CN101962582B - Ethyl levulinate-diesel oil mixed fuel - Google Patents

Ethyl levulinate-diesel oil mixed fuel Download PDF

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Publication number
CN101962582B
CN101962582B CN 201010531760 CN201010531760A CN101962582B CN 101962582 B CN101962582 B CN 101962582B CN 201010531760 CN201010531760 CN 201010531760 CN 201010531760 A CN201010531760 A CN 201010531760A CN 101962582 B CN101962582 B CN 101962582B
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CN
China
Prior art keywords
fuel
ethyl levulinate
diesel oil
diesel
improver
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN 201010531760
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Chinese (zh)
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CN101962582A (en
Inventor
雷廷宙
徐海燕
何晓峰
白炜
李再峰
赵宝珠
崔俊贞
吴铁良
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HENAN BIOMASS ENERGY SOURCES KEY LABORATORY
Energy Research Institute Co Ltd of Henan Academy of Sciences
Original Assignee
HENAN BIOMASS ENERGY SOURCES KEY LABORATORY
Energy Research Institute Co Ltd of Henan Academy of Sciences
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Application filed by HENAN BIOMASS ENERGY SOURCES KEY LABORATORY, Energy Research Institute Co Ltd of Henan Academy of Sciences filed Critical HENAN BIOMASS ENERGY SOURCES KEY LABORATORY
Priority to CN 201010531760 priority Critical patent/CN101962582B/en
Publication of CN101962582A publication Critical patent/CN101962582A/en
Application granted granted Critical
Publication of CN101962582B publication Critical patent/CN101962582B/en
Expired - Fee Related legal-status Critical Current
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Abstract

The invention belongs to the technical field of clean energy, and in particular relates to an ethyl levulinate-diesel oil mixed fuel. The fuel comprises the following components in percentage by volume: 10 to 30 percent of ethyl levulinate, 64.37 to 89.79 percent of commercial No.0 diesel oil, 0 to 5 percent of cosolvent, 0.2 to 0.6 percent of cetane number improver and 0.01 to 0.03 percent of flash point improver. Various indexes of the fuel meet the indexes of commercial diesel oil, and the oil consumption quantity and the oil consumption rate of the fuel are equivalent to those of the diesel oil; and the fuel has stable performance and can enable a diesel engine to work stably and reliably, the safety and the explosion resistance of the fuel can meet the safety requirement of the fuel for vehicles, and meanwhile, the fuel can achieve the effects of saving energy and reducing emission to a certain extent.

Description

A kind of ethyl levulinate diesel blended fuel
Technical field
The invention belongs to the clean energy technology field, particularly a kind of ethyl levulinate diesel blended fuel.
Background technology
Along with the traditional energy based on fossil oil is day by day exhausted, substitute energy more and more obtains people's attention.Biomass energy is to be only second to coal, oil and natural gas and the energy that occupies world energy sources total quantity consumed the 4th, and is renewable energy source.The scale operation biomass fuel helps to ensure energy security, developing agricultural economy and promotes energy-saving and emission-reduction.With biomass liquid-phase hydrolysis product levulinic acid is that the ethyl levulinate that raw material makes can partly substitute conventional diesel fuel, and can reduce pollution, for improving China's energy structure, realizes that Sustainable development has great importance.
Summary of the invention
The object of the present invention is to provide a kind of mixed clean fuel ethyl levulinate diesel blended fuel, substitute diesel oil, improve energy structure with part.
The technical solution used in the present invention is as follows:
A kind of ethyl levulinate diesel blended fuel, its volume percentage composition is as follows:
Ethyl levulinate 10%~30%, commercial 0# diesel oil 64.37%~89.79%, solubility promoter 0%~5%, cetane number improver 0.2%~0.6%, flash point improver 0.01%~0.03%.
Described solubility promoter is that carbon atom quantity is one or more the mixture in the straight chain saturated fatty alcohol of 4-8, more preferably butanols.
Preferably, the ethyl levulinate diesel blended fuel can carry out proportioning by following volume percent:
The volume percentage composition of propellant combination is as follows: ethyl levulinate 10%, commercial 0# diesel oil 89.79%, cetane number improver 0.2%, flash point improver 0.01%.
Perhaps be ethyl levulinate 20%, commercial 0# diesel oil 76.58%, butanols 3%, cetane number improver 0.4%, flash point improver 0.02%.
Perhaps be ethyl levulinate 30%, commercial 0# diesel oil 64.37%, butanols 5%, cetane number improver 0.6%, flash point improver 0.03%.
Described cetane number improver and flash point improver select the commercially available prod to get final product.
When obtaining described propellant combination, by volume ethyl levulinate, commercial 0# diesel oil, solubility promoter butanols, cetane number improver, flash point improver are mixed in same container and get final product, each composition adds order does not have particular requirement.
The present invention adds solubility promoter, cetane number improver and the flash point improver of low ratio in the propellant combination of ethyl levulinate and diesel oil to, make it can stable for extended periods of time not stratified, wherein, cetane value and flash-point all are on close level with commercial diesel oil, can make the reliable and stable work of diesel motor, oil consumption and rate of fuel consumption and diesel oil are on close level, and can be used as the alternative fuel of diesel oil.
The present invention has following advantage with respect to prior art:
1, every technical indicator of product of the present invention all reaches the index of commercial diesel oil.This product replaces diesel oil to use, and the result of use on engine can reach commercial diesel oil level, and oil consumption and rate of fuel consumption and diesel oil are on close level; And product performance of the present invention are stable, can make the reliable and stable work of diesel motor, security, and anti-bomb all can satisfy the vehicle fuel safety requirements.2, ethyl levulinate is made by the biological material hydrolysate, and its combustion heat value is higher, and extra discharge harmful can not reach the effect of energy-saving and emission-reduction to a certain extent.
Embodiment
Below with specific embodiment technical scheme of the present invention is described, but protection scope of the present invention is not limited thereto:
Used cetane number improver is the GK-T21716 cetane number improving agent that petrochemical complex additive company limited of Shandong Zibo state section produces in following examples; Flash point improver is the GT-T21773 flash-point rising agent that petrochemical complex additive company limited of Shandong Zibo state section produces.
Embodiment 1
A kind of ethyl levulinate diesel blended fuel, volume is composed as follows:
Ethyl levulinate 10%, commercial 0# diesel oil 89.79%, cetane number improver 0.2%, flash point improver 0.01%.
The performance of propellant combination sees Table 1.
Embodiment 2
A kind of ethyl levulinate diesel blended fuel, volume is composed as follows:
Ethyl levulinate 20%, commercial 0# diesel oil 76.58%, butanols 3%, cetane number improver 0.4%, flash point improver 0.02%.
The performance of propellant combination sees Table 1.
Embodiment 3
A kind of ethyl levulinate diesel blended fuel, volume is composed as follows:
Ethyl levulinate 30%, commercial 0# diesel oil 64.37%, butanols 5%, cetane number improver 0.6%, flash point improver 0.03%.
The performance of propellant combination sees Table 1.

Claims (6)

1. ethyl levulinate diesel blended fuel, its volume percentage composition is as follows:
Ethyl levulinate 10%~30%, commercial 0# diesel oil 64.37%~89.79%, solubility promoter 0%~5%, cetane number improver 0.2%~0.6%, flash point improver 0.01%~0.03%.
2. ethyl levulinate diesel blended fuel as claimed in claim 1 is characterized in that, described solubility promoter is that carbon atom quantity is one or more the mixture in the straight chain saturated fatty alcohol of 4-8.
3. ethyl levulinate diesel blended fuel as claimed in claim 2 is characterized in that, the volume percentage composition of propellant combination is as follows: ethyl levulinate 10%, commercial 0# diesel oil 89.79%, cetane number improver 0.2%, flash point improver 0.01%.
4. ethyl levulinate diesel blended fuel as claimed in claim 2 is characterized in that, the volume percentage composition of propellant combination is as follows: ethyl levulinate 20%, commercial 0# diesel oil 76.58%, solubility promoter 3%, cetane number improver 0.4%, flash point improver 0.02%.
5. ethyl levulinate diesel blended fuel as claimed in claim 2 is characterized in that, the volume percentage composition of propellant combination is as follows: ethyl levulinate 30%, commercial 0# diesel oil 64.37%, solubility promoter 5%, cetane number improver 0.6%, flash point improver 0.03%.
6. as claim 1 or 2 or 4 or 5 described ethyl levulinate diesel blended fuels, it is characterized in that solubility promoter is a butanols.
CN 201010531760 2010-11-04 2010-11-04 Ethyl levulinate-diesel oil mixed fuel Expired - Fee Related CN101962582B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 201010531760 CN101962582B (en) 2010-11-04 2010-11-04 Ethyl levulinate-diesel oil mixed fuel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 201010531760 CN101962582B (en) 2010-11-04 2010-11-04 Ethyl levulinate-diesel oil mixed fuel

Publications (2)

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CN101962582A CN101962582A (en) 2011-02-02
CN101962582B true CN101962582B (en) 2013-07-31

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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102585931B (en) * 2012-02-24 2014-08-13 河南省科学院能源研究所有限公司 Blended fuel of biomass-base liquid fuel and diesel oil and preparation method of blended fuel
CN102796573B (en) * 2012-07-24 2014-09-17 北京金骄生物质化工有限公司 Low-freezing biodiesel combined fuel and preparation method thereof
CN107841350A (en) * 2016-09-18 2018-03-27 北京特生物化工有限公司 A kind of bio-based esters micro emulsion diesel fuel and preparation method thereof
CN110117507B (en) * 2019-05-27 2020-09-18 中国科学院兰州化学物理研究所 Bio-based high-cetane-number diesel additive, preparation method thereof and clean diesel composition
CN111171883A (en) * 2020-03-11 2020-05-19 中国科学院兰州化学物理研究所 Valerate diesel oil mixed fuel
CN114806653A (en) * 2022-05-06 2022-07-29 中国科学院广州能源研究所 Biomass-based ester compound fuel and preparation method thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4308053C2 (en) * 1993-03-13 1997-05-15 Veba Oel Ag Liquid unleaded fuels
GB0111679D0 (en) * 2001-05-12 2001-07-04 Aae Tech Int Ltd Fuel composition

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Granted publication date: 20130731

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