CN101905954B - Binding material prepared from construction waste and preparation method thereof - Google Patents

Binding material prepared from construction waste and preparation method thereof Download PDF

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Publication number
CN101905954B
CN101905954B CN2010102305646A CN201010230564A CN101905954B CN 101905954 B CN101905954 B CN 101905954B CN 2010102305646 A CN2010102305646 A CN 2010102305646A CN 201010230564 A CN201010230564 A CN 201010230564A CN 101905954 B CN101905954 B CN 101905954B
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Prior art keywords
parts
building waste
wingdale
building
granularity
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CN2010102305646A
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CN101905954A (en
Inventor
夏举佩
张召述
任雪娇
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Kunming University of Science and Technology
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Kunming University of Science and Technology
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/24Cements from oil shales, residues or waste other than slag
    • C04B7/246Cements from oil shales, residues or waste other than slag from waste building materials, e.g. waste asbestos-cement products, demolition waste
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding

Abstract

The invention provides a binding material prepared from construction waste, which consists of the following components in part by mass: 80 to 90 parts of construction waste, 10 to 30 parts of auxiliary material, and 1.0 to 2.8 parts of additive, wherein the auxiliary material is one or both of yellow phosphorus slag and flyash, or one or both of lime stone and carbide slag; and the additive is two or three of 0.5 to 1 part of aluminum sulfate, 0.2 to 0.6 part of sodium sulfate and 0.5 to 1.2 parts of sodium carbonate. The hydraulic binding material produced by high temperature activation, mechanical activation and chemical activation can replace cement to be widely applied to producing baking-free bricks and roadbase materials. The binding material has the advantages of conveniently available raw materials, low cost, energy conservation and consumption reduction; and compared with the traditional cementing material, the binding material has the same using method and is convenient to promote and apply.

Description

Gelling material of processing with building waste and preparation method thereof
Technical field
The present invention relates to a kind of recycling of building waste, specifically a kind of gelling material that building waste processes and preparation method thereof of utilizing belongs to the material of construction preparing technical field.
Background technology
Building waste is the solid waste that produces in the construction, maintenance, demolishing process at buildings; Comprise waste material, various wrapping material and other wastes etc. that the mortar that is scattered in waste concrete piece, useless fragment of brick, bituminous concrete piece, the construction process and concrete, brickbat slag, metal, bamboo timber, decorations produce, its staple is main with concrete and sintering common brick.
In Europe, developed country such as U.S.A, day, the recycling of building waste has become the hot issue of present research.To the building waste of different sources and composition, processing mode is different, like the CYCLEAN company of the U.S. building waste to road excavation, adopts microwave technology, reclaims the old asphalt pavement material, and its quality is with newly to mix asphalt road surface material identical, and cost can reduce by 1/3.And the building waste that building demolition is obtained, Singapore is then building waste recycling be processed into iron, timber, leatheroid etc.To pretreated building waste, handle according to its composition, to material of construction such as concrete, sand, stones,, produce recycled cement and regeneration aggregate through certain means preparation material of construction of regenerating.And to flammable building waste, the destructive distillation combustion refuse treatment process of Siemens exploitation can make the various recyclable materials in the rubbish very separate neatly, is recycled, and the combustion gas that produces in the treating processes then is used for generating.Generally speaking, the recycling of building waste has all been obtained substantial progress from theoretical and actual two aspects abroad.
In China, the recycling of building waste has also caused numerous investigators' attention and has carried out big quantity research.In general, its basic ideas are carries out sorting with building waste, thereby carries out classified use, different according to investigator's research object, has obtained a large amount of theoretical property conclusions.As with blue bricks or common brick particle as light-weight aggregate, be aided with less fine aggregate of density or powder again, can make cement products such as better road brick of light in structure aggregate concrete member, ventilation property with load-bearing, heat insulation function and ornamental slab for paving the floor.As with sorting after the waste and old concrete fragmentation, modification is as regeneration aggregate; Waste and old mortar is pulverized the back be used as dry-mixed mortar etc.In the application facet of reality, real mass-producing utilizes the report of building waste, and is at present domestic less.
Analyzing China's building waste treatment technology can find; Although China's building waste is handled thinking and external basically identical; But on concrete technology and implement scale, still be in the junior stage, also do not having sophisticated mass-producing and the complete technological line that utilizes for the urban architecture rubbish of a large amount of complicated components.
At present, the quantity of China's building waste has accounted for 40%~50% of municipal wastes total amount.And most building wastes are handled with the mode of air storage or landfill, consume a large amount of soils, bury great potential safety hazard also for people's living environment.Therefore, building waste being recycled, turned waste into wealth, is to solve the building waste optimal path, also is simultaneously the effective way that economizes on resources, protects existing fragile ecological environment.Because the chemical constitution and the mineralogical character of building castoff are developed its recycle utilization at building field, can finally solve the handling problem of building waste.Amount of literature data shows, utilizes building waste to produce the adulterant of non-burning brick, roadbase, the steady layer of water, regeneration aggregate, dry-mixed mortar, manufacture of cement, is the focus of studying at present.
Say from the meaning of Eco-economy System; Waste is " resource that has misplaced the position "; It is recycled to produce building material, is decontamination, makes one of main method of its resource utilization; Not only can alleviate the pressure of China's urban environment load, also can realize Sustainable development economic and society.
Comprehensive existing document can be found out: aspect building waste production gelling material, mainly be in the form adding grog with adulterant, compare with the cement of producing equal label, reduce the grog parameter; Simultaneously, because its grindability is practiced thrift power consumption.Therefore, can reduce the manufacture of cement cost, reach the purpose of energy-saving and emission-reduction.It is gelling material with cement mainly that building waste is produced non-burning brick, is aided with other industrial slag, under natural or steam-cured condition, produces non-burning brick.When producing road basement material with building waste, building waste mainly is that its gelling material then adopts cement, lime, flyash etc. as aggregate.With the building waste is main raw, and through high-temperature activation, mechanical activation and chemical activation, preparation has the gelling material of the hydraulicity, does not appear in the newspapers yet and leads.
Summary of the invention
The object of the present invention is to provide a kind of gelling material of processing with building waste.
Another object of the present invention is to provide a kind of method with building waste production gelling material.
First purpose of the present invention is accomplished through following technical proposal: a kind of gelling material of processing with building waste is characterized in that being made up of following mass component:
80~90 parts of building wastes
10~30 parts of subsidiary material
1.0~2.8 parts of additives
Said subsidiary material are one or both and yellow phosphorus furnace slag, in the flyash one or both in Wingdale, the carbide slag;
Said additive is two or three in Tai-Ace S 150, sodium sulfate, the yellow soda ash, makes Na wherein 2O: SO 4=1: 0.2~0.5 mass ratio.
Second purpose of the present invention realizes through following technical proposal: a kind of method with building waste production gelling material; It is main raw material with the building waste; With lime or/and carbide slag and yellow phosphorus furnace slag or/and flyash is subsidiary material; Be additive with Tai-Ace S 150, sodium sulfate, yellow soda ash again; Produce hydraulic cementing materials through high-temperature activation, mechanical activation and chemical activation, can replace cement to be widely used in and produce non-burning brick, road basement material, it is characterized in that through the following step:
A. get the raw materials ready by following mass component:
80~90 parts of building wastes
10~30 parts of subsidiary material
1.0~2.8 parts of additives
Wherein:
Said subsidiary material are one or both in Wingdale, the carbide slag, and in the yellow phosphorus furnace slag, flyash one or both;
Said additive is two or three in Tai-Ace S 150, sodium sulfate, the yellow soda ash, makes Na wherein 2O: SO 4=1: 0.2~0.5 mass ratio;
B. in building waste that steps A was equipped with and subsidiary material Wingdale, the carbide slag one or both are mixed, at 800~900 ℃ of roasting temperature 1~3h, roasting material;
C. with step B gained roasting material, the subsidiary material yellow phosphorus furnace slag that is equipped with steps A, in the flyash one or both, and two or three in the additive sulfuric acid aluminium, sodium sulfate, yellow soda ash mixes, levigate to granularity less than 0.083mm, the gelling material powder.
Said building waste is a building castoff of removing plastics, timber and daily necessities, and it is crushed to granularity is 5~50mm, and with ordinary method and equipment deironing.
Said Wingdale is the Wingdale through fragmentation, and granularity is 5~30mm.
The examination of the performance of gained gelling material can be through following method:
(1) non-burning brick preparation: with 10~20 parts in step C gained gelling material powder, granularity is 80~90 parts of the building wastes of 0.2~2mm, 13~15 parts in water; Mix and stir; Get green compact with conventional shaper moulding, again with green compact after conventional natural curing or vapor cure, non-burning brick; Through conventional performance test is qualified, and provable thus step C gained gelling material powder is qualified.
(2) road basement material preparation: with 5~10 parts in step C gained gelling material powder; Granularity is 85~90 parts of the building wastes of 0.2~20mm; 5~15 parts in water; Through mixing 3 minutes, the preparation aspect ratio is 1 right cylinder test specimen under the forming pressure of 2MPa, carries out the maintenance and the performance test of test specimen according to the demand of technical standard of " highway road surface construction technique normalizing " JTJ034-2000 roadbase and subbase; Get qualified road basement material, provable thus step C gained gelling material powder is qualified.
The present invention compared with prior art has following advantage:
1) gelling material of the present invention's production has hydraulicity characteristics, and raw material sources are convenient, and cost is low, and is energy-saving and cost-reducing.
2) compare with traditional cement cementitious material, the present invention is main raw material with the building waste, and maturing temperature is low, and the time is short, and roasting material is prone to grinding, energy-conservation power saving again.
3) compare with traditional cement cementitious material, method of use is identical, is convenient to it and applies.
4) the non-burning brick and road basement material of preparing with gelling material provided by the invention, performance satisfies the respective standard requirement.
Description of drawings
Fig. 1 is technical process of the present invention.
Embodiment
Embodiment 1
A. get the raw materials ready by following mass component:
Building waste 80kg carbide slag 5kg
Yellow phosphorus furnace slag 10kg Tai-Ace S 150 0.5kg
Yellow soda ash 0.5kg
Wherein:
Building waste is a building removal waste of removing plastics, timber and daily necessities, is 5mm through being crushed to granularity, removes iron wherein with conventional magnet machine magnetic;
B. building waste that steps A is equipped with is mixed with carbide slag,, obtain roasting material at 850 ℃ of roasting 1h of maturing temperature;
C. step B gained roasting material is mixed with yellow phosphorus furnace slag that steps A is equipped with, Tai-Ace S 150, yellow soda ash, levigate to granularity less than 0.083mm, be the gelling material powder;
Performance Detection: with step C gained gelling material powder 20kg; Granularity is the building waste 80kg of 0.2mm; Water 15kg after mixing stirring, gets green compact with conventional block machine moulding; Green compact were through natural curing 10 days; Carry out performance test, test result: mean compressive strength 10.67MPa, average folding strength 2.67MPa, water-intake rate 14.12%, carbonization coefficient 81.37%, coefficient of softening 85.62%, 25 freeze-thaw cycle ultimate compression strength losses 8.6%, mass losses are 1.36%, prove that thus step C gained gelling material powder is qualified.
Embodiment 2
A. get the raw materials ready by following mass component:
Building waste 90kg Wingdale 5kg
Yellow phosphorus furnace slag 5kg flyash 10kg
Tai-Ace S 150 1kg sodium sulfate 0.6kg
Wherein:
Building waste is a building removal waste of removing plastics, timber and daily necessities, is 50mm through being crushed to granularity, removes iron wherein with conventional magnet machine magnetic; Wingdale is the Wingdale through fragmentation, and granularity is 30mm;
B. with being equipped with building waste in the steps A and Wingdale mixes,, obtain roasting material with 900 ℃ of roasting 2h of maturing temperature;
C. carry out abrasive dust with being equipped with yellow phosphorus furnace slag, Tai-Ace S 150, sodium sulfate in gained roasting material and the steps A among the step B, be milled to powder granularity, promptly obtain the gelling material powder less than 0.083mm;
The performance examination: get gelling material 10kg described in the step C, getting granularity is the building waste 90kg of 2mm, adds water 13kg; Stir the back and use the block machine moulding; Green compact carry out performance test, test result through normal pressure vapor cure 18 hours: mean compressive strength 12.21MPa, average folding strength 3.17MPa; Water-intake rate 12.10%, carbonization coefficient 83.40%, coefficient of softening 86.31%; 25 freeze-thaw cycle ultimate compression strength losses 7.7%, mass loss is 1.37%, provable thus step C gained gelling material powder is qualified.
Embodiment 3
A. get the raw materials ready by following mass component:
Building waste 85kg Wingdale 2kg
Carbide slag 3kg yellow phosphorus furnace slag 3kg
Flyash 5kg Tai-Ace S 150 0.7kg
Sodium sulfate 0.3kg yellow soda ash 1.0kg
Wherein:
Building waste is a building removal waste of removing plastics, timber and daily necessities, is 25mm through being crushed to granularity again, removes iron wherein with conventional magnet machine magnetic; Wingdale is the Wingdale through fragmentation, and granularity is 5mm.
B. with being equipped with building waste in the steps A and Wingdale, carbide slag mix,, obtain roasting material with 800 ℃ of roasting 3h of maturing temperature;
C. step B gained roasting material is mixed with yellow phosphorus furnace slag that steps A is equipped with, flyash, Tai-Ace S 150, sodium sulfate, yellow soda ash, levigate to granularity less than 0.083mm, promptly obtain the gelling material powder;
Performance Detection: get gelling material 10kg described in the step C; With granularity is that to be crushed to granularity once more be 0.2~20mm to 5~50mm building waste; Get 90kg, add water 15kg, stirred 3 minutes through biaxial rneader; The preparation aspect ratio is 1 right cylinder test specimen under the forming pressure of 2MPa; Carry out the maintenance and the performance test of test specimen according to the demand of technical standard of " highway road surface construction technique normalizing " JTJ034-2000 roadbase and subbase, test result: 7 days unconfined compression strength 1.31MPa, the steady coefficient 77.40% of water; 28 days unconfined compression strength 8.47MPa, the steady coefficient 89.10% of water, provable thus step C gained gelling material powder is qualified.
Embodiment 4
A. get the raw materials ready by following mass component:
Building waste 87kg Wingdale 5kg
Flyash 5kg Tai-Ace S 150 0.9kg
Sodium sulfate 0.8kg yellow soda ash 1.1kg
Wherein:
Building waste is a building removal waste of removing plastics, timber and daily necessities, is 28mm through being crushed to granularity again, removes iron wherein with conventional magnet machine magnetic; Wingdale is the Wingdale through fragmentation, and granularity is 10mm;
B. building waste that steps A is equipped with and Wingdale are mixed,, obtain roasting material at 820 ℃ of roasting 3h of maturing temperature;
C. step B gained roasting material is mixed with flyash that steps A is equipped with, Tai-Ace S 150, sodium sulfate, yellow soda ash, levigate to granularity less than 0.083mm, promptly obtain the gelling material powder;
Performance Detection: get gelling material 5kg described in the step C; With granularity is that to be crushed to granularity once more be 0.2~20mm to 5~50mm building waste; Get 85kg, add water 5kg, stirred 3 minutes through biaxial rneader; The preparation aspect ratio is 1 right cylinder test specimen under the forming pressure of 2MPa; Carry out the maintenance and the performance test of test specimen according to the demand of technical standard of " highway road surface construction technique normalizing " JTJ034-2000 roadbase and subbase, test result: 7 days unconfined compression strength 1.38MPa, the steady coefficient 77.58% of water; 28 days unconfined compression strength 8.86MPa, the steady coefficient 89.92% of water, provable thus step C gained gelling material powder is qualified.

Claims (3)

1. gelling material of processing with building waste is characterized in that being made up of following mass component:
80~90 parts of building wastes
10~30 parts of subsidiary material
1.0~2.8 parts of additives
Wherein:
Said subsidiary material are one or both in yellow phosphorus furnace slag, the flyash, and in the Wingdale, carbide slag one or both;
Said additive is two or three in Tai-Ace S 150, sodium sulfate, the yellow soda ash.
2. the preparation method of a gelling material of processing with building waste is characterized in that through the following step:
A. get the raw materials ready by following mass component:
80~90 parts of building wastes
10~30 parts of subsidiary material
1.0~2.8 parts of additives
Wherein:
Said building waste is a building castoff of removing plastics, timber and daily necessities, is 5~50mm through being crushed to granularity again, by ordinary method and equipment deironing;
Said subsidiary material are one or both in Wingdale, the carbide slag, and in the yellow phosphorus furnace slag, flyash one or both;
Said additive is two or three in Tai-Ace S 150, sodium sulfate, the yellow soda ash;
B. in building waste that steps A is equipped with and subsidiary material Wingdale, the carbide slag one or both are mixed,, obtain roasting material at 800~900 ℃ of roasting 1~3h of maturing temperature;
C. with step B gained roasting material, and be equipped with in subsidiary material yellow phosphorus furnace slag, the flyash one or both in the steps A, and two or three in the additive sulfuric acid aluminium, sodium sulfate, yellow soda ash mixes, levigate to granularity less than 0.083mm, the gelling material powder.
3. the preparation method of gelling material according to claim 2 is characterized in that said Wingdale is the Wingdale through fragmentation, and granularity is 5~30mm.
CN2010102305646A 2010-07-20 2010-07-20 Binding material prepared from construction waste and preparation method thereof Expired - Fee Related CN101905954B (en)

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CN102951880A (en) * 2012-12-04 2013-03-06 山东泰德新能源有限公司 Paving material produced by utilizing building garbage
CN103193428B (en) * 2013-04-19 2015-05-27 李迎春 Novel roadbed composite material and production and application methods thereof
CN103803830B (en) * 2014-01-21 2016-04-06 北京奥润开元环保科技研究院有限公司 A kind of activating treatment process of regenerative micro powder
CN104086131B (en) * 2014-07-25 2016-06-15 韩先福 Road pavements that building waste is prepared with agstone compound and preparation method thereof
CN105152553A (en) * 2015-07-10 2015-12-16 胡相明 Green expansive cementing material based on salt chemical industry solid waste and building garbage, preparation method and applications thereof
CN105060754B (en) * 2015-08-24 2018-02-13 盐城工学院 Useless ceramic tile powder cement mixture
CN105272116B (en) * 2015-09-25 2018-02-02 南昌理工学院 Fragment of brick prepared using building waste and preparation method thereof
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CN106673578A (en) * 2017-01-16 2017-05-17 河南国隆实业有限公司 3D printing building structure material and use method thereof
CN109369086A (en) * 2018-12-20 2019-02-22 贵州安凯达实业股份有限公司 Utilize building waste production self-compacting concrete and preparation method thereof
CN110668741A (en) * 2019-10-08 2020-01-10 广东凯恩德环保建材有限公司 Preparation method of dry-mixed mortar
CN110757618A (en) * 2019-10-31 2020-02-07 梁品 Method for producing baking-free bricks by comprehensively utilizing furnace slag
CN113354313B (en) * 2021-07-05 2022-06-28 常熟理工学院 Method for preparing non-fired cement by using concrete waste residues
CN113354314B (en) * 2021-07-20 2022-03-01 深圳市衡骏环保科技有限公司 High-activity cementing material based on engineering muck
CN115353331A (en) * 2022-07-27 2022-11-18 南京益夫新材料科技有限公司 Preparation method of regenerated plastering mortar

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