CN101913709A - Composite ecological intercepting padding material and preparation method - Google Patents

Composite ecological intercepting padding material and preparation method Download PDF

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Publication number
CN101913709A
CN101913709A CN2010102327397A CN201010232739A CN101913709A CN 101913709 A CN101913709 A CN 101913709A CN 2010102327397 A CN2010102327397 A CN 2010102327397A CN 201010232739 A CN201010232739 A CN 201010232739A CN 101913709 A CN101913709 A CN 101913709A
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China
Prior art keywords
padding material
nitrogen
preparation
phosphorus
aggregate
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CN2010102327397A
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CN101913709B (en
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朱亮
吴苏海
陈毓陵
董壮
赵林多
赵新磊
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Hohai University HHU
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Hohai University HHU
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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Abstract

The invention relates to a composite ecological intercepting padding material and a preparation method. The composite ecological intercepting padding material has an interception effect on nitrogen and phosphorus pollutants greatly increased due to urban storm flows and also has wave resistance and soil reinforcement effects on revetments for rivers and lakes. The padding material is prepared into a modularized revetment material with nitrogen and phosphorus absorption property and a large number of micro air spaces through the sintering method by using the nitrogen and phosphorus absorption function and the thermal stability of a special padding material. The padding material can restore a water body with a great change in load due to nitrogen and phosphorus pollution through the bio-contact degradation function and the absorption function, optimize and improve the water quality restoration function of the ecological revetment technology and solve the problem on placing and fixing the padding material in river and lake water bodies.

Description

A kind of composite ecological intercepting padding material and preparation method
Technical field
The present invention relates to a kind of ecological intercepting padding material and preparation method, relate in particular to and a kind of the nitrogen and phosphorus pollutants that increases considerably due to the urban storm runoff is had interception function, can be used as combined type ecological intercepting padding material and the preparation method that lake, river shore protection plays the wave resistance fixation simultaneously again.
Background technology
Along with the expansion and the expanding economy in city, in recent ten years, the eutrophication process of urban rivers and lakes is quickened greatly, and at present, Chinese most urban rivers and lakes water bodys have been in serious eutrophication state.The sink drainage in a lot of cities of China is the dirty interflow of a rain system, whenever rainfall, the pollutent that is stranded in the road surface can cause concentration of nitrogen and phosphorus sharply rising at short notice in the water body with rainwater inflow stream Lake Water Body, and this is an one of the main reasons that causes this urban rivers and lakes water eutrophication to take place.
The urban rivers and lakes bank is connecting water body and land, is the ecosystem and the abundantest place of species diversity, is the important transitional zone that aquatic ecosystem and TERRESTRIAL ECOSYSTEMS are carried out material, energy, message exchange.Rationally build the urban rivers and lakes shore protection to increasing species diversity, system productivity in the urban water-body, prevent erosion, increase water quality and beautifying the environment significant.Existing river course slope protection technology has natural style bank protection, hard bank protection and environmental bank protection, cuts both ways.The natural style bank protection be plant growing with well developed root system on the ramp in river course, prevent erosion, satisfy the ecotope needs, have certain natural landscape effect.Its shortcoming is a poor stability, and surperficial earth is easily by rain drop erosion.The main raw of hard bank protection mainly adopts and grouts or structure such as placed rockfill, onsite concrete, precast concrete block; it takes up an area of less, stability is high; but it is bigger for the river ecosystem negatively influencing; hydrobiont and microorganism with water purification function all are difficult to growth, and regular meeting reduces water body self-purification ability and causes water pollution.In addition, the hard bank protection can make to the domatic closing form of taking in river course that animals and plants and microorganism all are difficult to the existence procreation in the water body, thereby causes the deterioration of water ecological environment.Environmental bulkhead tech has multiple mode, in rubble aggregate species phytyl, the solid soil species phytyl of geotechnological material, vegetation type eco-concrete, cement ecospecies phytyl and geotechnological material afforestation etc., they all can build a suitable environment for the plant-growth of river course slope protection as geotechnological material aggregate species phytyl, wire netting.
Yet, no matter be nature bank protection, hard bank protection or ecological revetment, in the river Lake Water Body that typical storm runoff in the city is caused the nitrogen and phosphorus pollutants load in short-term in variation range greatly this phenomenon all lack special effective for repairing technology.Even be longer than natural style bank protection and the ecological type bank protection of safeguarding water quality, the former mainly relies on the assimilation of plant and removes the nitrogen phosphorus substance, be difficult in a short time the pollution substance of high density is reached removal effect, the latter adopts microbe carriers such as rubble base, geotextile to reduce Pollutant levels in the water body by the method for biological contact, too high or too low pollution load is lacked tolerance, and treatment effect can sharply descend when microorganism active was low in the winter time.Therefore, from current urban rivers and lakes bulkhead tech research and practice progress, be badly in need of exploitation the nitrogen and phosphorus pollutants that increases considerably due to the urban storm runoff is had interception function, can be used as the combined type ecological intercepting padding material that lake, river shore protection plays the wave resistance fixation simultaneously again.
Summary of the invention
The present invention is directed to the characteristics of getting dirty of urban rivers and lakes system and some defectives of present ecological revetment technology, propose a kind of making method of novel composite ecological intercepting padding material.It is intended to increase the processing mechanism type of filler, filler effect and pollutant removal mechanism is changed to combined type, multipath direction by single, thereby strengthen the treatment effect that water body in-situ is repaired.Simultaneously, the modularization that this kind filler is had, standardized characteristics can be used it with other sophisticated ecological revetment technology collocation, have solved the placement problem of filler when water body is repaired simultaneously.
Technical scheme of the present invention is:
A kind of composite ecological intercepting padding material and preparation method, the preparation material comprises aggregate, pore-forming material and gelling material, it is characterized in that:
The weight ratio of a, aggregate, pore-forming material and gelling material is 10: 1: 9;
B, described aggregate are yellow ground and nitrogen, phosphorus substance are had flyash, the perlite of adsorption effect, the vermiculite of 2~8mm;
C, described pore-forming material are wood chip;
D, described gelling material are for containing potter's clay, feldspar, dextrine powder, dextrin liquid, red iron oxide.
Wherein:
Flyash in the filler composition, yellow ground, vermiculite, perlitic weight ratio are 20: 65: 9: 6;
The weight ratio of potter's clay, feldspar, dextrine powder, dextrin liquid and red iron oxide is 44: 19: 13 in the gelling material composition: 13: 11.
Preparation method of the present invention mainly comprises the following steps:
A, the particle that will be crushed to 1~4mm size as the cinder of coarse aggregate are standby;
B, by above-mentioned weight ratio configuration material and add water and stir, add water and be no more than 30% of gross weight;
C, the batching of getting above-mentioned stirring and evenly mixing are put into grinding tool, use pressing hydraulic machine compression moulding;
D, the test specimen of above-mentioned compression moulding is placed retort furnace, be heated to 1000 ℃ and kept 3 hours, take out cooling afterwards.
Vermiculite, flyash, perlite are the fillers that a class has adsorption function, still are mainly used in drowned flow artificial wet land in actual engineering.Their absorption property makes them be suitable for repairing the bigger polluted-water of change of water quality, they can be simultaneously by the pollutent in biofilm system and the adsorption removal water body, and these two kinds of effects can be carried out synchronously, strengthen mutually, can not have a negative impact.On the one hand, the microorganism of filling surface growth can make filling adsorption regeneration with the pollutent that is adsorbed as the nutrition source assimilation.On the other hand, filler can be optimized the effect of microbial process as microbe carrier, and playing increases nitrobacteria, improves rate of nitrification, improves diversity, richness in the microflora, alleviates the influence of C/N comparison repairing effect.Yet in urban rivers and lakes water body in-situ recovery project, this class filler rarely has in default of effective placement fixing means makes inquiries.
Utilize filler inherent such as vermiculite, flyash absorption scrubbing characteristic, make firm block by processing treatment and be used for river Lake Water Body original position recovery project and still belong to initiative with water body scrubbing effect.
Novelty of the present invention is as follows:
1, construction process innovation: in natural water, be difficult for the fixed defective at the adsorption function filler, take the absorption property and the thermostability of this kind material are combined, avoided rainfall, current to wash away to filler by the agglomerating fixed form.
2, water body reparation theory innovation: traditional biology contact restorative procedure is combined with the adsorption function of filler, make both actings in conjunction, utilize the absorption property of particular fillers self, realized changing under the situation greatly removal phosphorus and nitrogen at pollution load.
3, shore protection modularization innovation: making method of the present invention can change finished product with mould arbitrarily, and this makes it can be easy to use with other ecological revetment technology collocation.
The present invention has following outstanding effect:
1, engineering materials is nature material and wide material sources, and is little to environmental influence;
2, to the industrial residue utilization of waste material of flyash one class, alleviate environmental stress;
3, the present invention has certain intensity, can effectively protect the two sides in lake, river, slows down water body and washes away the negative impact that brings;
4, to the removal effect of ammonia nitrogen by being obvious.
Finished product of the present invention can play the effect of repairing water body by physical and chemical adsorption function and biological contact function simultaneously.Under general condition, its space a large amount of, different size and good water-permeable not only can be tackled the macrobead pollution substance, can also provide condition for procreation, growth and the running of microflora.Load when higher when nitrogen and phosphorus pollution in the water body, it can be brought into play adsorption the Pollutant levels that increase are suddenly played interception function; After pollution load descended, the nitrogen and phosphorus pollution material of its absorption can be used as the nutrition of microflora, while self absorption regeneration.
Embodiment
Get the particle that cinder is crushed to 1~4mm size from power plant, cross the 30# sieve; Get the common building yellow ground, cross the 20# sieve; Get vermiculite and the perlite of 2~8mm.Flyash, yellow ground, vermiculite and the perlite of treated mistake were pressed 20: 65: 9: 6 mixed, range estimation mix the back as aggregate.Getting potter's clay, feldspar, dextrine powder, dextrin liquid, red iron oxide, is 44: 19: 13 by weight: 13: 11 preparation gelling material.Adding 5% water in aggregate stirs moistening, putting into gelling material then stirs once more, whether the range estimation gelling material mixing, the last pore-forming material wood chip that adds stirs behind the mixing, and above-mentioned aggregate, wood chip and gelling material are input in 10: 1: 9 by weight, get the above-mentioned material that stirs and put into mould, use pressing hydraulic machine compression moulding, test specimen with moulding places retort furnace again, is heated to 1000 ℃ and keeps 3 hours, takes out the test specimen cooling.
The use-pattern of finished product can be when making the difference of mould therefor and difference.Such as, if adopt interlock shape mould in making processes, it can be used as lake, river shore protection and is fixed on river course or the loke shore, can plant plant in the space that shore protection is reserved, and plays solid soil and falls dirty effect; If adopt rectangular die in making processes, it is vertical with the river course or place at an angle as ecological dam that it can make the dam body that interspaces in advance, and water body is passed through from dam body.

Claims (2)

1. composite ecological intercepting padding material and preparation method, the preparation material comprises aggregate, pore-forming material and gelling material, it is characterized in that:
The weight ratio of a, aggregate, pore-forming material and gelling material is 10: 1: 9;
B, described aggregate are yellow ground and nitrogen, phosphorus substance are had flyash, the vermiculite of 2~8mm, the perlite of adsorption effect that its weight ratio is: 65: 20: 9: 6;
C, described pore-forming material are wood chip;
D, described gelling material are potter's clay, feldspar, dextrine powder, dextrin liquid, red iron oxide, and its weight ratio is 44: 19: 13: 13: 11.
2. the preparation method of a kind of composite ecological intercepting padding material according to claim 1, its feature comprises the following steps:
A, the particle that will be crushed to 1~4mm size as the cinder of coarse aggregate are standby;
B, by the described weight ratio of claim 1 configuration material and add water and stir, wherein water is no more than 30% of gross weight;
C, the batching of getting above-mentioned stirring and evenly mixing are put into grinding tool, use pressing hydraulic machine compression moulding;
D, the test specimen of above-mentioned compression moulding is placed retort furnace, be heated to 1000 ℃ and kept 3 hours, take out cooling afterwards.
CN2010102327397A 2010-07-21 2010-07-21 Composite ecological intercepting padding material and preparation method Expired - Fee Related CN101913709B (en)

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Application Number Priority Date Filing Date Title
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CN101913709B CN101913709B (en) 2012-06-13

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102173506A (en) * 2011-03-21 2011-09-07 尹军 Bioactive compound filling material
CN102583763A (en) * 2012-03-12 2012-07-18 同济大学 Modular structure of small-scale artificial wetland and application technology
CN106348507A (en) * 2016-11-08 2017-01-25 河南城建学院 Method for treating black and odorous water in urban river and iron powder containing wall or manganese sand containing wall structure thereof
CN114314729A (en) * 2021-11-17 2022-04-12 安吉国千环境科技有限公司 Efficient denitrification composite material for water environment treatment

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1105652A (en) * 1994-01-20 1995-07-26 醴陵市工艺赛釉装饰材料厂 Light hollow block
JPH11285691A (en) * 1998-04-02 1999-10-19 Eiwa Chosa Sekkei Kk Waste water treating device
JP2005162984A (en) * 2003-12-05 2005-06-23 Kyokado Eng Co Ltd Gel-forming composition and method for using the same
CN101672090A (en) * 2009-08-07 2010-03-17 长沙威特消防新材料科技有限公司 Light fireproofing heat preservation partition board and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1105652A (en) * 1994-01-20 1995-07-26 醴陵市工艺赛釉装饰材料厂 Light hollow block
JPH11285691A (en) * 1998-04-02 1999-10-19 Eiwa Chosa Sekkei Kk Waste water treating device
JP2005162984A (en) * 2003-12-05 2005-06-23 Kyokado Eng Co Ltd Gel-forming composition and method for using the same
CN101672090A (en) * 2009-08-07 2010-03-17 长沙威特消防新材料科技有限公司 Light fireproofing heat preservation partition board and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102173506A (en) * 2011-03-21 2011-09-07 尹军 Bioactive compound filling material
CN102173506B (en) * 2011-03-21 2013-01-23 尹军 Bioactive compound filling material
CN102583763A (en) * 2012-03-12 2012-07-18 同济大学 Modular structure of small-scale artificial wetland and application technology
CN102583763B (en) * 2012-03-12 2013-09-04 同济大学 Modular structure of small-scale artificial wetland and application technology
CN106348507A (en) * 2016-11-08 2017-01-25 河南城建学院 Method for treating black and odorous water in urban river and iron powder containing wall or manganese sand containing wall structure thereof
CN114314729A (en) * 2021-11-17 2022-04-12 安吉国千环境科技有限公司 Efficient denitrification composite material for water environment treatment

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