type refrigeration circulation according to claim 3, it is characterized in that this method utilizes concentrated solution in the absorber (10) to absorb steam in the evaporation evaporative freezing chamber (5), for making environment under low pressure in evaporation evaporative freezing chamber (5), water evaporates the absorption self heat therein, is becoming on the ice production apparatus (6) to grow into fluid state ice.
5. the method for producing fluid state ice of the fluid state ice device for making based on lithium bromide absorbing type refrigeration circulation according to claim 3, the frozen water separation process that it is characterized in that this method is to separate through frozen water separator (7) at the ice crystal that becomes ice production apparatus (6) to go up formation, uniform pressure in maintenance and the evaporation evaporative freezing chamber in the middle ice storage appts. (8), open one-way cock (12), storage chamber (8) in the middle of under the gravity effect, entering, close one-way cock (12) then, open one-way cock (13) ice crystal and enter ice machine bin, finish the frozen water separation process; Finish the frozen water after separating, middle storage chamber (8) is vacuumized by vavuum pump.
CN2011100237371A 2011-01-21 2011-01-21 Flow ice making method and device based on lithium bromide absorption type refrigeration cycle Expired - Fee Related CN102062507B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102538331A (en) * 2012-03-30 2012-07-04 常熟南师大发展研究院有限公司 Method and device for fetching out flow-state ices from vacuum process flow-state ice preparing room
CN107014124A (en) * 2017-04-21 2017-08-04 高志栋 A kind of ice making method and ice-making system
CN107162344A (en) * 2017-07-03 2017-09-15 苏州华商新能源有限公司 A kind of sewage water treatment method
CN107726684A (en) * 2017-11-01 2018-02-23 江苏高菱蓄能科技有限公司 A kind of droxtal slurry preparation system
CN108592444A (en) * 2018-02-06 2018-09-28 华北电力大学 A kind of electric heat pump and the compound heat-exchange unit of absorption heat pump
CN109282397A (en) * 2018-08-14 2019-01-29 浙江理工大学 Novel energy storage air conditioner and method based on air cycle refrigeration circulation

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CN201589481U (en) * 2009-09-25 2010-09-22 天津商业大学 Fluidizing ice making system by utilizing seawater
CN201992924U (en) * 2011-01-21 2011-09-28 东南大学 Ice-slurry preparing device based on lithium bromide absorption refrigeration cycle

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JPH07280401A (en) * 1994-04-07 1995-10-27 Nkk Corp Vacuum ice-making apparatus
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102538331A (en) * 2012-03-30 2012-07-04 常熟南师大发展研究院有限公司 Method and device for fetching out flow-state ices from vacuum process flow-state ice preparing room
CN102538331B (en) * 2012-03-30 2013-12-18 常熟南师大发展研究院有限公司 Method and device for fetching out flow-state ices from vacuum process flow-state ice preparing room
CN107014124A (en) * 2017-04-21 2017-08-04 高志栋 A kind of ice making method and ice-making system
CN107162344A (en) * 2017-07-03 2017-09-15 苏州华商新能源有限公司 A kind of sewage water treatment method
CN107162344B (en) * 2017-07-03 2020-10-02 苏州华商新能源有限公司 Sewage treatment method
CN107726684A (en) * 2017-11-01 2018-02-23 江苏高菱蓄能科技有限公司 A kind of droxtal slurry preparation system
CN108592444A (en) * 2018-02-06 2018-09-28 华北电力大学 A kind of electric heat pump and the compound heat-exchange unit of absorption heat pump
CN108592444B (en) * 2018-02-06 2023-10-31 华北电力大学 Heat exchange unit combining electric heat pump and absorption heat pump
CN109282397A (en) * 2018-08-14 2019-01-29 浙江理工大学 Novel energy storage air conditioner and method based on air cycle refrigeration circulation
CN109282397B (en) * 2018-08-14 2020-06-19 浙江理工大学 Novel energy storage air conditioning device and method based on air compression refrigeration cycle

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