CN101966134B - Liquid soap with sterilizing and skin protecting functions and preparation method thereof - Google Patents
Liquid soap with sterilizing and skin protecting functions and preparation method thereof Download PDFInfo
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- CN101966134B CN101966134B CN201010295204A CN201010295204A CN101966134B CN 101966134 B CN101966134 B CN 101966134B CN 201010295204 A CN201010295204 A CN 201010295204A CN 201010295204 A CN201010295204 A CN 201010295204A CN 101966134 B CN101966134 B CN 101966134B
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Abstract
The invention discloses a liquid soap with sterilizing and skin protecting functions and a preparation method thereof, which relates to the field of cleaning and skin protection. The liquid soap comprises active ingredients including anion and nonionic surfactants and assistants including skin-protecting agent, sanitizer, humectant, lubricant, chelating agent and pH value regulator. The components above are synthesized to prepare a viscous transparent liquid which has a nearly neutral pH value, and the preparation process thereof does not need any complex equipment. The liquid soap has strong soil removability, little skin irritation, mild effect, refined and smooth foam and a disinfection function which effectively prevents germ from breeding. The liquid soap is added with skin protecting ingredient and therefore can prevent skin from being chapped and improve frizzing resistance to frost; and thus, the liquid soap can be normally used even in winter in northern areas.
Description
Technical field
The invention belongs to cleaning skin protection field, concrete, relate to a kind of sterilizing skin-protective hand cleanser and preparation method thereof.
Background technology
Sterilizing skin-protective hand cleanser is the very big cleaning product of urban and urual areas of whole country's consumption.Now, as the wash one's hands substitute products of fancy soap of tradition, washing one's hands has many advantages, and its liquid characteristic can be added all kinds of adjuvant very easily, resembles disinfection sanitizer, composes fat emollient, wetting agent, thickening agent etc., is fit to the needs of all kinds of different crowds.The change of the Personal hygiene custom of Along with people's; Experiencing SARS in 2003 and 2009 " swine flu " afterwards especially; The daily sterilization consciousness of people strengthens gradually; Particularly the importance to hand hygiene improves with sterilization consciousness gradually, and for fear of the cross infection of the used fancy soap of washing one's hands, handwashing liquid has just become requisite cleaning supplies in the life.Oil stain, dirt on the just skin surface that common handwashing liquid is washed off; For some antibacterial, virus then is powerless; So the sterilizing handwashing liquid has become daily best first-selected; The U.S. microbiologist charles lattice uncle say, washes one's hands with disinfection hand cleanser, can the ill risk of human body be reduced by 75% even more.At present, the sterilizing skin-protective hand cleanser that is used to clean, a multitude of names, its product is many, and the industrial chemicals price is higher with traditional handicraft production, and the sterilizing performance is low, and zest is high, and anti-hard water and resistance to frost are low, and skin is had big injury.Like patent CN101478579A, be antibacterial with the parachlorometaxylenol, cooperate anion surfactant, amphoteric surfactant, wetting agent, water-soluble grease, chelating agen etc. to be mixed with sterilizing skin-protective hand cleanser.Parachlorometaxylenol (PCMX), though to majority half Lan Shi rigidity, negative bacterium, fungus and mycete are all killed effect; It is a kind of hypotoxicity antibacterial; But its dissolubility in water is merely 0.03%, is prone to remain on the skin after washing one's hands, and has certain potential safety hazard.Publication number is in the patent of invention of CN101176700A, is antibacterial with the povidone iodine, cooperates sodium lauryl sulphate, NPE, dodecylbenzene sodium sulfonate to be mixed with antimicrobial disinfection hand cleanser; The bactericidal action of povidone iodine produces by decompositing free iodine gradually, and wherein the combination iodine of 80%-90% can depolymerize to free-iodine, directly makes the intravital protein denaturation of cause of disease; With the pathogen kill cell, thereby reach the purpose of disinfection, povidone iodine often is used to treat gynaecopathia; Povidone iodine is used and disinfection hand cleanser; Cost is high, and life-time service can produce toleration to antibacterial, is difficult for popularizing and popularization.
Summary of the invention
The object of the present invention is to provide a kind of sterilizing skin-protective hand cleanser, concrete provided a kind of sterilizing skin-protective hand cleanser that contains carbamide and Nipagin ester.
Sterilizing skin-protective hand cleanser of the present invention is to be active component with anion and non-ionic surface active agent, prepares nearly neutral, the adhesive transparency liquid that dirt-removing power is strong, little to skin irritation of synthetic pH value with appropriate amount of addition agent, is fit to the handwashing liquid of cold washing.The parts by weight of each component and additional proportion are: 5～20 parts in fat polyoxyethylenated alcohol sodium sulfate, soil temperature-805～20 part, 1～10 part of glycerol, 1～5 part in carbamide; 1.2～5 parts in sodium chloride, 0.5～2 part of hydrophilic lanoline, 0.1～1 part of sodium carboxymethyl cellulose, 0.1～0.5 part of edetate; 0.1～0.3 part of Nipagin ester, 0.1～5 part of citric acid (sodium), 0.1～0.5 part in essence; 0.1～0.5 part of pigment, all the other are distilled water, said raw material is technical grade.
In agitated reactor, add parts by weight and be 30～50 parts distilled water, be heated to 60～80 ℃ subsequent use, under agitation; In this system, add fat polyoxyethylenated alcohol sodium sulfate, soil temperature-80 in proportion successively, after the dissolving, reduce temperature fully; Under 40～60 ℃ of conditions; Add Nipagin ester, carbamide, hydrophilic lanoline successively, mix to stir, be cooled to room temperature after fully being dissolved into transparency liquid; Add glycerol in proportion successively; Sodium carboxymethyl cellulose, edetate, essence, pigment, remaining distilled water, sodium chloride fully stirred 1～6 hour, and using citric acid or sodium citrate to regulate pH value is 6～8; Fully behind the degassing froth breaking, obtain adhesive transparency liquid and be product.
The used Nipagin ester of the present invention comprises one or more in methyl hydroxybenzoate, ethyl hydroxybenzoate, propylparaben, butoben, nipalgin monooctyl ester and soluble metyl hydroxybenzoate, ethylparaben sodium, soluble propylhydroxybenzoate, nipabutyl sodium and the compound Sodium Paraben.Used edetate, it comprises but is not limited only to sodium ethylene diamine tetracetate, ethylenediaminetetraacetic acid potassium, ethylenediaminetetraacetic acid ammonium.
A kind of method for preparing of sterilizing skin-protective hand cleanser is characterized in that, is to be processed by following raw material by weight: 5～20 parts in fat polyoxyethylenated alcohol sodium sulfate; Soil temperature-805～20 part, 1～10 part of glycerol, 1～5 part in carbamide; 1.2～5 parts in sodium chloride, 0.5～2 part of hydrophilic lanoline, 0.1～1 part of sodium carboxymethyl cellulose; 0.1～0.5 part of edetate, 0.1～0.3 part of Nipagin ester, 0.1～5 part of citric acid (sodium); 0.1～0.5 part in essence, 0.1～0.5 part of pigment, all the other are distilled water;
Method for preparing:
(1) in agitated reactor, adding parts by weight is 30～50 parts distilled water, be heated to 60～80 ℃ subsequent use;
(2) under agitation; In (1) system, add fat polyoxyethylenated alcohol sodium sulfate, soil temperature-80 in proportion successively, after the dissolving, reduce temperature fully; Under 40～60 ℃ of conditions; Add Nipagin ester, carbamide, hydrophilic lanoline successively, mix to stir, be cooled to room temperature after fully being dissolved into transparency liquid;
(3) in the room temperature system; Add glycerol in proportion successively; Sodium carboxymethyl cellulose, edetate, essence, pigment, remaining distilled water, sodium chloride fully stirred 1～6 hour, and using citric acid or sodium citrate to regulate pH value is 6～8; Fully behind the degassing froth breaking, obtain adhesive transparency liquid and be product.
Main Ingredients and Appearance carbamide (urea) is colourless or white needles or bar-shaped crystalline solid; Water-soluble, pure; Be insoluble to ether, chloroform, be alkalescence, carbamide has epiderm skin horny layer and the effect that keeps skin moisturizing of removing; Effectively antibiotic skin-care, anti-chap, anti-chilblain and can suppress staphylococcus aureus, Candida albicans, and almost be free from side effects.Carbamide is for hardware, and advantage is a corroding metal not.Thereby carbamide is skin protectant, antiseptic, antifreezing agent, the antibacterial among the present invention.Main Ingredients and Appearance Nipagin ester, toxicity are extremely low, and be non-stimulated to human body, is good sterilization antiseptic.Parabens is typical growth inhibitor, and it can suppress the transfer of nutrient substance to bacterial cell.Through one of following several means, as permease is quit work, destroy how empty passage, change the pH value gradient of film or the charge potential of film both sides etc., the para hydroxybenzene esters of gallic acid has obviously suppressed the absorption of bacterial cell to nutrient substance.The change of transmembrane potential can prevent the transfer of enzyme substrate and the generation of ATP.The antibacterial mechanism of Nipagin ester: the cell membrane of destroy microorganisms makes intracellular protein denaturation, and can suppress the activity of respiratory enzyme system with the electron transport enzyme system of microbial cell.The bacteriostatic activity of Nipagin ester mainly is that molecular state works, and its intramolecular hydroxyl esterification, and no longer ionization is so it all has good fungistatic effect in the scope of pH 3～8.Nipagin ester is the disinfection sanitizer among the present invention.Nipagin ester and carbamide the two " synergism " have efficient, broad-spectrum, quick, safe sterilization effect.
Main active component fat polyoxyethylenated alcohol sodium sulfate is anion surfactant; Soluble in water; Have good decontamination, emulsifying, foam performance and anti-performance of hard water; Gentle washing character can injured skin, and it and the strong nonionic surfactant tween 80 of hydrophilic can produce " collaborative decontamination effect ", and mixing has improved the dirt-removing power of the two each other.The adding of adjuvant essence can make product distribute strong aromatic odor stably and lastingly, and it is the perfume agent among the present invention.
In sum; The present invention is an active component with anion and non-ionic surface active agent; Be equipped with other adjuvant and synthesize sterilizing skin-protective hand cleanser, preparation technology is simple, product excellent adsorption, chemical property are stable, the anticorrosion anti-low temperature of skin protection, sense organ are good, the fragrant odour stable and durable." cooperative effect " that particularly produces between component not only strengthens its dirt-removing power, and to the skin action temperature with, make stimulation drop to minimum to skin.
The specific embodiment
Embodiment 1
(1) in agitated reactor, add the 50g distilled water, be heated to 80 ℃ subsequent use;
(2) under agitation; In (1) system, add fat polyoxyethylenated alcohol sodium sulfate 15g, soil temperature-8017g in proportion successively, after the dissolving, reduce temperature fully; Under 60 ℃ of conditions; Add methyl hydroxybenzoate 0.15g, carbamide 3g, hydrophilic lanoline 1g successively, mix to stir, be cooled to room temperature after fully being dissolved into transparency liquid;
(3) in the room temperature system; Add glycerol 5g in proportion successively; Sodium carboxymethyl cellulose 0.2g, edetate 0.2g, essence 0.3g, pigment 0.3g, distilled water 5.05g, sodium chloride 1.5g fully stirred 6 hours, and using citric acid 1.3g to regulate pH value is 6.5; Fully behind the degassing froth breaking, obtain adhesive transparency liquid and be product.
Embodiment 2
(1) in agitated reactor, add the 110g distilled water, be heated to 70 ℃ subsequent use;
(2) under agitation; In (1) system, add fat polyoxyethylenated alcohol sodium sulfate 35g, soil temperature-8025g in proportion successively, after the dissolving, reduce temperature fully; Under 50 ℃ of conditions; Add ethyl hydroxybenzoate 0.2g, carbamide 3g, hydrophilic lanoline 1.5g successively, mix to stir, be cooled to room temperature after fully being dissolved into transparency liquid;
(3) in the room temperature system; Add glycerol 10g in proportion successively; Sodium carboxymethyl cellulose 1g, edetate 0.8g, essence 0.5g, pigment 0.3g, distilled water 2.55g, sodium chloride 3g fully stirred 3 hours, and using citric acid 2.1g to regulate pH value is 6.3; Fully behind the degassing froth breaking, obtain adhesive transparency liquid and be product.
Embodiment 3
(1) in agitated reactor, add the 100g distilled water, be heated to 60 ℃ subsequent use;
(2) under agitation; In (1) system, add fat polyoxyethylenated alcohol sodium sulfate 25g, soil temperature-8030g in proportion successively, after the dissolving, reduce temperature fully; Under 40 ℃ of conditions; Add propylparaben 0.25g, carbamide 2g, hydrophilic lanoline 1g successively, mix to stir, be cooled to room temperature after fully being dissolved into transparency liquid;
(3) in the room temperature system; Add glycerol 15g in proportion successively; Sodium carboxymethyl cellulose 1g, edetate 0.5g, essence 0.6g, pigment 0.25g, distilled water 15.65g, sodium chloride 5g fully stirred 4 hours, and using citric acid 1.2g to regulate pH value is 6.8; Fully behind the degassing froth breaking, obtain adhesive transparency liquid and be product.
Embodiment 4
(1) in agitated reactor, add the 40g distilled water, be heated to 65 ℃ subsequent use;
(2) under agitation; In (1) system, add fat polyoxyethylenated alcohol sodium sulfate 10g, soil temperature-8012g in proportion successively, after the dissolving, reduce temperature fully; Under 55 ℃ of conditions; Add soluble metyl hydroxybenzoate 0.15g, carbamide 3g, hydrophilic lanoline 0.6g successively, mix to stir, be cooled to room temperature after fully being dissolved into transparency liquid;
(3) in the room temperature system; Add glycerol 8g in proportion successively; Sodium carboxymethyl cellulose 0.4g, edetate 0.2g, essence 0.5g, pigment 0.2g, distilled water 22.05g, sodium chloride 1.4g fully stirred 5 hours, and using sodium citrate 1.5g to regulate pH value is 7.4; Fully behind the degassing froth breaking, obtain adhesive transparency liquid and be product.
Embodiment 5
(1) in agitated reactor, add the 50g distilled water, be heated to 75 ℃ subsequent use;
(2) under agitation; In (1) system, add fat polyoxyethylenated alcohol sodium sulfate 15g, soil temperature-8015g in proportion successively, after the dissolving, reduce temperature fully; Under 45 ℃ of conditions; Add ethylparaben sodium 0.3g, carbamide 2g, hydrophilic lanoline 1g successively, mix to stir, be cooled to room temperature after fully being dissolved into transparency liquid;
(3) in the room temperature system; Add glycerol 5g in proportion successively; Sodium carboxymethyl cellulose 0.5g, edetate 0.4g, essence 0.2g, pigment 0.2g, distilled water 6.5g, sodium chloride 1.4g fully stirred 6 hours, and using sodium citrate 2.5g to regulate pH value is 7.8; Fully behind the degassing froth breaking, obtain adhesive transparency liquid and be product.
Embodiment 6
(1) in agitated reactor, add the 120g distilled water, be heated to 70 ℃ subsequent use;
(2) under agitation; In (1) system, add fat polyoxyethylenated alcohol sodium sulfate 15g, soil temperature-8020g in proportion successively, after the dissolving, reduce temperature fully; Under 50 ℃ of conditions; Add ethylparaben sodium 0.4g, carbamide 5g, hydrophilic lanoline 2g successively, mix to stir, be cooled to room temperature after fully being dissolved into transparency liquid;
(3) in the room temperature system; Add glycerol 7g in proportion successively; Sodium carboxymethyl cellulose 1.5g, edetate 0.5g, essence 0.8g, pigment 0.2g, distilled water 20.1g, sodium chloride 2.5g fully stirred 4 hours, and using sodium citrate 5g to regulate pH value is 8.0; Fully behind the degassing froth breaking, obtain adhesive transparency liquid and be product.
Embodiment 7
(1) in agitated reactor, add the 150g distilled water, be heated to 80 ℃ subsequent use;
(2) under agitation; In (1) system, add fat polyoxyethylenated alcohol sodium sulfate 40g, soil temperature-8030g in proportion successively, after the dissolving, reduce temperature fully; Under 45 ℃ of conditions; Add soluble metyl hydroxybenzoate 0.9g, carbamide 12g, hydrophilic lanoline 3g successively, mix to stir, be cooled to room temperature after fully being dissolved into transparency liquid;
(3) in the room temperature system; Add glycerol 20g in proportion successively; Sodium carboxymethyl cellulose 1.5g, edetate 1g, essence 1g, pigment 0.5g, distilled water 31.1g, sodium chloride 4g fully stirred 5 hours, and using citric acid 5g to regulate pH value is 7.3; Fully behind the degassing froth breaking, obtain adhesive transparency liquid and be product.
Embodiment 8
(1) in agitated reactor, add the 160g distilled water, be heated to 78 ℃ subsequent use;
(2) under agitation; In (1) system, add fat polyoxyethylenated alcohol sodium sulfate 40g, soil temperature-8045g in proportion successively, after the dissolving, reduce temperature fully; Under 55 ℃ of conditions; Add propylparaben 0.6g, carbamide 11g, hydrophilic lanoline 6g successively, mix to stir, be cooled to room temperature after fully being dissolved into transparency liquid;
(3) in the room temperature system; Add glycerol 14g in proportion successively; Sodium carboxymethyl cellulose 2g, edetate 0.5g, essence 1.5g, pigment 1.5g, distilled water 1g, sodium chloride 5g fully stirred 4.5 hours, and using citric acid 8g to regulate pH value is 6.7; Fully behind the degassing froth breaking, obtain adhesive transparency liquid and be product.
Embodiment 9
(1) in agitated reactor, add the 100g distilled water, be heated to 68 ℃ subsequent use;
(2) under agitation; In (1) system, add fat polyoxyethylenated alcohol sodium sulfate 15g, soil temperature-8020g in proportion successively, after the dissolving, reduce temperature fully; Under 45 ℃ of conditions; Add ethyl hydroxybenzoate 0.6g, carbamide 6g, hydrophilic lanoline 4g successively, mix to stir, be cooled to room temperature after fully being dissolved into transparency liquid;
(3) in the room temperature system; Add glycerol 4g in proportion successively; Sodium carboxymethyl cellulose 1.5g, edetate 0.5g, essence 1g, pigment 1g, distilled water 37.4g, sodium chloride 3g fully stirred 5.5 hours, and using citric acid 6g to regulate pH value is 7.2; Fully behind the degassing froth breaking, obtain adhesive transparency liquid and be product.
Embodiment 10
(1) in agitated reactor, add the 105g distilled water, be heated to 72 ℃ subsequent use;
(2) under agitation; In (1) system, add fat polyoxyethylenated alcohol sodium sulfate 30g, soil temperature-8025g in proportion successively, after the dissolving, reduce temperature fully; Under 51 ℃ of conditions; Add methyl hydroxybenzoate 0.2g, carbamide 5g, hydrophilic lanoline 2g successively, mix to stir, be cooled to room temperature after fully being dissolved into transparency liquid;
(3) in the room temperature system; Add glycerol 12g in proportion successively; Sodium carboxymethyl cellulose 1g, edetate 0.4g, essence 1g, pigment 0.6g, distilled water 8.8g, sodium chloride 4g fully stirred 3.5 hours, and using citric acid 5g to regulate pH value is 7.5; Fully behind the degassing froth breaking, obtain adhesive transparency liquid and be product.
Claims (2)
1. sterilizing skin-protective hand cleanser according to claim 1 is characterized in that, is to be processed by following raw material by weight: 5～20 parts of polyoxyethylenated alcohol sodium sulfate; Soil temperature-805～20 part, 1～10 part of glycerol, 1～5 part in carbamide; 1.2～5 parts in sodium chloride, 0.5～2 part of hydrophilic lanoline, 0.1～1 part of sodium carboxymethyl cellulose; 0.1～0.5 part of edetate, 0.1～0.3 part of Nipagin ester, 0.1～5 part of citric acid or sodium citrate; 0.1～0.5 part in essence, 0.1～0.5 part of pigment, all the other are distilled water;
In agitated reactor, add parts by weight and be 30～50 parts distilled water, be heated to 60～80 ℃ subsequent use, under agitation; In this system, add polyoxyethylenated alcohol sodium sulfate, soil temperature-80 in proportion successively, after the dissolving, reduce temperature fully; Under 40～60 ℃ of conditions; Add Nipagin ester, carbamide, hydrophilic lanoline successively, mix to stir, be cooled to room temperature after fully being dissolved into transparency liquid; Add glycerol in proportion successively; Sodium carboxymethyl cellulose, edetate, essence, pigment, remaining distilled water, sodium chloride fully stirred 1～6 hour, and using citric acid or sodium citrate to regulate pH value is 6～8; Fully behind the degassing froth breaking, obtain adhesive transparency liquid and be product.
2. the method for preparing of a sterilizing skin-protective hand cleanser is characterized in that, is to be processed by following raw material by weight: 5～20 parts of polyoxyethylenated alcohol sodium sulfate; Soil temperature-805～20 part, 1～10 part of glycerol, 1～5 part in carbamide; 1.2～5 parts in sodium chloride, 0.5～2 part of hydrophilic lanoline, 0.1～1 part of sodium carboxymethyl cellulose; 0.1～0.5 part of edetate, 0.1～0.3 part of Nipagin ester, 0.1～5 part of citric acid or sodium citrate; 0.1～0.5 part in essence, 0.1～0.5 part of pigment, all the other are distilled water;
Method for preparing:
(1) in agitated reactor, adding parts by weight is 30～50 parts distilled water, be heated to 60～80 ℃ subsequent use;
(2) under agitation; In (1) system, add polyoxyethylenated alcohol sodium sulfate, soil temperature-80 in proportion successively, after the dissolving, reduce temperature fully; Under 40～60 ℃ of conditions; Add Nipagin ester, carbamide, hydrophilic lanoline successively, mix to stir, be cooled to room temperature after fully being dissolved into transparency liquid;
(3) in the room temperature system; Add glycerol in proportion successively; Sodium carboxymethyl cellulose, edetate, essence, pigment, remaining distilled water, sodium chloride fully stirred 1～6 hour, and using citric acid or sodium citrate to regulate pH value is 6～8; Fully behind the degassing froth breaking, obtain adhesive transparency liquid and be product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010295204A CN101966134B (en) | 2010-09-28 | 2010-09-28 | Liquid soap with sterilizing and skin protecting functions and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010295204A CN101966134B (en) | 2010-09-28 | 2010-09-28 | Liquid soap with sterilizing and skin protecting functions and preparation method thereof |
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| Publication Number | Publication Date |
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| CN101966134A CN101966134A (en) | 2011-02-09 |
| CN101966134B true CN101966134B (en) | 2012-10-03 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105832573A (en) * | 2016-04-19 | 2016-08-10 | 南京巨鲨显示科技有限公司 | Amine antibacterial liquid soap |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102949310B (en) * | 2012-10-31 | 2014-06-11 | 江西普正制药有限公司 | Traditional Chinese medicine antibacterial hand washing solution and preparation method thereof |
| CN103599003A (en) * | 2013-11-29 | 2014-02-26 | 曾凡勇 | Novel medical hand-washing solution and preparation method thereof |
| CN115590985B (en) * | 2021-12-22 | 2024-04-12 | 上海利康消毒高科技有限公司 | Sterile medical ultrasonic coupling agent and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1112157A (en) * | 1994-05-20 | 1995-11-22 | 武汉化院精细化工技术公司 | Skin-care hand-washing lotion |
| CN1977799A (en) * | 2005-11-28 | 2007-06-13 | 李镝 | Non-pungent clean hand-washing liquid |
| CN101219095A (en) * | 2007-12-26 | 2008-07-16 | 上海制皂(集团)如皋有限公司 | Froth hand cleanser |
| CN101785749A (en) * | 2010-02-09 | 2010-07-28 | 广东名臣有限公司 | Sterilizing skin moistening liquid soap |
-
2010
- 2010-09-28 CN CN201010295204A patent/CN101966134B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1112157A (en) * | 1994-05-20 | 1995-11-22 | 武汉化院精细化工技术公司 | Skin-care hand-washing lotion |
| CN1977799A (en) * | 2005-11-28 | 2007-06-13 | 李镝 | Non-pungent clean hand-washing liquid |
| CN101219095A (en) * | 2007-12-26 | 2008-07-16 | 上海制皂(集团)如皋有限公司 | Froth hand cleanser |
| CN101785749A (en) * | 2010-02-09 | 2010-07-28 | 广东名臣有限公司 | Sterilizing skin moistening liquid soap |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105832573A (en) * | 2016-04-19 | 2016-08-10 | 南京巨鲨显示科技有限公司 | Amine antibacterial liquid soap |
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