CN102020890A - Printing ink having the function of changing color and shining and suitable for film products - Google Patents
Printing ink having the function of changing color and shining and suitable for film products Download PDFInfo
- Publication number
- CN102020890A CN102020890A CN 200910186065 CN200910186065A CN102020890A CN 102020890 A CN102020890 A CN 102020890A CN 200910186065 CN200910186065 CN 200910186065 CN 200910186065 A CN200910186065 A CN 200910186065A CN 102020890 A CN102020890 A CN 102020890A
- Authority
- CN
- China
- Prior art keywords
- printing ink
- nanometer grade
- ink
- grade powder
- nano powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to a printing ink having the function of changing color and shining and suitable for lamination, the raw material formula of which comprises the following constituents by weight: 5% to 30% of acrylic resin, 40% to 85% of butanone, 3% to 5% of glycol ether, 0.6% to 1% of acetate, 2% to 25% of nano powder and 0.9% to 1.8% of conductive salt. The nano powder comprises one or more of the following powder: temperature-sensitive color-changeable nano powder, light-sensitive color-changeable, ultraluminescence nano powder and infrared-luminescent nano powder. By adopting the above technical scheme including taking acrylic resin as binder and using mixed solvents with specific formula accordingly, the adhesion between the ink and glass with smooth surface, polypropylene films and PET films is enhanced greatly. Particularly, the color-changeable or luminous nano powder is used in the ink, but the adhesion between the ink and the materials with smooth surface is strong. Therefore the ink can be applied to film products.
Description
Technical field
The present invention relates to a kind of printing ink, particularly relate to a kind of that have variable color or a lighting function and be suitable for printing ink on the pad pasting.
Background technology
Be flooded with at present a large amount of of poor quality and fake products on the market, playing the camouflage of so-and-so reputable brand often, almost can mix the spurious with the genuine in the outer packaging, human consumers can't differentiate, when suffering damage, the human consumer also influenced the goodwill of regular brand, therefore, the businessman of present regular brand generally all can stick unique anti-fake label and prevent this class situation on institute's product sold.
Yet the counterfeit phenomenon of all kinds of pad pasting products of Xiao Shouing is still very serious in the market.The pad pasting product, (also claim thermal isolation film, sheathing paper, pellicle space etc., wherein, " heat insulation " is meant the effective obstruct to the infrared light district, and " sun-proof " is meant and can effectively intercepts ultraviolet ray for example to sell the most widely the heat insulation sun film.), the anti scuffing that this series products is declared, every the ultraviolet ray, every functions such as infrared rays, ordinary consumer does not have instrumentation and differentiates, and existing this class pad pasting product can't use anti-fake label or can't directly spray the code-spraying printing ink of false proof usefulness, reason just is: normal Synolac, vinyl resins, the resol etc. of adopting are all kinds of code-spraying printing inks of main material production in the prior art, and this class code-spraying printing ink is difficult to be attached to materials such as glass with smooth surface, polypropylene screen, PET film, light-cured resin layer, is easy to be wiped out after these printing ink are sprayed; Particularly, be used to make anti-false trademark or direct general some powders luminous or variable color of needs interpolation on the code-spraying printing ink of the false proof usefulness of spray printing, further had a strong impact on the sticking power of printing ink after having added these powders to smooth surface.
Therefore, everybody wishes to develop the printing ink that is suitable on the pad pasting.
Summary of the invention
In order to solve the problems of the technologies described above, one aspect of the present invention provide have variable color or a lighting function and be suitable for printing ink on the pad pasting, the composition of raw materials of this printing ink comprises following component by weight percentage: 5%～30% acrylic resin, 40%～85% butanone, 3%～5% glycol ether, 0.6%～1% acetic ester, 2%～25% nanometer grade powder, 0.9%～1.8% conducting salt, described nanometer grade powder are the heat discoloration nanometer grade powder, the sensitization discoloration nanometer grade powder, the Ultraluminescence nanometer grade powder, the mixture of any one or a few in the Infrared fluorescence nanometer grade powder.
To nano level definition, described nanometer grade powder is meant that the powder median size is not more than the powder of 100nm according in the world.
Described heat discoloration nanometer grade powder is a kind of rising with temperature, decline and change the nanometer grade powder of color repeatedly.In general, raising with temperature changes to colouredly from colourless, and descending with temperature changes to colourlessly from coloured, and two processes all are reversible.The primitive colour of existing heat discoloration powder has 15 kinds (there is distinct colors in the differing temps interval), with three primary colors is that the basis can modulate any color, also can utilize differing temps the heat discoloration powder modulate two or more colour-change, also can mix with other pigment, as mixing into the mixed powder of two sections, three sections variable colors of temperature indication arbitrarily, these all are well-known to those skilled in the art.
Described sensitization discoloration nanometer grade powder, it is through visible light or UV-irradiation post-absorption energy and change to colouredly from colourless, and change procedure is reversible.The primitive colour of existing sensitization discoloration powder has 4 kinds, and is same, also can be with its any modulation.
Described Ultraluminescence nanometer grade powder, it very promptly is scattering into it long visible light of wavelength after absorbing UV-light, produced fluorescence phenomenon.If the time of lag of scattering is longer, will produce known phosphorus 30 fluorescence phenomenons, fluorescence color has indigo plant, green, red, Huang etc.
Described Infrared fluorescence nanometer grade powder, it is excited under the irradiation of infrared light and sends specific visible light, has produced fluorescence phenomenon.
The contriver is through a large amount of experimental studies have found that, adopt the printing ink of technique scheme, promptly be to connect material with the acrylic resin, and correspondingly use mixed solvent-butanone, glycol ether, the acetic ester of special formulation, the sticking power of materials such as its glass to smooth surface, polypropylene screen, PET film, light-cured resin layer strengthens greatly.Particularly, also used variable color or luminous nanometer grade powder in the printing ink of such scheme, but it is still very strong to sticking power with smooth surface material, goes for the pad pasting product.
Preferably, described acrylic resin is a thermoplastic acrylic resin.
Preferably, described glycol ether is a butyl glycol ether.
Preferably, described acetic ester is a vinyl acetic monomer.
Preferably, described conducting salt is a potassium sulfocyanate.
Preferably, the composition of raw materials of this printing ink also comprises 0.5%～2% the acrylic acid modified polyester of sticking power promotor.In the prescription of printing ink of the present invention, use this special sticking power promotor, strengthened the wear resistance of this printing ink spray printing gained number greatly.
The present invention also provides the pad pasting that uses above-mentioned printing ink on the other hand.
Pad pasting of the present invention is compared with the pad pasting of prior art, and the labeling that has used printing ink with variable color or lighting function or this printing ink spray printing to make has antifalse effect.
Embodiment
Below the specific embodiment of the present invention is described, but be not limited to these embodiment.
Embodiment 1
Ink formulations (by weight, the prescription gross weight is 100 parts):
15 parts of 25 parts of thermoplasticity acrylic acid resins (Kunshan San Wang resin company limited produce model be swu-9070), 53 parts of butanone, 4 parts of butyl glycol ethers, 0.8 part of acetic acid second vinegar, heat discoloration nanometer grade powder material (the heat discoloration nanometer grade powder that the high abundant nanometer industry and trade in Quanzhou company limited produces, median size is 100nm), 1.2 parts of potassium sulfocyanates, 1 part of the acrylic acid modified polyester of sticking power promotor (model that the triumphant mattress chemical industry in Shanghai company limited produces is EP2325).
The technological process of production:
Earlier above-mentioned thermoplasticity acrylic acid resin is added in the solvent, this solvent is the solvent of the above-mentioned butanone composition that component is mixed of butyl glycol ether, acetic acid second vinegar and about 60%, adds back high-speed stirring (stirring velocity is about 20 revolutions per seconds) about 20～30 minutes to thermoplasticity acrylic acid resin and fully dissolves; The butanone component that adds above-mentioned heat discoloration powder body material, potassium sulfocyanate, sticking power promotor and remaining 40% then successively, carry out high-speed stirring (stirring velocity is about 20 revolutions per seconds) about 20 minutes again, filter (12500 purpose strainer) after treating to dissolve fully, promptly be worth present embodiment printing ink after sampling inspection particle precision is less than 1 micron, packing is standby.
Detect through overtesting, adopt the pad pasting of made anti-fake label of present embodiment printing ink or direct coding, the spray printing place is glued repeatedly with mightiness belt draw (as 3～5 times) for several times, the printing ink trace of spraying is still excellent.
Embodiment 2
Ink formulations (by weight, the prescription gross weight is 100 parts):
15 parts of 25 parts of thermoplasticity acrylic acid resins (Kunshan San Wang resin company limited produce model be swu-9070), 53 parts of butanone, 4 parts of butyl glycol ethers, 0.8 part of acetic acid second vinegar, sensitization discoloration nanometer grade powder material (the sensitization discoloration nanometer grade powder that the high abundant nanometer industry and trade in Quanzhou company limited produces, median size is 100nm), 1.2 parts of potassium sulfocyanates, 1 part of the acrylic acid modified polyester of sticking power promotor (model that the triumphant mattress chemical industry in Shanghai company limited produces is EP2325).
The technological process of production:
Earlier above-mentioned thermoplasticity acrylic acid resin is added in the solvent, this solvent is the solvent of the above-mentioned butanone composition that component is mixed of butyl glycol ether, acetic acid second vinegar and about 60%, adds back high-speed stirring (stirring velocity is about 20 revolutions per seconds) about 20～30 minutes to thermoplasticity acrylic acid resin and fully dissolves; The butanone component that adds above-mentioned sensitization discoloration powder body material, potassium sulfocyanate, sticking power promotor and remaining 40% then successively, carry out high-speed stirring (stirring velocity is about 20 revolutions per seconds) about 20 minutes again, filter (12500 purpose strainer) after treating to dissolve fully, promptly be worth present embodiment printing ink after sampling inspection particle precision is less than 1 micron, packing is standby.
Detect through overtesting, adopt the pad pasting of made anti-fake label of present embodiment printing ink or direct coding, the spray printing place is glued repeatedly with mightiness belt draw (as 3～5 times) for several times, the printing ink trace of spraying is still excellent.
Claims (6)
1. printing ink, it is characterized in that, the composition of raw materials of this printing ink comprises following component by weight percentage: 5%～30% acrylic resin, 40%～85% butanone, 3%～5% glycol ether, 0.6%～1% acetic ester, 2%～25% nanometer grade powder, 0.9%～1.8% conducting salt, described nanometer grade powder are any one or a few the mixture in heat discoloration nanometer grade powder, sensitization discoloration nanometer grade powder, Ultraluminescence nanometer grade powder, the Infrared fluorescence nanometer grade powder.
2. printing ink as claimed in claim 1 is characterized in that: described acrylic resin is a thermoplastic acrylic resin.
3. printing ink as claimed in claim 1 is characterized in that: described glycol ether is a butyl glycol ether.
4. printing ink as claimed in claim 1 is characterized in that: described acetic ester is a vinyl acetic monomer.
5. printing ink as claimed in claim 1 is characterized in that: described conducting salt is a potassium sulfocyanate.
6. as any described printing ink in the claim 1～5, it is characterized in that: the composition of raw materials of this printing ink also comprises 0.5%～2% the acrylic acid modified polyester of sticking power promotor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910186065 CN102020890A (en) | 2009-09-17 | 2009-09-17 | Printing ink having the function of changing color and shining and suitable for film products |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910186065 CN102020890A (en) | 2009-09-17 | 2009-09-17 | Printing ink having the function of changing color and shining and suitable for film products |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102020890A true CN102020890A (en) | 2011-04-20 |
Family
ID=43862684
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200910186065 Pending CN102020890A (en) | 2009-09-17 | 2009-09-17 | Printing ink having the function of changing color and shining and suitable for film products |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102020890A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102241917A (en) * | 2011-06-10 | 2011-11-16 | 珠海市乐通化工股份有限公司 | Temperature change ink for printing drink label |
| CN102399470A (en) * | 2011-11-04 | 2012-04-04 | 江苏泰格油墨有限公司 | Anti-counterfeiting ink for cigarette packets |
| CN102715722A (en) * | 2012-06-18 | 2012-10-10 | 佛山市万佳塑料有限公司 | Discoloring luminous protective mobile phone case and processing technique thereof |
| CN105462402A (en) * | 2015-11-03 | 2016-04-06 | 澳达树熊涂料(惠州)有限公司 | Acrylic primer paint and preparation method thereof |
| CN106118247A (en) * | 2016-08-10 | 2016-11-16 | 苏州中亚油墨有限公司 | A kind of conducting fluorescence ink |
| CN107474634A (en) * | 2017-09-30 | 2017-12-15 | 北京赛腾标识***股份公司 | A kind of double anti-forge inkjet inks |
| CN109021706A (en) * | 2018-10-17 | 2018-12-18 | 杭州海维特化工科技有限公司 | It is a kind of can overlay film PVC furniture film water anti-forgery ink and preparation method thereof |
| CN116042019A (en) * | 2023-02-23 | 2023-05-02 | 重庆宏图新材料科技有限公司 | Environment-friendly ink special for temperature change of food packaging bag and preparation method thereof |
-
2009
- 2009-09-17 CN CN 200910186065 patent/CN102020890A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102241917A (en) * | 2011-06-10 | 2011-11-16 | 珠海市乐通化工股份有限公司 | Temperature change ink for printing drink label |
| CN102399470A (en) * | 2011-11-04 | 2012-04-04 | 江苏泰格油墨有限公司 | Anti-counterfeiting ink for cigarette packets |
| CN102715722A (en) * | 2012-06-18 | 2012-10-10 | 佛山市万佳塑料有限公司 | Discoloring luminous protective mobile phone case and processing technique thereof |
| CN102715722B (en) * | 2012-06-18 | 2014-08-06 | 周顺勇 | Discoloring luminous protective mobile phone case and processing technique thereof |
| CN105462402A (en) * | 2015-11-03 | 2016-04-06 | 澳达树熊涂料(惠州)有限公司 | Acrylic primer paint and preparation method thereof |
| CN106118247A (en) * | 2016-08-10 | 2016-11-16 | 苏州中亚油墨有限公司 | A kind of conducting fluorescence ink |
| CN107474634A (en) * | 2017-09-30 | 2017-12-15 | 北京赛腾标识***股份公司 | A kind of double anti-forge inkjet inks |
| CN109021706A (en) * | 2018-10-17 | 2018-12-18 | 杭州海维特化工科技有限公司 | It is a kind of can overlay film PVC furniture film water anti-forgery ink and preparation method thereof |
| CN116042019A (en) * | 2023-02-23 | 2023-05-02 | 重庆宏图新材料科技有限公司 | Environment-friendly ink special for temperature change of food packaging bag and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102020890A (en) | Printing ink having the function of changing color and shining and suitable for film products | |
| CN101688072B (en) | Dark pigments reflecting ir radiation, method for the production thereof, and use thereof | |
| CN109295806B (en) | Multicolor overprint tipping paper with metallic luster and preparation method thereof | |
| CN108059858B (en) | Coloring layer coating suitable for silver alumite hot stamping foil and preparation method thereof | |
| CN103436093A (en) | Anti-counterfeiting stamp-pad ink and preparation method thereof | |
| CN104277727A (en) | Multifunctional nanometer composite heat insulation film and making method thereof | |
| CN107513309B (en) | Three-dimensionally shaped photocuring transparent ink composition and its preparation method and application | |
| CN103627220B (en) | The preparation method of environment-friendlyaluminium aluminium pigment | |
| CN102618101B (en) | Antifoggant composition and antifog and heat-insulation colored window film formed by composition | |
| CN104449273A (en) | Ultraviolet-resistant water-based paint capable of reducing brightness of coating and applied to glass door and preparation method of ultraviolet-resistant water-based paint | |
| CN104004451A (en) | Automotive UV (Ultraviolet) light-cured camouflage coating and preparation method thereof | |
| CN101245200B (en) | UV gloss oil, preparation method and application thereof | |
| CN102673210B (en) | Thermal transfer coating film for metal products, preparation method thereof and metal products | |
| CN101671519B (en) | Odor-free alcoholic acid paint and preparation method thereof | |
| CN103254687B (en) | High-temperature resistant ester-soluble printing ink | |
| CN103351716A (en) | Environment-friendly pearly-luster ink | |
| CN104231741B (en) | A kind of glass UV photocuring marking ink and preparation method thereof | |
| CN105602323A (en) | Composition for poster paint and preparation method thereof | |
| CN107964345A (en) | A kind of water paint and its preparation and application method | |
| CN100556969C (en) | A kind of have changeable colors along with angle effect metal finish paint and preparation method thereof | |
| CN104149431A (en) | Ultraviolet-blocking colored antifogging and heat-insulating window film | |
| CN104191758A (en) | Colorful color-changing mobile phone shell with anti-counterfeiting and anti-scratching functions | |
| CN104191759A (en) | Colorful color-changing mobile phone shell with anti-counterfeiting and anti-scratching functions and manufacturing method thereof | |
| CN104559821B (en) | Reversible sunlight color changing anti-counterfeiting pre-coating film and preparation method thereof | |
| CN102807789A (en) | High-temperature-resistant ink for packaging of medical aluminum foil |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20110420 |