CN101906648B - Zinc-galvanizing once or twice electroplating method for preparing nickel-plating aluminium pole ears - Google Patents
Zinc-galvanizing once or twice electroplating method for preparing nickel-plating aluminium pole ears Download PDFInfo
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- CN101906648B CN101906648B CN2010102415843A CN201010241584A CN101906648B CN 101906648 B CN101906648 B CN 101906648B CN 2010102415843 A CN2010102415843 A CN 2010102415843A CN 201010241584 A CN201010241584 A CN 201010241584A CN 101906648 B CN101906648 B CN 101906648B
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Abstract
The invention relates to a zinc-galvanizing once or twice electroplating method for preparing nickel-plating aluminium pole ears, which is characterized in that zinc-galvanizing once or twice electroplating step is firstly adopted to prepare a large nickel-plating aluminium sheet, and then the large nickel-plating aluminium sheet is cut into the nickel-plating aluminium pole ears. Current utilized in the two electroplating steps is one or a current waveform combined by two of asymmetrical square wave, or asymmetrical sine wave, or asymmetrical triangular wave, or pulse wave. When the large nickel-plating aluminium sheet is cut into the nickel-plating aluminium pole ears, the area of the large nickel-plating aluminium sheet is three times to 10000 times that of the nickel-plating aluminium pole ear, and the width of the nickel-plating aluminium pole ear is any width ranging from 1 millimetre to 200 millimetres. The nickel-plating aluminium pole ears are utilized as fluid of a battery anode of a lithium ion battery and have the obvious advantages of safety, reliability, and the like.
Description
Technical field
The invention belongs to technical field of battery manufacture, relate to the preparation method of the nickel-plated aluminum lug of the lug of a kind of lithium cell and lithium ion battery, particularly polymer Li-ion battery, flexible packing lithium ion battery and the use of duricrust lithium ion battery.
Background technology
Aluminium and duraluminum have that density is little, ductility and good toughness, be easy to premium properties such as processing, extensively as the lug of lithium cell and lithium ion battery, particularly as the lug of polymer Li-ion battery, flexible packing lithium ion battery and duricrust lithium ion battery.Yet, the own corrosion-vulnerable of aluminium and duraluminum, big, the welding difficulty of not wear-resisting, contact resistance.And the nickel metallic surface can generate passive film as thin as a wafer rapidly, than aluminium pole ears better opposing corrosive power is arranged.Therefore, adopt modes such as riveted joint, ultrasonic spot welding or LBW more, on the aluminium pole ears that battery uses, connect nickel lug (promptly changeing nickel), the other end with the nickel lug is welded on the IC circuit card again.Like this, anode pole piece exists between the IC circuit card " aluminium-aluminium ", " aluminium-nickel ", " nickel-copper " several tie points (or solder joint).Because this tie point (or solder joint) belongs to a connection; The area of tie point (or solder joint) is little; Exist to connect that (or welding) is not firm, virtual connections (or rosin joint), tie point (or solder joint) contact resistance are big, tie point (or solder joint) is prone to problems such as oxidized when depositing, there are problems such as batch instability in the battery of preparation.When discharging, particularly during heavy-current discharge, possibly there are problems such as resistance is excessive, heating is excessive in tie point (or solder joint), the battery ability of externally doing work is obviously weakened, the insecurity that also causes battery to use.In when charging, possibly cause potential safety hazards such as heating that charging difficulty and charging cause, burning because of the sealing-off of tie point (or solder joint) and welding resistance are excessive.In addition, change the step that has increased cell preparation in the nickel process, increase battery cost.
In order to overcome above deficiency, the present invention provides the method for the nickel-plated aluminum lug of cutting on the large stretch of nickel plating aluminium flake of preparation.This nickel-plated aluminum lug can be extensively as the lug of lithium cell and lithium ion battery, particularly as the lug of polymer Li-ion battery, flexible packing lithium ion battery and duricrust lithium ion battery.During as the lug of lithium cell and lithium ion battery, anode pole piece has only between the IC circuit card with nickel-plated aluminum lug of the present invention " aluminium-aluminium ", " nickel-copper " two tie points.Point between original " aluminium-nickel " is connected face connection or the body connection of changing into " aluminium-nickel plating alloy ", obviously reduced contact resistance, improved the wearing quality of connecting zone, improved the consistence of different batches battery.The charge-discharge performance of battery, particularly high rate during charging-discharging have been improved.
Utility model patent ZL2008202125092 relates to a kind of lithium cell aluminium pole ears, comprises banded aluminum strip, at an end of aluminum strip chemical Ni-plating layer is arranged.But, this patent does not relate to the concrete preparation method of nickel-plated aluminum lug and complete structure formation.Though existing many papers and patent relate to the method for nickel plating on the aluminium; The method that relates to a kind of nickel plating on siliceous aluminum steel, sheet, rod like patent ZL 018091091; Patent relates to a kind of method of nickel plating on printed substrate; Patent ZL981149332 relate to a kind of on steel substrate the method for electroplating of low-stress nickel, patent CN101245480 relates to a kind of method at carbon, iron, copper electroplating nickel on surface.But, these patents all do not relate to a kind of method that is suitable as the nickel plating of battery aluminium pole ears.Since the nickel-plated aluminum lug that is used for lithium (ion) battery to the requirement of nickeling layer and common nickel plating aluminium flake to coating require different; Wherein, What want high spot review is factors such as contact resistance, resistance to bend(ing) ability, heat dispersion between nickeling layer and the aluminium flake in the nickel-plated aluminum lug, does not need to be concerned about for the luminance brightness of nickel plating aluminium flake.
Summary of the invention
The present invention prepares large stretch of nickel plating aluminium flake earlier, more large stretch of nickel plating aluminium flake is cut to nickel-plated aluminum lug.Preparing large stretch of nickel plating aluminium flake forms by soaking zinc-second time electroplating step:
The prescription of zinc dipping solution wherein, (in 1000ml) is following: ZnSO
480g~150g, FeCl
36H
2O 0.5g~5g, NiSO
46H
2O 30g~60g, Na
3C
6H
5O
72H
2O 10g~30g, NaKC
4H
4O
64H
2O 120g~240g, NaOH 100g~240g, NaNO
30.5g~10g.
The solution formula (in 1000ml) of the nickel plating first time of second time electroplating is as follows: NiSO
46H
2O 200g~400g, NiCl
26H
2O 20g~100g, H
3BO
320g~50g, sodium lauryl sulphate 0.01g~12g, elementary brightening agent 0.1g~5g, second-class brightener 0.05g~2g, 45 ℃~75 ℃ of bath temperatures, pH 3.2~5.2.
Described elementary brightening agent is asccharin, benzene sulfinic acid sodium salt, para toluene sulfonamide or unsaturated fatty acid derivative; Described second-class brightener is butynediol, propiolic alcohol or tonka bean camphor, or butynediol and oxirane reaction product, or the reaction product of butynediol and epoxy chloropropane.
The solution formula (in 1000ml) of the nickel plating second time of second time electroplating is as follows: NiSO
46H
2O 240g~300g, NiCl
26H
2O 2g~20g, H
3BO
335g~55g, MgSO
47H
2O 30g~50g, tensio-active agent 0.01g~12g, 50 ℃~70 ℃ of bath temperatures, plating bath pH 3.1~5.5.
Described tensio-active agent is meant sodium lauryl sulphate, X 2073 or TX10, in prescription, accounts between 0.1g~12g; Described tensio-active agent can also be Triple Pressed Stearic Acid, trimethyl-glycine, glycerin fatty acid ester or polysorbate, in prescription, accounts between 0.01g/L~2.0g/L.
The electric current of second time electroplating is one of asymmetrical square wave, asymmetric sine wave, asymmetric CW, asymmetric choppy sea or pulse wave, or a kind of current waveform of being combined into of above-mentioned two kinds of current waveforms.
The electroplating current frequency is 0.1Hz~10000Hz, and dutycycle is 1/100~10000/100, and current density is 0.01A/dm
2~2.5A/dm
2, electroplating time is 0.1 second~35 minutes.
When the large stretch of nickel plating aluminium flake for preparing was cut to nickel-plated aluminum lug, the area of large stretch of nickel plating aluminium flake was 3 times to 10000 times of nickel-plated aluminum lug, and the width of nickel-plated aluminum lug is any width between 1 millimeter to 200 millimeters.Here specify the size of nickel-plated aluminum lug to satisfy following relation: length>width>thickness.
Embodiment
Below in conjunction with embodiment the present invention is further specified.Embodiment only is to further the replenishing and explanation of patent of the present invention, rather than to the restriction of patent of the present invention.
Embodiment 1
Present embodiment is the large stretch of nickel plating aluminium flake of preparation earlier, more large stretch of nickel plating aluminium flake is cut to nickel-plated aluminum lug.Preparing large stretch of nickel plating aluminium flake forms by soaking zinc-second time electroplating step:
Wherein, the prescription of zinc dipping solution (in 1000ml) as follows: ZnSO
480g/L, FeCl
36H
2O 0.5g/L, NiSO
46H
2O30g/L, Na
3C
6H
5O
72H
2O 10g/L, NaKC
4H
4O
64H
2O 120g/L, NaOH 100g/L, NaNO
30.5g/L.
The solution formula (in 1000ml) of the nickel plating first time of second time electroplating is as follows: NiSO
46H
2O 200g/L, NiCl
26H
2O20g/L, H
3BO
320g/L, sodium lauryl sulphate 0.01g/L, benzene sulfinic acid sodium salt 0.1g/L, tonka bean camphor 0.05g/L, 45 ℃ of bath temperatures, pH 3.2.
Galvanized electric current is an asymmetrical square wave for the first time, and power frequency is 0.1Hz, and dutycycle is 1/100, and current density is 0.01A/dm
2, electroplating time is 0.1 second.
The solution formula (in 1000ml) of the nickel plating second time of second time electroplating is as follows: NiSO
46H
2O 240g/L, NiCl
26H
2O2g/L, H
3BO
335g/L, MgSO
47H
2O 30g/L, sodium lauryl sulphate 0.1g/L, 50 ℃ of bath temperatures, plating bath pH 3.1.
The electric current of nickel plating for the second time is an asymmetrical square wave, and power frequency is 0.5Hz, and dutycycle is 1/100, and current density is 0.01A/dm
2, electroplating time is 10 seconds.
When the large stretch of nickel plating aluminium flake for preparing was cut to nickel-plated aluminum lug, the area of large stretch of nickel plating aluminium flake was 3 times of nickel-plated aluminum lug, and the width of nickel-plated aluminum lug is 1 millimeter.
Embodiment 2
Present embodiment is the large stretch of nickel plating aluminium flake of preparation earlier, more large stretch of nickel plating aluminium flake is cut to nickel-plated aluminum lug.Preparing large stretch of nickel plating aluminium flake forms by soaking zinc-second time electroplating step:
Wherein, the prescription of zinc dipping solution (in 1000ml) as follows: ZnSO
480g/L, FeCl
36H
2O 0.5g/L, NiSO
46H
2O30g/L, Na
3C
6H
5O
72H
2O 10g/L, NaKC
4H
4O
64H
2O 120g/L, NaOH 100g/L, NaNO
30.5g/L.
The solution formula of the twice galvanized nickel plating first time (in 1000ml) is as follows: NiSO
46H
2O 400g/L, NiCl
26H
2O100g/L, H
3BO
350g/L, sodium lauryl sulphate 12g/L, para toluene sulfonamide 5/L, propiolic alcohol 2g/L, 75 ℃ of bath temperatures, pH 5.2.
The electric current of nickel plating for the first time is asymmetric sine wave, and power frequency is 0.1Hz, and dutycycle is 1/100, and current density is 0.01A/dm
2, electroplating time is 0.1 second.
The solution formula (in 1000ml) of the nickel plating second time of second time electroplating is as follows: NiSO
46H
2O 300g/L, NiCl
26H
2O20g/L, H
3BO
355g/L, MgSO
47H
2O 50g/L, X 2073 12g/L, 70 ℃ of bath temperatures, plating bath pH 5.5.
Galvanized electric current is an asymmetrical square wave for the second time, and power frequency is 10000Hz, and dutycycle is 10000/100, and current density is 2.5A/dm
2, electroplating time is 35 minutes.
When the large stretch of nickel plating aluminium flake for preparing was cut to nickel-plated aluminum lug, the area of large stretch of nickel plating aluminium flake was 10000 times of nickel-plated aluminum lug, and the width of nickel-plated aluminum lug is 1 millimeter.
Embodiment 3
Present embodiment is the large stretch of nickel plating aluminium flake of preparation earlier, more large stretch of nickel plating aluminium flake is cut to nickel-plated aluminum lug.Preparing large stretch of nickel plating aluminium flake forms by soaking zinc-second time electroplating step:
Wherein, the prescription of zinc dipping solution (in 1000ml) as follows: ZnSO
480g/L, FeCl
36H
2O 0.5g/L, NiSO
46H
2O30g/L, Na
3C
6H
5O
72H
2O 10g/L, NaKC
4H
4O
64H
2O 120g/L, NaOH 100g/L, NaNO
30.5g/L.
The solution formula (in 1000ml) of the nickel plating first time of second time electroplating is as follows: NiSO
46H
2O 400g/L, NiCl
26H
2O100g/L, H
3BO
350g/L, sodium lauryl sulphate 3g/L, asccharin 5/L, butynediol 2g/L, 75 ℃ of bath temperatures, pH5.2.
The electric current of nickel plating for the first time is asymmetric choppy sea, and power frequency is 10000Hz, and dutycycle is 10000/100, and current density is 2.5A/dm
2, electroplating time is 35 minutes.
The solution formula (in 1000ml) of the nickel plating second time of second time electroplating is as follows: NiSO
46H
2O 240g/L, NiCl
26H
2O2g/L, H
3BO
335g/L, MgSO
47H
2O 30g/L, X 2073 0.1g/L, 50 ℃ of bath temperatures, plating bath pH3.1.
The current waveform of nickel plating for the second time is a pulse wave, and power frequency is 10000Hz, and dutycycle is 10000/100, and current density is 2.5A/dm
2, electroplating time is 35 minutes.
When the large stretch of nickel plating aluminium flake for preparing was cut to nickel-plated aluminum lug, the area of large stretch of nickel plating aluminium flake was 300 times of nickel-plated aluminum lug, and the width of nickel-plated aluminum lug is 100 millimeters.
Embodiment 4
Present embodiment is the large stretch of nickel plating aluminium flake of preparation earlier, more large stretch of nickel plating aluminium flake is cut to nickel-plated aluminum lug.Preparing large stretch of nickel plating aluminium flake forms by soaking zinc-second time electroplating step:
Wherein, the prescription of zinc dipping solution (in 1000ml) as follows, ZnSO
480g/L, FeCl
36H
20 0.5g/L, NiSO
46H
2O60g/L, Na
3C
6H
5O
72H
2O 10g/L, NaKC
4H
4O
64H
2O 120g/L, NaOH 100g/L, NaNO
30.5g/L.
The solution formula (in 1000ml) of the nickel plating first time of second time electroplating is as follows: NiSO
46H
2O 200g/L, NiCl
26H
2O20g/L, H
3BO
320g/L, sodium lauryl sulphate 0.01g/L, benzene sulfinic acid sodium salt 0.1g/L, propiolic alcohol 0.05g/L, 45 ℃ of bath temperatures, pH 3.2.
The current waveform of nickel plating for the first time is an asymmetrical square wave, and power frequency is 10000Hz, and dutycycle is 10000/100, and current density is 1.5A/dm
2, electroplating time is 35 minutes.
The solution formula (in 1000ml) of the nickel plating second time of second time electroplating is as follows: NiSO
46H
2O 300g/L, NiCl
26H
2O20g/L, H
3BO
355g/L, MgSO
47H
2O 50g/L, TX10 0.1g/L, 70 ℃ of bath temperatures, plating bath pH 5.5,
The current waveform of nickel plating for the second time is a pulse wave, and power frequency is 0.1Hz, and dutycycle is 1/100, and current density is 0.01A/dm
2, electroplating time is 0.1 second.
When the large stretch of nickel plating aluminium flake for preparing was cut to nickel-plated aluminum lug, the area of large stretch of nickel plating aluminium flake was 10000 times of nickel-plated aluminum lug, and the width of nickel-plated aluminum lug is 1 millimeter.
Embodiment 5
Present embodiment is the large stretch of nickel plating aluminium flake of preparation earlier, more large stretch of nickel plating aluminium flake is cut to nickel-plated aluminum lug.Preparing large stretch of nickel plating aluminium flake forms by soaking zinc-second time electroplating step:
Wherein, the prescription of zinc dipping solution (in 1000ml) as follows: ZnSO
4120g/L, FeCl
36H
2O 3g/L, NiSO
46H
2O45g/L, Na
3C
6H
5O
72H
2O 20g/L, NaKC
4H
4O
64H
2O 170g/L, NaOH 170g/L, NaNO
35g/L.
The solution formula of the nickel plating first time of second time electroplating is following, NiSO
46H
2O 300g/L, NiCl
26H
2O 80g/L, H
3BO
330g/L, sodium lauryl sulphate 2g/L, para toluene sulfonamide 4g/L, tonka bean camphor 1g/L, 65 ℃ of bath temperatures, pH5.0.
The current waveform of nickel plating for the first time is a kind of current waveform that asymmetrical square wave and pulse wave are combined into, and power frequency is 1000Hz, and dutycycle is 50/100, and current density is 1.5A/dm
2, electroplating time is 15 minutes.
The solution formula of the nickel plating second time of second time electroplating is following, NiSO
46H
2O 280g/L, NiCl
26H
2O 16g/L, H
3BO
345g/L, MgSO
47H
2O 42g/L, TX10 3g/L, 60 ℃ of bath temperatures, plating bath pH 4.5.
The electric current of nickel plating for the second time is an asymmetrical square wave, and power frequency is 5000Hz, and dutycycle is 10000/100, and current density is 1.1A/dm
2, electroplating time is 5 minutes.
When the large stretch of nickel plating aluminium flake for preparing was cut to nickel-plated aluminum lug, the area of large stretch of nickel plating aluminium flake was 10 times of nickel-plated aluminum lug, and the width of nickel-plated aluminum lug is 10 millimeters.
Embodiment 6
Present embodiment is the large stretch of nickel plating aluminium flake of preparation earlier, more large stretch of nickel plating aluminium flake is cut to nickel-plated aluminum lug.Preparing large stretch of nickel plating aluminium flake forms by soaking zinc-second time electroplating step:
Wherein, the prescription of zinc dipping solution (in 1000ml) as follows: ZnSO
480g/L, FeCl
36H
2O 0.5g/L, NiSO
46H
2O30g/L, Na
3C
6H
5O
72H
2O 10g/L, NaKC
4H
4O
64H
2O 120g/L, NaOH 100g/L, NaNO
30.5g/L.
The solution formula (in 1000ml) of the nickel plating first time of second time electroplating is as follows: NiSO
46H
2O 300g/L, NiCl
26H
2O70g/L, H
3BO
335g/L, sodium lauryl sulphate 2g/L, para toluene sulfonamide 3g/L, tonka bean camphor 1g/L, 60 ℃ of bath temperatures, pH 3.8.
The current waveform of nickel plating for the first time is a pulse wave, and power frequency is 10000Hz, and dutycycle is 10/100, and current density is 0.1A/dm
2, electroplating time is 100 seconds.
The solution formula (in 1000ml) of the nickel plating second time of second time electroplating as follows, NiSO
46H
2O 300g/L, NiCl
26H
2O20g/L, H
3BO
355g/L, MgSO
47H
2O 50g/L, Triple Pressed Stearic Acid 3g/L, 70 ℃ of bath temperatures, plating bath pH 5.5.
The current waveform of nickel plating for the second time is asymmetric choppy sea, and power frequency is 10000Hz, and dutycycle is 1/100, and current density is 2.1A/dm
2, electroplating time is 30 seconds.
When the large stretch of nickel plating aluminium flake for preparing was cut to nickel-plated aluminum lug, the area of large stretch of nickel plating aluminium flake was 1000 times of nickel-plated aluminum lug, and the width of nickel-plated aluminum lug is 2 millimeters.
Embodiment 7
Present embodiment is the large stretch of nickel plating aluminium flake of preparation earlier, more large stretch of nickel plating aluminium flake is cut to nickel-plated aluminum lug.Preparing large stretch of nickel plating aluminium flake forms by soaking zinc-second time electroplating step:
Wherein, the prescription of zinc dipping solution (in 1000ml) as follows: ZnSO
4150g/L, FeCl
36H
2O 5g/L, NiSO
46H
2O60g/L, Na
3C
6H
5O
72H
2O 30g/L, NaKC
4H
4O
64H
2O 240g/L, NaOH 240g/L, NaNO
310g/L.
The solution formula (in 1000ml) of the nickel plating first time of second time electroplating is as follows: NiSO
46H
2O 400g/L, NiCl
26H
2O100g/L, H
3BO
350g/L, sodium lauryl sulphate 3g/L, asccharin 5/L, tonka bean camphor 2g/L, 75 ℃ of bath temperatures, pH 5.2.
The current waveform of nickel plating for the first time is asymmetric sine wave, and power frequency is 500Hz, and dutycycle is 1/100, and current density is 0.01A/dm
2, electroplating time is 20 minutes.
The solution formula of the nickel plating second time of second time electroplating is following, NiSO
46H
2O 280g/L, NiCl
26H
2O 12g/L, H
3BO
342g/L, MgSO
47H
2O 45g/L, polysorbate 0.1g/L, 60 ℃ of bath temperatures, plating bath pH 4.1.
The current waveform of nickel plating for the second time is asymmetric sine wave, and power frequency is 50Hz, and dutycycle is 1/100, and current density is 0.01A/dm
2, electroplating time is 1 minute.
When the large stretch of nickel plating aluminium flake for preparing was cut to nickel-plated aluminum lug, the area of large stretch of nickel plating aluminium flake was 100 times of nickel-plated aluminum lug, and the width of nickel-plated aluminum lug is 200 millimeters.
Claims (2)
1. one kind is soaked zinc-second time electroplating legal system and is equipped with the method for nickel-plated aluminum lug, it is characterized in that the large stretch of nickel plating aluminium flake of preparation earlier, more large stretch of nickel plating aluminium flake is cut to nickel-plated aluminum lug; Preparing large stretch of nickel plating aluminium flake forms by soaking zinc-two step plating step:
In 1000ml, the prescription of zinc dipping solution is following: ZnSO
480g~150g, FeCl
36H
2O 0.5g~5g, NiSO
46H
2O 30g~60g, Na
3C
6H
5O
72H
2O 10g~30g, NaKC
4H
4O
64H
2O 120g~240g, NaOH 100g~240g, NaNO
30.5g~10g;
In 1000ml, the solution formula of the nickel plating first time of second time electroplating is following: NiSO
46H
2O 200g~400g, NiCl
26H
2O 20g~100g, H
3BO
320g~50g, sodium lauryl sulphate 0.01g~12g, elementary brightening agent 0.1g~5g, second-class brightener 0.05g~2g, 45 ℃~75 ℃ of bath temperatures, pH 3.2~5.2;
In 1000ml, the solution formula of the nickel plating second time of second time electroplating is following: NiSO
46H
2O 240g~300g, NiCl
26H
2O 2g~20g, H
3BO
335g~55g, MgSO
47H
2O 30g~50g, tensio-active agent 0.01g~12g, 50 ℃~70 ℃ of bath temperatures, plating bath pH 3.1~5.5;
The electric current of second time electroplating is one of asymmetrical square wave, asymmetric sine wave, asymmetric CW, asymmetric choppy sea or pulse wave, or a kind of current waveform of being combined into of above-mentioned two kinds of current waveforms; Power frequency is 0.1Hz~10000Hz, and dutycycle is 1/100~10000/100, and current density is 0.01A/dm
2~2.5A/dm
2, electroplating time is 0.1 second~35 minutes;
When the large stretch of nickel plating aluminium flake for preparing was cut to nickel-plated aluminum lug, the area of large stretch of nickel plating aluminium flake was 3 times to 10000 times of nickel-plated aluminum lug, and the width of nickel-plated aluminum lug is any width between 1 millimeter to 200 millimeters; Relation below the size of the nickel-plated aluminum lug here satisfies: length>width>thickness;
Described elementary brightening agent is asccharin, benzene sulfinic acid sodium salt, para toluene sulfonamide or unsaturated fatty acid derivative;
Described second-class brightener is butynediol, propiolic alcohol or tonka bean camphor, or butynediol and oxirane reaction product, or the reaction product of butynediol and epoxy chloropropane;
Described tensio-active agent is meant sodium lauryl sulphate, X 2073 or TX10, in prescription, accounts between 0.1g~12g.
2. a kind of zinc-second time electroplating legal system of soaking according to claim 1 is equipped with the method for nickel-plated aluminum lug, it is characterized in that described tensio-active agent is Triple Pressed Stearic Acid, trimethyl-glycine, glycerin fatty acid ester or polysorbate, accounts between 0.01g/L~2.0g/L in prescription.
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CN2010102415843A CN101906648B (en) | 2010-07-30 | 2010-07-30 | Zinc-galvanizing once or twice electroplating method for preparing nickel-plating aluminium pole ears |
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CN1394988A (en) * | 2002-08-20 | 2003-02-05 | 中国科学院电子学研究所 | Multi-layer nickel-plating process by adopting single bath process |
CN101771142B (en) * | 2010-02-10 | 2012-09-19 | 力佳电源科技(深圳)有限公司 | Tab material of flexible-packaging lithium battery as well as electroplating method and application method thereof |
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