CN101967415A - Method for preparing coal-based fuel carbon - Google Patents

Method for preparing coal-based fuel carbon Download PDF

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Publication number
CN101967415A
CN101967415A CN2010105420896A CN201010542089A CN101967415A CN 101967415 A CN101967415 A CN 101967415A CN 2010105420896 A CN2010105420896 A CN 2010105420896A CN 201010542089 A CN201010542089 A CN 201010542089A CN 101967415 A CN101967415 A CN 101967415A
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China
Prior art keywords
percent
coal
based fuel
fuel carbon
making method
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CN2010105420896A
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CN101967415B (en
Inventor
黄光许
刘全润
马名杰
张传祥
邢宝林
秦欣欣
黄山秀
夏浩
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Henan University of Technology
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Henan University of Technology
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Priority to CN 201010542089 priority Critical patent/CN101967415B/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

The invention discloses a method for preparing coal-based fuel carbon, which comprises the following steps of: a, taking the following components in percentage by mass: 80 to 95 percent of bituminous coal, 0 to 10 percent of crop straw and 4 to 10 percent of organic binder, uniformly mixing, and adding a proper amount of water for uniform mixing; b, pressing materials obtained in the step a into spheroids on a molding machine, and naturally airing the obtained green pellets; and c, putting the naturally aired green pellets into a carbonization furnace, carbonizing at the temperature of between 400 and 700 DEG C for 980 to 120 minutes, and cooling to prepare the coal-based fuel carbon. The coal-based fuel carbon has the advantages of cheap and readily available raw materials, low cost, effective utilization of biomass energy, the compressive strength of the prepared fuel carbon product of 25kg/piece, 75 percent of fixed carbon, 10 percent of volatile matter, 10 percent of ash content, 6,500 kilocalorie/kg of heat value, 0.4 percent of sulfur content, easy ignition, fire resistance, complete combustion, no smoke, no spark or smoke dust, high furnace surface temperature, high stability, and no collapse or break in the combustion process.

Description

A kind of making method of coal derived fuel charcoal
Technical field
The present invention relates to a kind of fuel, relate to a kind of making method of coal derived fuel charcoal specifically.
Background technology
In recent years, increasing both at home and abroad to demand as the various fuel charcoals of heating and food and drink fuel, along with the protection increasing of country, be that the former char yield of raw material constantly descends with natural forest to the forest reserves.Machine-made charcoal is the substitute products of charcoal, and it is big to have density, the calorific value height, smokeless, tasteless, pollution-free, do not explode, advantage such as inflammable, be the Green Product of generally acknowledging in the world, current throughput even do not satisfy the market requirement.Machine-made carbon is a raw material with agricultural residuums such as sawdust, stalks, processes through operations such as super-dry, plasticizing forming, charing, cooling, packings.Plasticizing forming is to utilize the contained xylogen of biomass self cohesiveness that (140-280 ℃) produces when being heated, and adopts the screw rod extrusion forming technology, makes grain formings such as wood chip under certain pressure; Charing is the pyrolytic process of wood chip rod in kiln of moulding, finally obtains machine-made carbon, simultaneously recyclable inflammable gas and wood vinegar.
At present the problem that exists of machine-made carbon industry is, the screw rod extrusion forming technology yields poorly, the energy consumption height, the consumable accessory life-span is short, ingredient requirement is harsh; In addition, the production of machine-made carbon is difficult to obtain continuous and competent raw material supply.
Summary of the invention
Purpose of the present invention provides a kind of making method of coal derived fuel charcoal just at existing weak point in the above-mentioned prior art.
Purpose of the present invention can realize by following technique measures:
The making method of coal derived fuel charcoal of the present invention comprises the steps:
A, get bituminous coal 80 ~ 95, agricultural crop straw 0 ~ 10 and organic binder bond 4 ~ 10 by mass ratio, puddle evenly after, add an amount of moisture and mix thoroughly once more;
B, the resulting material of step a is pressed into spheroplast on shaper, afterwards the gained green-ball is dried in air naturally;
C, will put into charring furnace through natural air dried green-ball, be 400~700 ℃ in temperature, and carbonization time is to carry out charing under the condition of 90min~120min, again through cool off the coal derived fuel charcoal.
The granularity of bituminous coal described in the present invention is less than 3mm; Described agricultural crop straw is to be crushed to particle diameter less than 3mm with pulverizer behind natural air drying; Described organic binder bond is a Sodium salts humic acids; The moisture 14-16% of material before the moulding.
Shaper described in the present invention is a roller briquetting machine commonly used in the moulded coal industry.
Carbonization time described in the present invention contains the heating-up time.
Beneficial effect of the present invention is as follows:
Coal derived fuel charcoal of the present invention is main raw material with bituminous coal and agricultural crop straw, and is cheap and easy to get, adds the combustioncharacteristics that agricultural crop straw can effectively utilize biomass energy, improve fuel charcoal product.Material forming is selected roller briquetting machine for use, and the output height, energy consumption is low, equipment attrition is little.Carbonization temperature is low, the time is short, energy consumption is little.Gained coal derived fuel charcoal product physical strength height, ultimate compression strength〉25kg/; Fixed carbon〉75%; Fugitive constituent〉10%; Ash<10%; Calorific value〉7000 kilocalories/Kg; Easily igniting, anti-burning, burning are complete, no smoke, no Mars flue dust, stove table temperature height.
 
Embodiment
The present invention is further described below with reference to embodiment:
Embodiment 1
Get granularity less than 3mm bituminous coal, pulverize the back granularity through the natural wind dry doubling and mix thoroughly according to the mass ratio mixing of 85:10:5 less than 3mm agricultural crop straw and Sodium salts humic acids, total mass is 5kg, adds water and mixes thoroughly once more, the material total moisture is controlled at 14-16%; With the moulding on roller briquetting machine of above-mentioned material, the gained green-ball dries in air naturally; Through the charing in charring furnace of air dried green-ball, carbonization temperature is 600 ℃, and carbonization time is that 100min(contains the heating-up time), again through cool off the coal derived fuel charcoal.Gained coal derived fuel charcoal product physical strength height, ultimate compression strength 35kg/; Moisture 1.8%; Fixed carbon 83.5%; Fugitive constituent 7%; Ash 7.7 %; 7180 kilocalories/Kg of calorific value; Sulphur content 0.31%.
Embodiment 2
Get granularity less than 3mm bituminous coal, pulverize the back granularity through the natural wind dry doubling and mix thoroughly according to the mass ratio mixing of 82:10:8 less than 3mm and Sodium salts humic acids, total mass is 5kg, adds water and mixes thoroughly once more, the material total moisture is controlled at 14-16%; With the moulding on roller briquetting machine of above-mentioned material, the gained green-ball dries in air naturally.Through the charing in charring furnace of air dried green-ball, carbonization temperature is 700 ℃, and carbonization time is that 120min(contains the heating-up time), again through cool off the coal derived fuel charcoal.Gained coal derived fuel charcoal product physical strength height, ultimate compression strength 30kg/; Moisture 2.0%; Fixed carbon 82.1%; Fugitive constituent 8.3%; Ash 6.8%; 7088 kilocalories/Kg of calorific value; Sulphur content 0.35%.
Embodiment 3
Get granularity and mix thoroughly according to the mass ratio mixing of 94:6 less than 3mm bituminous coal and Sodium salts humic acids, total mass is 5kg, adds water and mixes thoroughly once more, and the material total moisture is controlled at 14-16%; With the moulding on roller briquetting machine of above-mentioned material, the gained green-ball dries in air naturally; Through the charing in charring furnace of air dried green-ball, carbonization temperature is 500 ℃, and carbonization time is that 90min(contains the heating-up time), again through cool off the coal derived fuel charcoal.Gained coal derived fuel charcoal product physical strength height, ultimate compression strength 28kg/; Moisture 1.9%; Fixed carbon 84%; Fugitive constituent 6.5%; Ash 7.6%; 7178 kilocalories/Kg of calorific value; Sulphur content 0.33%.

Claims (4)

1. the making method of a coal derived fuel charcoal, it is characterized in that: described method comprises the steps:
A, get bituminous coal 80 ~ 95, agricultural crop straw 0 ~ 10 and organic binder bond 4 ~ 10 by mass ratio, puddle evenly after, add an amount of moisture and mix thoroughly once more;
B, the resulting material of step a is pressed into spheroplast on shaper, afterwards the gained green-ball is dried in air naturally;
C, will put into charring furnace through natural air dried green-ball, be 400~700 ℃ in temperature, and carbonization time is to carry out charing under the condition of 90min~120min, again through cool off the coal derived fuel charcoal.
2. making method according to claim 1 is characterized in that: the granularity of bituminous coal described in the step a is less than 3mm; Described agricultural crop straw is to be crushed to particle diameter less than 3mm with pulverizer behind natural air drying; Described organic binder bond is a Sodium salts humic acids; The moisture of material is 14-16% before the moulding.
3. making method according to claim 1 is characterized in that: described shaper is a roller briquetting machine commonly used in the moulded coal industry.
4. making method according to claim 1 is characterized in that: described carbonization time contains the heating-up time.
CN 201010542089 2010-11-13 2010-11-13 Method for preparing coal-based fuel carbon Expired - Fee Related CN101967415B (en)

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CN 201010542089 CN101967415B (en) 2010-11-13 2010-11-13 Method for preparing coal-based fuel carbon

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Application Number Priority Date Filing Date Title
CN 201010542089 CN101967415B (en) 2010-11-13 2010-11-13 Method for preparing coal-based fuel carbon

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CN101967415B CN101967415B (en) 2013-06-26

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102925178A (en) * 2012-10-19 2013-02-13 西安建筑科技大学 Method for preparing iron alloy, calcium carbide and formed coke for gasification industry from low-metamorphic powdered coal
CN103466616A (en) * 2013-08-23 2013-12-25 宁夏宝塔石化科技实业发展有限公司 Preparation method for coal-based activated carbon for recovery of organic solvent
CN104694191A (en) * 2014-12-09 2015-06-10 山东大学 Gas-containing coal similar material and preparation method thereof
CN105316013A (en) * 2014-07-31 2016-02-10 宝山钢铁股份有限公司 Method for producing coke by replacing part of coal by sawdust
CN106190410A (en) * 2016-08-24 2016-12-07 太湖县享有新能源有限责任公司 A kind of straw biomass rod of combustion-supporting type desulfurization and preparation method thereof
CN104962334B (en) * 2015-06-16 2017-11-10 中南大学 A kind of agglomeration for iron mine biomass char hybrid fuel

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54146803A (en) * 1978-05-10 1979-11-16 Nippon Kokan Kk <Nkk> Production of metallurgical briquette coke
CN1337441A (en) * 2001-09-03 2002-02-27 李志远 Metallurgical coke briquette
CN1560195A (en) * 2004-03-12 2005-01-05 李玉林 Production method of formed coke using coking powder as row-material and special formed coke furnace
CN101139537A (en) * 2007-10-09 2008-03-12 赵宜文 High-temperature casting molded coal and method for producing the same
CN101550372A (en) * 2009-05-16 2009-10-07 山西中元煤洁净技术有限公司 Method for producing carbonized coal with coal material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54146803A (en) * 1978-05-10 1979-11-16 Nippon Kokan Kk <Nkk> Production of metallurgical briquette coke
CN1337441A (en) * 2001-09-03 2002-02-27 李志远 Metallurgical coke briquette
CN1560195A (en) * 2004-03-12 2005-01-05 李玉林 Production method of formed coke using coking powder as row-material and special formed coke furnace
CN101139537A (en) * 2007-10-09 2008-03-12 赵宜文 High-temperature casting molded coal and method for producing the same
CN101550372A (en) * 2009-05-16 2009-10-07 山西中元煤洁净技术有限公司 Method for producing carbonized coal with coal material

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102925178A (en) * 2012-10-19 2013-02-13 西安建筑科技大学 Method for preparing iron alloy, calcium carbide and formed coke for gasification industry from low-metamorphic powdered coal
CN103466616A (en) * 2013-08-23 2013-12-25 宁夏宝塔石化科技实业发展有限公司 Preparation method for coal-based activated carbon for recovery of organic solvent
CN103466616B (en) * 2013-08-23 2015-11-04 宁夏宝塔石化科技实业发展有限公司 The preparation method of coal mass active carbon is reclaimed for organic solvent
CN105316013A (en) * 2014-07-31 2016-02-10 宝山钢铁股份有限公司 Method for producing coke by replacing part of coal by sawdust
CN105316013B (en) * 2014-07-31 2018-03-09 宝山钢铁股份有限公司 A kind of method that coal production coke in part is substituted using wood chip
CN104694191A (en) * 2014-12-09 2015-06-10 山东大学 Gas-containing coal similar material and preparation method thereof
CN104694191B (en) * 2014-12-09 2017-04-19 山东大学 Gas-containing coal similar material and preparation method thereof
CN104962334B (en) * 2015-06-16 2017-11-10 中南大学 A kind of agglomeration for iron mine biomass char hybrid fuel
CN106190410A (en) * 2016-08-24 2016-12-07 太湖县享有新能源有限责任公司 A kind of straw biomass rod of combustion-supporting type desulfurization and preparation method thereof

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