CN101857981B - Process for producing nanometer bamboo carbon fiber by adopting polylactic acid group - Google Patents
Process for producing nanometer bamboo carbon fiber by adopting polylactic acid group Download PDFInfo
- Publication number
- CN101857981B CN101857981B CN201010151762A CN201010151762A CN101857981B CN 101857981 B CN101857981 B CN 101857981B CN 201010151762 A CN201010151762 A CN 201010151762A CN 201010151762 A CN201010151762 A CN 201010151762A CN 101857981 B CN101857981 B CN 101857981B
- Authority
- CN
- China
- Prior art keywords
- temperature
- polylactic acid
- spinning
- melt
- flange
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 235000017166 Bambusa arundinacea Nutrition 0.000 title claims abstract description 39
- 235000017491 Bambusa tulda Nutrition 0.000 title claims abstract description 39
- 241001330002 Bambuseae Species 0.000 title claims abstract description 39
- 235000015334 Phyllostachys viridis Nutrition 0.000 title claims abstract description 39
- 239000011425 bamboo Substances 0.000 title claims abstract description 39
- 229920000747 poly(lactic acid) Polymers 0.000 title claims abstract description 25
- 239000004626 polylactic acid Substances 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims abstract description 22
- 229920000049 Carbon (fiber) Polymers 0.000 title claims abstract description 12
- 239000004917 carbon fiber Substances 0.000 title claims abstract description 12
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- 238000005516 engineering process Methods 0.000 claims abstract description 9
- 239000000835 fiber Substances 0.000 claims description 33
- 239000003610 charcoal Substances 0.000 claims description 26
- 238000009987 spinning Methods 0.000 claims description 19
- 238000010438 heat treatment Methods 0.000 claims description 11
- 239000011858 nanopowder Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 238000000465 moulding Methods 0.000 claims description 6
- 238000009998 heat setting Methods 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 238000007654 immersion Methods 0.000 claims description 4
- 239000000155 melt Substances 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 238000007664 blowing Methods 0.000 claims description 3
- 238000005520 cutting process Methods 0.000 claims description 3
- 230000009477 glass transition Effects 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 238000007906 compression Methods 0.000 claims description 2
- 230000006835 compression Effects 0.000 claims description 2
- 235000019628 coolness Nutrition 0.000 claims description 2
- 238000002074 melt spinning Methods 0.000 claims description 2
- 238000012216 screening Methods 0.000 claims description 2
- 230000007613 environmental effect Effects 0.000 abstract description 6
- 238000000578 dry spinning Methods 0.000 abstract description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- 230000015556 catabolic process Effects 0.000 abstract 1
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 229920000297 Rayon Polymers 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- 150000001450 anions Chemical class 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 230000001877 deodorizing effect Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 208000035985 Body Odor Diseases 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229920000433 Lyocell Polymers 0.000 description 1
- 206010040904 Skin odour abnormal Diseases 0.000 description 1
- 208000013738 Sleep Initiation and Maintenance disease Diseases 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 206010003246 arthritis Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 206010022437 insomnia Diseases 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
Images
Landscapes
- Artificial Filaments (AREA)
Abstract
The invention discloses a process for producing nanometer bamboo carbon fiber by adopting a polylactic acid group. In the process, the nanometer bamboo carbon fiber is produced from polylactic acid as a carrier and nanometer bamboo carbon powder by a dry spinning technology. The nanometer bamboo carbon fiber produced by the invention has the advantages of greenness, environmental protection, easy recovery and degradation, low carbon emission during production, simple production process, easy operation and low cost.
Description
Technical field
The present invention relates to the process of suitability for industrialized production nanometer bamboo carbon fiber, specifically is the process that adopts polylactic acid based production nanometer bamboo carbon fiber.
Background technology
In modern society, research and produce ecological with the healthy functional textile that is beneficial to man and become a kind of trend.Bamboo charcoal is a kind of new function material, has the environment-friendly materials of excellent performance, has the good reputation of " black diamond ", is described as " the new bodyguard of the environmental protection of 21 century " in the world, is the brand-new developing direction that bamboo timber resource effectively utilizes.Bamboo-carbon fibre is to select nano bamboo powder (bamboo charcoal micropowder) for use, and it is added in section or the spinning solution again through the approximate spun fibre new species of conventional spinning technique through special process.
Bamboo-carbon fibre and the fabric of processing thereof have function and effects such as absorbing and deodorizing, antibacterial mildew-resistant, emission far infrared, anion.According to surveying and determination, there are micropore, mesopore and macropore in bamboo-carbon fibre inside, and specific area is big.1cm
3The specific area of bamboo charcoal can reach 350m
2, make the bamboo charcoal textiles can adsorb multiple pernicious gas, eliminate body odor and airborne peculiar smell.Bamboo-carbon fibre can continue to discharge anion, through detecting, when measuring distance 1cm, discharges 2000/cm of anion
3, during measuring distance 2cm, discharge 1600/cm of anion
3Bamboo-carbon fibre can absorb and the far infrared that radiates 4-14 μ m again, and the growth of the far infrared of this section wavelength and biology has utmost point confidential relation, so be called " fertility light " or " growth light " again.Far infrared is absorbed by the body easily, can increase the microvascular blood circulation of human body surface, and the effect that have heat accumulation thermal, enhances metabolism there is obvious effect for prevention and treatment of arthritis, insomnia etc.Except that above premium properties, bamboo-carbon fibre also has characteristics such as environmental protection, electrostatic screen, antibacterial and mouldproof, and grey, the black of the nature that all has of bamboo-carbon fibre, do not need to make it dyeing, does not contain the harmful substance of chemical dye, so environment protection health.
2003, egression chemical fibre group in Xinxiang, Henan successfully developed bamboo-carbon viscose fibre.The fragrant charcoal nanoscale of the bamboo micro mist that this fiber adopts the hill mao bamboon of China's south high-quality to process is a raw material, is added in the viscose glue, is made through special process.In the same year, Shanghai Hualy Superfines Science and Technology Co.,Ltd. of East China University of Science has released a bamboo-carbon fibre new varieties.This fiber is to process at the ultra-fine bamboo charcoal additive that fiber surface is coated a kind of pure natural.Since 2004, the Taiwan is also reported successively has New-type bamboo charcoal fibre to come out.Weaving center, Taiwan utilizes nanometer technology with bamboo charcoal micropowderization, incorporates bamboo charcoal in the polyester fiber equably through the melt spinning program, thereby processes bamboo-carbon fibre.2005, Japanese natural science magazine reported that Japan produces 500 purpose bamboo-carbon fibres, and its processing method is that bamboo charcoal is processed as the first step, then bamboo fibre is elongated and with weave ins such as chemical fibre, cotton thread.2006, the great strong color polyester in Shangyu, Zhejiang Co., Ltd successfully developed the multifunction environment-protection type bamboo-carbon fibre.The processing of this bamboo-carbon fibre is after pure oxygen high temperature intercepts the novel technique processing with nitrogen through moment the above bamboo of life in 5 years; Pass through physical method; Make its particle diameter reach micron order; Polyester modified section after handling through the particular polymeric technology is fused among the spinning melt then, processes bamboo-carbon fibre through spinning again.
PLA (being called for short PLA) is to be the resulting high molecular polymer of main raw material polymerization with lactic acid.And the raw material of lactic acid is the material of all carbohydrate enrichments, and for example corn, potato and organic waste etc. can constantly be regenerated, therefore inexhaustible.Acid fiber by polylactic is the tencel cellulose fiber that the polylactic resin section is processed through the melting spinning.It is the environmentally friendly regenerated celulose fibre of a kind of intrinsic antibiotic property of not adding all harmful chemicals and anti-flammability, weather fastness.Detect according to the charcoal discharge capacity, the regenerated celulose fibre viscose that adopts traditional viscose process production is 14680CO
2Kg/t, to represent the polyester of synthetic fiber be 6443 CO
2Kg/t, and acid fiber by polylactic 3650 CO only
2Kg/t, its carrying capacity of environment characteristic is remarkable.
Discuss according to the front, can know that traditional bamboo-carbon fibre produces used carrier and be mainly viscose glue and two kinds of polyester, its charcoal discharge capacity occupies high, and the oil product resource is nervous, is difficult for degrading.The acid fiber by polylactic recyclable regenerative, aboundresources, intrinsic antibiotic property and characteristics such as anti-flammability, weather, environment protection health.
Summary of the invention
The invention provides a kind of process that adopts polylactic acid based production nanometer bamboo carbon fiber; Be that the employing PLA is a carrier; Add the bamboo charcoal nano powder, utilize the dry spinning technology to produce environmental protection, be prone to the nanometer bamboo carbon fiber process that reclaims, is prone to degraded, produces low charcoal discharging.
The technical scheme of invention is down:
Adopt the process of polylactic acid based production nanometer bamboo carbon fiber, may further comprise the steps:
(1), with polylactic acid slice and bamboo charcoal nano powder by the mass percent of 95-97%:3-5% mix mixed material; Mixed material carries out the heating, vacuum drying; Dry process conditions are: descended predrying 100-140 minute at 103-107 ℃, be warmed up to 118-122 ℃ of dry 6.5-7.5 hour then;
(2), dried mixed material is transported in six casees screw extruders carries out heating and melting through one to six the casees successively and get melt; One to six casees temperature is set to respectively successively: 158-162 ℃, 180-190 ℃, 170-180 ℃, 165-175 ℃, 165-175 ℃, 170-180 ℃; Then melt Conveying is got in the filament spinning component flange and continue heating at 170-180 ℃; With the melt that continues to obtain after the heating carry out spinning, wire vent gets long filament, spinning temperature is 170-180 ℃;
(3), with long filament through cooling forming; The long filament of moulding through seal wire, oil, doff; Long filament behind the doff stretches drawing of fiber 3.5-4 times that obtains long filament through boundling immersion oil, 55-65 ℃ following water-bath drawing-off, physics then; Silk is wide through regulating then, coiling, HEAT SETTING, cooling, cut-out, packing, finished product.
The molecular weight of described polylactic acid slice is 33.5 ten thousand, and fusing point is 155-165 ℃, and degree of crystallinity is 74-78%, and glass transition temperature is 58-59 ℃, and the L-content of isomer of section molecule is more than 99%; The particle diameter of described bamboo charcoal nano powder is 90-100nm, and the screening particle diameter is the 15000-18000 order.
Described spinning, wire vent are to be spinning after 165-175 ℃ filter is conveyed into manifold with melt through temperature, are that compression pump, the frequency of 10-20Mpa is the measuring pump of 40-50HZ through excess pressure then, supply with spinning pack uniformly, by nozzle ejection silk; Described cooling forming adopts low temperature ring blowing carrying out cooling forming, and temperature 19-21 ℃, wind speed are 0.22-0.27m/s; The finish addition of described boundling immersion oil is 5-7kg/T; It is to carry out the physics stretching through deflector roll and take up roll that described physics stretches, and the deflector roll frequency is 20-30HZ, and the take up roll frequency is 20-25HZ; Described adjusting silk is wide to be with the wide silk ribbon of furnishing 100mm on tension bracket of the long filament after the drawing-off; Described coiling is to reel with 800-1200m/min speed; Described HEAT SETTING is that the silk after reeling is come on the lax heat setting machine, utilizes vapours to carry out dryness finalization through baking oven 1 and 2 pairs of long filaments of baking oven successively, and the temperature of baking oven 1 is 75-85 ℃, and the temperature of baking oven 2 is 80-90 ℃; Described cut-out is to cut off through cutting machine with the speed of 90-110m/min.
Six casees screw extruders of the present invention are to be produced by Anhui Nanao Carpet Co., Ltd., and model is JLG120.
Polylactic acid slice of the present invention is to be produced with victory Science and Technology Ltd. by Anhui; Described bamboo charcoal nano powder is commercially available by Shanghai Keruisen Environmental Protection Technology Co., Ltd..
The present invention has following advantage:
1, raw material sources are wide, and PLA belongs to regenerated celulose fibre, are regenerated resources, and the production process greenization does not have the oilization of genus;
2, the PLA energy consumption is low, and the charcoal discharge capacity is merely 3650 CO
2Kg/t, less than 1/3 of viscose glue, 1/2 of about polyester, its carrying capacity of environment characteristic is remarkable;
3, biological degradability is good, and is free from environmental pollution, and can reclaim granulation again after the bamboo charcoal nano powder of the present invention use, realizes reclaiming spinning 2 times, economizes on resources;
4, the fiber of bamboo charcoal nano and the fabric processed thereof have function and effects such as absorbing and deodorizing, antibacterial mildew-resistant, emission far infrared, anion, belong to green functional property new material.
Description of drawings
Fig. 1 doesProcess chart of the present invention.
The specific embodiment
Adopt the process of polylactic acid based production nanometer bamboo carbon fiber, comprise following processing step:
(1), the apolegamy of raw material:
The polylactic acid slice that the present invention uses is come Anhui and is won Science and Technology Ltd.'s self-control, and molecular weight is 33.5 ten thousand, 162 ℃ of fusing points, and degree of crystallinity is about 76%, 58.5 ℃ of glass transition temperatures, the L-content of isomer of section molecule is more than 99%; The bamboo charcoal nano powder is commercially available black 18000 orders of Shanghai Keruisen Environmental Protection Technology Co., Ltd., the specification of 100nm; The mass ratio of polylactic acid slice and bamboo charcoal nano powder is among the present invention: polylactic acid slice 95%, bamboo charcoal nano powder 5%.
(2), raw materials mix oven dry:
The ratio that polylactic acid slice and bamboo charcoal nano powder gather (1) according to the step is mixed, render to vacuum drier then and carry out heat drying.Dry technology does, predrying temperature is 106 ℃, and be 2.5 hours drying time; Stretch temperature then to 120 ℃, dry 7 hours.Dried polylactic acid slice moisture content remains on below the 30ppm.
(3), melt spinning:
The mixed material that is gathered (2) middle drying the step is transported to and carries out heating and melting in six casees screw extruders, and the temperature of the temperature of control from one to six each case is respectively: 160 ℃, 185 ℃, 175 ℃, 170 ℃, 170 ℃, 175 ℃.Raw materials melt through after the screw extruder heating becomes melt, and melt Conveying is got in the filament spinning component flange (flange divides three zones: big flange, flange 1, flange 2) continue heating again, be that the melt melted by heating is more even.Its control temperature is: 175 ℃.Get into manifold (temperature is 175 ℃) through the melt Conveying behind the flange assembly through filter (temperature is 172 ℃) and carry out spinning.Melt gets into manifold after excess pressure pump (pressure is 17Mpa), measuring pump (frequency is 45HZ) are supplied with spinning pack uniformly, by nozzle ejection silk.
(4), cold and hot moulding:
By the long filament of spinneret ejection, adopt the blowing of low temperature ring to cool off (20 ℃ of temperature, wind speed are 0.25m/s) moulding.When the long filament of moulding passes through the deflector roll seal wire, utilize deflector roll to oil, give a silk doff then.Long filament behind the doff is again through creel boundling (30) immersion oil, through water-bath, oil bath two procedures, through deflector roll and take up roll with 3.6 times of tensile fibers.Wherein bath temperature is: 604 ℃, the finish addition is 6kg/T, deflector roll frequency: 25HZ, take up roll frequency: 25HZ.With the silk wide silk ribbon of furnishing 100mm on tension bracket after the drawing-off, reel with 1000m/min speed.The silk of reeling is come on the lax heat setting machine, utilize vapours let the long filament dryness finalization through baking oven 1 and 2 (temperature is respectively 80 ℃, 85 ℃).After baking oven 3 coolings, cut off through cutting machine with the speed of 100m/min, wind send packing again.
Claims (1)
1. adopt the process of polylactic acid based production nanometer bamboo carbon fiber, it is characterized in that: may further comprise the steps:
(1), raw materials mix oven dry:
Polylactic acid slice and bamboo charcoal nano powder are mixed by 95%: 5% mass percent, render to vacuum drier then and carry out heat drying, dry technology is: predrying temperature is 106 ℃, and be 2.5 hours drying time; Be warmed up to 120 ℃ then, dry 7 hours; Dried polylactic acid slice moisture content remains on below the 30ppm;
Wherein, the molecular weight of polylactic acid slice is 33.5 ten thousand, 162 ℃ of fusing points, and degree of crystallinity 76%, 58.5 ℃ of glass transition temperatures, the L-content of isomer of section molecule is more than 99%; The particle diameter of bamboo charcoal nano powder is 100nm, and the screening particle diameter is 18000 orders;
(2), melt spinning:
The mixed material that is gathered (1) middle drying the step is transported to and carries out heating and melting in six casees screw extruders, and the temperature of the temperature of control from one to six each case is respectively: 160 ℃, 185 ℃, 175 ℃, 170 ℃, 170 ℃, 175 ℃;
Raw materials melt through after the screw extruder heating becomes melt, melt Conveying is got into continue heating in the filament spinning component flange again, and flange is divided into big flange, flange 1 and 2 three zones of flange, and its control temperature is 175 ℃;
Get into manifold through the melt Conveying behind the flange assembly through filter and carry out spinning, filter temperature is 172 ℃, and condition of spinning manifold temperature is 175 ℃;
Melt gets into manifold after excess pressure pump, measuring pump are supplied with spinning pack uniformly, and by nozzle ejection silk, compression pump pressure is 17Mpa, and the measuring pump frequency is 45HZ;
(3), cold and hot moulding:
By the long filament of spinneret ejection, adopt the blowing of low temperature ring to carry out cooling forming, temperature is 20 ℃, wind speed is 0.25m/s;
When the long filament of moulding passes through the deflector roll seal wire, utilize deflector roll to oil, give a silk doff then;
Long filament behind the doff is again through 30 immersion oil of creel boundling, and through water-bath, oil bath two procedures, with 3.6 times of tensile fibers, wherein bath temperature is 604 ℃ through deflector roll and take up roll, and the finish addition is 6kg/T, and the deflector roll frequency is 25HZ, and the take up roll frequency is 25HZ;
With the silk wide silk ribbon of furnishing 100mm on tension bracket after the drawing-off, reel with 1000m/min speed;
The silk of reeling is come on the lax heat setting machine, utilize vapours to let long filament dryness finalization, baking oven 1 and 2 temperature be respectively 80 ℃, 85 ℃ through baking oven 1 and 2;
After after baking oven 3 coolings, cut off through cutting machine with the speed of 100m/min, wind send packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010151762A CN101857981B (en) | 2010-04-20 | 2010-04-20 | Process for producing nanometer bamboo carbon fiber by adopting polylactic acid group |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010151762A CN101857981B (en) | 2010-04-20 | 2010-04-20 | Process for producing nanometer bamboo carbon fiber by adopting polylactic acid group |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101857981A CN101857981A (en) | 2010-10-13 |
| CN101857981B true CN101857981B (en) | 2012-10-03 |
Family
ID=42944133
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010151762A Active CN101857981B (en) | 2010-04-20 | 2010-04-20 | Process for producing nanometer bamboo carbon fiber by adopting polylactic acid group |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101857981B (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102691152A (en) * | 2012-05-22 | 2012-09-26 | 宋朔 | Off-line steam drawing process method of polyacrylonitrile-based protofilament |
| CN103088552B (en) * | 2013-02-05 | 2014-12-17 | 宁波市奇兴无纺布有限公司 | Manufacturing technology of polyethylene spunbond cloth |
| CN103526375B (en) * | 2013-10-26 | 2016-02-17 | 上海婉静纺织科技有限公司 | Far infrared polylactic acid fiber home textile fabric |
| CN105463589B (en) * | 2016-01-11 | 2018-02-16 | 河南省龙都生物科技有限公司 | Bamboo charcoal particles of polylactic acid spinning technique |
| CN105504236B (en) * | 2016-01-11 | 2018-06-26 | 河南省龙都生物科技有限公司 | Polylactic acid bamboo charcoal is sliced production technology |
| CN105463588B (en) * | 2016-01-11 | 2018-02-16 | 河南省龙都生物科技有限公司 | Bamboo charcoal polylactic acid melt direct spinning |
| CN105671648B (en) * | 2016-01-11 | 2018-03-23 | 河南省龙都生物科技有限公司 | Bamboo charcoal micropowder polylactic acid slice produces fibre technology |
| CN108060466A (en) * | 2017-12-15 | 2018-05-22 | 衢州瀚心科技有限公司 | Newborn traditional instrument charcoal anti-biotic material and preparation method thereof and newborn traditional instrument charcoal antibacterial sanitary napkin |
| CN109647674B (en) * | 2019-01-26 | 2019-08-02 | 三门县旭月日用品有限公司 | A kind of PVC electrostatic flocked glove and its processing method |
| CN113981562A (en) * | 2021-10-15 | 2022-01-28 | 安徽元琛环保科技股份有限公司 | Preparation method of nano activated carbon particle doped PLA (polylactic acid) bio-based degradable fiber filter material for industrial flue gas |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1814867A (en) * | 2006-02-24 | 2006-08-09 | 兰平 | Method for preparing polyactide fiber filament |
| US20080139069A1 (en) * | 2006-12-06 | 2008-06-12 | Taiwan Textile Research Institute | Spunbond non-woven containing bamboo charcoal and method for fabricating the same |
| CN101307510A (en) * | 2007-05-18 | 2008-11-19 | 上海德福伦化纤有限公司 | Process for preparing bamboo charcoal fiber |
| CN101311390A (en) * | 2008-06-11 | 2008-11-26 | 浙江恒逸集团有限公司 | Production process of bamboo charcoal polyester fibres |
| CN101602882A (en) * | 2008-06-13 | 2009-12-16 | 中国科学院宁波材料技术与工程研究所 | Bamboo powder filled biomass-based resin composite material and preparation method thereof |
-
2010
- 2010-04-20 CN CN201010151762A patent/CN101857981B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1814867A (en) * | 2006-02-24 | 2006-08-09 | 兰平 | Method for preparing polyactide fiber filament |
| US20080139069A1 (en) * | 2006-12-06 | 2008-06-12 | Taiwan Textile Research Institute | Spunbond non-woven containing bamboo charcoal and method for fabricating the same |
| CN101307510A (en) * | 2007-05-18 | 2008-11-19 | 上海德福伦化纤有限公司 | Process for preparing bamboo charcoal fiber |
| CN101311390A (en) * | 2008-06-11 | 2008-11-26 | 浙江恒逸集团有限公司 | Production process of bamboo charcoal polyester fibres |
| CN101602882A (en) * | 2008-06-13 | 2009-12-16 | 中国科学院宁波材料技术与工程研究所 | Bamboo powder filled biomass-based resin composite material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101857981A (en) | 2010-10-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101857981B (en) | Process for producing nanometer bamboo carbon fiber by adopting polylactic acid group | |
| CN101724265B (en) | Denier/superfine denier nylon master granule, preoriented yarn (POY) and draw textured yarn (DTY) stretch yarn and preparation method thereof | |
| CA3005917C (en) | Modified fiber and preparation method therefor | |
| CN101735608B (en) | Hydroscopic fine denier/superfine denier chinlon master batch, chinlon POY filaments and preparation method thereof | |
| CN104532387A (en) | Low-melting-point colored special-shaped polyester filament and preparation method thereof | |
| CN102586933A (en) | Method for preparing polyester staple fibers by using waste polyester raw material | |
| CN102168320A (en) | Production technology for producing porous fine denier colored terylene pre-oriented filament by utilizing recycled polyester bottle flakes | |
| CN109706546B (en) | Graphene sea-island fiber and manufacturing method thereof | |
| CN101503832A (en) | Method for processing high shrinkage superfine denier polyester staple fiber | |
| CN103305960A (en) | Method for manufacturing polyester staple fibers through recycled polyester bottles | |
| CN104532388A (en) | Colored special-shaped size-stabilized type polyester monofilament and preparation method thereof | |
| CN102864511A (en) | Method for producing hollow colored terylene pre-oriented filament yarn through recyclable polyester bottle pieces | |
| CN106400175A (en) | Production method of pre-spinning colored high-shrinkage polyester FDYs (Fully Drawn Yarns) | |
| CN107217319A (en) | A kind of regenerated terylene draw textured yarn, its production method and regeneration polar fleece fabric | |
| CN109234820A (en) | A kind of preparation method of polylactic acid short-fiber | |
| CN109023564A (en) | A kind of preparation method of polylactic acid coloured cut staple | |
| CN111979645A (en) | Bio-based polyester non-woven fabric and preparation method thereof | |
| CN102425015B (en) | Method for preparing fibers with performance of sheep wool and imitated wool fabric | |
| KR20170103281A (en) | Method for producing the 4-hole hollow-fiber used R-PET | |
| CN109706545B (en) | Microporous hollow graphene sea-island fiber and manufacturing method thereof | |
| CN103590140B (en) | A kind of imitative multiple polyisocyanate of linen look is combined short fibre and manufacture method thereof | |
| CN102912461A (en) | Method for producing antibacterial fire-resistant polyester filaments by utilizing recycled polyester bottle chips | |
| CN110129901A (en) | A kind of preparation method of creeping chill fiber | |
| CN103938285A (en) | Modified nylon-6 cool DTY filament production method | |
| CN109440223A (en) | A kind of wet fiber material preparation method of spiral porous structure |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20101013 Assignee: ANHUI HANLIAN TEXTILE CO., LTD. Assignor: Anhui Hesheng New Material Technology Co., Ltd. Contract record no.: 2013340000006 Denomination of invention: Process for producing nanometer bamboo carbon fiber by adopting polylactic acid group Granted publication date: 20121003 License type: Exclusive License Record date: 20130206 |
|
| LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160215 Address after: 236700 No. 22 West Yongxing Road, Lixin County Industrial Park, Anhui, Bozhou Patentee after: ANHUI HANLIAN TEXTILE CO., LTD. Address before: 230088 D-608 room, National University Science Park, 602 Mount Huangshan Road, Hefei hi tech Zone, Anhui, China Patentee before: Anhui Hesheng New Material Technology Co., Ltd. |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Process for producing nanometer bamboo carbon fiber by adopting polylactic acid group Effective date of registration: 20170728 Granted publication date: 20121003 Pledgee: Lixin Anhui rural commercial bank Limited by Share Ltd Pledgor: ANHUI HANLIAN TEXTILE CO., LTD. Registration number: 2017340000134 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 236700 No. 22 West Yongxing Road, Lixin County Industrial Park, Anhui, Bozhou Patentee after: Anhui Han Lian color textile Limited by Share Ltd Address before: 236700 No. 22 West Yongxing Road, Lixin County Industrial Park, Anhui, Bozhou Patentee before: ANHUI HANLIAN TEXTILE CO., LTD. |
|
| CP01 | Change in the name or title of a patent holder |