CN101845223B - Silicone high-density elastomer and production method thereof - Google Patents
Silicone high-density elastomer and production method thereof Download PDFInfo
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- CN101845223B CN101845223B CN2010101643560A CN201010164356A CN101845223B CN 101845223 B CN101845223 B CN 101845223B CN 2010101643560 A CN2010101643560 A CN 2010101643560A CN 201010164356 A CN201010164356 A CN 201010164356A CN 101845223 B CN101845223 B CN 101845223B
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- silicone
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- 229920001296 polysiloxane Polymers 0.000 title claims abstract description 71
- 229920001971 elastomer Polymers 0.000 title claims abstract description 24
- 239000000806 elastomer Substances 0.000 title claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000000463 material Substances 0.000 claims abstract description 118
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 60
- -1 polysiloxane Polymers 0.000 claims abstract description 45
- 239000003054 catalyst Substances 0.000 claims abstract description 36
- 239000000843 powder Substances 0.000 claims abstract description 33
- 239000003063 flame retardant Substances 0.000 claims abstract description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 28
- 229920002554 vinyl polymer Polymers 0.000 claims description 26
- 125000000217 alkyl group Chemical group 0.000 claims description 22
- 229910052739 hydrogen Inorganic materials 0.000 claims description 20
- 239000001257 hydrogen Substances 0.000 claims description 20
- 229910052697 platinum Inorganic materials 0.000 claims description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 17
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 17
- 239000000377 silicon dioxide Substances 0.000 claims description 14
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 12
- RFAFBXGYHBOUMV-UHFFFAOYSA-N calcium chromate Chemical compound [Ca+2].[O-][Cr]([O-])(=O)=O RFAFBXGYHBOUMV-UHFFFAOYSA-N 0.000 claims description 12
- 239000000049 pigment Substances 0.000 claims description 12
- 229910052703 rhodium Inorganic materials 0.000 claims description 11
- 239000010948 rhodium Substances 0.000 claims description 11
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 11
- 239000004615 ingredient Substances 0.000 claims description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 9
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 6
- 239000006229 carbon black Substances 0.000 claims description 6
- 229910052741 iridium Inorganic materials 0.000 claims description 6
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052762 osmium Inorganic materials 0.000 claims description 6
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 6
- 229910052763 palladium Inorganic materials 0.000 claims description 6
- 229910052707 ruthenium Inorganic materials 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 5
- 239000004411 aluminium Substances 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 claims description 5
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 4
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 229920002050 silicone resin Polymers 0.000 claims description 4
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 239000006260 foam Substances 0.000 abstract description 14
- 229920002323 Silicone foam Polymers 0.000 abstract description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 5
- 238000012423 maintenance Methods 0.000 abstract description 5
- 239000013514 silicone foam Substances 0.000 abstract description 3
- 238000006073 displacement reaction Methods 0.000 abstract description 2
- 231100000331 toxic Toxicity 0.000 abstract description 2
- 230000002588 toxic effect Effects 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000003973 paint Substances 0.000 abstract 2
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 238000004079 fireproofing Methods 0.000 abstract 1
- 239000003292 glue Substances 0.000 abstract 1
- 230000035515 penetration Effects 0.000 abstract 1
- 238000005187 foaming Methods 0.000 description 8
- 230000001404 mediated effect Effects 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 229920002545 silicone oil Polymers 0.000 description 7
- 238000003756 stirring Methods 0.000 description 6
- 229920001821 foam rubber Polymers 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 230000003068 static effect Effects 0.000 description 4
- 238000005987 sulfurization reaction Methods 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 206010039509 Scab Diseases 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 239000010425 asbestos Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000010285 flame spraying Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000011344 liquid material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000004482 other powder Substances 0.000 description 2
- 229910052895 riebeckite Inorganic materials 0.000 description 2
- 235000016936 Dendrocalamus strictus Nutrition 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920000914 Metallic fiber Polymers 0.000 description 1
- 229920003354 Modic® Polymers 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- CGMFKBXPQJJHBR-UHFFFAOYSA-N [SiH3]O[SiH](C=C)C=C Chemical compound [SiH3]O[SiH](C=C)C=C CGMFKBXPQJJHBR-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 150000003818 basic metals Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- FSIJKGMIQTVTNP-UHFFFAOYSA-N bis(ethenyl)-methyl-trimethylsilyloxysilane Chemical compound C[Si](C)(C)O[Si](C)(C=C)C=C FSIJKGMIQTVTNP-UHFFFAOYSA-N 0.000 description 1
- 239000011083 cement mortar Substances 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 239000003779 heat-resistant material Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910052909 inorganic silicate Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- UHUUYVZLXJHWDV-UHFFFAOYSA-N trimethyl(methylsilyloxy)silane Chemical compound C[SiH2]O[Si](C)(C)C UHUUYVZLXJHWDV-UHFFFAOYSA-N 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
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CN2010101643560A CN101845223B (en) | 2010-05-06 | 2010-05-06 | Silicone high-density elastomer and production method thereof |
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CN2010101643560A CN101845223B (en) | 2010-05-06 | 2010-05-06 | Silicone high-density elastomer and production method thereof |
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CN101845223A CN101845223A (en) | 2010-09-29 |
CN101845223B true CN101845223B (en) | 2012-06-20 |
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CN2010101643560A Expired - Fee Related CN101845223B (en) | 2010-05-06 | 2010-05-06 | Silicone high-density elastomer and production method thereof |
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Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103122239B (en) * | 2011-11-18 | 2014-06-18 | 镇江亿致能源科技孵化器有限公司 | High-density room temperature vulcanization two-component silicone sealant used in nuclear power station and preparation process thereof |
CN102504544B (en) * | 2011-12-02 | 2013-08-14 | 海龙核材科技(江苏)有限公司 | Biological shielding type liquid silicone rubber and preparation method thereof |
CN102504545B (en) * | 2011-12-02 | 2013-07-17 | 海龙核材科技(江苏)有限公司 | High-density fire-proof silicone rubber and preparation method thereof |
FR3008710B1 (en) * | 2013-07-16 | 2017-11-24 | Kaefer Wanner | BIOLOGICAL PROTECTIVE MATERIAL BASED ON SILICONE POLYMER MATRIX AND LOADS. |
CN104887108A (en) * | 2015-05-21 | 2015-09-09 | 蚌埠市耀得保温容器有限公司 | High and low temperature resistant and aging resistant vacuum bottle and production method of sealing sleeve thereof |
CN105802111A (en) * | 2016-05-04 | 2016-07-27 | 江苏欣安新材料技术有限公司 | Dense-type silicone elastic material and production method thereof |
CN106380855A (en) * | 2016-09-07 | 2017-02-08 | 福建农林大学 | Double-component organosilicon foam material and simple auxiliary foaming technique thereof |
CN107746578A (en) * | 2017-09-22 | 2018-03-02 | 镇江市太浪新材料科技有限公司 | A kind of preparation technology of Building Fire Protection foam |
EP4021982A4 (en) * | 2019-08-26 | 2023-06-14 | Henkel AG & Co. KGaA | Foamable silicone composition, preparation method and use thereof |
CN113773650B (en) * | 2021-07-30 | 2022-10-21 | 中国化工株洲橡胶研究设计院有限公司 | Silicone rubber sponge and preparation method thereof |
US20240158594A1 (en) * | 2022-11-15 | 2024-05-16 | Saint-Gobain Performance Plastics Corporation | Silicone-based foam layer |
WO2024107789A1 (en) * | 2022-11-15 | 2024-05-23 | Saint-Gobain Performance Plastics Corporation | Multilayer composite |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101121820A (en) * | 2007-09-19 | 2008-02-13 | 上海回天化工新材料有限公司 | Halogen-free anti-flaming silicon rubber and its preparing method and use |
CN101284946A (en) * | 2007-04-10 | 2008-10-15 | 信越化学工业株式会社 | Heat conductive cured product and making method |
CN101407635A (en) * | 2008-11-14 | 2009-04-15 | 成都硅宝科技股份有限公司 | Addition type heat conducting silicon rubber and manufacturing method thereof |
CN101575452A (en) * | 2008-12-23 | 2009-11-11 | 海龙艾默生(镇江)能源科技有限公司 | Silicone foam material and preparation method thereof |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3803058B2 (en) * | 2001-12-11 | 2006-08-02 | 信越化学工業株式会社 | Thermally conductive silicone composition, cured product thereof, laying method, and heat dissipation structure of semiconductor device using the same |
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2010
- 2010-05-06 CN CN2010101643560A patent/CN101845223B/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101284946A (en) * | 2007-04-10 | 2008-10-15 | 信越化学工业株式会社 | Heat conductive cured product and making method |
CN101121820A (en) * | 2007-09-19 | 2008-02-13 | 上海回天化工新材料有限公司 | Halogen-free anti-flaming silicon rubber and its preparing method and use |
CN101407635A (en) * | 2008-11-14 | 2009-04-15 | 成都硅宝科技股份有限公司 | Addition type heat conducting silicon rubber and manufacturing method thereof |
CN101575452A (en) * | 2008-12-23 | 2009-11-11 | 海龙艾默生(镇江)能源科技有限公司 | Silicone foam material and preparation method thereof |
Non-Patent Citations (2)
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程买增等.阻燃性有机硅高分子材料的研究进展.《有机硅材料》.2003,第17卷(第6期),21-25,46. * |
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CN101845223A (en) | 2010-09-29 |
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