CN101967242B - Wood plastic material blending-modified by using a plurality of recycling plastics - Google Patents
Wood plastic material blending-modified by using a plurality of recycling plastics Download PDFInfo
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- CN101967242B CN101967242B CN201010296870XA CN201010296870A CN101967242B CN 101967242 B CN101967242 B CN 101967242B CN 201010296870X A CN201010296870X A CN 201010296870XA CN 201010296870 A CN201010296870 A CN 201010296870A CN 101967242 B CN101967242 B CN 101967242B
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Abstract
The invention discloses a wood plastic material blending-modified by using a plurality of recycling plastics. The wood plastic material comprises the following component in percentage by weight: 15-25% of recycling PE (Poly Ethylene); 3-15 % of recycling PP (Propene Polymer): 3-15% of recycling EVA (Ethylene Vinyl Acetate copolymer); 0.3-1% of maleic anhydride; 2-8% of PP modified Kaolin clay; 40-60% of vegetable meal; 0.5-1.5% of methyl silane coupling agent; 0.5-1.5% of methyl silicone oil; 0.5-1.5% of zinc stearate; 0.5-1.5 of ethylene bis stearamide; 0.1-1.5% of antioxygen; 0.1-0.5% of UV-absorber; 0-3% of pigment; and 0-1% of carbon black. The recycling PP is completely or partly copolymerized PP. The invention also provides a production process of the wood plastic material. The wood plastic material has superior mechanical property, higher wear resistance, bending resistance and impact resistance, and is more suitable for the functional field of building bearing compared with the common single resin wood plastic material.
Description
Technical field
The present invention relates to wood plastic composite, be widely used in fields such as outdoor scene, highway, building decoration.
Background technology
The wood-plastic products that existing market is common often adopts unitary plastic as matrix resin, though processing and drawing materials has conveniently often followed the defective of unmodified resin.As single with PE as resin, though better wilful, rigidity is not enough, is prone to creep, often causes fragility excessive, easy to crack to add again after a large amount of stopping composition are adjusted rigidity, and proportion is excessive.Single with PP as resin, though rigidity is strong, often submissive deficiency, machine-shaping difficulty, and product is prone to degradation with aging.
Summary of the invention
The present invention the technical problem that will just solve just provide a kind of Wood-plastic material that adopts the modification of multiple recovery plastic blend to make; This Wood-plastic material possesses superior mechanical property; Higher wear-resisting, bending resistance, anti-impact are applicable to building bearing more than general single resin Wood-plastic material.
The present invention adopts following technical scheme: adopt the Wood-plastic material of multiple recovery plastic blend modification, it is characterized in that being made up of following component, specifically composition and weight proportion umber are following:
Reclaim PE 15-25 and reclaim PP 3-15
Reclaim EVA 3-15 maleic anhydride 0.3-1
PP modified kaolin 2-8
Plant fiber powder 40-60 methyl-monosilane coupling agent 0.5-1.5
Methyl-silicone oil 0.5-1.5
Zinic stearas 0.5-1.5 ethylene bis stearamide 0.5-1.5
Oxidation inhibitor 0.1-0.5 uv-absorbing agent 0.1-0.5
Pigment 0-3 carbon black 0-1;
Said recovery PP is all or part of copolymerization PP.
Preferably, said recovery PE mainly adopts HDPE, is aided with a small amount of LDPE or/and LLDPE, and HDPE accounts for more than 80%.
Wood-plastic material of the present invention adopts the modification of multiple recovery plastic blend as matrix resin, when taking into account the consistency of various resins own, learns from other's strong points to offset one's weaknesses.For guaranteeing better machining property, use a part of PE (when selecting feed back, be mainly HDPE and cooperate a small amount of LDPE and LLDPE); For remedying the insufficient shortcoming of PE rigidity; Add part flowability feed back PP preferably, consider the consistency between PE and PP, selected PP must be all or part of copolymerization PP; Be equipped with an amount of EVA simultaneously, make to have toughening effect concurrently.For better increasing base-material rigidity, hardness, an amount of modified kaolin is introduced in the crystallization that improves resin, has flame retardant effect simultaneously concurrently.No matter be PE or PP, all belong to non-polar resin, for guarantee with the polarity wood powder between the interface combine, in resin, introduce maleic anhydride, the grafting of use reaction method.
The present invention also provides the production technique of above-mentioned Wood-plastic material, specifically comprises the steps:
1) will reclaim PE, recovery PP, recovery EVA fragmentation, dry, with maleic anhydride, PP modified kaolin mechanically mixing, high-temperature fusion blend again, granulation, cooling make component A again;
2) plant fiber powder, methyl-monosilane coupling agent, methyl-silicone oil mechanically mixing is even, make B component;
3) Zinic stearas, ethylene bis stearamide, oxidation inhibitor, uv-absorbing agent, pigment, carbon black and component A, B component mechanically mixing is even; High-temperature fusion, plasticizing granulation, cooling, fragmentation again moulded special-purpose forcing machine fusion, typing, cooling, cutting through wood again and promptly made Wood-plastic material.
Said step 1) and 3) prilling temperature is controlled at 150～180 ℃ in.
Said step 1) and 3) tablets press is selected flat two tablets press for use in.
Technology of the present invention is simply effective, and the Wood-plastic material that adopts this technology to make possesses superior mechanical property, and higher wear-resisting, bending resistance, anti-impact are applicable to the functional domain of building bearing more than general single resin Wood-plastic material.
Embodiment
The present invention adopts the Wood-plastic material of multiple recovery plastic blend modification to be made up of following component, and specifically composition and weight proportion umber are following,
Reclaim PE 15-25 and reclaim PP 3-15
Reclaim EVA 3-15 maleic anhydride 0.3-1
PP modified kaolin 2-8
Plant fiber powder 40-60 methyl-monosilane coupling agent 0.5-1.5
Methyl-silicone oil 0.5-1.5
Zinic stearas 0.5-1.5 ethylene bis stearamide 0.5-1.5
Oxidation inhibitor 0.1-0.5 uv-absorbing agent 0.1-0.5
Pigment 0-3 carbon black 0-1;
Said recovery PP can all be copolymerization PP, and perhaps mixing of copolymerization PP and homopolymerization PP, said recovery PE mainly adopts HDPE, is aided with a small amount of LDPE or/and LLDPE, and HDPE accounts for more than 80%.
Embodiment one, the present invention adopt the Wood-plastic material of multiple recovery plastic blend modification to be made up of following component, and specifically composition and weight proportion umber are following,
Reclaim PE 15 and reclaim PP 3
Reclaim EVA 3 maleic anhydrides 0.3
PP modified kaolin 2
Plant fiber powder 40 methyl-monosilane coupling agents 0.5
Methyl-silicone oil 0.5
Zinic stearas 0.5 ethylene bis stearamide 0.5
Oxidation inhibitor 0.15 uv-absorbing agent 0.1
Pigment 0.5 carbon black 0.5
Said recovery PP must be all or part of copolymerization PP, and said recovery PE mainly adopts HDPE, is aided with a small amount of LDPE and LLDPE, and HDPE accounts for 80%, and LDPE and LLDPE account for 10% respectively.
Embodiment two, the present invention adopt the Wood-plastic material of multiple recovery plastic blend modification to be made up of following component, and specifically composition and weight proportion umber are following,
Reclaim PE 20 and reclaim PP 10
Reclaim EVA 8 maleic anhydrides 0.6
PP modified kaolin 5
Plant fiber powder 50 methyl-monosilane coupling agents 1
Methyl-silicone oil 1
Zinic stearas 1 ethylene bis stearamide 0.5-1.5
Oxidation inhibitor 0.3 uv-absorbing agent 0.3
Pigment 1.5 carbon blacks 0.5;
Said recovery PP must be all or part of copolymerization PP, and said recovery PE mainly adopts HDPE, is aided with a small amount of LDPE and LLDPE, and HDPE accounts for 90%, and LDPE and LLDPE account for 5% respectively.
Embodiment three, the present invention adopt the Wood-plastic material of multiple recovery plastic blend modification to be made up of following component, and specifically composition and weight proportion umber are following,
Reclaim PE 25 and reclaim PP 15
Reclaim EVA 15 maleic anhydrides 1
PP modified kaolin 8
Plant fiber powder 60 methyl-monosilane coupling agents 1.5
Methyl-silicone oil 1.5
Zinic stearas 1.5 ethylene bis stearamides 1.5
Oxidation inhibitor 0.5 uv-absorbing agent 0.5
Pigment 3 carbon blacks 1;
Said recovery PP must be all or part of copolymerization PP, and said recovery PE mainly adopts HDPE, is aided with a small amount of LDPE or LLDPE, and HDPE accounts for 90%, and LDPE or LLDPE account for 10%.
Wood-plastic material production technique provided by the invention comprises the steps:
1) will reclaim PE, recovery PP, recovery EVA fragmentation, dry, with maleic anhydride, PP modified kaolin mechanically mixing, high-temperature fusion blend again, granulation, cooling make component A again;
2) plant fiber powder, methyl-monosilane coupling agent, methyl-silicone oil mechanically mixing is even, make B component;
3) Zinic stearas, ethylene bis stearamide, oxidation inhibitor, uv-absorbing agent, pigment, carbon black and component A, B component mechanically mixing is even; High-temperature fusion, plasticizing granulation, cooling, fragmentation again moulded special-purpose forcing machine fusion, typing, cooling, cutting through wood again and promptly made Wood-plastic material.
Said step 1) and 3) prilling temperature is controlled at 150～180 ℃ in, and tablets press is selected common flat two tablets presss for use.
Claims (6)
1. adopt the Wood-plastic material of multiple recovery plastic blend modification, it is characterized in that being made up of following component, specifically composition and weight proportion umber are following:
2. the Wood-plastic material of the multiple recovery plastic blend of employing according to claim 1 modification is characterized in that: said recovery PP all is copolymerization PP or contains part copolymerization PP.
3. the Wood-plastic material of the multiple recovery plastic blend of employing according to claim 1 modification is characterized in that: said recovery PE mainly adopts HDPE, is aided with a small amount of LDPE or/and LLDPE, and HDPE accounts for more than 80%.
4. the production technique of Wood-plastic material according to claim 1 comprises the steps:
1) will reclaim PE, recovery PP, recovery EVA fragmentation, dry, with maleic anhydride, PP modified kaolin mechanically mixing, high-temperature fusion blend again, granulation, cooling make component A again;
2) plant fiber powder, methyl-monosilane coupling agent, methyl-silicone oil mechanically mixing is even, make B component;
3) Zinic stearas, ethylene bis stearamide, oxidation inhibitor, uv-absorbing agent, pigment, carbon black and component A, B component mechanically mixing is even; High-temperature fusion, plasticizing granulation, cooling, fragmentation again moulded special-purpose forcing machine fusion, typing, cooling, cutting through wood again and promptly made Wood-plastic material.
5. the production technique of Wood-plastic material according to claim 4 is characterized in that: prilling temperature is controlled at 150～180 ℃ said step 1) and 3).
6. the production technique of Wood-plastic material according to claim 4 is characterized in that: tablets press is selected flat two tablets presss for use said step 1) and 3).
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| Application Number | Priority Date | Filing Date | Title |
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| CN201010296870XA CN101967242B (en) | 2010-09-28 | 2010-09-28 | Wood plastic material blending-modified by using a plurality of recycling plastics |
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| CN201010296870XA CN101967242B (en) | 2010-09-28 | 2010-09-28 | Wood plastic material blending-modified by using a plurality of recycling plastics |
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| CN101967242A CN101967242A (en) | 2011-02-09 |
| CN101967242B true CN101967242B (en) | 2012-07-04 |
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Cited By (1)
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|---|---|---|---|---|
| US11884821B2 (en) | 2018-02-01 | 2024-01-30 | Dow Silicones Corporation | Composition, polymer composite article formed therewith, and method of preparing same |
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| CN104744955B (en) * | 2013-12-25 | 2017-06-06 | 格林美股份有限公司 | A kind of entire body imitation wood line polyethylene plastic-wood section and preparation method thereof |
| CN104311948A (en) * | 2014-10-10 | 2015-01-28 | 周伟 | Formula and production process of PE sythetic-wood decoration surface plate |
| CN104448464B (en) * | 2014-11-03 | 2015-10-14 | 深圳市心立方节能新技术有限公司 | A kind of steel wire mesh framework composite tube material |
| CN104629152B (en) * | 2015-02-16 | 2017-03-01 | 康硕电气集团有限公司 | Recycle the method that discarded high-density polyethylene plastics prepare 3D printing material |
| CN106317739B (en) * | 2015-06-17 | 2018-07-03 | 中国石油化工股份有限公司 | polyethylene composition and preparation method thereof |
| CN106349726A (en) * | 2015-07-17 | 2017-01-25 | 山东绿森塑木复合材料有限公司 | Polyolefin wood-plastic composite material and preparation method thereof |
| KR102326113B1 (en) | 2019-08-07 | 2021-11-16 | 다우 실리콘즈 코포레이션 | Solid Carrier Components Comprising Liquid Polyorganosiloxanes, and Methods of Making and Using Solid Carrier Components |
| CN112654679B (en) | 2019-08-07 | 2023-02-03 | 美国陶氏有机硅公司 | Alkenyl-functionalized polydiorganosiloxane compositions and methods of use thereof in forming wood-plastic composites |
| EP3799595B1 (en) | 2019-08-07 | 2022-07-06 | Dow Silicones Corporation | Solid carrier component including a liquid polydiorganosiloxane and methods for preparation and use of the solid carrier component |
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| CN101747652A (en) * | 2010-01-15 | 2010-06-23 | 重庆理工大学 | Preparation method of wood plastic material |
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| CN1858102A (en) * | 2006-05-24 | 2006-11-08 | 威海市广通塑胶制品有限公司 | Plastic-wood building formwork and its producing method |
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| US11884821B2 (en) | 2018-02-01 | 2024-01-30 | Dow Silicones Corporation | Composition, polymer composite article formed therewith, and method of preparing same |
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| C14 | Grant of patent or utility model | ||
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| ASS | Succession or assignment of patent right |
Owner name: ZHEJIANG TANMIKE TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: ZHEJIANG ZHONGYUAN FENGYE PIPES CO., LTD. Effective date: 20131225 |
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Effective date of registration: 20131225 Address after: 311814, No. 478, Central Road, shop Town, Zhuji, Zhejiang Patentee after: Zhejiang Tanmike Technology Co. Ltd. Address before: 311814 new type pipe industry park, shop Town, Zhuji, Zhejiang Patentee before: Zhejiang Zhongyuan Fengye Pipes Co., Ltd. |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Wood plastic materials modified by blending a variety of recycled plastics Effective date of registration: 20220425 Granted publication date: 20120704 Pledgee: Diankou sub branch of Zhejiang Zhuji Rural Commercial Bank Co.,Ltd. Pledgor: Zhejiang Tanmike Technology Co.,Ltd. Registration number: Y2022980004714 |
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