CN101967561A - Technological method for treating waste containing cobalt and nickel and waste batteries - Google Patents
Technological method for treating waste containing cobalt and nickel and waste batteries Download PDFInfo
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- CN101967561A CN101967561A CN2010102955771A CN201010295577A CN101967561A CN 101967561 A CN101967561 A CN 101967561A CN 2010102955771 A CN2010102955771 A CN 2010102955771A CN 201010295577 A CN201010295577 A CN 201010295577A CN 101967561 A CN101967561 A CN 101967561A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Abstract
The invention discloses a technological method for treating waste containing cobalt and nickel and waste batteries, which comprises the following steps: (1) breaking and separating the recovered waste containing cobalt and nickel and waste batteries after heat treatment; (2) ball milling and acid dissolving the broken materials after breaking and separating to obtain a crude solution of nickel and cobalt; (3) carrying out chemical purification and purification by extraction on the crude solution of nickel and cobalt to obtain waste water, a lithium solution, an aluminum solution, a cadmium solution, a nickel solution, a copper solution, a high-purity cobalt and nickel solution and a high-purity cobalt solution; (4) obtaining cobalt sulfate crystals and nickel sulfate crystals by crystallization of the high-purity cobalt and nickel solution and the high-purity cobalt solution; (5) synthesizing the high-purity cobalt and nickel solution and the high-purity cobalt solution in a liquid phase to obtain nickel precursor and cobalt precursor; (6) obtaining nickel powder by high-temperature heat treatment of the nickel precursor; and (7) obtaining cobalt powder by high-temperature heat treatment of the cobalt precursor. The invention has the beneficial effects that the method is simple, has no pollution to the environment, can refine superfine cobalt powder and superfine nickel powder, and fully utilizes the waste.
Description
Technical field
The present invention relates to a kind of processing method that contains cobalt nickel waste material, old and useless battery treatment.
Background technology
As everyone knows, old and useless battery and deleterious cured article are sneaked in the domestic refuse usually, and treatment process mainly is sanitary landfill, compost and three kinds of methods of burning, and the deficiency of landfill is polluted source and soil, particularly contain heavy metal in the battery, heavier by transudation to water source and soil pollution.The method that adopts heap to bury is handled the downgrade that makes compost again.Incinerating method is to adopt incinerator to burn, incinerator is made up of cylindrical furnace and chimney, body of heater is provided with dog-house, ash removing hole, the deficiency of this method is an etching apparatus, heavy metal in the old and useless battery volatilizees in flying dust in incinerator, cause great gas to pollute, the accumulation of incinerator furnace bottom heavy metal makes the lime-ash of generation form new source of pollution, and the reflection of employing stove fire metallurgy method is also arranged now, though this method can be carried out recycling, but the rate of recovery is low, and remaining lead is discharged with the form of gas and dust, causes secondary pollution, sulfurous gas in the while smelting process is polluted air also, and the healthy harm to the operator is bigger in addition.
Summary of the invention
The objective of the invention is to overcome above-mentioned the deficiencies in the prior art part, a kind of processing method that contains cobalt nickel waste material, old and useless battery treatment is provided, this method is simple, and is how pollution-free to ring.
The invention discloses a kind of processing method that contains cobalt nickel waste material, old and useless battery treatment, described treatment process comprises the steps:
1) broken apart containing after cobalt nickel waste material, the old and useless battery thermal treatment of reclaiming;
2) particle after broken apart is carried out ball milling, the molten thick solution of nickel cobalt that obtains of acid;
3) the thick solution of nickel cobalt obtains high-purity cobalt nickel solution and high-purity cobalt solution by chemical purification, purification by liquid extraction;
4) high-purity cobalt nickel solution and high-purity cobalt solution obtain rose vitriol and nickel sulfate hexahydrate crystal by crystallization;
5) synthetic nickel presoma and the cobalt precursor of obtaining of high-purity cobalt nickel solution and high-purity cobalt solution liquid phase;
6) the nickel presoma obtains the nickel powder body by high-temperature heat treatment;
7) cobalt precursor obtains the cobalt powder body by high-temperature heat treatment.
The further method of the present invention is: described step 3) also will obtain waste water, lithium solution, aluminum solutions, cadmium solution, nickel solution and Tongling solution.
The present invention further method is: the waste water of described step 3) by wastewater treatment after, the waste water slag is handled again, waste water returns use.
The further again method of the present invention is: the lithium solution of described step 3) leads to Quilonum Retard by deposition.
The further again method of the present invention is: described step 3) aluminum solutions obtains aluminium hydroxide by crystallization.
The further again method of the present invention is: the cadmium solution of described step 3) enters existing treatment scheme and handles.
The further again method of the present invention is: the nickel solution of described step 3) obtains electro deposited nickel by electrodeposition.
The further again method of the present invention is: the copper solutions of described step 3) obtains electro deposited copper by electrodeposition.
The further again method of the present invention is: the nickel powder body of described step 6) is the extra-fine nickel powder body.
The further again method of the present invention is: the cobalt powder body of described step 7) is the super-fine cobalt powder body.
A kind of beneficial effect that contains the processing method of cobalt nickel waste material, old and useless battery treatment of the present invention is: this method is the method for environmental protection treatment, and method is simple, and how pollution-free ring is, but refine goes out super-fine cobalt powder and extra-fine nickel powder, makes full use of waste material.
Description of drawings
Fig. 1 is the schema of the embodiment of the invention.
Embodiment
Below in conjunction with accompanying drawing preferred embodiment of the present invention is described in detail, thereby protection scope of the present invention is made more explicit defining so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that.
Be illustrated in figure 1 as the schema of the embodiment of the invention.The invention discloses a kind of processing method that contains cobalt nickel waste material, old and useless battery treatment, described treatment process comprises the steps:
A kind of processing method that contains cobalt nickel waste material, old and useless battery treatment, described treatment process comprises the steps:
1) broken apart containing after cobalt nickel waste material, the old and useless battery thermal treatment of reclaiming;
2) particle after broken apart is carried out ball milling, the molten thick solution of nickel cobalt that obtains of acid;
3) the thick solution of nickel cobalt obtains waste water, lithium solution, aluminum solutions, cadmium solution, nickel solution, Tongling solution, high-purity cobalt nickel solution and high-purity cobalt solution by chemical purification, purification by liquid extraction, waste water by wastewater treatment after, the waste water slag is handled again, waste water returns use, and lithium solution leads to Quilonum Retard by deposition, and aluminum solutions obtains aluminium hydroxide by crystallization, cadmium solution enters existing treatment scheme and handles, nickel solution obtains electro deposited nickel by electrodeposition, and copper solutions obtains electro deposited copper by electrodeposition;
4) high-purity cobalt nickel solution and high-purity cobalt solution obtain rose vitriol and nickel sulfate hexahydrate crystal by crystallization;
5) synthetic nickel presoma and the cobalt precursor of obtaining of high-purity cobalt nickel solution and high-purity cobalt solution liquid phase;
6) the nickel presoma obtains the extra-fine nickel powder body by high-temperature heat treatment;
7) cobalt precursor obtains the super-fine cobalt powder body by high-temperature heat treatment.
Abovely the present invention is described in detail in conjunction with embodiment; only be explanation technical conceive of the present invention and characteristics; its purpose is to allow the people that is familiar with this technology understand content of the present invention and is implemented; can not limit protection scope of the present invention with this; all equivalences that spirit is done according to the present invention change or modify, and all should be encompassed in protection scope of the present invention.
Claims (10)
1. processing method that contains cobalt nickel waste material, old and useless battery treatment, it is characterized in that: described treatment process comprises the steps:
1) broken apart containing after cobalt nickel waste material, the old and useless battery thermal treatment of reclaiming;
2) particle after broken apart is carried out ball milling, the molten thick solution of nickel cobalt that obtains of acid;
3) the thick solution of nickel cobalt obtains high-purity cobalt nickel solution and high-purity cobalt solution by chemical purification, purification by liquid extraction;
4) high-purity cobalt nickel solution and high-purity cobalt solution obtain rose vitriol and nickel sulfate hexahydrate crystal by crystallization;
5) synthetic nickel presoma and the cobalt precursor of obtaining of high-purity cobalt nickel solution and high-purity cobalt solution liquid phase;
6) the nickel presoma obtains the nickel powder body by high-temperature heat treatment;
7) cobalt precursor obtains the cobalt powder body by high-temperature heat treatment.
2. a kind of processing method that contains cobalt nickel waste material, old and useless battery treatment according to claim 1, it is characterized in that: described step 3) also will obtain waste water, lithium solution, aluminum solutions, cadmium solution, nickel solution and Tongling solution.
3. a kind of processing method that contains cobalt nickel waste material, old and useless battery treatment according to claim 1 is characterized in that: the waste water of described step 3) by wastewater treatment after, the waste water slag is handled again, waste water returns use.
4. a kind of processing method that contains cobalt nickel waste material, old and useless battery treatment according to claim 1, it is characterized in that: the lithium solution of described step 3) leads to Quilonum Retard by deposition.
5. a kind of processing method that contains cobalt nickel waste material, old and useless battery treatment according to claim 1, it is characterized in that: described step 3) aluminum solutions obtains aluminium hydroxide by crystallization.
6. a kind of processing method that contains cobalt nickel waste material, old and useless battery treatment according to claim 1 is characterized in that: the cadmium solution of described step 3) enters existing treatment scheme and handles.
7. a kind of processing method that contains cobalt nickel waste material, old and useless battery treatment according to claim 1, it is characterized in that: the nickel solution of described step 3) obtains electro deposited nickel by electrodeposition.
8. a kind of processing method that contains cobalt nickel waste material, old and useless battery treatment according to claim 1, it is characterized in that: the copper solutions of described step 3) obtains electro deposited copper by electrodeposition.
9. a kind of processing method that contains cobalt nickel waste material, old and useless battery treatment according to claim 1, it is characterized in that: the nickel powder body of described step 6) is the extra-fine nickel powder body.
10. a kind of processing method that contains cobalt nickel waste material, old and useless battery treatment according to claim 1, it is characterized in that: the cobalt powder body of described step 7) is the super-fine cobalt powder body.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102955771A CN101967561A (en) | 2010-09-28 | 2010-09-28 | Technological method for treating waste containing cobalt and nickel and waste batteries |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102955771A CN101967561A (en) | 2010-09-28 | 2010-09-28 | Technological method for treating waste containing cobalt and nickel and waste batteries |
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| CN101967561A true CN101967561A (en) | 2011-02-09 |
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| CN2010102955771A Pending CN101967561A (en) | 2010-09-28 | 2010-09-28 | Technological method for treating waste containing cobalt and nickel and waste batteries |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103334009A (en) * | 2013-06-14 | 2013-10-02 | 山东青龙山有色金属有限公司 | Method for recycling valuable metal from waste lithium batteries |
| CN103332720A (en) * | 2013-06-14 | 2013-10-02 | 山东青龙山有色金属有限公司 | Method for recycling valuable metal from waste petroleum chemical catalysts |
| CN112575195A (en) * | 2020-12-02 | 2021-03-30 | 贵州鹏程新材料有限公司 | Process for re-extracting cobalt and nickel from waste and old waste slag |
-
2010
- 2010-09-28 CN CN2010102955771A patent/CN101967561A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103334009A (en) * | 2013-06-14 | 2013-10-02 | 山东青龙山有色金属有限公司 | Method for recycling valuable metal from waste lithium batteries |
| CN103332720A (en) * | 2013-06-14 | 2013-10-02 | 山东青龙山有色金属有限公司 | Method for recycling valuable metal from waste petroleum chemical catalysts |
| CN103334009B (en) * | 2013-06-14 | 2015-02-04 | 山东青龙山有色金属有限公司 | Method for recycling valuable metal from waste lithium batteries |
| CN103332720B (en) * | 2013-06-14 | 2015-06-17 | 山东青龙山有色金属有限公司 | Method for recycling valuable metal from waste petroleum chemical catalysts |
| CN112575195A (en) * | 2020-12-02 | 2021-03-30 | 贵州鹏程新材料有限公司 | Process for re-extracting cobalt and nickel from waste and old waste slag |
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Application publication date: 20110209 |