CN101999996A - Sterilization hand sanitizer containing microcrystal salt particles and preparation method thereof - Google Patents
Sterilization hand sanitizer containing microcrystal salt particles and preparation method thereof Download PDFInfo
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- CN101999996A CN101999996A CN 201010560991 CN201010560991A CN101999996A CN 101999996 A CN101999996 A CN 101999996A CN 201010560991 CN201010560991 CN 201010560991 CN 201010560991 A CN201010560991 A CN 201010560991A CN 101999996 A CN101999996 A CN 101999996A
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Abstract
The invention discloses a sterilization hand sanitizer containing microcrystal salt particles and a preparation method thereof, and belongs to the technical field of daily chemicals. The hand sanitizer consists of the following raw materials in percentage by mass: 15.0 to 30.0 percent of salt, 12.0 to 25.0 percent of surfactant, 3.0 to 8.0 percent of moisturizer, 0.5 to 3.0 percent of thickener, 0.1 to 0.5 percent of essence, 0.1 to 2.0 percent of pH regulator and the balance of pure water. Through intensively study on the characteristics of the hand sanitizer with high salt content and by combining the requirement of hand washing function and optimizing the formula, the sterilization hand sanitizer is finally compounded by adopting a unique multi-element formula, so the liquidity of the sterilization hand sanitizer is similar to that of common hand sanitizer; and the microcrystal salt particles can be felt in the sterilization hand sanitizer.
Description
Technical field
The invention belongs to the household chemicals technical field, particularly a kind of crystallite salt grain disinfection hand cleanser and preparation method thereof that contains.
Background technology
People's hand-washing article in the past mainly is soap, fancy soap or the like. easy landing when they use, chance water logging, high temperature can soften again and expend naturally, especially easily are infected with on hand dirt, antibacterial, become the secondary pollution source.Along with the transformation of growth in the living standard and consumption idea, handwashing liquid becomes the succedaneum of traditional hand-washing article gradually, has been widely used in various places such as hospital, hotel, food and drink, family at present.The contact surface of handwashing liquid and hands generally is the bottle pump head, and is easy to clean, avoided cross infection.By the squash type amount of getting, only need one press nozzle gently, liquid just flows into the palm of the hand, and consumption is by own grasp, and it is all very convenient to deposit use.Nowadays, along with the maturation of handwashing liquid production technology and popularizing of market, the special-purpose handwashing liquid with various special efficacies has also constantly come out.As the heavy duty detergent handwashing liquid, except that paint handwashing liquid, anhydrous washing hand liquid, disinfection handwashing liquid or the like.Wherein, the disinfection handwashing liquid is a class of occupancy volume maximum in the special-purpose handwashing liquid in market.
It is reported, the handwashing liquid that generally uses on the present market, part has bactericidal effect, but aspect the sterilization propaganda, common existence enlarges false words, because country does not have certain standard to define to the bacteria-eliminating efficacy of product, so Ministry of Public Health requires from July 1st, 2005, and the cosmetics of new production are forbidden propaganda or hint " antibiotic, antibacterial, degerming " and other medical function in its packing, label, description and other relevant publicity materials.Make consumer be hard to tell hand cleanser products so whether biocidal efficacies is arranged.For this reason, we utilize consumer to Sal (NaCl) have sterilization, antiinflammatory, invigorate blood circulation, the common cognition of effect such as antipruritic and skin protection, developed a kind of crystallite salt grain disinfection hand cleanser that contains, do not adding under any sterilization antiseptic situation, reach the antisepsis and sterilization effect, to remedy this kind deficiency of this series products.
Prior art: in personal-care supplies, sodium chloride have thickening, stable, regulate effect such as profit surface tension, be widely used in the products such as shampoo, bath gel, handwashing liquid, cleansing milk, the white toothpaste of salt, mouthwash, water outlet frost.But its content generally is controlled at below 3%, and too high because of sodium chloride content, the surfactant micelle will be by the crosslinked bar-shaped stratiform that transfers to, and viscosity will descend again, make the product viscosity not reach requirement.Application number is in 200510010817.8 patents " a kind of oil-in-water type handwashing liquid and preparation method thereof " application of high-load salt in hand cleanser products to have been arranged, sodium chloride content described in its claims is 9% ~ 34%, but fill a prescription by described in the embodiment, when the salt shot-like particle was arranged in the prepared product, product was prone to solid-liquid layering situation.
Summary of the invention
Goal of the invention:The invention provides a kind of crystallite salt grain disinfection hand cleanser that contains, the clean skin of this product energy deep-pollution-removing, and can have the bactericidal antiphlogistic effect by the effect of Sal (NaCl); Another object of the present invention provides a kind of preparation method of this handwashing liquid.
Technical scheme:A kind of disinfection hand cleanser that contains the crystallite salt particle is made up of the raw material of following mass ratio: salt: 15.0～30.0%; Surfactant: 12.0～25.0%; Wetting agent: 3.0～8.0%; Thickening agent: 0.5～3.0%; Essence: 0.1～0.5%; PH regulator agent: 0.1～2.0%; Surplus is pure water.
Described salt was the minus sieve shape salt of 0.4 mm sieve.
Described surfactant is anion, nonionic or amphoteric ionic surfactant, described anion surfactant is one or more mixture of dodecyl alcohol ether sulphuric acid acid sodium, sodium lauryl sulphate or polyoxyethylene ether sulfosuccinic acid disodium, non-ionic surface active agent is lauroyl diglycollic amide or lauroyl single ethanol amide, and zwitterionic surfactant is one or both mixture of fatty acid distribution of coconut oil CAB or imidazoline.
Described wetting agent is one or more the mixture in silicone oil, tea tree oil, cation pantothenylol or the polyhydric alcohol.
Described thickening agent is the two or more mixture of guar gum, carboxymethyl cellulose, hydroxyethyl-cellulose or acrylic acid polymer.
Described pH regulator agent is citric acid or sodium citrate salt.
Preparation contains the method for the disinfection hand cleanser of crystallite salt particle, and this method comprises the step of following order: add deionized water in the water pot of vacuum homogeneous emulsifying machine, add sodium chloride and stir, making the sodium chloride mass concentration in the deionized water is 2%; Order adds anion surfactant, zwitterionic surfactant and non-ionic surface active agent again, is heated to 60 ~ 70 ℃, the dissolving of 30 ~ 40r/min stirring at low speed; Wetting agent is added in the oil phase pot, add thickening agent, fully stir moistening and disperse; Material in the water pot is evacuated in the mulser homogenizing pot, under 30 ~ 40r/min stirring at low speed, material in the oil phase pot is added again, be heated to 60 ~ 70 ℃ of stirring and dissolving; After the cooling, under the evacuation state, add 13 ~ 28% sodium chloride, open the homogenizing function, set homogenizing rotating speed 1200-1800r/min, open simultaneously and stir speed of agitator 30-40r/min; To go up step gained material and be evacuated in the finished product jar, still aging 24 ~ 48 hours, get product.
Beneficial effect:Effects such as Sal (NaCl) has sterilization, antiinflammatory, invigorates blood circulation, antipruritic and skin protection, its application in handwashing liquid can be given full play to its effect.
The present invention has furtherd investigate the characteristics of handwashing liquid under the high content of salt, in conjunction with the needs of the function of washing one's hands, carries out formulation optimization, finally adopts unique polynary prescription composite, makes the flowability of product close with common handwashing liquid, and the crystallite salt grain that has the energy sense of touch to arrive in the product.Prescription adopts easily degraded surfactant raw material, and to select natural crystalline salt for use be sterilization, antiinflammatory, massage agent, adds functional Safflower Oil again, and the outward appearance of product and serviceability are all good.Often use, can effectively prevent spread of germs and handle inlet etc.
Description of drawings
Fig. 1 is the saline solution standing demix situation comparison diagram of washing one's hands;
The specific embodiment
By specific embodiment given below and typical Application Example, can further be well understood to the present invention, but they not limitation of the invention.
Embodiment 1:
A kind of crystallite salt grain disinfection hand cleanser that contains, the quality percentage composition of its each component is:
Salt: 15.0～30.0%;
Surfactant: 12.0～25.0%;
Wetting agent: 3.0～8.0%;
Thickening agent: 0.5～3.0%;
Essence: 0.1～0.5%;
PH regulator agent: 0.1～2.0%;
Surplus is pure water.
Described component: salt was the minus sieve shape salt of 0.4 mm sieve; Surfactant is anion, nonionic and amphoteric ionic surfactant; Wetting agent is one or more the combination of silicone oil, tea tree oil, cation pantothenylol or polyhydric alcohol; Thickening agent is the two or more combination of guar gum, carboxymethyl cellulose, hydroxyethyl-cellulose or acrylic acid polymer; The pH regulator agent is citric acid or sodium citrate salt.Anion surfactant is one or more the combination of dodecyl alcohol ether sulphuric acid acid sodium, sodium lauryl sulphate or polyoxyethylene ether sulfosuccinic acid disodium, zwitterionic surfactant is one or more the combination of fatty acid distribution of coconut oil CAB or imidazoline, and non-ionic surface active agent is lauroyl diglycollic amide or lauroyl single ethanol amide.(down together)
Salt: 15.0～20.0%;
Surfactant: 12.0～16.0%;
Wetting agent: 3.0～8.0%;
Thickening agent: 0.5～3.0%;
Essence: 0.1～0.5%;
PH regulator agent: 0.1～2.0%;
Surplus is pure water.
Embodiment 3
A kind of crystallite salt grain disinfection hand cleanser that contains, the best proportioning of the quality percentage composition of its each component is:
Salt: 24.0%;
Surfactant: 18.0%;
Wetting agent: 5.0%;
Thickening agent: 1.5%;
Essence: 0.2%;
PH regulator agent: 0.1%;
Surplus is pure water.
Described component: salt was the minus sieve shape salt of 0.4 mm sieve; Surfactant is anion, nonionic and amphoteric ionic surfactant; Wetting agent is one or more the combination of silicone oil, tea tree oil, cation pantothenylol or polyhydric alcohol; Thickening agent is the two or more combination of guar gum, carboxymethyl cellulose, hydroxyethyl-cellulose or acrylic acid polymer; The pH regulator agent is citric acid or sodium citrate salt.Anion surfactant is one or more the combination of dodecyl alcohol ether sulphuric acid acid sodium, sodium lauryl sulphate or polyoxyethylene ether sulfosuccinic acid disodium, zwitterionic surfactant is one or more the combination of fatty acid distribution of coconut oil CAB or imidazoline, and non-ionic surface active agent is lauroyl diglycollic amide or lauroyl single ethanol amide.(down together)
A kind of crystallite salt grain disinfection hand cleanser that contains, the quality percentage composition of its each component is:
Salt: 25.0～30.0%;
Surfactant: 18.0～25.0%;
Wetting agent: 3.0～8.0%;
Thickening agent: 0.5～3.0%;
Essence: 0.1～0.5%;
PH regulator agent: 0.1～2.0%;
Surplus is pure water.
Embodiment 5
A kind of crystallite salt grain disinfection hand cleanser that contains, the best proportioning of the quality percentage composition of its each component is:
Salt: 28.0%;
Surfactant: 22.0%;
Wetting agent: 5.0%;
Thickening agent: 2.0%;
Essence: 0.2%;
PH regulator agent: 0.2%;
Surplus is pure water.
Table 1 handwashing liquid microorganism detection national standard
| Total number of bacteria (cfu/g) | Excrement colibacillus group |
| ≤1000 | Must not detect |
Table 2 embodiment 3 crystallite salt disinfection hand cleanser (not adding preservative agent) microorganism detection results
| Place natural law | Total number of bacteria (cfu/g) | |
| 1 | <100 | Do not detect |
| 7 | <10 | Do not detect |
| 30 | <10 | Do not detect |
| 90 | <10 | Do not detect |
Table 3 embodiment 3 crystallite salt disinfection hand cleansers and common handwashing liquid bactericidal effect be (cfu/cm relatively
2
)
Respectively according to 200510010817.8 patents and configuration sodium chloride content average out to 24% of the present invention wash one's hands saline solution each 5 parts, standing demix 1,2,4, June, behind timing node, get the 1/3 mixed evenly back, upper strata of a copy of it and detect sodium chloride content, get its lower floor 1/3 mixed evenly back simultaneously and detect sodium chloride content, sodium chloride content is relatively as Fig. 1.Among the figure, the saline solution upper strata 1/3 sodium chloride content change curve in time of washing one's hands of the described preparation of series 1 expression this patent, the saline solution lower floor 1/3 sodium chloride content change curve in time of washing one's hands of the described preparation of series 2 expression this patents, the saline solution upper strata 1/3 sodium chloride content change curve in time of washing one's hands of the described preparation of series 3 expression 200510010817.8 patents, the saline solution lower floor 1/3 sodium chloride content change curve in time of washing one's hands of the described preparation of series 4 expression 200510010817.8 patents.By curve among Fig. 1 as can be known, the saline solution of washing one's hands according to the described configuration sodium chloride content of 200510010817.8 patents average out to 24%, upper strata sodium chloride amount prolongs sharply to reduce behind the sodium chloride saturated solution behind the salt-free grain with time of repose and stablizes, and lower floor's sodium chloride amount rises gradually, illustrates that it the sodium chloride lamination occurs.And according to the saline solution of washing one's hands of the described configuration sodium chloride content of this patent average out to 24%, the levels sodium chloride content does not leave standstill in time and changes, and properties of product are stable.
Claims (7)
1. a disinfection hand cleanser that contains the crystallite salt particle is characterized in that being made up of the raw material of following mass ratio: salt: 15.0～30.0%; Surfactant: 12.0～25.0%; Wetting agent: 3.0～8.0%; Thickening agent: 0.5～3.0%; Essence: 0.1～0.5%; PH regulator agent: 0.1～2.0%; Surplus is pure water.
2. the disinfection hand cleanser that contains the crystallite salt particle according to claim 1 is characterized in that described salt was the minus sieve shape salt of 0.4 mm sieve.
3. the disinfection hand cleanser that contains the crystallite salt particle according to claim 1, it is characterized in that described surfactant is anion, nonionic or amphoteric ionic surfactant, described anion surfactant is one or more mixture of dodecyl alcohol ether sulphuric acid acid sodium, sodium lauryl sulphate or polyoxyethylene ether sulfosuccinic acid disodium, non-ionic surface active agent is lauroyl diglycollic amide or lauroyl single ethanol amide, and zwitterionic surfactant is one or both mixture of fatty acid distribution of coconut oil CAB or imidazoline.
4. the disinfection hand cleanser that contains the crystallite salt particle according to claim 1 is characterized in that described wetting agent is one or more the mixture in silicone oil, tea tree oil, cation pantothenylol or the polyhydric alcohol.
5. the disinfection hand cleanser that contains the crystallite salt particle according to claim 1 is characterized in that described thickening agent is the two or more mixture of guar gum, carboxymethyl cellulose, hydroxyethyl-cellulose or acrylic acid polymer.
6. the disinfection hand cleanser that contains the crystallite salt particle according to claim 1 is characterized in that described pH regulator agent is citric acid or sodium citrate salt.
7. prepare the described method that contains the disinfection hand cleanser of crystallite salt particle of claim 1, it is characterized in that this method comprises that the step of following order: a. adds deionized water in the water pot of vacuum homogeneous emulsifying machine, add sodium chloride and stir, making the sodium chloride mass concentration in the deionized water is 2%; B. order adds anion surfactant, zwitterionic surfactant and non-ionic surface active agent again, is heated to 60 ~ 70 ℃, the dissolving of 30 ~ 40r/min stirring at low speed; C. wetting agent is added in the oil phase pot, add thickening agent, fully stir moistening and disperse; D. material in the water pot is evacuated in the mulser homogenizing pot, under 30 ~ 40r/min stirring at low speed, material in the oil phase pot is added again, be heated to 60 ~ 70 ℃ of stirring and dissolving; E. after the cooling, under the evacuation state, add 13 ~ 28% sodium chloride, open the homogenizing function, set homogenizing rotating speed 1200-1800r/min, open simultaneously and stir speed of agitator 30-40r/min; F. step e gained material is evacuated in the finished product jar, still aging 24 ~ 48 hours, gets product.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105609910A CN101999996B (en) | 2010-11-26 | 2010-11-26 | Preparation method of sterilization hand sanitizer containing microcrystal salt particles |
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| CN2010105609910A CN101999996B (en) | 2010-11-26 | 2010-11-26 | Preparation method of sterilization hand sanitizer containing microcrystal salt particles |
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| CN101999996B CN101999996B (en) | 2012-03-14 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104306176A (en) * | 2014-09-23 | 2015-01-28 | 广州大学 | Quaternary ammonium salt type antibacterial hand washing solution |
| CN105125425A (en) * | 2015-09-23 | 2015-12-09 | 北京水木中天植物科学研究院 | Oral anti-inflammation collutory |
| CN105748332A (en) * | 2016-04-15 | 2016-07-13 | 江苏省苏盐连锁有限公司南京分公司 | High-salinity bath gel |
| CN108567643A (en) * | 2018-07-12 | 2018-09-25 | 哈尔滨伟平科技开发有限公司 | A kind of preparation method of anti-bacterial hand lotion |
| WO2023159563A1 (en) * | 2022-02-28 | 2023-08-31 | L'oreal | Composition for skin care and/or cleansing |
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| CN1695599A (en) * | 2005-05-20 | 2005-11-16 | 云南盐化股份有限公司 | Emulsified salt type cream for cleaning face and preparation method |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104306176A (en) * | 2014-09-23 | 2015-01-28 | 广州大学 | Quaternary ammonium salt type antibacterial hand washing solution |
| CN104306176B (en) * | 2014-09-23 | 2017-12-08 | 广州大学 | A kind of quaternary anti-bacterial hand sanitizer |
| CN105125425A (en) * | 2015-09-23 | 2015-12-09 | 北京水木中天植物科学研究院 | Oral anti-inflammation collutory |
| CN105748332A (en) * | 2016-04-15 | 2016-07-13 | 江苏省苏盐连锁有限公司南京分公司 | High-salinity bath gel |
| CN108567643A (en) * | 2018-07-12 | 2018-09-25 | 哈尔滨伟平科技开发有限公司 | A kind of preparation method of anti-bacterial hand lotion |
| WO2023159563A1 (en) * | 2022-02-28 | 2023-08-31 | L'oreal | Composition for skin care and/or cleansing |
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| CN101999996B (en) | 2012-03-14 |
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Address after: 223200 No. 1 Jingshen Road, Chuzhou District, Huaian City, Jiangsu Province Co-patentee after: Jiangsu Salt Industry Research Institute Co., Ltd. Patentee after: Jiangsu Yanjingshen Co., Ltd. Address before: 223200 No. 1 Jingshen Road, Chuzhou District, Huaian City, Jiangsu Province Co-patentee before: Jiangsu Salt Industry Research Institute Patentee before: Jiangsu Jingshen Salt & Chemical Industry Co., Ltd. |
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