CN101913035B - High-tenacity gas shielded welding wire for welding low-temperature steel and using method thereof - Google Patents
High-tenacity gas shielded welding wire for welding low-temperature steel and using method thereof Download PDFInfo
- Publication number
- CN101913035B CN101913035B CN2010102628341A CN201010262834A CN101913035B CN 101913035 B CN101913035 B CN 101913035B CN 2010102628341 A CN2010102628341 A CN 2010102628341A CN 201010262834 A CN201010262834 A CN 201010262834A CN 101913035 B CN101913035 B CN 101913035B
- Authority
- CN
- China
- Prior art keywords
- welding
- welding wire
- percent
- low
- gas shielded
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000003466 welding Methods 0.000 title claims abstract description 67
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 16
- 239000010959 steel Substances 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims description 7
- 239000000126 substance Substances 0.000 claims abstract description 15
- 239000012535 impurity Substances 0.000 claims abstract description 10
- 229910052786 argon Inorganic materials 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims description 12
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 5
- 239000007789 gas Substances 0.000 abstract description 19
- 229910052751 metal Inorganic materials 0.000 abstract description 10
- 239000002184 metal Substances 0.000 abstract description 10
- XKRFYHLGVUSROY-UHFFFAOYSA-N argon Substances [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 abstract description 7
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 6
- 229910052717 sulfur Inorganic materials 0.000 abstract description 6
- 229910052760 oxygen Inorganic materials 0.000 abstract description 5
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 4
- 229910052719 titanium Inorganic materials 0.000 abstract description 4
- 229910052726 zirconium Inorganic materials 0.000 abstract description 4
- 229910052748 manganese Inorganic materials 0.000 abstract description 3
- 229910052759 nickel Inorganic materials 0.000 abstract description 3
- 229910052799 carbon Inorganic materials 0.000 abstract description 2
- 229910052750 molybdenum Inorganic materials 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 3
- 229910000859 α-Fe Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000007771 core particle Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004021 metal welding Methods 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- ZVWKZXLXHLZXLS-UHFFFAOYSA-N zirconium nitride Chemical compound [Zr]#N ZVWKZXLXHLZXLS-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Arc Welding In General (AREA)
- Nonmetallic Welding Materials (AREA)
Abstract
The invention provides a high-tenacity gas shielded welding wire for welding low-temperature steel, which is suitable for welding the low-temperature steel subjected to service in the environment of over minus 60 DEG C. The gas shielded welding wire comprises the following chemical components in percentage by mass: 0.04 to 0.10 percent of C, 0.20 to 0.60 percent of Si, 1.20 to 1.60 percent of Mn,1.5 to 2.0 percent of Ni, 0.10 to 0.30 percent of Mo, 0.02 to 0.10 percent of Ti, 0.02 to 0.08 percent of Zr, less than or equal to 0.010 percent of S, less than or equal to 0.010 percent of P, less than or equal to 0.0025 percent of O, less than or equal to 0.0070 percent of N, and the balance of Fe and inevitable impurities. The welding wire welds by adopting Ar + 20%CO2 full-argon gas shielding so a weld metal has high low-temperature tenacity in a welding state and under a heat treatment condition after welding.
Description
Technical field
The invention belongs to field of welding material, it is higher to be specially a kind of Ni content, the high-ductility gas shielded welding wire and the method for using thereof of Ti, Zr microalloying.
Background technology
Along with Welding Structure under low temperature environment, be on active service and use increasingly extensive, all need under low temperature environment, use like low-temperature pressure container, gas transmission line, petrochemical equipment, freezing equipment, food industry and liquid gas storage facilities etc.Therefore, the ability that requires this type of steel to have enough low-temperature flexibilities and high anti-low temperature brittleness is an overriding concern.This will be to the low-temperature flexibility of welding point, and then welding material and welding procedure are had higher requirement.Yet it is few in existing technology, can to satisfy the gas protecting welding wire that on low temperature environment military service equipment more than-60 ℃, uses.
The at present disclosed solid core welding wire that is used for the low-temperature steel welding mainly contains Chinese invention patent has two.A kind of welding wire is owing to S, P content are higher, and ni content is lower, can not satisfy the low-temperature flexibility requirement of weld metal under-60 ℃ of environment; Another kind of welding wire belongs to submerged-arc welding wire, needs the corresponding solder flux of coupling could satisfy the low-temperature flexibility requirement of weld seam, so can not be as the welding material of gas shielded arc welding.
Summary of the invention
The gas protecting welding wire and the method for using thereof that the object of the present invention is to provide a kind of low-temperature steel that is suitable for being on active service to weld at environment more than-60 ℃; C, S, P, O content have been controlled in the welding wire strictness; Add Ti, the Zr element of an amount of Ni element and trace; And adopt argon-rich gas shielded welding, make deposited metal have the ability of good low-temperature flexibility and anti-low temperature brittleness.
For realizing above-mentioned purpose, the present invention adopts following technical proposals:
A kind of high-tenacity gas shielded welding wire for welding low-temperature steel, described welding wire comprise that the mass percent (%) of following chemical composition and each chemical composition is: C:0.04～0.10, Si:0.20～0.60, Mn:1.20～1.60; Ni:1.5～2.0, Mo:0.10～0.30, Ti:0.02～0.10; Zr:0.02～0.08, S :≤0.010, P :≤0.010; O :≤0.0025, N :≤0.0070, surplus is Fe and unavoidable impurities.
Above-mentioned high-tenacity gas shielded welding wire for welding low-temperature steel, the mass percent of its chemical composition (%) is: C:0.052, Si:0.45, Mn:1.53; Ni:1.56, Mo:0.18, Ti:0.047; Zr:0.032, S:0.003, P:0.008; O:0.0018, N:0.0048, surplus is Fe and unavoidable impurities.
Above-mentioned high-tenacity gas shielded welding wire for welding low-temperature steel, the mass percent of its chemical composition (%) is: C:0.070, Si:0.46, Mn:1.48; Ni:1.79, Mo:0.24, Ti:0.056; Zr:0.042, S:0.004, P:0.007; O:0.0021, N:0.0053, surplus is Fe and unavoidable impurities.
Above-mentioned high-tenacity gas shielded welding wire for welding low-temperature steel, C mass percent (%) content is 0.04～0.10 in the welding wire, mass percent (%) scope of adding Ni and Mo element is Ni1.5～2.0; The Ti of trace, mass percent (%) scope Ti:0.02～0.10 of Zr element are added, Zr:0.02～0.08 in Mo:0.10～0.30; And each mass percent (%) S≤0.010; P≤0.010, O≤0.0025, N≤0.0070.
A kind of method for using of above-mentioned welding wire, adopting volume ratio during this welding wire welding is 80%Ar+20%CO
2Mixed gas protected.
Reduce the content of impurity elements such as C content and strict control S, P, O, N in the welding wire of the present invention, help reducing the ductile-brittle transition temperature of weld metal, improve the low-temperature flexibility of weld seam;
Add an amount of Mn, Si element, good deoxidation can be arranged, favourable to improving toughness, the effect that while Mn takes off S in addition;
Add the Ni element, solid solution can significantly improve the low-temperature flexibility of weld seam in ferrite; Add a spot of Mo and can improve the temper brittleness of weld metal;
Add further refinement seam organization of micro-Ti, Zr element, improve the low-temperature flexibility of weld metal.
TiO and ZrO that Ti, Zr and O form have promoted the formation of weld seam acicular ferrite structure, and Zr also can generate zirconium nitride with N chemical combination simultaneously, reduces the nomadic nitrogen in the weld seam, improves the toughness of weld seam.
Welding wire of the present invention compared with prior art has following characteristics:
1. welding wire of the present invention is low owing to C content, and has added an amount of Mn, Ni element, has reduced the ductile-brittle transition temperature of weld seam.
2. welding wire of the present invention forms oxide forming core particle through adding Ti, the Zr element of trace with O, impels the formation of weld seam acicular ferrite, has further improved the toughness of weld metal.
3. welding wire of the present invention is controlled impurity elements such as S, P, O, N owing to strict, and has good cracking resistance and low-temperature flexibility
4. welding wire of the present invention adopts 80%Ar+20%CO
2Mixed gas protected, can be welded on the low-temperature steel that environment is on active service more than-60 ℃.
The specific embodiment
Below in conjunction with test data and embodiment the present invention is described further.
The chemical composition scope of welding wire and the used mass percent of following examples according to the present invention; Adopt many stoves of vacuum induction furnace smelting welding wire steel; Through forge, rolling, hot candied, copper facing and twine operation such as axle; Be processed into the finished product welding wire of diameter 1.2mm, the chemical composition of each stove welding wire is as shown in table 1.
Each stove welding wire all adopts volume 80%Ar+20%CO
2Argon-rich gas shielded, same parts to be carried out same people weld equally, the identical time used identical device under the same conditions it to be carried out the same mechanical performance test after welding was accomplished, and the mechanical performance of gained deposited metal is as shown in table 2.
The chemical composition of welding wire in table 1 embodiment and each example
(mass percent %, surplus is Fe and unavoidable impurities in the listed chemical analysis)
The mechanical performance of each embodiment welding wire deposited metal of table 2
This shows, S, P content height among the present invention, and C content has been controlled in strictness; Add Ti, the Zr element of an amount of Ni element and trace, and S≤0.010, P≤0.010; O≤0.0025, N≤0.0070 can be satisfied the low-temperature flexibility requirement of weld metal under-60 ℃ of environment fully.
At 80%Ar+20%CO
2The argon-rich gas shielded welding can be found out by table 2, adopts the welding wire of this chemical composition, and good mechanical property guarantees that metal welding seam has excellent low-temperature flexibility.
Claims (4)
1. a high-tenacity gas shielded welding wire for welding low-temperature steel is characterized in that, described welding wire comprises that the mass percent (%) of following chemical composition and each chemical composition is: C:0.04～0.10, Si:0.20～0.60; Mn:1.20～1.60, Ni:1.5～2.0, Mo:0.10～0.30, Ti:0.02～0.10; Zr:0.02～0.08, S :≤0.010, P :≤0.010; O :≤0.0025, N :≤0.0070, surplus is Fe and unavoidable impurities.
2. high-tenacity gas shielded welding wire for welding low-temperature steel according to claim 1 is characterized in that, the mass percent of its chemical composition (%) is: C:0.052, Si:0.45; Mn:1.53, Ni:1.56, Mo:0.18, Ti:0.047; Zr:0.032, S:0.003, P:0.008; O:0.0018, N:0.0048, surplus is Fe and unavoidable impurities.
3. high-tenacity gas shielded welding wire for welding low-temperature steel according to claim 1 is characterized in that, the mass percent of its chemical composition (%) is: C:0.070, Si:0.46; Mn:1.48, Ni:1.79, Mo:0.24, Ti:0.056; Zr:0.042, S:0.004, P:0.007; O:0.0021, N:0.0053, surplus is Fe and unavoidable impurities.
4. the method for using of any said welding wire of claim 1 to 3 is characterized in that, adopting volume ratio during this welding wire welding is 80%Ar+20%CO
2Mixed gas protected.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102628341A CN101913035B (en) | 2010-08-23 | 2010-08-23 | High-tenacity gas shielded welding wire for welding low-temperature steel and using method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102628341A CN101913035B (en) | 2010-08-23 | 2010-08-23 | High-tenacity gas shielded welding wire for welding low-temperature steel and using method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101913035A CN101913035A (en) | 2010-12-15 |
| CN101913035B true CN101913035B (en) | 2012-08-15 |
Family
ID=43320753
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010102628341A Active CN101913035B (en) | 2010-08-23 | 2010-08-23 | High-tenacity gas shielded welding wire for welding low-temperature steel and using method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101913035B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102049597B (en) * | 2011-01-07 | 2012-07-25 | 南京钢铁股份有限公司 | Argon-enriched mixed gas protection welding method for high-strength abrasion-resistant steel |
| JP5792050B2 (en) * | 2011-01-31 | 2015-10-07 | 株式会社神戸製鋼所 | Submerged arc welding method for low temperature steel |
| CN103111772A (en) * | 2013-02-25 | 2013-05-22 | 江苏省沙钢钢铁研究院有限公司 | Weather-resistance steel gas-protection welding wire with excellent toughness under low temperature |
| CN103464930B (en) * | 2013-09-18 | 2016-05-18 | 海宁瑞奥金属科技有限公司 | Welding wire and solder flux and the application thereof for submerged arc welding of a kind of 9Ni low-temperature steel |
| CN111571061A (en) * | 2020-05-26 | 2020-08-25 | 哈尔滨焊接研究院有限公司 | Gas shielded welding wire |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1118295A (en) * | 1995-07-21 | 1996-03-13 | 冶金工业部钢铁研究总院 | Gas shielded welding wire |
| CN1343544A (en) * | 2000-09-20 | 2002-04-10 | 中国科学院金属研究所 | High-strength high-toughness weld wire for hidden arc welding of pressure container |
| CN1533315A (en) * | 2002-01-31 | 2004-09-29 | ������������ʽ���� | Steel wire for carbon dioxide shielded arc welding and welding process asing the same |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GC0000233A (en) * | 2000-08-07 | 2006-03-29 | Exxonmobil Upstream Res Co | Weld metals with superior low temperature toughness for joining high strength, low alloy steels |
| JP4811166B2 (en) * | 2006-07-24 | 2011-11-09 | Ｊｆｅスチール株式会社 | Manufacturing method of super high strength welded steel pipe exceeding tensile strength 800MPa |
-
2010
- 2010-08-23 CN CN2010102628341A patent/CN101913035B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1118295A (en) * | 1995-07-21 | 1996-03-13 | 冶金工业部钢铁研究总院 | Gas shielded welding wire |
| CN1343544A (en) * | 2000-09-20 | 2002-04-10 | 中国科学院金属研究所 | High-strength high-toughness weld wire for hidden arc welding of pressure container |
| CN1533315A (en) * | 2002-01-31 | 2004-09-29 | ������������ʽ���� | Steel wire for carbon dioxide shielded arc welding and welding process asing the same |
Non-Patent Citations (1)
| Title |
|---|
| JP特开2008-23569A 2008.02.07 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101913035A (en) | 2010-12-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100560273C (en) | High-strength high-tenacity gas shielded welding wire | |
| CN101913035B (en) | High-tenacity gas shielded welding wire for welding low-temperature steel and using method thereof | |
| CN103056549B (en) | Alkaline CO2 gas protection dilute alloy heat resistant steel flux-cored wire | |
| EP3476522A1 (en) | Ultra-low silicon wire for welding having excellent porosity resistance and electrodeposition coating properties, and deposited metal obtained therefrom | |
| CN101987403B (en) | 900MPa-level high-performance gas shielded welding wire | |
| CN101844281A (en) | Stainless steel welding material | |
| CN105026100B (en) | Welding metal and the welding structural body for possessing it | |
| CN103391829B (en) | There is provided excellent low temperature toughness and the medicated core arc welding wire of weldability for welding point and use its welding point | |
| CN107900556A (en) | A kind of austenitic stainless steel self-protection flux-cored wire | |
| CN107877031A (en) | A kind of lead-free low-temperature solder and preparation method thereof | |
| KR101688310B1 (en) | Solid wire for gas metal arc welding | |
| CN105880871A (en) | Gas-shielded high-toughness solid welding wire and use method and application thereof | |
| CN102019517A (en) | Novel stainless steel submerged-arc welding wire for improving tensile strength after heat treatment | |
| CN103056550B (en) | A kind of welding wire for gas shielded welding of yield strength 900MPa rank | |
| CN102581512B (en) | A kind of point defect control method for nickel-based weld joint | |
| JP5457859B2 (en) | Weld metal with excellent low temperature toughness and drop characteristics | |
| CN100469512C (en) | Copper phosphorus brazing alloy containing ni-sn element | |
| CN103084753B (en) | A kind of ferronickel Precise Alloy welding wire | |
| CN106271205B (en) | A kind of alloy welding wire | |
| CN1192851C (en) | Low-alloy high-strength high-toughness electric welding rod | |
| CN105252170A (en) | Stainless steel submerged-arc welding strip with improved room temperature tensile strength | |
| CN107614189A (en) | Welding metal and welding structural body | |
| CN1257039C (en) | High-strength welding electrode | |
| CN1569386A (en) | High strength welding rod with excellent low-temperature toughness | |
| CN104745943B (en) | A kind of heating resisting metal of molten heap and its submerged arc deposition preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee | ||
| CP01 | Change in the name or title of a patent holder |
Address after: Shandong 271612 Shandong province Feicheng Shiheng town suolide welding materials Co. Ltd. Patentee after: SHANDONG SOLID SOLDER CO.,LTD. Address before: Shandong 271612 Shandong province Feicheng Shiheng town suolide welding materials Co. Ltd. Patentee before: Shandong Solid Solder Co.,Ltd. |
|
| C56 | Change in the name or address of the patentee | ||
| CP02 | Change in the address of a patent holder |
Address after: Shandong 271612 Shandong province Feicheng Shiheng town suolide welding materials Limited by Share Ltd Patentee after: SHANDONG SOLID SOLDER CO.,LTD. Address before: Shandong 271612 Shandong province Feicheng Shiheng town suolide welding materials Co. Ltd. Patentee before: SHANDONG SOLID SOLDER CO.,LTD. |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: High-tenacity gas shielded welding wire for welding low-temperature steel and using method thereof Effective date of registration: 20190826 Granted publication date: 20120815 Pledgee: Tai'an financing Company limited by guarantee Pledgor: SHANDONG SOLID SOLDER CO.,LTD. Registration number: Y2019370000018 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20200409 Granted publication date: 20120815 Pledgee: Tai'an financing Company limited by guarantee Pledgor: SHANDONG SOLID SOLDER Co.,Ltd. Registration number: Y2019370000018 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: High-tenacity gas shielded welding wire for welding low-temperature steel and using method thereof Effective date of registration: 20200428 Granted publication date: 20120815 Pledgee: Tai'an financing Company limited by guarantee Pledgor: SHANDONG SOLID SOLDER Co.,Ltd. Registration number: Y2020370000062 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20200817 Granted publication date: 20120815 Pledgee: Tai'an financing Company limited by guarantee Pledgor: SHANDONG SOLID SOLDER Co.,Ltd. Registration number: Y2020370000062 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A high toughness gas shielded wire for welding low temperature steel and its application method Effective date of registration: 20200907 Granted publication date: 20120815 Pledgee: Tai'an financing Company limited by guarantee Pledgor: SHANDONG SOLID SOLDER Co.,Ltd. Registration number: Y2020980005757 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20231116 Granted publication date: 20120815 Pledgee: Tai'an financing Company limited by guarantee Pledgor: SHANDONG SOLID SOLDER CO.,LTD. Registration number: Y2020980005757 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A high toughness gas shielded welding wire for low-temperature steel welding and its usage method Effective date of registration: 20231213 Granted publication date: 20120815 Pledgee: Tai'an financing Company limited by guarantee Pledgor: SHANDONG SOLID SOLDER CO.,LTD. Registration number: Y2023980071277 |