CN101857944A - Anode steel claw material for aluminum electrolysis - Google Patents
Anode steel claw material for aluminum electrolysis Download PDFInfo
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- CN101857944A CN101857944A CN 201010206978 CN201010206978A CN101857944A CN 101857944 A CN101857944 A CN 101857944A CN 201010206978 CN201010206978 CN 201010206978 CN 201010206978 A CN201010206978 A CN 201010206978A CN 101857944 A CN101857944 A CN 101857944A
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- Prior art keywords
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- steel claw
- anode steel
- percent
- anode
- Prior art date
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 49
- 239000010959 steel Substances 0.000 title claims abstract description 49
- 239000000463 material Substances 0.000 title claims abstract description 37
- 210000000078 claw Anatomy 0.000 title claims abstract description 20
- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 18
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title abstract description 12
- 229910052782 aluminium Inorganic materials 0.000 title abstract description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 12
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 10
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 10
- 239000011572 manganese Substances 0.000 claims abstract description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 9
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052802 copper Inorganic materials 0.000 claims abstract description 9
- 239000010949 copper Substances 0.000 claims abstract description 9
- 229910052742 iron Inorganic materials 0.000 claims abstract description 9
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 9
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 9
- 239000010703 silicon Substances 0.000 claims abstract description 9
- 229910052804 chromium Inorganic materials 0.000 claims description 9
- 239000011651 chromium Substances 0.000 claims description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000005864 Sulphur Substances 0.000 claims description 8
- 229910052698 phosphorus Inorganic materials 0.000 claims description 8
- 239000011574 phosphorus Substances 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000005275 alloying Methods 0.000 abstract description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 238000010114 lost-foam casting Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 2
- 229910001051 Magnalium Inorganic materials 0.000 description 1
- 244000070406 Malus silvestris Species 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
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- Electrolytic Production Of Metals (AREA)
Abstract
The invention discloses an anode steel claw material for aluminum electrolysis, and relates to the anode steel claw material for the aluminum electrolysis which can reduce anode steel claw pressure drop. The anode steel claw material is characterized by comprising the following components in percentage by weight: 0.05 to 0.12 percent of carbon, 0.25 to 0.5 percent of manganese, 0.05 to 0.37 percent of silicon, 0 to 0.1 percent of copper, less than 0.05 percent of phosphor, less than 0.05 percent of sulfur, less than 0.1 percent of chrome, less than 0.05 percent of nickel (Ni) and the balance of iron. In the anode steel claw material for the aluminum electrolysis, by re-designing the alloying element content of the steel claw material and particularly reducing the elements, such as carbon, manganese and the like, the resistivity of the steel claw and anode steel claw pressure drop are reduced and the production cost is effectively reduced.
Description
Technical field
A kind of anode steel claw material for aluminum electrolysis relates to a kind of anode steel claw material for aluminum electrolysis that can reduce the anode steel jaw pressure drop.
Background technology
In the production process of electrolysis of aluminum, anode is described as " electrolytic heart ", and as one of vitals of anode assembling, and the pressure drop of anode steel jaw is determining the power consumption of ton aluminium to a certain extent.
The material of early stage anode steel jaw mainly is ZG230-450, and it is all higher that this material contains the kind and the quantity of alloying element, thereby resistivity is bigger, and the pressure drop of steel pawl is also higher; Recently, Kweiyang magnalium designing institute has designed the new anode steel jaw (patent No.: 200510200136.8) with ZG200-400 for material, new material is compared with original material, steel interalloy composition decreases, the conductive capability of material slightly increases, but its steel pawl pressure drop still maintains in the higher numerical range.Pingguo, Guangxi Aluminum has been invented a kind of Energy-saving model anodic steel claw, and (patent No.: 200310117269.X), the crossbeam of this steel pawl is a skeleton with aluminium, and the surface has wrapped Plate Steel, links together by welding and pawl.The application of this steel pawl has reduced pressure drop in a short time to a certain extent, but along with the increase of life cycle, because the difference of the steel and the aluminothermy coefficient of expansion, makes to produce the gap between the contact surface of steel and aluminium, has caused pressure drop not fall counter increasing.
Summary of the invention
The object of the invention is exactly the deficiency that exists at above-mentioned prior art, and the electroconductibility that can effectively improve anode steel jaw is provided, and reduces the pressure drop of steel pawl, reaches the purpose electrolysis anode steel claw material that saves production cost.
The objective of the invention is to be achieved through the following technical solutions.
A kind of electrolysis anode steel claw material is characterized in that the weight percent of this material consists of: carbon 0.05%-0.12%, manganese 0.25%-0.5%, silicon 0.05%-0.37%, copper 0-0.1%, phosphorus are less than 0.05%, and sulphur is less than 0.05%, chromium is less than 0.1%, and Ni is less than 0.05%, and all the other are iron.
A kind of electrolysis anode steel claw material of the present invention, optimize, designed the composition and the alloying element content of steel pawl material, especially elements such as carbon, chromium have been reduced, by reducing carbon, the manganese content in the steel claw material, and interpolation copper increases conductivity, reduce the resistivity of steel pawl, effectively reduced the production cost of enterprise.
Embodiment
A kind of electrolysis anode steel claw material, the weight percent of this material consists of: carbon 0.05%-0.12%, manganese 0.25%-0.5%, silicon 0.05%-0.37%, copper 0-0.1%, phosphorus are less than 0.05%, and sulphur is less than 0.05%, chromium is less than 0.1%, and Ni is less than 0.05%, and all the other are iron.
Embodiment 1
Electrolysis is formed with the weight of the selected material of anode steel jaw and is comprised carbon 0.07%, and manganese 0.25%, silicon 0.05%, copper 0.1%, phosphorus are less than 0.05%, and sulphur is less than 0.05%, and chromium is less than 0.1%, and Ni is less than 0.05%, and all the other are iron.Select lost foam casting process for use, anode steel jaw is through cast form.The low 0.129 μ Ω .m that reaches of the resistivity of the material of new shaped steel pawl.
Embodiment 2
Electrolysis is formed with the weight of the selected material of anode steel jaw and is comprised carbon 0.05%, and manganese 0.30%, silicon 0.06%, copper 0.08%, phosphorus are less than 0.05%, and sulphur is less than 0.05%, and chromium is less than 0.1%, and Ni is less than 0.05%, and all the other are iron.Select sand mold shape casting technology for use, anode steel jaw is through cast form.The low 0.130 μ Ω .m that reaches of the resistivity of the material of new shaped steel pawl.
Embodiment 3
Electrolysis is formed with the weight of the selected material of anode steel jaw and is comprised carbon 0.09%, and manganese 0.35%, silicon 0.08%, copper 0.06%, phosphorus are less than 0.05%, and sulphur is less than 0.05%, and chromium is less than 0.1%, and Ni is less than 0.05%, and all the other are iron.Select lost foam casting process for use, anode steel jaw is through cast form.The low 0.132 μ Ω .m that reaches of the resistivity of the material of new shaped steel pawl.
Embodiment 4
The electrolysis selected material of anode steel jaw, the weight percent of this material consists of: carbon 0.05%, manganese 0.25% silicon 0.05%, copper 0.1%, phosphorus are less than 0.05%, and sulphur is less than 0.05%, and chromium is less than 0.1%, and Ni is less than 0.05%, and all the other are iron.Select lost foam casting process for use, anode steel jaw is through cast form.The low 0.13 μ Ω .m that reaches of the resistivity of the material of new shaped steel pawl.
Embodiment 5
A kind of electrolysis anode steel claw material, the weight percent of this material consists of: carbon 0.12%, manganese 0.5%, silicon 0.37%, phosphorus are less than 0.05%, and sulphur is less than 0.05%, and chromium is less than 0.1%, and Ni is less than 0.05%, and all the other are iron.Select lost foam casting process for use, anode steel jaw is through cast form.The low 0.131 μ Ω .m that reaches of the resistivity of the material of new shaped steel pawl.
Claims (1)
1. an electrolysis anode steel claw material is characterized in that the weight percent of this material consists of: carbon 0.05%-0.12%, manganese 0.25%-0.5%, silicon 0.05%-0.37%, copper 0-0.1%, phosphorus are less than 0.05%, and sulphur is less than 0.05%, chromium is less than 0.1%, and Ni is less than 0.05%, and all the other are iron.
Priority Applications (1)
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CN 201010206978 CN101857944A (en) | 2010-06-13 | 2010-06-13 | Anode steel claw material for aluminum electrolysis |
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CN 201010206978 CN101857944A (en) | 2010-06-13 | 2010-06-13 | Anode steel claw material for aluminum electrolysis |
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CN 201010206978 Pending CN101857944A (en) | 2010-06-13 | 2010-06-13 | Anode steel claw material for aluminum electrolysis |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102628148A (en) * | 2012-05-09 | 2012-08-08 | 武汉钢铁(集团)公司 | Acid-washing hot-rolled low-carbon steel without line defects on surface and production method thereof |
CN103305747A (en) * | 2013-06-26 | 2013-09-18 | 李会民 | Steel bar or steel claw section for electric conduction of electrolytic aluminum and manufacturing method of steel bar or steel claw section |
CN106521557A (en) * | 2016-11-01 | 2017-03-22 | 秦皇岛秦冶重工有限公司 | Anode steel stud for electrolytic aluminum |
CN109338228A (en) * | 2018-11-21 | 2019-02-15 | 钢铁研究总院 | A kind of high conductivity anode steel claw steel and preparation method thereof |
CN115747679A (en) * | 2022-08-23 | 2023-03-07 | 云南云铝绿源慧邦工程技术有限公司 | Preparation method of high-performance microalloyed anode steel claw |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1791694A (en) * | 2003-05-21 | 2006-06-21 | 住友金属工业株式会社 | Steel pipe for an airbag system and a method for its manufacture |
-
2010
- 2010-06-13 CN CN 201010206978 patent/CN101857944A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1791694A (en) * | 2003-05-21 | 2006-06-21 | 住友金属工业株式会社 | Steel pipe for an airbag system and a method for its manufacture |
Non-Patent Citations (2)
Title |
---|
《Journal of Magnetism and Magnetic Materials》 20041231 F.Kovac ETAL. Columnar grain growth in non-oriented electrical steels 333-340 1 第269卷, 2 * |
《METALLURGICAL AND MATERIALS TRANSACTIONS A》 19990131 DONG-KUK KIM ETAL. Analysis and Prevention of Cracking Phenomenon Occurring during Cold Forging of Two AISI 1010 Steel Pulleys 第82页表1 A-Steel 1 第30A卷, 2 * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102628148A (en) * | 2012-05-09 | 2012-08-08 | 武汉钢铁(集团)公司 | Acid-washing hot-rolled low-carbon steel without line defects on surface and production method thereof |
CN102628148B (en) * | 2012-05-09 | 2013-09-11 | 武汉钢铁(集团)公司 | Acid-washing hot-rolled low-carbon steel without line defects on surface and production method thereof |
CN103305747A (en) * | 2013-06-26 | 2013-09-18 | 李会民 | Steel bar or steel claw section for electric conduction of electrolytic aluminum and manufacturing method of steel bar or steel claw section |
CN103305747B (en) * | 2013-06-26 | 2016-10-05 | 李会民 | A kind of rod iron for electric conduction of electrolytic aluminum, steel claw type material and manufacture method thereof |
CN106521557A (en) * | 2016-11-01 | 2017-03-22 | 秦皇岛秦冶重工有限公司 | Anode steel stud for electrolytic aluminum |
CN109338228A (en) * | 2018-11-21 | 2019-02-15 | 钢铁研究总院 | A kind of high conductivity anode steel claw steel and preparation method thereof |
CN115747679A (en) * | 2022-08-23 | 2023-03-07 | 云南云铝绿源慧邦工程技术有限公司 | Preparation method of high-performance microalloyed anode steel claw |
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Open date: 20101013 |