CN101891896B - 含氟-磷-氮低聚物膨胀型阻燃剂及其制备方法 - Google Patents
含氟-磷-氮低聚物膨胀型阻燃剂及其制备方法 Download PDFInfo
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- CN101891896B CN101891896B CN 201010220758 CN201010220758A CN101891896B CN 101891896 B CN101891896 B CN 101891896B CN 201010220758 CN201010220758 CN 201010220758 CN 201010220758 A CN201010220758 A CN 201010220758A CN 101891896 B CN101891896 B CN 101891896B
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- phosphorus
- fire retardant
- diphosphate ester
- nitrogen
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 87
- 238000002360 preparation method Methods 0.000 title claims abstract description 28
- SASGRYXPUKWRAZ-UHFFFAOYSA-N [N].[P].[F] Chemical compound [N].[P].[F] SASGRYXPUKWRAZ-UHFFFAOYSA-N 0.000 title abstract 3
- 238000006243 chemical reaction Methods 0.000 claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- 150000004985 diamines Chemical class 0.000 claims abstract description 22
- 238000001035 drying Methods 0.000 claims abstract description 16
- 238000005406 washing Methods 0.000 claims abstract description 15
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 3
- -1 fluoro-phosphorus-nitrogen Chemical compound 0.000 claims description 74
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical class ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 claims description 63
- 239000001177 diphosphate Substances 0.000 claims description 43
- 235000011180 diphosphates Nutrition 0.000 claims description 43
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims description 42
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 31
- 239000008367 deionised water Substances 0.000 claims description 18
- 229910021641 deionized water Inorganic materials 0.000 claims description 18
- 238000001291 vacuum drying Methods 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 229910019213 POCl3 Inorganic materials 0.000 claims description 10
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 229940059574 pentaerithrityl Drugs 0.000 claims description 10
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 9
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 9
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 6
- 239000001294 propane Substances 0.000 claims description 5
- NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical compound FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 claims description 3
- KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 13
- 239000012298 atmosphere Substances 0.000 abstract description 11
- 238000000034 method Methods 0.000 abstract description 10
- 239000007789 gas Substances 0.000 abstract description 7
- 239000002253 acid Substances 0.000 abstract description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 abstract description 4
- 239000003610 charcoal Substances 0.000 abstract description 4
- 229910052731 fluorine Inorganic materials 0.000 abstract description 4
- 239000011737 fluorine Substances 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 3
- 238000001914 filtration Methods 0.000 abstract description 2
- 238000012545 processing Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 238000000465 moulding Methods 0.000 abstract 1
- 229920000307 polymer substrate Polymers 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 21
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 15
- 239000001301 oxygen Substances 0.000 description 15
- 229910052760 oxygen Inorganic materials 0.000 description 15
- 239000002904 solvent Substances 0.000 description 9
- 239000004743 Polypropylene Substances 0.000 description 8
- 239000012757 flame retardant agent Substances 0.000 description 8
- 238000007599 discharging Methods 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 238000002791 soaking Methods 0.000 description 7
- 230000004580 weight loss Effects 0.000 description 7
- 239000011159 matrix material Substances 0.000 description 4
- 238000013508 migration Methods 0.000 description 4
- 230000005012 migration Effects 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000001902 propagating effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
Description
Claims (10)
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CN 201010220758 CN101891896B (zh) | 2010-07-07 | 2010-07-07 | 含氟-磷-氮低聚物膨胀型阻燃剂及其制备方法 |
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CN 201010220758 CN101891896B (zh) | 2010-07-07 | 2010-07-07 | 含氟-磷-氮低聚物膨胀型阻燃剂及其制备方法 |
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CN101891896A CN101891896A (zh) | 2010-11-24 |
CN101891896B true CN101891896B (zh) | 2012-08-22 |
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Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102225998A (zh) * | 2011-04-19 | 2011-10-26 | 浙江科峰化工有限公司 | 一种聚己戊四醇磷三乙醇酰胺的制备方法 |
CN102585135B (zh) * | 2012-03-05 | 2013-08-07 | 中北大学 | 聚氨酯用反应型膨胀型阻燃剂及其合成方法 |
CN102627771B (zh) * | 2012-04-11 | 2014-05-07 | 苏州科技学院 | 季戊四醇二磷酸酯二磷酰氯缩乙二胺大分子型阻燃剂及其制备方法 |
CN102757580A (zh) * | 2012-07-31 | 2012-10-31 | 广东聚石化学股份有限公司 | 一种反应型磷-氮阻燃剂及其合成方法 |
CN106521969B (zh) * | 2016-11-14 | 2018-10-02 | 约克夏染料(中山)有限公司 | 一种织物阻燃剂及其制备方法和应用 |
CN106867366B (zh) * | 2017-02-07 | 2019-08-13 | 东莞市道尔新材料科技有限公司 | 高效阻燃性环氧树脂涂料 |
CN116102835B (zh) * | 2023-01-08 | 2024-03-19 | 江苏中煜橡塑科技有限公司 | 一种钠电池用阻燃耐高温氟橡胶及其加工工艺 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1414000A (zh) * | 2002-09-26 | 2003-04-30 | 东北林业大学 | 季戊四醇双磷酸酯二酰氯的合成方法 |
CN101671568A (zh) * | 2009-09-06 | 2010-03-17 | 青岛科技大学 | 一种含磷有机硅树脂阻燃剂及其制备方法 |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1414000A (zh) * | 2002-09-26 | 2003-04-30 | 东北林业大学 | 季戊四醇双磷酸酯二酰氯的合成方法 |
CN101671568A (zh) * | 2009-09-06 | 2010-03-17 | 青岛科技大学 | 一种含磷有机硅树脂阻燃剂及其制备方法 |
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Address after: Jinzhai road in Baohe District of Hefei city of Anhui Province, No. 856 230022 Patentee after: ANHUI JIANZHU University Address before: Jinzhai road in Baohe District of Hefei city of Anhui Province, No. 856 230022 Patentee before: anhui university of architecture |
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Application publication date: 20101124 Assignee: HEFEI PUTE CHEMICAL LIGHT MATERIAL Co.,Ltd. Assignor: ANHUI JIANZHU University Contract record no.: 2014340000143 Denomination of invention: Expansible fire retardant containing fluorine-phosphorus-nitrogen oligomer and preparation method thereof Granted publication date: 20120822 License type: Exclusive License Record date: 20140717 |
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Effective date of registration: 20210720 Address after: No.28 Changning Road, Chahe Town Economic Development Zone, Lai'an county, Chuzhou City, Anhui Province 239200 Patentee after: HENGTONG RUBBER & PRODUCTS Co.,Ltd. Address before: No. 856, Jinzhai Road, Baohe District, Hefei City, Anhui Province, 230022 Patentee before: ANHUI JIANZHU University |
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Address after: No.28 Changning Road, Chahe Town Economic Development Zone, Lai'an county, Chuzhou City, Anhui Province 239200 Patentee after: Anhui Jinyue Hengtong Transportation Equipment Co.,Ltd. Address before: No.28 Changning Road, Chahe Town Economic Development Zone, Lai'an county, Chuzhou City, Anhui Province 239200 Patentee before: HENGTONG RUBBER & PRODUCTS CO.,LTD. |
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