CN101876193A - Double-layer resin glazed tile - Google Patents

Double-layer resin glazed tile Download PDF

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Publication number
CN101876193A
CN101876193A CN 201010202479 CN201010202479A CN101876193A CN 101876193 A CN101876193 A CN 101876193A CN 201010202479 CN201010202479 CN 201010202479 CN 201010202479 A CN201010202479 A CN 201010202479A CN 101876193 A CN101876193 A CN 101876193A
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China
Prior art keywords
double
glazed tile
layer
layer resin
raw material
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Pending
Application number
CN 201010202479
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Chinese (zh)
Inventor
林建国
陈炎
卢景峰
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Anhui Honglu Steel Structure Group Co Ltd
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Anhui Honglu Steel Structure Group Co Ltd
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Priority to CN 201010202479 priority Critical patent/CN101876193A/en
Publication of CN101876193A publication Critical patent/CN101876193A/en
Pending legal-status Critical Current

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Abstract

The invention belongs to the technical field of building material, and more particularly relates to a double-layer resin glazed tile which takes on a sheet shape or a plate shape and is formed by a plurality of wave peaks and/ or wave troughs which are sequentially connected. The glazed tile is formed by a surface layer and a bottom layer, wherein the surface layer is formed by modified resin ASA, and the bottom layer is formed by 60-80% of polyvinyl chloride resin, 1-3% of foaming agent, 8-15% of shock-resistant modifying agent, 2-5% of lubricating agent and 9-17% of processing auxiliary agent by weight percent, wherein the foaming agent is azo-compound or/ and sodium hydrogen carbonate, the shock-resistant modifying agent is chlorinated polyethylene, the lubricating agent is one or mixture of more in oxidized polyethlene wax, stearic acids or paraffin, and the processing auxiliary agent is one or mixture of more in ACR, compound stabilizer, calcium carbonate or pigment. The glazed tile is light in weight and durable, and has good effects of noise reduction and heat insulation.

Description

Double-layer resin glazed tile
Technical field
The invention belongs to building material technical field, be specifically related to a kind of double-layer resin glazed tile.
Background technology
The existing building decorative watt general resin tile that adopts brick and tile or single layer structure, in actual use, because the resin tile weight of brick and tile and single layer structure is bigger, bring a lot of inconvenience, the erosion of wind-engaging solarization on rain day simultaneously is bigger, impact resistance is relatively poor, and application life is shorter, and the noise reduction effect of heat insulation is poor.
Summary of the invention
The purpose of this invention is to provide a kind of double-layer resin glazed tile, this glazed roof tile light weight is durable, the noise reduction good heat-insulation effect.
For achieving the above object, the present invention has adopted following technical scheme: a kind of double-layer resin glazed tile, these glazed roof tile in the form of sheets or tabular, constitute by some crest and/or troughs that link to each other successively, described glazed roof tile are made of top layer and bottom, described top layer is made up of modified resin ASA, and bottom is made up of 60~80% Corvic, 1~3% blowing agent, 8~15% anti-impact modifiers, 2~5% sliding agents, 9~17% processing aids by weight percentage;
Described blowing agent is that azo-compound is or/and sodium acid carbonate; Described anti-impact modifier is a haloflex; Described sliding agent is one or more the mixture in OPE, stearic acid or the paraffin; Described processing aid is one or more the mixture in ACR, compound stabilizer, calcium carbonate or the pigment.
Adopt technique scheme, double-layer resin glazed tile of the present invention is made of top layer and bottom, and its mesexine is made up of modified resin, and the coloring of modified resin is good, and good weatherability can be dyed shades of colour and colour-fast, stable physical property; Bottom is a primary raw material by Corvic, adds blowing agent, anti-impact modifier, sliding agent and processing aid simultaneously, and wherein Corvic is a kind of universal macromolecular material, has excellent mechanical property; Anti-impact modifier can improve the impact strength of Corvic; Blowing agent can produce a large amount of abscesses, and these abscesses have the noise reduction effect of heat insulation, can also alleviate the weight of glazed roof tile simultaneously; Sliding agent and other processing aid all improve the performance of resin glazed tile of the present invention to a certain extent, so the impact resistance of double-layer resin glazed tile of the present invention is good, decay resistance is strong, and application life is longer, and the noise reduction good heat-insulation effect.
Another object of the present invention provides a kind of preparation method of above-mentioned double-layer resin glazed tile, this method is simple to operation, and good by the impact resistance of the double-layer resin glazed tile of this method preparation, decay resistance is strong, application life is longer, and the noise reduction good heat-insulation effect.
For achieving the above object, the present invention has adopted following technical scheme: the preparation method of above-mentioned double-layer resin glazed tile may further comprise the steps:
A, the bottom raw material for preparing is mixed the back in temperature is 170~200 ℃ extruder, carry out granulation; The top layer raw material is carried out drying to be handled;
B, be to plastify under 180~210 ℃ the condition the above-mentioned pellet of making in temperature;
C, the bottom raw material of above-mentioned plasticizing and dry top layer raw material are extruded 180~200 ℃ the time by two co-extrusion machines respectively, and top layer and the bottom extruded is overlapping, get final product by draw-gear traction and forming press die mould simultaneously.
Adopt technique scheme, preparation method of the present invention at first carries out granulation after the bottom raw material mixing that will prepare to plastify again, and the top layer raw material is carried out drying handle, respectively the underlying material and the dry top layer raw material of plasticizing are extruded simultaneously by two co-extrusion machines then, guarantee that bottom and top layer overlap fully, get final product by draw-gear traction and forming press die mould then, when reality is used, can cut into required size according to different demands, so the preparation method of double-layer resin glazed tile of the present invention is simple to operation, impact resistance by the double-layer resin glazed tile of this method preparation is good, decay resistance is strong, application life is longer, and the noise reduction good heat-insulation effect.
Description of drawings
Fig. 1 is a schematic diagram of the present invention.
The specific embodiment
As shown in Figure 1, double-layer resin glazed tile 10 of the present invention in the form of sheets or tabular, constitute by some crest and/or troughs that link to each other successively, described glazed roof tile are made of top layer 11 and bottom 12, described top layer 11 is made up of modified resin ASA, and bottom 12 is made up of 60~80% Corvic, 1~3% blowing agent, 8~15% anti-impact modifiers, 2~5% sliding agents, 9~17% processing aids by weight percentage;
Described blowing agent is that azo-compound is or/and sodium acid carbonate; Described anti-impact modifier is a haloflex; Described sliding agent is one or more the mixture in OPE, stearic acid or the paraffin; Described processing aid is one or more the mixture in ACR, compound stabilizer, calcium carbonate or the pigment.
Adopt technique scheme, the cross sectional shape undulate of this double-layer resin glazed tile 10, V-arrangement or W shape, the top layer 11 of this double-layer resin glazed tile 10 is made up of modified resin, and anti-static ability is good, and self-cleaning function is strong, decorative effect is attractive in appearance, have favorable mechanical physical property and very strong weatherability simultaneously, nondiscoloration when using for a long time out of doors, impact strength and elongation rate can not descend, detect proof through experiment, this double-layer resin glazed tile 10 can guarantee that 15 years Δ E values are less than 5; Adopt double-decker to be beneficial to how much variations that stretch of resin glazed tile 10, ultraviolet aging decomposition has been resisted on top layer 11, bottom 12 has been alleviated the internal stress variation, the polyvinyl chloride resin of bottom raw material employing simultaneously belongs to nonflammable material, the blowing agent that adds in the bottom raw material makes bottom 12 have foaming structure, the noise reduction good heat-insulation effect simultaneously, simultaneously can make resin glazed tile 10 low, can not cause phenomenons such as tiling breakage, cracking roof leaking because of the cataclysm of temperature in the difference variation rate; Double-layer resin glazed tile 10 of the present invention can be the direct tile hanging of framework with the steel work, gets final product with self threading pin is fixing; Also be suitable for the roof modified application of cast-in-place roof and wooden frame.
Two adjacent wave peaks of double-layer resin glazed tile 10 of the present invention or the spacing between the trough are 65mm, and the vertical interval of crest and trough is 18mm.Top layer 11 thickness of this double-layer resin glazed tile 10 are 0.1~0.3mm simultaneously.
Adopt technique scheme, the skin depth of double-layer resin glazed tile 10 of the present invention is generally 0.1~0.3mm, guaranteed the weather resistance of double-layer resin glazed tile 10, generally the thickness specification of double-layer resin glazed tile 10 comprises 1.0mm, 1.2mm, 1.5mm, 2.0mm, 2.5mm, 3.0mm; The width specifications of double-layer resin glazed tile 10 commonly used comprises 720mm, 900mm, 1050mm, 1080mm, and the thickness of double-layer resin glazed tile 10 can be according to different Demand Design with width usually.
The preparation method of double-layer resin glazed tile of the present invention may further comprise the steps:
A, the bottom raw material for preparing mixed 10~15 minutes in homogenizer after, in extruder, carry out granulation, temperature is 170~200 ℃; The top layer raw material is carried out drying at 60~90 ℃ to be handled;
B, be to plastify under 180~210 ℃ the condition the above-mentioned pellet of making in temperature;
C, the bottom raw material of above-mentioned plasticizing and dry top layer raw material are extruded 180~200 ℃ the time by two co-extrusion machines respectively, and top layer and the bottom extruded is overlapping, get final product by draw-gear traction and forming press die mould simultaneously.
The present invention is further illustrated below by embodiment:
Embodiment 1
A, the Corvic with 60%, 3% blowing agent, 15% anti-impact modifier, 5% sliding agent, 17% processing aid mix 10 minutes in homogenizer after, in being 170 ℃ extruder, temperature carries out granulation; Top layer material modification resin is carried out drying at 60 ℃ to be handled; Described blowing agent is an azo-compound, described anti-impact modifier is a haloflex, described sliding agent is an OPE, described processing aid is ACR, ACR (Acrylic copolymer) is the acrylic acid esters co-polymer with nucleocapsid structure, is a kind of high comprehensive performance processing aid;
B, be to plastify under 180 ℃ the condition the above-mentioned pellet of making in temperature;
C, the underlying material of above-mentioned plasticizing and dry top layer raw material are extruded 180 ℃ the time overlapping respectively by two co-extrusion machines, and got final product by draw-gear traction and forming press die mould.
Embodiment 2
A, the Corvic with 80%, 1% blowing agent, 8% anti-impact modifier, 2% sliding agent, 9% processing aid mix 12 minutes in homogenizer after, in being 180 ℃ extruder, temperature carries out granulation; Top layer material modification resin is carried out drying at 80 ℃ to be handled; Described blowing agent is a sodium acid carbonate, and described anti-impact modifier is a haloflex, and described sliding agent is the mixture of OPE and paraffin; Described processing aid is the mixture of ACR and pigment;
B, be to plastify under 200 ℃ the condition the above-mentioned pellet of making in temperature;
C, the underlying material of above-mentioned plasticizing and dry top layer raw material are extruded 200 ℃ the time overlapping respectively by two co-extrusion machines, and got final product by draw-gear traction and forming press die mould.
Embodiment 3
A, the Corvic with 75%, 2% blowing agent, 9% anti-impact modifier, 3% sliding agent, 11% processing aid mix 15 minutes in homogenizer after, in being 200 ℃ extruder, temperature carries out granulation; Top layer material modification resin is carried out drying at 90 ℃ to be handled; Described blowing agent is a sodium acid carbonate, and described anti-impact modifier is a haloflex, and described sliding agent is the mixture of stearic acid and paraffin; Described processing aid is the mixture of compound stabilizer, calcium carbonate and pigment;
B, be to plastify under 210 ℃ the condition the above-mentioned pellet of making in temperature;
C, the underlying material of above-mentioned plasticizing and dry top layer raw material are extruded 190 ℃ the time overlapping respectively by two co-extrusion machines, and got final product by draw-gear traction and forming press die mould.

Claims (6)

1. double-layer resin glazed tile, it is characterized in that: these glazed roof tile in the form of sheets or tabular, constitute by some crest and/or troughs that link to each other successively, described glazed roof tile are made of top layer and bottom, described top layer is made up of modified resin ASA, and bottom is made up of 60~80% Corvic, 1~3% blowing agent, 8~15% anti-impact modifiers, 2~5% sliding agents, 9~17% processing aids by weight percentage;
Described blowing agent is that azo-compound is or/and sodium acid carbonate; Described anti-impact modifier is a haloflex; Described sliding agent is one or more the mixture in OPE, stearic acid or the paraffin; Described processing aid is one or more the mixture in ACR, compound stabilizer, calcium carbonate or the pigment.
2. double-layer resin glazed tile according to claim 1 is characterized in that: two adjacent wave peaks of described glazed roof tile or the spacing between the trough are 65mm, and the vertical interval of crest and trough is 18mm.
3. double-layer resin glazed tile according to claim 1 is characterized in that: described skin depth is 0.1~0.3mm.
4. preparation method as the described double-layer resin glazed tile of claim 1~3 may further comprise the steps:
A, the bottom raw material for preparing is mixed the back in temperature is 170~200 ℃ extruder, carry out granulation; The top layer raw material is carried out drying to be handled;
B, be to plastify under 180~210 ℃ the condition the above-mentioned pellet of making in temperature;
C, the bottom raw material of above-mentioned plasticizing and dry top layer raw material are extruded 180~200 ℃ the time by two co-extrusion machines respectively, and top layer and the bottom extruded is overlapping, get final product by draw-gear traction and forming press die mould simultaneously.
5. the preparation method of double-layer resin glazed tile according to claim 4, it is characterized in that: the mixing among the described step a is to mix in mixer 10~15 minutes.
6. the preparation method of double-layer resin glazed tile according to claim 4, it is characterized in that: the baking temperature of described step b mesexine raw material is 60~90 ℃.
CN 201010202479 2010-06-09 2010-06-09 Double-layer resin glazed tile Pending CN101876193A (en)

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102617962A (en) * 2012-02-26 2012-08-01 新疆蓝山屯河型材有限公司 Color bending-resistant co-extruded section bar reflecting infrared rays and preparation method thereof
CN103965567A (en) * 2014-05-04 2014-08-06 安徽正隆新材料有限公司 PVC (Polyvinyl Chloride) synthetic resin tile
CN105331022A (en) * 2015-12-01 2016-02-17 贵州国塑科技管业有限责任公司 High-weatherability high-strength three-layer sound-insulating glazed tile and preparation method thereof
CN106284856A (en) * 2016-09-24 2017-01-04 成都九十度工业产品设计有限公司 A kind of corrosion-resisting resin watt
CN107513237A (en) * 2017-09-11 2017-12-26 广州市禾沣环保建材有限公司 A kind of wood plastic composite and its production technology with weatherability
CN107601963A (en) * 2017-09-27 2018-01-19 太仓经济开发区蕴源吉光工艺美术品工作室 Light glazed tile
CN107686608A (en) * 2017-08-11 2018-02-13 秦皇岛市地维建材有限公司 Hollow glass micropearl blending and modifying PVB/ABS resin tiles and preparation method thereof
CN108314861A (en) * 2018-02-08 2018-07-24 佛山市高筑瓦业有限公司 A kind of PVC thermal insulation tiles and preparation method thereof
CN108673987A (en) * 2018-04-13 2018-10-19 成都菲斯特新材料有限公司 A kind of imitative glaze color plastic glazed tiles and preparation method thereof
CN110195492A (en) * 2019-05-28 2019-09-03 安徽国邦永盛高分子科技有限公司 One kind having the function of VOC light degradation ASA synthetic resin watt and its preparation process
CN111088875A (en) * 2020-03-25 2020-05-01 广东奥悦斯科技有限公司 PVC tile and preparation method thereof
CN113248845A (en) * 2021-06-07 2021-08-13 佛山市越豪建材科技有限公司 APVC weather-resistant resin tile and manufacturing method thereof
CN113650391A (en) * 2021-07-28 2021-11-16 颍上县博浩塑业科技有限公司 Double-layer resin tile with sound insulation function and production device thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05318674A (en) * 1992-05-15 1993-12-03 Suminoe Textile Co Ltd Tile carpet having good shape stability and production thereof
CN2617572Y (en) * 2003-04-25 2004-05-26 佛山市红波建材有限公司 Atmospheric composite plastic board
CN1544235A (en) * 2003-11-14 2004-11-10 吴彩云 Production method and dies for plastic section material by different plastic material coextru lamination
CN1556140A (en) * 2004-01-05 2004-12-22 离石市欣欣实业有限公司 Hard polyvinyl chloride tile board and its manufacturing method
CN101143954B (en) * 2007-10-24 2010-07-14 华东理工大学 Polyvinyl chloride modified resin

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05318674A (en) * 1992-05-15 1993-12-03 Suminoe Textile Co Ltd Tile carpet having good shape stability and production thereof
CN2617572Y (en) * 2003-04-25 2004-05-26 佛山市红波建材有限公司 Atmospheric composite plastic board
CN1544235A (en) * 2003-11-14 2004-11-10 吴彩云 Production method and dies for plastic section material by different plastic material coextru lamination
CN1556140A (en) * 2004-01-05 2004-12-22 离石市欣欣实业有限公司 Hard polyvinyl chloride tile board and its manufacturing method
CN101143954B (en) * 2007-10-24 2010-07-14 华东理工大学 Polyvinyl chloride modified resin

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102617962A (en) * 2012-02-26 2012-08-01 新疆蓝山屯河型材有限公司 Color bending-resistant co-extruded section bar reflecting infrared rays and preparation method thereof
CN102617962B (en) * 2012-02-26 2014-06-11 新疆蓝山屯河型材有限公司 Color bending-resistant co-extruded section bar reflecting infrared rays and preparation method thereof
CN103965567A (en) * 2014-05-04 2014-08-06 安徽正隆新材料有限公司 PVC (Polyvinyl Chloride) synthetic resin tile
CN105331022A (en) * 2015-12-01 2016-02-17 贵州国塑科技管业有限责任公司 High-weatherability high-strength three-layer sound-insulating glazed tile and preparation method thereof
CN106284856A (en) * 2016-09-24 2017-01-04 成都九十度工业产品设计有限公司 A kind of corrosion-resisting resin watt
CN107686608A (en) * 2017-08-11 2018-02-13 秦皇岛市地维建材有限公司 Hollow glass micropearl blending and modifying PVB/ABS resin tiles and preparation method thereof
CN107513237A (en) * 2017-09-11 2017-12-26 广州市禾沣环保建材有限公司 A kind of wood plastic composite and its production technology with weatherability
CN107601963A (en) * 2017-09-27 2018-01-19 太仓经济开发区蕴源吉光工艺美术品工作室 Light glazed tile
CN108314861A (en) * 2018-02-08 2018-07-24 佛山市高筑瓦业有限公司 A kind of PVC thermal insulation tiles and preparation method thereof
CN108673987A (en) * 2018-04-13 2018-10-19 成都菲斯特新材料有限公司 A kind of imitative glaze color plastic glazed tiles and preparation method thereof
CN108673987B (en) * 2018-04-13 2020-06-30 成都菲斯特新材料有限公司 Glaze-like colored plastic glazed tile and preparation method thereof
CN110195492A (en) * 2019-05-28 2019-09-03 安徽国邦永盛高分子科技有限公司 One kind having the function of VOC light degradation ASA synthetic resin watt and its preparation process
CN111088875A (en) * 2020-03-25 2020-05-01 广东奥悦斯科技有限公司 PVC tile and preparation method thereof
CN111088875B (en) * 2020-03-25 2020-08-11 广东奥悦斯科技有限公司 PVC tile and preparation method thereof
CN113248845A (en) * 2021-06-07 2021-08-13 佛山市越豪建材科技有限公司 APVC weather-resistant resin tile and manufacturing method thereof
CN113650391A (en) * 2021-07-28 2021-11-16 颍上县博浩塑业科技有限公司 Double-layer resin tile with sound insulation function and production device thereof

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Open date: 20101103