CN101948161A - Waste water treatment method and device by mixing water and vapor - Google Patents

Waste water treatment method and device by mixing water and vapor Download PDF

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Publication number
CN101948161A
CN101948161A CN 201010266981 CN201010266981A CN101948161A CN 101948161 A CN101948161 A CN 101948161A CN 201010266981 CN201010266981 CN 201010266981 CN 201010266981 A CN201010266981 A CN 201010266981A CN 101948161 A CN101948161 A CN 101948161A
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gas
steam
water
sewage
ionization
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CN 201010266981
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金俊哲
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Abstract

The invention relates to a waste water treatment method by mixing water and vapor. The method comprises the following steps of: providing gas containing oxygen for purifying; ionizing oxygen in the gas to improve the oxidability of the gas; and ensuring that the ionized gas and sewage flow along opposite directions to sufficiently mix the gas and the sewage. The invention also provides a waste water treatment device by mixing the water and the vapor, comprising a plasma generation device, a fan and a water and vapor mixing tower, wherein the plasma generation device is used for ionizing the introduced gas into a plasma state; the fan is used for conveying the plasma-state substance formed by the plasma generation device to the water and vapor mixing tower; and the water and vapor mixing tower is used for sufficiently mixing the sewage to be treated and the ionized gas. The invention has the advantages that the sewage is subjected to oxidation treatment by adopting strong oxidants such as atomic oxygen after gas ionization, hydroxyl groups, and the like, thereby expensive treatment raw materials such as a large quantity of chemical agents or biological floras, and the like are avoided, and the purposes of saving the process cost and purifying the sewage are also achieved.

Description

Steam composite waste treatment process and device
[technical field]
The present invention relates to a kind of steam blended method of wastewater treatment and device, relate in particular to a kind of gas and sewage that will have strong oxidizing property and pass through the spray column thorough mixing to remove the method and the device of organic impurity.
[background technology]
Along with improving constantly of industrial society's degree, energy-saving and emission-reduction become the field that people pay close attention to day by day.Because the environmental pollution that trade effluent causes is one of important source of present environmental pollution.One of important step of trade effluent being carried out purifying treatment purifies the impurity in the trade effluent exactly, reduces the chemical oxygen demand (COD) of waste water.Because the impurity in the water much all can be oxidized, therefore waste water is carried out the content that oxide treatment can reduce impurity in the waste water, reach the purpose of purification.
Common effluent purification method comprises chemical purification and biological clarification etc. at present.Chemical purification method is to utilize pharmaceutical chemicals to reduce the nitrogen in the sewage and the content of phosphorus, thereby reaches the purpose of purifying waste water, and biological purification method then is to utilize special biological flora to decompose nitrogen and phosphorus in the sewage, to purify waste water.No matter be the chemistry or the method for biopurification, all need to expend a large amount of funds and constantly replenish chemical agent and biological flora, can satisfy the continuous running of sewage work.
[summary of the invention]
Technical problem to be solved by this invention is, steam blended method of wastewater treatment and device are provided, and can save the technology cost of sewage disposal under the prerequisite that guarantees wastewater treatment efficiency.
In order to address the above problem, the invention provides a kind of steam blended method of wastewater treatment, comprise the steps: to provide the purge gas that contains oxygen; With the oxygen ionization in the gas, to improve its oxidisability; Gas after the ionization is flowed along opposite direction subtend with sewage, to obtain thorough mixing.
As optional technical scheme, contain water vapor in the described gas, purpose is to improve after the ionization content of hydroxyl in the gas.
As optional technical scheme, the method that adopts plasma discharge is with ionization of gas.
The present invention further provides a kind of steam blended wastewater treatment equipment, having comprised: plasma generator, the ionization of gas that is used for feeding becomes plasma state; Blower fan, the outlet UNICOM of the inlet mouth of described blower fan and plasma generator is used to the plasma state material of carrying plasma producing apparatus to form; The steam mixing column, described steam mixing column comprises inlet mouth, air outlet, water-in and water outlet, inlet mouth is positioned at tower bottom, and link with the air outlet of blower fan, be used for the gas after the ionization is fed the steam mixing column, the air outlet is positioned at top of tower, and water-in is positioned at top of tower and water outlet is positioned at tower bottom, pending sewage flows into and flows out from water outlet from water-in, thus with ionization after the gas thorough mixing.
As optional technical scheme, further comprise filler in the described steam mixing column, can slow down the speed of passing through of gas and sewage, make both thorough mixing.
As optional technical scheme, the inlet mouth of described plasma producing apparatus further comprises humidifier.
As optional technical scheme, further comprise backflow gas circuit from steam mixing column air outlet to the plasma producing apparatus inlet mouth.
The invention has the advantages that, by strong oxidizers such as atomic oxygen behind the employing ionization of gas and hydroxyls sewage is carried out oxide treatment, avoid adopting the processing raw material of costlinesses such as a large amount of chemical agents or biological flora, both saved the technology cost, can reach the purpose of purifying waste water again.
[description of drawings]
It shown in the accompanying drawing 1 the apparatus structure synoptic diagram of the specific embodiment of the invention.
Be along the sectional view of AA direction shown in the accompanying drawing 2 in the accompanying drawing 1.
Be along the sectional view of BB direction shown in the accompanying drawing 3 in the accompanying drawing 1.
[embodiment]
Next introduce the embodiment of steam blended method of wastewater treatment of the present invention and device in conjunction with the accompanying drawings in detail.
Be the apparatus structure synoptic diagram of the specific embodiment of the invention shown in the accompanying drawing 1, comprise: plasma generator 1 has inlet mouth 11, air outlet 12 and humidifier 13; Blower fan 2 comprises inlet mouth 21 and air outlet 22; Steam mixing column 3 has inlet mouth 31, air outlet 32, water-in 33 and water outlet 34.Described device also comprises backflow gas circuit 4, and backflow gas circuit 4 is arranged on the air outlet 32 of steam mixing column 3 between plasma producing apparatus 1 inlet mouth 11.
Said apparatus is when work, and the gas that at first will purify usefulness feeds in the middle of the plasma producing apparatus 1, and the gas that purifies usefulness contains oxygen, so that can form atomic oxygen and the hydroxyl with strong oxidizing property after entering plasma producing apparatus 1.Can adopt air in the present embodiment.
Shown in the accompanying drawing 2 be in the accompanying drawing 1 along the sectional view of AA direction, showed the internal structure synoptic diagram of plasma producing apparatus 1, comprise anodal 101, negative pole 102 and be arranged on emission thorn 103 on anodal 101.The gas that feeds plasma generator 1 can partial ionization become plasma state under the effect of such plasma producing apparatus, wherein oxygen is ionized to atomic oxygen, if communicate as gas in contain water vapor, can also further form hydroxyl, two kinds of materials of above-mentioned atomic oxygen and hydroxyl all have strong oxidizing property.Certainly, though plasma body is not the complete ionization of gas to feeding, and just partial ionization, but experiment shows, because the oxidisability of atomic oxygen and hydroxyl is very strong, therefore for follow-up step of purifying waste water, partial ionization can have been satisfied the demand of sewage purification.The electricity input parameter of regulating plasma producing apparatus 1 can improve it to ionisation of gas efficient.
Humidifier 13 is optional accessories, and purposes is to improve the content of water vapor in the gas of feeding.Therefore water vapor can provide enough hydrogen atoms, can increase the content of hydroxyl behind the ionization of gas.
Gas after plasma producing apparatus 1 is handled enters blower fan 2.The inlet mouth 21 of blower fan 2 and air outlet 12 UNICOMs of plasma generator 1, inlet mouth 31 UNICOMs of air outlet 22 and steam mixing column 3, the gas delivery that contains atomic oxygen and hydroxyl that plasma producing apparatus 1 can be formed is among steam mixing column 3.Because atomic oxygen and hydroxy chemical character that gas forms after plasma treatment are active, in order to guarantee that these active substances have enough ratios can enter steam mixing column 3 rather than consume on the path that transports, so need blower fan 2 to improve gas from the velocity of flow of plasma producing apparatus 1 to steam mixing column 3.
Gas after the ionization is entered after the steam mixing column 3, will flow along opposite direction subtend, mix fully obtaining with the sewage that enters steam mixing column 3 equally.Specifically, steam mixing column 3 comprises inlet mouth 31, air outlet 32, water-in 33 and water outlet 34.Inlet mouth 31 is positioned at tower bottom, and link with the air outlet 22 of blower fan 2, be used for the gas after the ionization is fed steam mixing column 3, and the air outlet is positioned at the top of steam mixing column 3, the gas that such being provided with guaranteed to feed steam mixing column 3 is mobile from bottom to top.And the water-in 33 of steam mixing column 3 is positioned at the top of tower and water outlet 34 is positioned at tower bottom, and such being provided with guaranteed that the flow direction of sewage is to flow to the bottom from top.Pending sewage flows into and flows out from water outlet 34 from water-in 33, thus can with the gas thorough mixing after the ionization.Sewage has the atomic oxygen of strong oxidizing property and the material generation oxidizing reactions such as organic matter in hydroxyl and the sewage with after gas after the ionization mixes in the gas, can reduce the chemical oxygen demand (COD) of sewage, reaches the purpose of purifying waste water.
Accompanying drawing 3 is accompanying drawing 1 sectional views along the BB direction, has showed the internal structure of steam mixing column 3.Steam mixing column 3 can further include filler 35, the use of filler 35 can slow down the speed of passing through of gas and sewage, especially can reduce sewage speed by steam mixing column 3 under action of gravity, and sewage can also increase the surface-area of sewage attached to the surface of filler 35, thereby makes itself and the gas thorough mixing that feeds.
Backflow gas circuit 4 is optional accessories.Backflow gas circuit 4 is arranged on the air outlet 32 of steam mixing column 3 between plasma producing apparatus 1 inlet mouth 11.Because the gas that comes out from steam mixing column 3 contains a large amount of water vapors, plasma producing apparatus 1 is needed exactly and contain the gas of water vapor, and existence that therefore should backflow gas circuit 4 can improve the content that plasma producing apparatus 1 enters steam in the gas.Certainly, because the reaction in the steam mixing column 3 is to consume oxygen, therefore replenishing new gas when refluxing, to enter plasma producing apparatus 1 also be necessary.
For polluting comparatively serious sewage, said apparatus may can not be purified to it degree that meets discharging standards fully.In this case a plurality of said apparatus can also be set further, and the steam mixing column 3 in each device is cascaded, sewage is purified step by step.
The previously described preferred implementation of the present invention is in order to illustrate and to describe purpose of the present invention.Should not limit the present invention within the disclosed content, also might be by coming from the enlightenment in the above-mentioned record content and practice of the present invention being obtained adjustment of the present invention and change.Therefore, the given embodiment of the present invention is not restriction but explains technical spirit of the present invention that protection scope of the present invention is not limited by embodiment.Protection scope of the present invention should be determined by claim, is equal to replacement and also should be considered as not exceeding protection scope of the present invention of the present invention.

Claims (7)

1. a steam composite waste treatment process is characterized in that, comprises the steps:
The purge gas that contains oxygen is provided;
With the oxygen ionization in the gas, to improve its oxidisability;
Gas after the ionization is flowed along opposite direction subtend with sewage, to obtain thorough mixing.
2. steam composite waste treatment process according to claim 1 is characterized in that, contains water vapor in the described gas, and purpose is to improve after the ionization content of hydroxyl in the gas.
3. steam composite waste treatment process according to claim 1 is characterized in that, the method that adopts plasma discharge is with ionization of gas.
4. a steam composite waste treatment unit is characterized in that, comprising:
Plasma generator, the ionization of gas that is used for feeding becomes plasma state;
Blower fan, the outlet UNICOM of the inlet mouth of described blower fan and plasma generator is used to the plasma state material of carrying plasma producing apparatus to form;
The steam mixing column, described steam mixing column comprises inlet mouth, air outlet, water-in and water outlet, inlet mouth is positioned at tower bottom, and link with the air outlet of blower fan, be used for the gas after the ionization is fed the steam mixing column, the air outlet is positioned at top of tower, and water-in is positioned at top of tower and water outlet is positioned at tower bottom, pending sewage flows into and flows out from water outlet from water-in, thus with ionization after the gas thorough mixing.
5. steam blended wastewater treatment equipment according to claim 4 is characterized in that, further comprises filler in the described steam mixing column, can slow down the speed of passing through of gas and sewage, makes both thorough mixing.
6. steam blended wastewater treatment equipment according to claim 4 is characterized in that the inlet mouth of described plasma producing apparatus further comprises humidifier.
7. steam blended wastewater treatment equipment according to claim 4 is characterized in that, further comprises the backflow gas circuit from steam mixing column air outlet to the plasma producing apparatus inlet mouth.
CN 201010266981 2010-08-27 2010-08-27 Waste water treatment method and device by mixing water and vapor Pending CN101948161A (en)

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CN 201010266981 CN101948161A (en) 2010-08-27 2010-08-27 Waste water treatment method and device by mixing water and vapor

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Application Number Priority Date Filing Date Title
CN 201010266981 CN101948161A (en) 2010-08-27 2010-08-27 Waste water treatment method and device by mixing water and vapor

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102631052A (en) * 2012-03-31 2012-08-15 苏州卫鹏机电科技有限公司 Low-temperature plasma discharging treatment equipment for surface of shoe material and treatment method thereof
CN103681200A (en) * 2013-12-11 2014-03-26 苏州市奥普斯等离子体科技有限公司 Liquid material plasma treating device
CN104003590B (en) * 2014-06-19 2015-08-12 上海环境卫生工程设计院 With the device and method of low-temperature plasma coupled biological method treating refuse percolate
GB2565852A (en) * 2017-08-25 2019-02-27 Air Quality Res Limited Method and apparatus for treating a fluid
CN110092448A (en) * 2019-05-06 2019-08-06 重庆工商大学 A kind of concentric circles bipolar electrode discharge plasma O/W emulsion breaking device
CN115487534A (en) * 2022-10-10 2022-12-20 北京金山生态动力素制造有限公司 Process for the preparation of mineral solutions

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2351426Y (en) * 1997-09-29 1999-12-01 深圳市精锐实业有限公司 Plasma oxygen sterilizing water generator
WO2004103912A1 (en) * 2003-05-23 2004-12-02 Watertech Holdings Ltd. A swimming pool cleaning and sanitising system
CN101148285A (en) * 2007-09-06 2008-03-26 浙江大学 Method for processing waste water by high-voltage impulse gas-phase humidification discharge
CN101148286A (en) * 2007-09-06 2008-03-26 浙江大学 Desulfurization waste water quality recovery method and device thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2351426Y (en) * 1997-09-29 1999-12-01 深圳市精锐实业有限公司 Plasma oxygen sterilizing water generator
WO2004103912A1 (en) * 2003-05-23 2004-12-02 Watertech Holdings Ltd. A swimming pool cleaning and sanitising system
CN101148285A (en) * 2007-09-06 2008-03-26 浙江大学 Method for processing waste water by high-voltage impulse gas-phase humidification discharge
CN101148286A (en) * 2007-09-06 2008-03-26 浙江大学 Desulfurization waste water quality recovery method and device thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102631052A (en) * 2012-03-31 2012-08-15 苏州卫鹏机电科技有限公司 Low-temperature plasma discharging treatment equipment for surface of shoe material and treatment method thereof
CN103681200A (en) * 2013-12-11 2014-03-26 苏州市奥普斯等离子体科技有限公司 Liquid material plasma treating device
CN104003590B (en) * 2014-06-19 2015-08-12 上海环境卫生工程设计院 With the device and method of low-temperature plasma coupled biological method treating refuse percolate
GB2565852A (en) * 2017-08-25 2019-02-27 Air Quality Res Limited Method and apparatus for treating a fluid
GB2565852B (en) * 2017-08-25 2022-04-06 Air Quality Res Limited Dielectric barrier discharge device and method and apparatus for treating a fluid
CN110092448A (en) * 2019-05-06 2019-08-06 重庆工商大学 A kind of concentric circles bipolar electrode discharge plasma O/W emulsion breaking device
CN110092448B (en) * 2019-05-06 2021-12-17 重庆工商大学 Concentric circle double-electrode discharge plasma O/W emulsion breaking device
CN115487534A (en) * 2022-10-10 2022-12-20 北京金山生态动力素制造有限公司 Process for the preparation of mineral solutions

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Application publication date: 20110119